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刘红磊, 李艳英, 于丹, 邵晓龙, 张彦, 李慧. 工业园区典型行业废水的理化性质及急性毒性[J]. 环境化学, 2016, 35(12): 2582-2591. doi: 10.7524/j.issn.0254-6108.2016.12.2016050901
引用本文: 刘红磊, 李艳英, 于丹, 邵晓龙, 张彦, 李慧. 工业园区典型行业废水的理化性质及急性毒性[J]. 环境化学, 2016, 35(12): 2582-2591. doi: 10.7524/j.issn.0254-6108.2016.12.2016050901
shu
LIU Honglei, LI Yanying, YU Dan, SHAO Xiaolong, ZHANG Yan, LI Hui. Physicochemical properties and acute toxicities of typical industrial effluents[J]. Environmental Chemistry, 2016, 35(12): 2582-2591. doi: 10.7524/j.issn.0254-6108.2016.12.2016050901
Citation: LIU Honglei, LI Yanying, YU Dan, SHAO Xiaolong, ZHANG Yan, LI Hui. Physicochemical properties and acute toxicities of typical industrial effluents[J]. Environmental Chemistry, 2016, 35(12): 2582-2591. doi: 10.7524/j.issn.0254-6108.2016.12.2016050901
shu

工业园区典型行业废水的理化性质及急性毒性

  • 1.

    天津市环境保护科学研究院, 天津, 300191

  • 基金项目:

    国家“十二五”水体污染控制与治理科技重大专项“重点流域典型工业园区水污染防治技术评估和管理制度研究”（2014ZX07504-005）资助.

Physicochemical properties and acute toxicities of typical industrial effluents

  • 1.

    Tianjin Academy of Environmental Sciences, Tianjin, 300191, China

  • Fund Project: Supported by the National Water Pollution Control and Management Technology Major Projects (2014ZX07504-005).

  • 摘要: 利用理化检测和发光细菌法对天津市某工业园区内16家行业典型企业的进出水进行理化分析和急性毒性试验.结果表明，16家企业原水水质较差，且废水的污染特征差异明显.发光细菌毒性试验表明，16家企业原水对发光细菌的急性毒性等级在重毒以上的比例占到81.25%.预处理后，废水的常规指标基本上满足园区污水处理厂收水标准，但部分企业出水中仍能检出一定浓度的非常规污染物.预处理后，企业废水的整体毒性得到有效削减，低毒和中毒的比例分别达到了25%和37.5%.相关性分析实验表明，企业原水急性毒性与各化学参数间均无相关性，企业出水的急性毒性则与化学需氧量（r=-0.589，Pr=-0.566，Pr=-0.670，Pr=-0.659，Pr=-0.684，Pr=-0.678，Pr=-0.682，P<0.01）具有显著相关性.将理化性质与急性毒性指标有机结合起来，能够更加全面、准确的判断工业废水水质状况.建议在制订工业园区纳管标准时设置急性毒性指标.
    Abstract: Physico-chemical analysis and luminescent bacteria acute toxicity assays were applied to industrial effluents from 16 enterprises in Tianjin City before and after wastewater treatment. The results indicated that the raw industrial effluents had bad quality with many toxic pollutants being inferior to standard. 81.25% raw industrial effluents presented a very high level of toxicity with relative luminosity below 50%. After wastewater treatment, the percentage of the industrial effluents with low toxicity and medium toxicity reached 25% and 37.5% respectively. Nevertheless, the effluents still contained some level of toxic substances. The correlation analysis indicates that there is no correlation between acute toxicity and physico-chemical indexes in raw industrial effluents. However, significant correlation was observed between acute toxicity and seven pollutants in the treated effluents such as chemical oxygen demand (r=-0.589, Pr=-0.566, Pr=-0.670, Pr=-0.659, Pr=-0.684, Pr=-0.678, Pr=-0.682, P<0.01). It is believed that the combined physicochemical analysis and acute toxicity testing can improve the judgement accurally on the industrial wastewater quality.
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  • [1] 周岳溪,宋玉栋,蒋进元,等.工业废水有毒有机物全过程控制技术策略与实践[J].环境工程技术学报,2011,1(1):7-14.

