雾霾天气下室内外颗粒物粒径分布特征
Size distribution of indoor and outdoor particulate matters during haze pollution
-
摘要: 采用Andersen八级采样器于2016年10月—2017年1月对保定市某居民小区室内外颗粒物进行分级采样测定,利用扫描电子显微镜(SEM)与能谱分析仪(EDS)对颗粒物的形貌与元素相对含量进行了研究.结果表明,PM1.1-4.7是室内外可吸入颗粒物的主要组成部分.室外PM4.7—10与PM1.1占比受大气污染水平影响较小,粒径小于2.1 μm颗粒物(PM2.1)主要由1.1 μm以下颗粒物(PM1.1)构成.在相同污染条件下室内可吸入颗粒物的总浓度仅为室外的44%.室外C元素占比高于室内,颗粒物主要为烟尘集合体,有小部分球形飞灰;室内Al、Ca、Fe元素所占比例高于室外,颗粒物呈现烟尘集合体、飞灰、矿物共存现象.Abstract: In order to investigate the size distribution and bioavailability of indoor and outdoor particulate matters (PM) in a community, PM samples were collected throughout 3 months by an Andersen sampler in Baoding city. Scanning electron microscopy(SEM) and X-ray energy dispersive spectroscopy (EDS) were used to investigate the morphology and the chemical composition of the individual particles. The results showed that PM1.1-4.7 was the main component of indoor and outdoor particulate matters. The air pollution levels had little effect on the distribution of outdoor PM4.7-10 and PM1.1.PM1.1 was the main component of outdoor PM2.1.The mass concentration of indoor particulate matters was only 44% of the outdoors' at the same air pollution level. The contents of C in outdoor PM were much higher than indoor, while the contents of Al, Ca, Fe in indoor PM were higher than outdoor. The characterization results indicated that the indoor particulates consisted of soot aggregates, fly ash and minerals.
-
Key words:
- particulate matters /
- indoor and outdoor /
- size distribution /
- bioavailability /
- haze
-
-
[1] ULIRSCH G V, BALL L M, KAYE W, et al. Effect of particulate matter air pollution on hospital admissions and medical visits for lung and heart disease in two southeast Idaho cities[J]. Journal of Exposure Science & Environmental Epidemiology, 2007, 17(5):478-487. [2] CAO J, YANG C, LI J, et al. Corrigendum to "Association between long-term exposure to outdoor air pollution and mortality in China:A cohort study"[J. Hazard. Mater. 186(2011) 1594-1600] [J]. Journal of Hazardous Materials, 2011, 191(1-3):398-398. [3] LI Y, LEUNG G M, TANG J W, et al. Role of ventilation in airborne transmission of infectious agents in the built environment-a multidisciplinary systematic review[J]. Indoor Air, 2007, 17(1):2-18. [4] KLEPEIS N E, NELSON W C, OTT W R, et al. The National Human Activity Pattern Survey (NHAPS):A resource for assessing exposure to environmental pollutants[J]. J Expo Anal Environ Epidemiol, 2001, 11(3):231-252. [5] YEH S, SMALL M J. Incorporating exposure models in probabilistic assessment of the risks of premature mortality from particulate matter[J]. Journal of Exposure Analysis & Environmental Epidemiology, 2002, 12(6):389-403. [6] ROSENDAHL K E. Health effects and social costs of particulate pollution:A case study for Oslo[J]. Environmental Modeling & Assessment, 1998, 3(1):47-61. [7] [8] 高军,房艳兵,江畅兴,等. 上海地区冬季住宅室内外颗粒物浓度的相关性[J]. 土木建筑与环境工程, 2014,36(2):110-114. GAO J, FANG Y B, JIANG C X, et al. Relationship between indoor and outdoor particulate matter concentrations in a residential building in winter of Shanghai[J]. Journal of Civil,Architectural & Environmental Engineering, 2014,36(2):110-114(in Chinese).
[9] 张振江, 赵若杰, 曹文文, 等. 天津市可吸入颗粒物及元素室内外相关性[J]. 中国环境科学, 2013, 33(2):357-364. ZHANG Z J,ZHAO R J,CAO W W, et al. Residential indoor-outdoor relationships of PM10 and elements in Tianjin[J]. China Environmental Science, 2013, 33(2):357-364(in Chinese).
