高级搜索

大气颗粒物重金属元素消解方法的响应面优化

,  ,  ,  ,  , 

downloadPDF

上一篇

下一篇

杏艳, 王舒婷, 田渭花, 高飞, 郭晋君, 窦蓓蕾. 大气颗粒物重金属元素消解方法的响应面优化[J]. 环境保护科学, 2019, (4): 114-120. doi: 10.16803/j.cnki.issn.1004-6216.2019.04.021
引用本文: 杏艳, 王舒婷, 田渭花, 高飞, 郭晋君, 窦蓓蕾. 大气颗粒物重金属元素消解方法的响应面优化[J]. 环境保护科学, 2019, (4): 114-120. doi: 10.16803/j.cnki.issn.1004-6216.2019.04.021
shu
XING Yan, WANG Shuting, TIAN Weihua, GAO Fei, GUO Jinjun, DOU Beilei. Optimization of Digestion Parameters for Heavy Metal in Atmospheric Particles Using Response Surface Methodology[J]. Environmental Protection Science, 2019, (4): 114-120. doi: 10.16803/j.cnki.issn.1004-6216.2019.04.021
Citation: XING Yan, WANG Shuting, TIAN Weihua, GAO Fei, GUO Jinjun, DOU Beilei. Optimization of Digestion Parameters for Heavy Metal in Atmospheric Particles Using Response Surface Methodology[J]. Environmental Protection Science, 2019, (4): 114-120. doi: 10.16803/j.cnki.issn.1004-6216.2019.04.021
shu

大气颗粒物重金属元素消解方法的响应面优化

  • 陕西省环境监测中心站，陕西 西安 710054

    • 作者简介: 杏艳(1978-),女,博士、高级工程师。研究方向:环境监测与评价。E-mail:19816857@qq.com
  • 基金项目:

    陕西省级大气污染防治项目(陕财办建(2014)156号)资助

  • 中图分类号: X513;X830.2

Optimization of Digestion Parameters for Heavy Metal in Atmospheric Particles Using Response Surface Methodology

  • Shanxi Province Environmental Monitoring Central Station, Xi'an 710054, China

  • Fund Project:

  • 摘要: 运用Plackett-Burman法确定了影响滤膜颗粒物中重金属元素提取效果的显著因素,利用Box-Behnken试验设计法得出回归模型,通过Minitab软件进行响应面分析得到最优消解条件:HNO3-HF体积比3.6:1、恒温温度184.8℃、恒温时间13.8min。标准滤膜GBW(E)080212中元素Pb最大的预测浓度为63.3μg/L,验证试验测定值与回归方程预测值的相对误差为0.2%,与标准滤膜真实值的相对误差为-0.3%。预测值与验证试验平均值基本一致,模型能较好的反应消解的实际情况。
    Abstract: Plackett-Burman method was applied to determine the significant factors affecting the extraction efficiency of heavy metals in filter particulates, meanwhile, regression model was obtained by using Box-Behnken experimental design method. Response surface methodology was carried out by Minitab software to obtain the optimal digestion conditions:HNO3-HF volume ratio of 3.6:1, constant temperature of 184.8℃, with 13.8 min. The maximum predicted concentration of element Pb in standard filter membrane GBW (E) 080212 was 63.3 μg/L. The relative error between verification test value and predicted value of regression equation was 0.2%, the relative error between the verification test value and the true values of standard filter membrane was-0.3%. The predicted value was basically consistent with the average value of the validation test, and the model could properly reflect the actual situation of the digestion.
  • 加载中
  • 加载中
WeChat 点击查看大图
计量
  • 文章访问数:  561
  • HTML全文浏览数:  561
  • PDF下载数:  6
  • 施引文献:  0
出版历程
  • 收稿日期:  2019-01-21
杏艳, 王舒婷, 田渭花, 高飞, 郭晋君, 窦蓓蕾. 大气颗粒物重金属元素消解方法的响应面优化[J]. 环境保护科学, 2019, (4): 114-120. doi: 10.16803/j.cnki.issn.1004-6216.2019.04.021
引用本文: 杏艳, 王舒婷, 田渭花, 高飞, 郭晋君, 窦蓓蕾. 大气颗粒物重金属元素消解方法的响应面优化[J]. 环境保护科学, 2019, (4): 114-120. doi: 10.16803/j.cnki.issn.1004-6216.2019.04.021
shu
XING Yan, WANG Shuting, TIAN Weihua, GAO Fei, GUO Jinjun, DOU Beilei. Optimization of Digestion Parameters for Heavy Metal in Atmospheric Particles Using Response Surface Methodology[J]. Environmental Protection Science, 2019, (4): 114-120. doi: 10.16803/j.cnki.issn.1004-6216.2019.04.021
Citation: XING Yan, WANG Shuting, TIAN Weihua, GAO Fei, GUO Jinjun, DOU Beilei. Optimization of Digestion Parameters for Heavy Metal in Atmospheric Particles Using Response Surface Methodology[J]. Environmental Protection Science, 2019, (4): 114-120. doi: 10.16803/j.cnki.issn.1004-6216.2019.04.021
shu

大气颗粒物重金属元素消解方法的响应面优化

    作者简介: 杏艳(1978-),女,博士、高级工程师。研究方向:环境监测与评价。E-mail:19816857@qq.com
  • 陕西省环境监测中心站，陕西 西安 710054
  • 收稿日期:  2019-01-21
基金项目:

陕西省级大气污染防治项目(陕财办建(2014)156号)资助

摘要: 运用Plackett-Burman法确定了影响滤膜颗粒物中重金属元素提取效果的显著因素,利用Box-Behnken试验设计法得出回归模型,通过Minitab软件进行响应面分析得到最优消解条件:HNO3-HF体积比3.6:1、恒温温度184.8℃、恒温时间13.8min。标准滤膜GBW(E)080212中元素Pb最大的预测浓度为63.3μg/L,验证试验测定值与回归方程预测值的相对误差为0.2%,与标准滤膜真实值的相对误差为-0.3%。预测值与验证试验平均值基本一致,模型能较好的反应消解的实际情况。

English Abstract

    全文HTML

参考文献 (0)

返回顶部

目录

/

返回文章
返回

Copyright © 2019 中国科学院生态环境研究中心

辽ICP备16002020号-2