高级搜索

大气铊污染现状及治理技术研究进展

,  ,  ,  ,  ,  ,  , 

downloadPDF

上一篇

下一篇

马强, 王学谦, 宁平, 王郎郎, 徐博雯, 陈军辉, 黄嘉珩, 郝吉明. 大气铊污染现状及治理技术研究进展[J]. 环境化学, 2020, (12): 3362-3370. doi: 10.7524/j.issn.0254-6108.2020042801
引用本文: 马强, 王学谦, 宁平, 王郎郎, 徐博雯, 陈军辉, 黄嘉珩, 郝吉明. 大气铊污染现状及治理技术研究进展[J]. 环境化学, 2020, (12): 3362-3370. doi: 10.7524/j.issn.0254-6108.2020042801
shu
MA Qiang, WANG Xueqian, NING Ping, WANG Langlang, XU Bowen, CHEN Junhui, HUANG Jiaheng, HAO Jiming. Status of atmospheric thallium pollution and research progress of treatment technology[J]. Environmental Chemistry, 2020, (12): 3362-3370. doi: 10.7524/j.issn.0254-6108.2020042801
Citation: MA Qiang, WANG Xueqian, NING Ping, WANG Langlang, XU Bowen, CHEN Junhui, HUANG Jiaheng, HAO Jiming. Status of atmospheric thallium pollution and research progress of treatment technology[J]. Environmental Chemistry, 2020, (12): 3362-3370. doi: 10.7524/j.issn.0254-6108.2020042801
shu

大气铊污染现状及治理技术研究进展

  • 1. 昆明理工大学环境科学与工程学院, 昆明, 650500;

  • 2. 四川省生态环境科学研究院, 成都, 610041;

  • 3. 中国电信成都分公司, 成都, 610000;

  • 4. 清华大学环境科学与工程研究院, 北京, 100084

    • 通讯作者: 王学谦, E-mail: xqwang214@163.com ; 
  • 基金项目:

    国家自然科学基金（51868030，51568027），国家重点研发计划项目（2017YFC0210500，2018YFC0213400）和云南省中青年学术和技术带头人后备人才项目（2015HB012）资助.

Status of atmospheric thallium pollution and research progress of treatment technology

  • 1. Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming, 650500, China;

  • 2. Sichuan Academy of Environmental Science, Chengdu, 610041, China;

  • 3. China Telecom Co. Ltd. Chengdu Branch, Chengdu, 610000, China;

  • 4. State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing, 100084, China

    • Corresponding author: WANG Xueqian, xqwang214@163.com ; 
  • Fund Project: Supported by the National Natural Science Foundation of China (51868030,51568027), National Key R&D Program of China (2017YFC0210500, 2018YFC0213400) and the Candidates of the Young and Middle Aged Academic Leaders of the Yunnan Province (2015HB012).

  • 摘要: 铊及其化合物是一类毒性强，传播广泛的大气污染物.铊的气态污染主要来源是矿物冶炼、火力发电、水泥等行业.铊及其化合物毒性高而排放量较低，已经在国内外富铊地区引起中毒事件.目前，由于冶炼，火电等行业在国内的飞速发展，其排放造成的大气铊污染又给人群健康和生态安全造成了严重的威胁.铊进入大气后，能够伴随大气活动，食物链和沉降等与人体接触.现有的尾气治理措施如除尘和酸洗对废气中的铊具有一定程度的去除效果但不能彻底解决废气中的铊污染问题.通过对铊不同价态化合物的物理化学特征分析，将高毒性，易迁移的一价化合物转化为难迁移，低毒性的三价铊氧化物的新思路是可行的.
    Abstract: Thallium and its compounds are widespread air pollutants with extremely toxicity. The primary sources of gaseous pollution of thallium are mineral smelting, thermal power generation and cement. Thallium and its compounds have high toxicity and low emission, which have caused poisoning events in thallium affluent areas. Due to the rapid development of smelting, thermal power, and other industries in China, the atmospheric thallium pollution caused by its emissions poses a severe threat to people's health and ecological security. When thallium enters the atmosphere, it can contact the human body with atmospheric activities, food chains, and sedimentation. The existing tail gas treatment such as dust removal and acid washing can remove thallium in flue gas to a certain extent, but it can not completely solve the problem of thallium pollution in flue gas. It is feasible to transform the highly toxic and quickly migrating univalent compounds into the trivalent thallium oxides with low toxicity by analyzing the physicochemical characteristics of different valence state compounds of thallium.
  • 加载中
  • [1] ERSHOV B G, HENGLEIN A. ChemInform abstract:Optical spectrum and some chemical properties of colloidal thallium in aqueous solution[J]. Cheminform, 1993, 97(13):3434-3436.
    [2] SADDIQUE A. PETERSON C D. Thallium poisoning:A review[J]. Veterinary & Human Toxicology, 1983, 25(1):16-22.
    [3] DAVIS L E, STANDEFER J C, KORNFELD M, et al. Acute thallium poisoning:Toxicological and morphological studies of the nervous system[J]. Annals of Neurology, 2010, 10(1):38-44.
    [4] HIRATA M, TAODA K, ONOOGASAWARA M, et al. A probable case of chronic occupational thallium poisoning in a glass factory[J]. Industrial Health, 1998, 36(3):300-303.
    [5] MADEJÓN P. Thallium[J]. Environmental Pollution, 2013, doi:10.1007/978-94-007-4470-7_23.
    [6] LAIA C B, SòNIA S, GEMMA M E, et al. Anagen effluvium due to thallium poisoning derived from the intake of chinese herbal medicine and rodenticide containing thallium salts[J]. Journal of Dermatology, 2015, 42(10):1027-1029.
    [7] CORDERO M M. Superconduction:Thallium's merits[J]. IEEE Potentials, 2002, 9(1):28-31.
    [8] WEINIG E, SCHMIDT G. On the distribution of thallium in the organism in fatal thallium poisoning[J]. Arch Toxikol, 1966, 21(4):199-215.
    [9] 谢文彪, 陈永亨, 陈穗玲. 硫铁矿焙烧灰渣中铊分布规律及环境效应的研究[J]. 矿物岩石地球化学通报, 2000, 19(3):204-206.

