高级搜索

淮南燃煤电厂烟气中颗粒相和气相中多环芳烃的赋存特征

,  ,  ,  ,  , 

downloadPDF

上一篇

下一篇

袁晶晶, 笪春年, 王儒威, 陈自祥, 孙若愚, 刘腾. 淮南燃煤电厂烟气中颗粒相和气相中多环芳烃的赋存特征[J]. 环境化学, 2018, 37(6): 1382-1390. doi: 10.7524/j.issn.0254-6108.2017090201
引用本文: 袁晶晶, 笪春年, 王儒威, 陈自祥, 孙若愚, 刘腾. 淮南燃煤电厂烟气中颗粒相和气相中多环芳烃的赋存特征[J]. 环境化学, 2018, 37(6): 1382-1390. doi: 10.7524/j.issn.0254-6108.2017090201
shu
YUAN Jingjing, DA Chunnian, WANG Ruwei, CHEN Zixiang, SUN Ruoyu, LIU Teng. Occurence of polycyclic aromatic hydrocarbons in PM10-and gaseous phases of flue gases emitted from Huainan coal-fired power plant[J]. Environmental Chemistry, 2018, 37(6): 1382-1390. doi: 10.7524/j.issn.0254-6108.2017090201
Citation: YUAN Jingjing, DA Chunnian, WANG Ruwei, CHEN Zixiang, SUN Ruoyu, LIU Teng. Occurence of polycyclic aromatic hydrocarbons in PM10-and gaseous phases of flue gases emitted from Huainan coal-fired power plant[J]. Environmental Chemistry, 2018, 37(6): 1382-1390. doi: 10.7524/j.issn.0254-6108.2017090201
shu

淮南燃煤电厂烟气中颗粒相和气相中多环芳烃的赋存特征

  • 1.

    天津大学表层地球系统科学院研究院, 天津, 300072;

  • 2.

    合肥学院生物与环境工程系, 合肥, 230022;

  • 3.

    中国科学院壳幔与环境重点实验室, 中国科技大学地球与空间科学学院, 合肥, 230026

  • 基金项目:

    国家重点研发计划（2016YFC0201600），安徽省自然科学基金（1608085MD78），国家海洋局近岸域生态环境重点实验室资助项目（201802）和2016年高校优秀青年人才支持计划重点项目（gxyqZD2016274）.

Occurence of polycyclic aromatic hydrocarbons in PM10-and gaseous phases of flue gases emitted from Huainan coal-fired power plant

  • 1.

    Institute of Surface-Earth System Science, Tianjin University, Tianjin, 300072, China;

  • 2.

    Department of Biology & Environmental Engineering, Hefei University, Hefei, 230022, China;

  • 3.

    CAS Key Laboratory of Crust-Mantle Materials and the Environments, School of Earth and Space Sciences, Hefei, 230026, China

  • Fund Project: Supported by the National Key R&D Program of China (2016YFC0201600), Natural Science Foundation of Anhui Province (1608085MD78), The Key Laboratory for Ecological Environment in Coastal Areas, State Oceanic Administration (201802) and Key Projects of Anhui Province University Outstanding Youth Talent Support Program (gxyqZD2016274).

