基于UASB-缺氧好氧-混凝沉淀工艺处理印染废水的中试研究
Pilot-scale study on treatment of dyeing wastewater based on a process combining UASB,anoxic-aerobic and coagulation-sedimentation
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摘要: 采用UASB-缺氧好氧-混凝沉淀组合工艺处理以印染纯棉纤维、涤纶、腈纶和棉混纺织物为主的综合性印染废水。结果表明,控制UASB反应器水力负荷为0.4 m3·(m2·h)-1(冬季反应器温度低于15℃时降至0.3 m3·(m2·h)-1)、UASB进水pH=7.0~8.0、活性污泥A反应器DO=0.5~0.8 mg·L-1、B反应器DO=0.2 mg·L-1、接触氧化反应器采用渐减曝气且气水比12:1、混凝剂PAC(配制浓度10%)和PAM(配制浓度0.1%)投加1.2 mL·L-1和0.9 mL·L-1、絮凝30 min,可以实现COD、色度、氮和硫化物的同步去除,出水指标达到并优于《纺织染整工业水污染物排放标准》(GB 4287-2012)表2的直接排放标准,处理效果好。同时,工艺直接运行成本仅为0.624元·m-3废水,普遍低于同类印染废水处理工程。Abstract: A pilot process combining UASB,anoxic-aerobic and coagulation-sedimentation was used to treat the comprehensive dyeing wastewater,mainly from the dyeing of cotton,polyester,acrylic and cotton blended fabrics. The results showed that the synchronous removal of COD,chroma,nitrogen and sulfide was achieved,while the effluent indices met and transcended the direct discharge standards of water pollutants for the dyeing and textile finishing industry (GB 4287-2012),when the hydraulic loading of UASB was 0.4 m3·(m2·h)-1 (0.3 m3·(m2·h)-1 when the temperature of the reactor was lower than 15℃ in winter),the effluent pH of UASB was from 7.0 to 8.0, the dissolved oxygen of A and B stages of anoxic activated sludge reactor were from 0.5 to 0.8 mg·L-1 and 0.2 mg·L-1,respectively,the aeration mode was decrescent and the air-water ratio was 12:1 in the contact oxidation reactor,the dosing amount of PAC (compound concentration of 10%)and PAM (compound concentration of 0.1%)were 1.2 mL·L-1 and 0.9 mL·L-1, respectively,and the flocculating time was 30 min. This process was not only effective,but the direct-running cost of process was also only 0.624 yuan per ton of wastewater,under optimum conditions,which was generally lower than other comparable dyeing wastewater treatment projects.
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