    XIE W B, CHEN Y H, CHEN H L, Study on the distribution of thallium in calcined cinders of pyrite and its environmental effect[J]. Mineral Rock Geochemistry Bulletin, 2000, 19(3):204-206(in Chinese).

    [10] 张兴茂. 云南南华砷铊矿床的矿床和环境地球化学[J]. 矿物岩石地球化学通报, 1998, 17(1):44-45.

    ZHANG X M, Deposit and environmental geochemistry of the nanhua arsenic-thallium deposit in Yunnan Province[J].Mineral Rock Geochemistry Bulletin, 1998, 17(1):44-45(in Chinese).

    [11] 张忠, 陈国丽, 张宝贵,等. 滥木厂铊矿床及其环境地球化学研究[J]. 中国科学:地球科学, 1999, 29(5):71-77.

    ZHANG Z, CHEN G L, ZHANG B G, et al. Study on environmental geochemistry of the Thallium deposit in Lanmuchuang[J]. Chinese Science:Earth Science, 1999, 29(5):71-77(in Chinese).

    [12] CAMPANELLA B, CASIOT C, ONOR M, et al. Thallium release from acid mine drainages:Speciation in river and tap water from valdicastello mining district (northwest Tuscany)[J]. Talanta, 2017, 171:255-261.
    [13] VIRARAGHAVAN T, SRINIVASAN A. Thallium:Environmental pollution and health effects[J]. Encyclopedia of Environmental Health, 2011:325-333.
    [14] PETER A L J, VIRARAGHAVAN T. Thallium:A review of public health and environmental concerns[J]. Environment International, 2005, 31(4):493-501.
    [15] TREMEL A, MASSON P, GARRAUD H, et al. Thallium in french agrosystems-Ⅱ. Concentration of thallium in field-grown rape and some other plant species[J]. Environmental Pollution, 1997, 97(1/2):161.
    [16] LAW S, TURNER A. Thallium in the hydrosphere of south west England[J]. Environmental Pollution, 2011, 159(12):3484-3489.
    [17] WALDRON H A. Environmental health criteria[J]. Occupational & Environmental Medicine, 1976, 33(6):608-611.
    [18] 吴颖娟, 陈永亨, 张汝国,等. 淋滤条件对矿物废渣中铊释放的影响[J]. 环境化学, 2002, 21(1):78-82.

    WU Y J, CHEN Y H, ZHANG R G, et al. The effect of thallium release in mineral slag under leaching condition[J]. Environmental Chemistry, 2002, 21(1):78-82(in Chinese).

    [19] 涂军桥. 云浮硫铁矿区伴生铊分布特征及迁移富集规律[J]. 现代矿业, 2013, 29(9):68-69.

    TU J Q, Distribution characteristics and migration and enrichment rule of associated thallium in Yunfu Pyrite Mine[J]. Morden Mine, 2013, 29(9):68-69(in Chinese).