    ZHOU Y X,SONG Y D,JIANG J Y,et al.Whole process control techniques and practices for toxic organics in industrial wastewaters[J].Journal of Environmental Engineering Technology,2011,1(1):7-14(in Chinese).

    [2] 李专,刘淼,王霞,等.淡水发光菌对工业废水的生物毒性研究[J].中国环境监测,2011,27(s1):38-40.

    LI Z,LIU M,WANG X,et al.Study on the biotoxcity of industry wastewater by luminescent bacteria[J].Environmental Monitoring in China,2011,27(s1):38-40(in Chinese).

    [3] FARRE M,PASINI O,ALONSO M C,et al.Toxicity assessment of organic pollution in wastewaters using a bacterial biosensor[J].Analytica Chimica Acta,2001,426(2):155-165.
    [4] BULICH AA,ISENBERG D.Use of the luminescent bacterial system for the rapid assessment of aquatic toxicity[J].Isa Transactions,1980,20(1):29-33.
    [5] 邹叶娜,蔡焕兴,薛银刚,等.成组生物毒性测试法综合评价典型工业废水毒性[J].生态毒理学报,2012,7(4):381-388.

    ZOU Y N,CAI H X,XUE Y G,et al.Synthetic evaluation on toxicity of typical industrial effluents using a battery of bioassays[J].Journal of Ecotoxicology,2012,7(4):381-388(in Chinese).

    [6] 任春,卢延娜,张虞,等.综合毒性指标在水污染物排放标准中的应用探讨[J].工业水处理,2014,34(12):4-7.

    REN C,LU Y N,ZHANG Y,et al.Discussion on the application of comprehensive toxicity indexes to the water pollutant discharge standards[J].Industrial Water Treatment,2014,34(12):4-7(in Chinese).

    [7] Federal Ministry for the Environment,Nature conservation and nuclear safety,Germany.Ordinance on requirements for the discharge of waste water into waters[S].2002.
    [8] USEPA.Technical support document for water quality-based toxics control (EPA/505/2-90-001)[R].Washington DC:Office of water U,1991.
    [9] Regulations MME.SOR/2002-222[M].June.2002.
    [10] 国家环境保护总局.水和废水监测分析方法[M].北京:中国环境科学出版社,2002.Ministry of Environmental Protection of the People's Republic of China.Water and Wastewater monitoring analysis method[M].4th Edition.Beijing:China Environmental Science Press,2002:38

    -47(in Chinese).

    [11] HUANG S,WANG Z,MA M.Measuring the bioavailable/toxic concentration of copper in natural water by using anodic stripping voltammetry and Vibrio-qinghaiensis sp.Nov.-Q67 bioassay[J].Chemical Speciation&Bioavailability,2003,15(2):37-45.
    [12] WANG L J,LIU S S,YUAN J,et al.Remarkable hormesis induced by 1-ethyl-3-methyl imidazolium tetrafluoroborate on vibrio qinghaiensis sp.-Q67[J].Chemosphere,2011,84(10):1440-1445.
    [13] 周艳荣,马文斋,高振会.唐岛湾海域营养状态及有机污染状况分析[J].海洋环境科学,2008,27(A02):70-73.

    ZHOU Y R,MA W Z,GAO Z H.Analysis on condition of nutrients and organic pollution in Tangdao Bay[J].Marine Environmental Science,2008,27(A02):70-73(in Chinese).

    [14] EPA U.National recommended water quality criteria[S].United States Environmental Protection Agency,Office of Water,Office of Science and Technology,2009.https://www.epa.gov/wqc/national-recommended-water-quality-criteria
    [15] 王华东.水环境污染概论[M].北京:北京师范大学出版社,1984.WANG H.Introduction to water environment pollution[M].Beijing:Beijing Normal University Publishing House,1984(in Chinese).
    [16] 吴彬,臧淑英,那晓东.灰色关联分析与内梅罗指数法在克钦湖水体重金属评价中的应用[J].安全与环境学报,2012,12(5):134-137.

