矿区周边农田土壤重金属污染风险评价
Risk assessment of heavy metal pollution in farmland soil around mining area
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摘要: 为了系统的评价矿区周边土壤-农作物-人体系统中重金属的污染风险,为矿区生态风险的分类治理和农作物安全生产提供科学依据,选择在重庆市黔江区金洞乡主要农耕区采集表层土壤样品321件、水稻和对应根系土样品30套,分析了土壤和水稻中重金属(Cd、Hg、Pb、As和Cr)的含量、土壤中有机质和Mn的含量及土壤pH,利用潜在生态风险指数法和人体健康风险评估模型进行重金属污染风险评价.结果表明,研究区土壤中Cd和Hg均存在一定程度的超标现象,土壤重金属含量受到成土母质、矿业活动及农业活动的影响.土壤总体潜在生态风险较小,主要以轻微污染为主,Cd和Hg存在点状的很强-极强的污染点位,是主要的土壤污染因子.水稻样品存在Cd和As的超标问题,水稻重金属含量主要受到土壤中重金属的含量、土壤pH、土壤有机质含量及土壤Mn含量的影响.通过食物摄入的暴露途径存在一定程度的非致癌风险,主要的贡献因子为As和Cd.可根据重金属污染在土壤-农作物-人体系统中的不同特点,进行污染分类管理、分类治理,以达到土地安全利用的目的.Abstract: In order to systematically evaluate the pollution risk of heavy metals in the soil-crop-human system around the mining area, and to provide a scientific basis for the classification and management of ecological risks in the mining area and the safe production of crops, 321 surface soil samples and 30 sets of rice and corresponding root soil samples were collected in the main farming area of Jindong Township, Qianjiang District, Chongqing City to analyze the content of heavy metals (Cd, Hg, Pb, As and Cr) in the soil and rice, the content of organic matter and Mn in the soil, and the soil pH. By using the potential ecological risk index method and the human health risk assessment model to carry out heavy metal pollution risk assessment. The results show that both Cd and Hg in the soil of the studying area exceed the standard to a certain extent, and the content of heavy metals in the soil is affected by soil parent materials, mining activities and agricultural activities. The overall potential ecological risk of the soil is relatively small, mainly caused by slight pollution. Cd and Hg have very strong-extremely strong spot-like pollution points, which are the main soil pollution factors. Rice samples have the problem of excessive Cd and As. The content of heavy metals in rice is mainly affected by the content of heavy metals in the soil, soil pH, soil organic matter content and soil Mn content. Exposure intake through food has a certain degree of non-carcinogenic risk whose main contributing factors are As and Cd. According to the different characteristics of heavy metal pollution in the soil-crop-human body system, pollution classification management and classification treatment can be carried out to achieve the purpose of safe land use.
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Key words:
- mining area /
- soil /
- crops /
- heavy metals /
- pollution risk /
- human health risk
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[1] 于靖靖,师华定,王明浩,等.湘江子流域重点污染企业影响区土壤重金属镉污染源识别[J].环境科学研究, 2020, 33(4):1013-1020. YU J J, SHI H D, WANG M H, et al. Identification of soil cadmium pollution sources in affected areas of key pollution enterprises in Xiangjiang sub-basin[J]. Research of Environmental Sciences, 2020, 33(4):1013-1020(in Chinese).
[2] 盛维康, 侯青叶, 杨忠芳,等.湘江水系沉积物重金属元素分布特征及风险评价[J].中国环境科学, 2019, 39(5):2230-2240. SHENG W K, HOU Q Y, YANG Z F, et al. Distribution characteristics and ecological risk assessment of heavy metals in sediments from Xiang River[J]. China Environmental Science, 2019, 39(5):2230-2240(in Chinese).
[3] 刘春早, 黄益宗, 雷鸣,等.湘江流域土壤重金属污染及其生态环境风险评价[J].环境科学, 2012, 33(1):260-265. LIU C Z, HUANG Y Z, LEI M, et al. Soil contamination and assessment of heavy metals of Xiangjiang River Basin[J]. Environmental Science, 2012, 33(1):260-265(in Chinese).