    [20] 周涛发, 范裕, 袁峰,等. 铊的环境地球化学研究进展及铊污染的防治对策[J]. 地质论评, 2005, 51(2):181-188.

    ZHOU T F, FAN Y, YUAN F, et al. Research progress of environmental geochemistry of thallium and countermeasures for prevention and control of thallium pollution[J]. Geological Review, 2005, 51(2):181-188(in Chinese).

    [21] 马荣骏. 铜铅锌冶炼中稀散金属的综合回收(续)第三部分铊、铼、硒、碲的回收[J]. 有色金属(冶炼部分), 1978(11):43-48. MA J R, Comprehensive recovery of dispersed metals in copper, lead and zinc smelting, nonferrous metals[J]. Nonferrous Metals (Smelting), 1978(11):43-48(in Chinese).
    [22] 郭天立, 程永强, 奚英洲.锌铅铜冶炼中铊的治理途径探索[J]. 中国有色冶金, 2015, 44(1):67-70.

    GUO T L, CHENG Y Q, XI Y Z, Exploration of thallium treatment in zinc, lead and copper smelting[J]. Chinese Nonferrous Metallurgy, 2015, 044(1):67-70(in Chinese).

    [23] 张冬生. 山东乳山金矿区及外围铊地球化学找矿矿究[J]. 环境科学, 1988,9(2):31-34.

    ZHANG D S, Geochemical prospecting for thallium in rushan gold mine and surrounding area of Shandong Province[J]. Environmental Sciences, 1988, 9(2):31-34(in Chinese).

    [24] 小西正芳. 水泥制造设备中的铊的回收方法及回收装置[P].[2011-2-16] MASAYOSHI K. Methods and devices for recovery of thallium in cement manufacturing equipment[P].[2011-2-16](in Chinese).
    [25] 韩恒斌, 倪哲明. 无载体泡沫塑料吸附平台石墨炉原子吸收法测定土壤、河底泥、煤飞灰、水泥样品中痕量铊[J]. 环境化学, 1983, 2(2):46-51.

    HAN H B, NI Z M, Determination of trace thallium in soil, river sediment, coal fly ash and cement samples by graphite furnace atomic absorption spectrometry without carrier foam adsorption platform[J]. Environmental Chemistry, 1983, 2(2):46-51(in Chinese).

    [26] 王春霖, 陈永亨, 张平,等. 含铊硫铁矿生产硫酸过程中铊的排放特性[J]. 环境化学, 2011,30(11):1894-1899.

    WANG C L, CHEN Y H, ZHANG P, et al. Thallium release in the process of sulfur acid production with tl-containing pyrite roasting[J]. Environmental Chemistry, 2011, 30(11):1894-1899(in Chinese).

    [27] 吴颖娟, 杨春霞, 陈永亨,等. 黄铁矿焙烧产物中铊的分布和环境贡献[J]. 广州大学学报(自然科学版), 2009, 8(5):62-67. WU Y J, YANG C X, CHEN Y H, et al. Distribution and environmental contribution of thallium in pyrite roasting products[J]. Journal of Guangzhou University, 2009, 8(5):62-67(in Chinese).
    [28] ŠKRBEC A, HRŠAK J, VADIĆ V, et al. Soil Contamination by thallium from a cement industry[J]. Treći Hrvatski Znanstveno-stručni Skup Zaštita Zraka, 2001(1):349-353.
    [29] BROCKHAUS A, DOLGNER R, EWERS U, et al. Intake and health effects of thallium among a population living in the vicinity of a cement plant emitting thallium containing dust[J]. International Archives of Occupational & Environmental Health, 1981, 48(4):375-389.
    [30] XIAO T, YANG F, LI S, et al. Thallium pollution in China:A geo-environmental perspective[J]. Science of the Total Environment, 2012, 421/422(1):51-58.
    [31] 谢文彪, 常向阳, 陈穗玲,等. 铊资源的分布及利用中的环境问题[J]. 广州大学学报(自然科学版), 2004, 3(6):510-514. XIE W B, CHANG X Y, CHEN S L, et al. Environmental problems in the distribution and utilization of thallium resources[J]. Journal of Guangzhou University, 2004, 3(6):510-514(in Chinese).
    [32] 邓红梅, 陈永亨. 水中铊的污染及其生态效应[J]. 环境化学,2008,27(3):363-367.

    DENG H M, CHEN Y H. Thallium pollution and its ecological effect in water[J]. Environmental Chemistry, 2008, 27(3):363-367(in Chinese).

    [33] 刘娟, 王津, 陈永亨,等. 大气气溶胶中铊污染问题的研究进展[J]. 有色冶金设计与研究, 2013, 34(3):79-81.