  • 摘要: 采集安徽省淮南市3个燃煤发电锅炉排放的气态和颗粒态样品，通过GC-MS测定美国环保局优控的16种多环芳烃（PAHs），并对其残留、赋存和分配特征进行了分析研究.结果表明，PM10相和气相中PAHs的质量浓度范围分别为2.9—7.5 μg·m-3和6.0—15.1 μg·m-3，PAHs的质量浓度明显受到锅炉类型、装机容量与燃烧条件的影响，静电除尘器（ESP）对气相PAHs清除效率较低；PM10相中PAHs主要为中分子量4环和高分子量5环，分别占总PAHs的35.8%—49.3%和16.2%—27.3%，与PM10相相比，气相PAHs主要分布为2—3环，而4—6环PAHs含量较少.脱硫装置有效地提高了高分子PAHs的去除率；PM10相及气相中PAHs分布不均衡，吸收作用主导了PM10相与气相之间的PAHs分配；PAHs单体显示出不同的主导分配机制，主要由于它们之间不同的化学亲和力和蒸气压所导致的.
    Abstract: In this study, 16 US EPA priority polycyclic aromatic hydrocarbons (PAHs) in PM10 and gaseous phases emitted from three coal-fired utility boilers in Huainan, Anhui Province were analyzed. The partitioning mechanisms of PAHs between PM10-and gaseous phases were investigated. Results indicate that the concentration ranges of PM10-and gas-phase PAHs in flue gas are 2.9 to 7.5 μg·m-3 and 6.0 to 15.1 μg·m-3, in addition, they are primarily influenced by boiler capacity and operation conditions. The removal efficiency of gas phase PAHs through Electrostatic precipitator (ESP) is lower. PM10-phase PAHs are predominated by 4-and 5-ring PAHs, accounting for 35.8%-49.3% and 16.2%-27.3% of total PAHs, respectively. Moreover, gas-phase PAHs are significantly depleted in 4-to 6-ring species and mostly characterized by 2-and 3-ring PAHs. The wet flue gas desulphurization (WFGD) had significant effect on the elimination of PAHs in both PM10 and gaseous phases, especially for the high molecular weight PAHs. PAH partitioning between PM10 and gaseous phases was dominated by the absorption behavior. Individual PAHs exhibitd different dominant distribution due to their different chemical affinities and vapor pressures.
  • 加载中
  • [1] 王超, 张霖琳, 刀谞, 等. 京津冀地区城市空气颗粒物中多环芳烃的污染特征及来源[J]. 中国环境科学, 2015, 35(1):1-6.

    WANG C, ZHANG L L, DAO X, et al. Pollution characteristics and source identification of polycyclic aromatic hydrocarbons in airborne particulates of Beijing-Tianjin-Hebei Region, China[J]. China Environmental Science, 2015, 35(1):1-6(in Chinese).

    [2] 杨成阁, 胡菁, 郭军, 等. 贵阳市冬、夏季PM2.5中多环芳烃污染特征及来源解析[J]. 环境化学, 2014, 33(1):161-162.

    YANG C G, HU J, G J, et al. Characteristics and sources of polycyclic aromatic hydrocarbons in PM2.5 in Winter and Summer in Guiyang[J]. Environmental Chemistry, 2014, 33(1):161-162(in Chinese).

    [3] HUANG H, XING X, ZHANG Z, et al. Polycyclic aromatic hydrocarbons (PAHs) in multimedia environment of Heshan coal district, Guangxi:distribution, source diagnosis and health risk assessment[J]. Environmental Geochemistry and Health, 2016, 38(5):1169-1181.
    [4] 张小凤, 文雪琴, 杨亚丽. 不同变质程度煤中夹矸中多环芳烃的分布特征[J]. 煤炭技术, 2016, 35(11):180-182.

    ZHANG X F, WEN X Q,YANG Y L.Distribution characteristic of polycyclic aromatic hydrocarbons (PAHs) in different coal rank of coals gangue[J]. Coal Technology,2016,35(11):180-182(in Chinese).

    [5] ROTA M, BOSETTI C, BOCCIA S, et al. Occupational exposures to polycyclic aromatic hydrocarbons and respiratory and urinary tract cancers:An updated systematic review and a meta-analysis to 2014[J]. Archives of Toxicology, 2014, 88(8):1479-1490.
    [6] CABRERIZOA, GALBAN-MALAGON C, DEL VENTO S, et al. Sources and fate of polycyclic aromatic hydrocarbons in the Antarctic and Southern Ocean atmosphere[J]. Global Biogeochemical Cycles, 2014, 28(12):1424-1436.
    [7] 李英红, 饶志国, 谭吉华, 等. 兰州大气细颗粒物中多环芳烃污染特征及来源分析[J]. 环境科学, 2016,37(7):2428-2435.

    LI Y H, RAO Z G, TAN J H, et al. Characteristics and sources of polycyclic aromatic hydrocarbons in fine particulate matter in Lanzhou[J]. Environmental Science, 2016, 37(7):2428-2435(in Chinese).

    [8] 赵雪艳, 任丽红, 姬亚芹, 等. 重庆主城区春季大气PM10及PM2.5中多环芳烃来源解析[J]. 环境科学研究, 2014, 27(12):1395-1402.