[4] 余嘉衍, 李冰玉, 周一敏,等.湖南省某矿遗址周围农业土壤重金属污染及风险评价[J].环境化学, 2020, 39(4):1024-1030. YU J Y, LI B Y, ZHOU Y M, et al. Pollution and risk assessment of heavy metal in agricultural soil around an abandon mine site in Hunan Province[J]. Environmental Chemistry, 2020, 39(4):1024-1030(in Chinese).
[5] 高月, 孙荣国, 叶彩, 等.贵州省丹寨县某铅锌矿区土壤重金属污染生态风险评价[J].生态学杂志, 2020, 39(3):928-936. GAO Y, SUN G R, YE C, et al. Ecological risk assessment of heavy metal pollution in soil of a lead-zinc mine area in Danzhai County, Guizhou Province, China[J].Chinese Journal of Ecology, 2020, 39(3):928-936(in Chinese).
[6] 孙德尧, 薛忠财, 韩兴, 等.冀北山区某矿区周边耕地土壤重金属污染特征及生态风险评价[J].生态与农村环境学报, 2020, 36(2):242-249. SUN D Y, XUE Z C, HAN X, et al. Polluting characteristics and ecological risk assessment of heavy metals in cultivated land around a mining area in northern Hebei Province[J].Journal of Ecology and Rural Environment, 2020, 36(2):242-249(in Chinese).
[7] 陆泗进, 王业耀, 何立环. 会泽某铅锌矿周边农田土壤重金属生态风险评价[J].生态环境学报, 2014, 23(11):1832-1838. LU S J, WANG Y Y, HE L H. Heavy metal pollution and ecological risk assessment of the paddy soils around a Pb-Zn mine in Huize Country[J]. Ecology and Environmental Sciences, 2014, 23(11):1832-1838(in Chinese).
[8] 陈凤, 董泽琴, 王程程, 等. 锌冶炼区耕地土壤和农作物重金属污染状况及风险评价[J].环境科学, 2017, 38(10):4360-4369. CHEN F, DONG Z Q, WANG C C, et al. Heavy metal contamination of soils and crops near a zinc smelter[J].Environmental Sciences, 2017, 38(10):4360-4369(in Chinese).
[9] 杨敏, 滕应, 任文杰, 等. 石门雄黄矿周边农田土壤重金属污染及健康风险评估[J].土壤, 2016, 48(6):1172-1178. YANG M, TENG Y, REN W J, et al. Pollution and health risk assessment of heavy metals in agricultural soil around Shimen realgar mine[J].Soils, 2016, 48(6):1172-1178(in Chinese).
[10] 陈怡先, 姜小三, 王勇, 等.基于GIS矿区土壤重金属生态环境及人体健康评价[J].环境科学学报, 2018, 38(4):1642-1652. CHEN Y X, JIANG X S, WANG Y, et al. Assessment of ecological environment and human health of heavy metals in mining area based on GIS[J]. Acta Scientiae Circumstantiae, 2018, 38(4):1642-1652(in Chinese).
[11] LEE C S, LI X D, SHI W D, et al. Metal contamination in urban,suburban,and country park soils of Hong Kong:A study based on GIS and multivariate statistics[J]. Science of the Total Environment, 2006, 356:45-61. [12] DZ/T 0295-2016, 土地质量地球化学评价规范[S]. [13] LIN Q, LIU E, ZHANG E, et al. Spatial distribution, contamination and ecological risk assessment of heavy metals in surface sediments of Erhai Lake, a large eutrophic plateau lake in southwest China[J].Catena, 2016,145:193-203. [14] 赵东杰, 王学求. 滇黔桂岩溶区河漫滩土壤重金属含量、来源及潜在生态风险[J].中国环境科学, 2020, 40(4):1609-1619. ZHAO D J, WANG X Q. Distribution, sources and potential ecological risk of heavy metals in the floodplain soils of the karst area of Yunnan, Guizhou, Guangxi[J]. China Environmental Science, 2020, 40(4):1609-1619(in Chinese).