[10] 史建平, 梁丽绒, 张燕萍, 等. 太原市室内外空气中颗粒物污染特征[J]. 环境与健康杂志, 2008, 25(3):224-226. SHI J P, LIANG L R, ZHANG Y P, et al. Indoor and outdoor particulate air pollution character in Taiyuan city[J]. Journal of Environment and Health,2008,25(3):224-226(in Chinese).
[11] 韩月梅, 沈振兴, 曹军骥, 等. 室内外细粒子PM2.5和总悬浮颗粒物污染水平的对比研究[J]. 中国粉体技术, 2009, 15(2):14-17. HAN Y M, SHEN Z X, CAO J J, et al. Pollution levels of indoor/outdoor particulate matter PM2.5 and total suspended particulate matters[J]. China Powder Science and Technology, 2009, 15(2):14-17(in Chinese).
[12] 鄢超, 杨凌霄, 董灿, 等. 济南冬季典型商业室内环境颗粒物污染特征[J]. 中国环境科学, 2012, 32(4):584-592. YAN C, YANG L X, DONG C, et al. Indoor particle pollution feature in commercial environment of Jinan, in winter, 2010[J]. China Environmental Science, 2012, 32(4):584-592(in Chinese).
[13] MOHAMMADYAN M, GHOOCHANI M, KLOOG I, et al. Assessment of indoor and outdoor particulate air pollution at an urban background site in Iran[J]. Environmental Monitoring and Assessment, 2017, 189(5):235. [14] 蒋颖, 司马菁珂, 赵玲, 等. 上海市居民区与工业区大气颗粒物重金属生物可给性与健康风险评估[J]. 环境化学, 2016, 35(7):1337-1345. JIANG Y,SIMA J K, ZHAO L, et al. Bioaccessibility and health risk of heavy metals in particulate matters from residential and industrial areas in Shanghai,China[J].Environmental Chemistry, 2016, 35(7):1337-1345(in Chinese).
[15] 王臻, 王辰. 可吸入颗粒物对呼吸系统危害的研究进展[J]. 国际呼吸杂志, 2004, 24(4):231-232. WANG Z, WANG C. Research of respiratory system hazards of inhalable particles[J]. International Journal of Respiration, 2004, 24(4):231-232(in Chinese).
[16] 李红, 曾凡刚, 邵龙义, 等. 可吸入颗粒物对人体健康危害的研究进展[J]. 环境与健康杂志, 2002, 19(1):85-87. LI H,ZENG F G,SHAO L Y,et al. Current status of study on the human health effects of inhalable particulates[J]. Journal of Environment and Health, 2002, 19(1):85-87(in Chinese).
[17] 齐冰, 杜荣光, 于之锋, 等. 杭州地区大气细颗粒物浓度变化特征分析[J]. 环境化学, 2015, 34(1):77-82. QI B,DU R G, YU Z F, et al. Characteristics of atmospheric fine particles concentrations in Hangzhou region[J]. Environmental Chemistry, 2015, 34(1):77-82(in Chinese).
[18] 刘丁彧. 云南宣威肺癌高发区大气不同粒径颗粒物的表征及其在肺部沉积特征的模拟研究[D].上海:上海大学, 2015. LIU D Y.Physicochemical characterization of ambient size-resolved particles collected in the atmosphere of Xuanhua,an area of high lung cancer incidence in China, and their deposition fraction in human lung[D].Shanghai:Shanghai University,2015(in Chinese). [19] 吴丹, 曹双, 汤莉莉, 等. 南京北郊大气颗粒物的粒径分布及其影响因素分析[J]. 环境科学, 2016, 37(9):3268-3279. WU D,CAO S,TANG L L,et al. Variation of size distribution and the influencing factors of aerosol in northern suburbs of Nanjing[J]. Environmental Chemistry, 2016, 37(9):3268-3279(in Chinese).
[20] 马利英, 董泽琴, 吴可嘉, 等. 贵州农村地区室内空气质量及细颗粒物污染特征[J]. 中国环境监测, 2015, 31(1):28-34. MA L Y, DONG Z Q, WU K J, et al. Indoor air quality and characteristics of fine particle for rural Guizhou[J]. Environmental Monitoring in China,2015, 31(1):28-34(in Chinese).
[21] GUO H, MORAWSKA L, HE C, et al. Characterization of particle number concentrations and PM2.5 in a school:influence of outdoor air pollution on indoor air[J]. Environmental Science & Pollution Research, 2010, 17(6):1268-1278. [22] 赵力, 陈超, 王平, 等. 北京市某办公建筑夏冬季室内外PM2.5浓度变化特征[J]. 建筑科学, 2015, 31(4):32-39. ZHAO L,CHEN C, WANG P,et al. Characteristics of change of PM2.5 mass concentration indoors and outdoors in an office building in Beijing in summer and winter[J]. Building Science,2015, 31(4):32-39(in Chinese).