    ZHAO X Y, REN L H, JI YQ, et al.Characteristics of polycyclic aromatic hydrocarbons in spring atmosphere PM10 and PM2.5 in Chongqing Urban Area[J]. Environmental Science Research, 2014, 27(12):1395-1402(in Chinese).

    [9] 王丽, 王利军, 史兴民, 等. 西安市地表灰尘中多环芳烃分布特征与来源解析[J]. 环境科学, 2016, 37(4):1279-1286.

    WANG L J, WANG L J, SHI X M, et al. Characteristics and sources of PAHs in surface dust of Xi'an[J]. Environmental Science, 2016, 37(4):1279-1286(in Chinese).

    [10] MA Y H, SUW, WANG Q H, et al. Discharge and disposal of coking residue and distribution characteristics of PAHs in it[J]. Applied Mechanics and Materials. Trans Tech Publications, 2014, 448:448-452.
    [11] SONG J, LIU Y. Prediction of polycyclic aromatic hydrocarbons from vehicle exhaust emission and coal combustion based on grey model GM (1, 1)[J]. Journal of Computational and Theoretical Nanoscience, 2016, 13(9):6377-6381.
    [12] QIN L, ZHANG Y, HAN J, et al. Influences of waste iron residue on combustion efficiency and polycyclic aromatic hydrocarbons release during coal catalytic combustion[J]. Aerosol Air Qual. Res, 2015, 15:2720-2729.
    [13] WU D, WANG Z, CHEN J, et al. Polycyclic aromatic hydrocarbons (PAHs) in atmospheric PM2.5 and PM10 at a coal-based industrial city:Implication for PAH control at industrial agglomeration regions, China[J]. Atmospheric Research, 2014, 149:217-229.
    [14] WANG Y, XU Y, CHEN Y, et al. Influence of different types of coals and stoves on the emissions of parent and oxygenated PAHs from residential coal combustion in China[J]. Environmental Pollution, 2016, 212:1-8.
    [15] LIU G, NIU Z, VAN NIEKERK D, et al. Polycyclic aromatic hydrocarbons (PAHs) from coal combustion:emissions, analysis, and toxicology//Reviews of environmental contamination and toxicology[M]. New York:Springer 2008:1-28.
    [16] BAYARD R, BARNA L, MHJOUB B, et al. Influence of the presence of PAHs and coal tar on naphthalene sorption in soils[J]. Journal of Contaminant Hydrology, 2000, 46(1):61-80.
    [17] VAN METRE P C, MAHLER B J. Contribution of PAHs from coal-tar pavement sealcoat and other sources to 40 US lakes[J]. Science of the Total Environment, 2010, 409(2):334-344.
    [18] ROGERS S W, ONG S K, MOORMAN T B. Mineralization of PAHs in coal-tar impacted aquifer sediments and associated microbial community structure investigated with FISH[J]. Chemosphere, 2007, 69(10):1563-1573.
    [19] SUN Y Z, FAN J S, QIN P, et al. Pollution extents of organic substances from a coal gangue dump of Jiulong Coal Mine, China[J]. Environmental Geochemistry and Health, 2009, 31(1):81-89.
    [20] LEE R G M, CEMAN P, JONES J L, et al. Emission factors and importance of PCDD/Fs, PCBs, PCNs, PAHs and PM10 from the domestic burning of coal and wood in the UK[J]. Environmental Science & Technology, 2005, 39(6):1436-1447.
    [21] WANG X W, ZHONG N N, HU D M, et al. Polycyclic aromatic hydrocarbon (PAHs) pollutants in groundwater from coal gangue stack area:characteristics and origin[J]. Water Science and Technology, 2009, 59(5):1043-1051.
    [22] METRE P C V, MAHLER B J, WILSON J T. PAHs underfoot:Contaminated dust from coal-tar sealcoated pavement is widespread in the United States[J]. Environmental Science & Technology, 2008, 43(1):20-25.
    [23] QIN L, HAN J, HE X, et al. The emission characteristic of PAHs during coal combustion in a fluidized bed combustor[J]. Energy Sources, Part A:Recovery, Utilization, and Environmental Effects, 2014, 36(2):212-221.
    [24] MAHLER B J, METRE P C V, CRANE J L, et al. Coal-tar-based pavement sealcoat and PAHs:implications for the environment, human health, and stormwater management[J]. Environmental Science & Technology, 2012, 46:3039-3045
    [25] MACKAY A A, GSCHWEND P M. Enhanced concentrations of PAHs in groundwater at a coal tar site[J]. Environmental Science & Technology, 2001, 35(7):1320-1328.
    [26] ANTIZA-LADISLAO B, LOPEZ-REAL J, BEK A J. Degradation of polycyclic aromatic hydrocarbons (PAHs) in an aged coal tar contaminated soil under in-vessel composting conditions[J]. Environmental Pollution, 2006, 141(3):459-468.
  • 加载中
WeChat 点击查看大图
计量
  • 文章访问数:  1049
  • HTML全文浏览数:  1029
  • PDF下载数:  145
  • 施引文献:  0
出版历程
  • 收稿日期:  2017-09-02
  • 刊出日期:  2018-06-15
袁晶晶, 笪春年, 王儒威, 陈自祥, 孙若愚, 刘腾. 淮南燃煤电厂烟气中颗粒相和气相中多环芳烃的赋存特征[J]. 环境化学, 2018, 37(6): 1382-1390. doi: 10.7524/j.issn.0254-6108.2017090201
引用本文: 袁晶晶, 笪春年, 王儒威, 陈自祥, 孙若愚, 刘腾. 淮南燃煤电厂烟气中颗粒相和气相中多环芳烃的赋存特征[J]. 环境化学, 2018, 37(6): 1382-1390. doi: 10.7524/j.issn.0254-6108.2017090201
shu
YUAN Jingjing, DA Chunnian, WANG Ruwei, CHEN Zixiang, SUN Ruoyu, LIU Teng. Occurence of polycyclic aromatic hydrocarbons in PM10-and gaseous phases of flue gases emitted from Huainan coal-fired power plant[J]. Environmental Chemistry, 2018, 37(6): 1382-1390. doi: 10.7524/j.issn.0254-6108.2017090201
Citation: YUAN Jingjing, DA Chunnian, WANG Ruwei, CHEN Zixiang, SUN Ruoyu, LIU Teng. Occurence of polycyclic aromatic hydrocarbons in PM10-and gaseous phases of flue gases emitted from Huainan coal-fired power plant[J]. Environmental Chemistry, 2018, 37(6): 1382-1390. doi: 10.7524/j.issn.0254-6108.2017090201
shu