    LIU J, WANG J, CHEN Y H, et al. Research progress of thallium pollution in atmospheric aerosols[J]. Design and Research of Nonferrous Metallurgy, 2013, 34(3):79-81(in Chinese).

    [34] HRSAK J, SKRBEC A, BALAGOVI I, et al. Thallium content in zagreb air[J]. Bulletin of Environmental Contamination & Toxicology, 2003, 71(1):131.
    [35] 黄丽春, 霍学义. 兴仁县回龙村矿石,废矿渣对周围环境的铊污染调查[J]. 工业卫生与职业病, 1996, 22(3):158-160.

    HUANG L C, HUO X Y. Investigation on thallium pollution of ore and waste slag in Huilong Village, Xingren County[J]. Industrial Hygiene and Occupational Disease, 1996, 22(3):158-160(in Chinese).

    [36] LI J, SUN C. Evaluation of the migration of thallium, cadmium, vanadium, and chromium from a thermal power plant[J]. Environmental Earth Sciences, 2016, 75(5):388.
    [37] 尹明根, 李文斌. 42例铊中毒随访检查结果分析[J]. 中国工业医学杂志, 1993, 6(4):223-224.

    YIN M G, LI W B. The Results of 42 cases of thallium poisoning were analyzed.[J]. Chinese Journal of Industrial Medicine, 1993, 6(4):223-224(in Chinese).

    [38] 黎季瑜, 黄丽春, 潘建敏,等. 关于兴仁县回龙村慢性铊中毒的调查研究(第二次远期后果追踪观察)[J]. 贵州医药, 1986(6):37-39. LI J Y, HUANG L C, PAN J M, et al. Investigation on chronic thallium poisoning in Huilong Village, Xingren County[J]. Guizhou Medicine, 1986

    (6):39-39(in Chinese).

    [39] 王国梅. 贵州遵义地区地方性铊中毒调查[J]. 微量元素与健康研究, 1991(2):48-49. WANG G M, Investigation of endemic thallium poisoning in Zunyi, Guizhou Province[J]. Trace Elements and Health Studies,1991

    (2):48-49(in Chinese).

    [40] MELCHER D L G, MULLER D L E, WEIGEL D L H. The KIVCET cyclone smelting process for impure copper concentrates[J]. JOM, 1976, 28(7):4-8.
    [41] HUGHES S. Applying ausmelt technology to recover Cu, Ni, and Co from slags[J]. JOM, 2000, 52(8):30-33.
    [42] 王春霖, 张永波, 陈永亨. 重金属铊在典型排放源周边大气颗粒物中的形态及来源分析[J]. 环境保护科学, 2016, 42(2):114-119.

    WANG C L, ZHANG Y B, CHEN Y H. Morphology and source analysis of thallium in atmospheric particulates around typical emitter[J]. Environmental Protection Science, 2016, 42(2):114-119(in Chinese).

    [43] 刘志宏, 李鸿飞, 李启厚,等. 铊在有色冶炼过程中的行为和危害及防治[J]. 山西化工, 2007, 27(6):47-51.

    LIU Z H, LI H F, LI Q H, et al. Behavior, harm and prevention of thallium in nonferrous smelting process[J]. Shanxi Chemical Industry, 2007, 27(6):47-51(in Chinese).

    [44] 王春霖, 陈永亨, 王津,等. 粤西某工厂周边大气细颗粒物中铊的分布特征[C]//.中国矿物岩石地球化学学会第15届学术年会论文摘要集(3), 2015. WANG C L, CHEN Y H, WANG J, et al. Distribution characteristics of thallium in atmospheric fine particulate matter around a factory in west Guangdong[C]//. Abstracts Of Papers From The 15

    th Annual Meeting of the Geochemical Society(3), 2015(in Chinese).

    [45] 末永近志, 刘荣瑞. 佐贺关冶炼厂金属铊的生产[J]. 中国有色冶金, 1991(5):35-39. WO Y J Z, LIU R R. Production of thallium in Saga Smelter[J]. Chinese Nonferrous Metallurgy, 1991

    (5):35-39(in Chinese).