    WU B,ZANG S Y,NA X D.Application of grey relation analysis and Nemerow pollution index in water quality evaluation for heavy metals in Keqin Lake[J].Journal of Safety and Environment,2012,12(5):134-137(in Chinese).

    [17] 张绮,王克波,赵人铮.发光细菌毒性试验在水质监测与评价中的应用[C].2006年全国水体污染控制治理技术与突发性水污染事故应急处理体系建设高级研讨会论文集,上海,2006.ZHANG Q,WANG K B,ZHAO R Z.Application of luminescent bacteria on monitoring and assessing water[C].Proceedings of the national academy on the water pollution control technology and emergency management system for accidental water pollution,Shanghai,2006(in Chinese).
    [18] 李雪梅,柯真山,杜青,等.采用淡水发光菌评估污水处理厂进出水毒性的研究[J].给水排水,2010,36(1):130-134.

    LI X M,KE Z S,DU Q,et al.Study on the toxicity of industrial effluents before and after being submitted to wastewater treatment by freshwater luminescent bacteria[J].Water&Wastewater Engineering,2010,36(1):130-134(in Chinese).

    [19] BOLUDA R,QUINTANILLA J,BONILLA J,et al.Application of the microtox test and pollution indices to the study of water toxicity in the Albufera Natural Park (Valencia,Spain)[J].Chemosphere,2002,46(2):355-369.
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  • 收稿日期:  2016-05-09
  • 刊出日期:  2016-12-15
刘红磊, 李艳英, 于丹, 邵晓龙, 张彦, 李慧. 工业园区典型行业废水的理化性质及急性毒性[J]. 环境化学, 2016, 35(12): 2582-2591. doi: 10.7524/j.issn.0254-6108.2016.12.2016050901
引用本文: 刘红磊, 李艳英, 于丹, 邵晓龙, 张彦, 李慧. 工业园区典型行业废水的理化性质及急性毒性[J]. 环境化学, 2016, 35(12): 2582-2591. doi: 10.7524/j.issn.0254-6108.2016.12.2016050901
shu
LIU Honglei, LI Yanying, YU Dan, SHAO Xiaolong, ZHANG Yan, LI Hui. Physicochemical properties and acute toxicities of typical industrial effluents[J]. Environmental Chemistry, 2016, 35(12): 2582-2591. doi: 10.7524/j.issn.0254-6108.2016.12.2016050901
Citation: LIU Honglei, LI Yanying, YU Dan, SHAO Xiaolong, ZHANG Yan, LI Hui. Physicochemical properties and acute toxicities of typical industrial effluents[J]. Environmental Chemistry, 2016, 35(12): 2582-2591. doi: 10.7524/j.issn.0254-6108.2016.12.2016050901
shu

工业园区典型行业废水的理化性质及急性毒性

  • 1. 天津市环境保护科学研究院, 天津, 300191
  • 收稿日期:  2016-05-09
基金项目:

国家“十二五”水体污染控制与治理科技重大专项“重点流域典型工业园区水污染防治技术评估和管理制度研究”（2014ZX07504-005）资助.

摘要: 利用理化检测和发光细菌法对天津市某工业园区内16家行业典型企业的进出水进行理化分析和急性毒性试验.结果表明，16家企业原水水质较差，且废水的污染特征差异明显.发光细菌毒性试验表明，16家企业原水对发光细菌的急性毒性等级在重毒以上的比例占到81.25%.预处理后，废水的常规指标基本上满足园区污水处理厂收水标准，但部分企业出水中仍能检出一定浓度的非常规污染物.预处理后，企业废水的整体毒性得到有效削减，低毒和中毒的比例分别达到了25%和37.5%.相关性分析实验表明，企业原水急性毒性与各化学参数间均无相关性，企业出水的急性毒性则与化学需氧量（r=-0.589，Pr=-0.566，Pr=-0.670，Pr=-0.659，Pr=-0.684，Pr=-0.678，Pr=-0.682，P<0.01）具有显著相关性.将理化性质与急性毒性指标有机结合起来，能够更加全面、准确的判断工业废水水质状况.建议在制订工业园区纳管标准时设置急性毒性指标.

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