淮南燃煤电厂烟气中颗粒相和气相中多环芳烃的赋存特征

  • 1.  天津大学表层地球系统科学院研究院, 天津, 300072;
  • 2.  合肥学院生物与环境工程系, 合肥, 230022;
  • 3.  中国科学院壳幔与环境重点实验室, 中国科技大学地球与空间科学学院, 合肥, 230026
  • 收稿日期:  2017-09-02
基金项目:

国家重点研发计划（2016YFC0201600），安徽省自然科学基金（1608085MD78），国家海洋局近岸域生态环境重点实验室资助项目（201802）和2016年高校优秀青年人才支持计划重点项目（gxyqZD2016274）.

摘要: 采集安徽省淮南市3个燃煤发电锅炉排放的气态和颗粒态样品，通过GC-MS测定美国环保局优控的16种多环芳烃（PAHs），并对其残留、赋存和分配特征进行了分析研究.结果表明，PM10相和气相中PAHs的质量浓度范围分别为2.9—7.5 μg·m-3和6.0—15.1 μg·m-3，PAHs的质量浓度明显受到锅炉类型、装机容量与燃烧条件的影响，静电除尘器（ESP）对气相PAHs清除效率较低；PM10相中PAHs主要为中分子量4环和高分子量5环，分别占总PAHs的35.8%—49.3%和16.2%—27.3%，与PM10相相比，气相PAHs主要分布为2—3环，而4—6环PAHs含量较少.脱硫装置有效地提高了高分子PAHs的去除率；PM10相及气相中PAHs分布不均衡，吸收作用主导了PM10相与气相之间的PAHs分配；PAHs单体显示出不同的主导分配机制，主要由于它们之间不同的化学亲和力和蒸气压所导致的.

English Abstract

    全文HTML

参考文献 (26)

返回顶部

目录

/

返回文章
返回

Copyright © 2019 中国科学院生态环境研究中心