[23] 严丽, 刘亮, 谢伟, 等. 西安市商场建筑室内外颗粒物污染状况调查[J]. 环境工程, 2013, 31(s1):642-644. YAN L,LIU L,XIE W,et al. An investigation on indoor and outdoor particulate matter pollution of shopping centre in Xi'an city[J].Environmental Engineering, 2013, 31(s1):642-644(in Chinese).
[24] LI J, ANDERSON J R, BUSECK P R. TEM study of aerosol particles from clean and polluted marine boundary layers over the North Atlantic[J]. Journal of Geophysical Research, 2003, 108(6):335-346. [25] FENG X, DANG Z, HUANG W, et al. Microscopic morphology and size distribution of particles in PM2.5 of Guangzhou City[J]. Journal of Atmospheric Chemistry, 2009, 64(1):37-51. [26] 张睿, 吕森林, 尚羽, 等. 上海大气超细颗粒物和工业纳米颗粒的表征及细胞毒性的比较研究[J]. 环境科学, 2012, 33(5):1431-1437. ZHANG R, LV S L, SHANG Y,et al. Comparison of physicochemical characterization of Shanghai ambient ultrafine particles and engineered Nano particles and their cytotoxicity[J].Environmental Science, 2012, 33(5):1431-1437(in Chinese).
[27] 孙俊民. 燃煤飞灰结构演化与元素富集机制[D]. 徐州:中国矿业大学, 1999. SUN J M. Structure Evolution and Element Enrichment Machine of coal fly ash[D]. Xuzhou:China University of Mining and Technology, 1999(in Chinese). [28] LI W, SHAO L. Transmission electron microscopy study of aerosol particles from the brown hazes in northern China[J]. Journal of Geophysical Research Atmospheres, 2009, 114:D09302. [29] 吕森林, 郝晓洁, 易飞, 等. 云南宣威肺癌高发区不同粒径大气颗粒物的表征[C]. 中国矿物岩石地球化学学会学术年会, 2013. LV S L, HAO X J, YI F, et al. Characterization of airborne particles with different particle size in Yunnan Province[C].Chinese Society For Mineralogy Petrology And Geochemistry,2013(in Chinese). [30] 王清勤, 李国柱, 孟冲, 等. 室外细颗粒物(PM2.5)建筑围护结构穿透及被动控制措施[J]. 暖通空调, 2015, 45(12):8-13. WANG Q Q,LI G Z,MENG C,et al. Penetration of outdoor fine particulate matter(PM2.5) through building envelope and passive control methods[J]. Journal of HV & AC, 2015, 45(12):8-13(in Chinese).
[31] HE C, MORAWSKA L, HITCHINS J, et al. Contribution from indoor sources to particle number and mass concentrations in residential houses[J]. Atmospheric Environment, 2004, 38(21):3405-3415. [32] 熊志明, 张国强, 彭建国, 等. 室内可吸入颗粒物污染研究现状[J]. 暖通空调, 2004, 34(4):32-36. XIONG Z M,ZHANG G Q, PENG J G,et al. Indoor inhalable particles:A review[J]. Journal of HV & AC, 2004, 34(4):32-36(in Chinese).
[33] SHI Z, SHAO L, JONES T P, et al. Characterization of airborne individual particles collected in an urban area, a satellite city and a clean air area in Beijing, 2001[J]. Atmospheric Environment, 2003, 37(29):4097-4108. [34] LIU Y, CHEN R, SHEN X, et al. Wintertime indoor air levels of PM10, PM2.5 and PM1 at public places and their contributions to TSP[J]. Environment International, 2004, 30(2):189-197. [35] 孙俊民, 温茂, 刘惠永, 等. 燃煤排放可吸入颗粒物的显微结构与物质组成研究[J]. 地球化学, 2007, 36(1):55-61. SUN J M, WEN M, LIU H Y, et al. Microstructure and compositon of inhalable particulate matter(PM10) from coal-fired power plants in Southwest China[J].Geochimica, 2007, 36(1):55-61(in Chinese).
-

计量
- 文章访问数: 2187
- HTML全文浏览数: 2122
- PDF下载数: 331
- 施引文献: 0