    [46] 邵传兵, 鲁兴武, 马爱军,等. 萃取法从含铊烟尘中综合回收稀散金属的研究[J]. 有色金属(冶炼部分), 2014(10):57-58. SHAO C B, LU X W, MA A J, et al. Comprehensive recovery of dispersed metal from thallium-containing soot by extraction method[J]. Nonferrous Metals, 2014(10):57-58(in Chinese).
    [47] 谢文彪, 陈永亨, 陈穗玲,等. 云浮硫铁矿及其焙烧灰渣中元素铊的组成特征[J]. 矿产综合利用, 2001(2):23-25. XIE W B, CHEN Y H, CHEN S L, et al. Composition characteristics of thallium in Yunfei pyrite and its calcined ash[J]. Multipurpose Utilization of Mineral Resources, 2001

    (2):23-25(in Chinese).

    [48] HAJDU S, NESSLER F. ChemInform abstract:Chemistry, physics, and occurrence of thallium and its compounds[J]. Cheminform, 1986, 17(19):752-755.
    [49] LI H, LI X, XIAO T, et al. Efficient removal of thallium(Ⅰ) from wastewater using flower-like manganese dioxide coated magnetic pyrite cinder[J]. Chemical Engineering Journal, 2018, 353:867-877.
    [50] REHMAN S U, ULLAH N, KAMALI A R, et al. Study of thallium(Ⅲ) adsorption onto multiwall carbon nanotubes[J]. Carbon, 2013, 55(6):375-381.
    [51] MA Q, JIA L, WANG X, et al. Efficient removal of thallium from flue gas using manganese-based mof catalysts by gas-solid phase catalytic oxidation and adsorption[J]. Industrial & Engineering Chemistry Research, 2020.doi:10.1021/acs.iecr.0c01676
  • 加载中
WeChat 点击查看大图
计量
  • 文章访问数:  5004
  • HTML全文浏览数:  5004
  • PDF下载数:  126
  • 施引文献:  0
出版历程
  • 收稿日期:  2020-04-28
马强, 王学谦, 宁平, 王郎郎, 徐博雯, 陈军辉, 黄嘉珩, 郝吉明. 大气铊污染现状及治理技术研究进展[J]. 环境化学, 2020, (12): 3362-3370. doi: 10.7524/j.issn.0254-6108.2020042801
引用本文: 马强, 王学谦, 宁平, 王郎郎, 徐博雯, 陈军辉, 黄嘉珩, 郝吉明. 大气铊污染现状及治理技术研究进展[J]. 环境化学, 2020, (12): 3362-3370. doi: 10.7524/j.issn.0254-6108.2020042801
shu
MA Qiang, WANG Xueqian, NING Ping, WANG Langlang, XU Bowen, CHEN Junhui, HUANG Jiaheng, HAO Jiming. Status of atmospheric thallium pollution and research progress of treatment technology[J]. Environmental Chemistry, 2020, (12): 3362-3370. doi: 10.7524/j.issn.0254-6108.2020042801
Citation: MA Qiang, WANG Xueqian, NING Ping, WANG Langlang, XU Bowen, CHEN Junhui, HUANG Jiaheng, HAO Jiming. Status of atmospheric thallium pollution and research progress of treatment technology[J]. Environmental Chemistry, 2020, (12): 3362-3370. doi: 10.7524/j.issn.0254-6108.2020042801
shu

大气铊污染现状及治理技术研究进展

    通讯作者: 王学谦, E-mail: xqwang214@163.com ; 
  • 1. 昆明理工大学环境科学与工程学院, 昆明, 650500;
  • 2. 四川省生态环境科学研究院, 成都, 610041;
  • 3. 中国电信成都分公司, 成都, 610000;
  • 4. 清华大学环境科学与工程研究院, 北京, 100084
  • 收稿日期:  2020-04-28
基金项目:

国家自然科学基金（51868030，51568027），国家重点研发计划项目（2017YFC0210500，2018YFC0213400）和云南省中青年学术和技术带头人后备人才项目（2015HB012）资助.

摘要: 铊及其化合物是一类毒性强，传播广泛的大气污染物.铊的气态污染主要来源是矿物冶炼、火力发电、水泥等行业.铊及其化合物毒性高而排放量较低，已经在国内外富铊地区引起中毒事件.目前，由于冶炼，火电等行业在国内的飞速发展，其排放造成的大气铊污染又给人群健康和生态安全造成了严重的威胁.铊进入大气后，能够伴随大气活动，食物链和沉降等与人体接触.现有的尾气治理措施如除尘和酸洗对废气中的铊具有一定程度的去除效果但不能彻底解决废气中的铊污染问题.通过对铊不同价态化合物的物理化学特征分析，将高毒性，易迁移的一价化合物转化为难迁移，低毒性的三价铊氧化物的新思路是可行的.

English Abstract

    全文HTML

参考文献 (51)

返回顶部

目录

/

返回文章
返回

Copyright © 2019 中国科学院生态环境研究中心