[15] HAKANSON L. An ecological risk index for aquatic pollution control:A sedimentological approach[J]. Water Research, 1980, 14(8):975-1001. [16] GB 15618-2018, 土壤环境质量农用地土壤污染风险管控标准(试行)[S]. [17] 王帅, 胡恭任, 于瑞莲, 等.九龙江河口表层沉积物中重金属污染评价及来源[J]. 环境科学研究, 2014, 27(10):1110-1118. WANG S, HU G R, YU R L, et al. Pollution assessment and source analysis of heavy metals in surface sediments from Jiulong river estuary[J]. Research of Environmental Sciences, 2014, 27(10):1110-1118(in Chinese).
[18] GU Q B, YU T, YANG Z F, et al. Prediction and risk assessment of five heavy metals in maize and peanut:A case study of Guangxi, China.[J]. Environmental Toxicology and Pharmacology, 2019, 70:1-8. [19] 李一蒙, 马建华, 刘德新, 等.开封城市土壤重金属污染及潜在生态风险评价[J]. 环境科学, 2015,36(3):1037-1044. LI Y M, MA J H, LIU D X, et al. Assessment of heavy metal pollution and potential ecological risks of urban soils in Kaifeng City, China[J].Environmental Science, 2015, 36(3):1037-1044(in Chinese).
[20] 熊佳, 韩志伟, 吴攀, 等.独山锑冶炼厂周边土壤锑砷空间分布特征、污染评价及健康风险评估[J].环境科学学报, 2020, 40(2):655-664. XIONG J, HAN Z W, WU P, et al. Spatial distribution characteristics, contamination evaluation and health risk assessment of arsenic and antimony in soil around an antimony smelter of Dushan County[J].Acta Scientiae Circumstantiae, 2020, 40(2):655-664(in Chinese).
[21] 陈月芳, 孙善伟, 段小丽, 等.兰州市西固区儿童饮用水重金属暴露及健康风险精细化评估[J].环境科学, 2020, 41(1):262-272. CHEN Y F, SUN S W, DUAN X L, et al. Refined assessment of exposure and health risks of heavy metals in water for the children in Xigu district, Lanzhou[J]. Environmental Science, 2020, 41(1):262-272(in Chinese).
[22] 王锐, 胡小兰, 张永文, 等.重庆市主要农耕区土壤Cd生物有效性及影响因素[J].环境科学, 2020, 41(4):353-359. WANG R, HU X L, ZHANG Y W, et al. Bioavailability and influencing factors of soil Cd in the major farming areas of Chongqing[J]. Environmental Science, 2020, 41(4):353-359(in Chinese).
[23] 王利民, 刘佳, 姚保民, 等. 样本正态分布对降低空间抽样数量的重要性[J].中国农学通报, 2019, 35(20):150-157. WANG L M, LIU J, YAO B M, et al. Sample normal distribution:The importance for decreasing spatial sampling size[J]. Chinese Agricultural Science Bulletin, 2019, 35(20):150-157(in Chinese).
[24] CAMBARDELLA C A, MOOIMAN T B, PARKIN T B, et al. Field-scale variability of soil properties in central Iowa soils[J].Soil Science Society of America Journal, 1994, 58(5):1501-1511 [25] 吴正祥, 周勇, 木合塔尔·艾买提, 等.鄂西北山区耕层土壤pH值空间变异特征及其影响因素研究[J].长江流域资源与环境, 2020, 29(2):488-498. WU Z X, ZHOU Y, MUHTAR A, et al. Spatial variability of soil pH value and its influencing factors in the soil layer of northwestern Hubei Province[J].Resources and Environment in the Yangtze Basin, 2020, 29(2):488-498(in Chinese).
[26] GB 2762-2017, 食品安全国家标准食品中污染物限量[S]. [27] 湛天丽, 黄阳, 滕应, 等.贵州万山汞矿区某农田土壤重金属污染特征及来源解析[J].土壤通报,2017, 48(2):474-480. ZHAN T L, HUANG Y, TENG Y, et al. Pollution characteristics and sources of heavy metals in farmland soil in Wanshan mining areas, Guizhou Province[J].Chinese Journal of Soil Science,2017,48(2):474-480(in Chinese).
[28] XIA X Q, JI J F, YANG Z F, et al. Cadmium risk in the soil-plant system caused by weathering of carbonate bedrock[J]. Chemosphere, 2020, 254:126799. [29] WEN Y B, LI W, YANG Z F, et al. Enrichment and source identification of Cd and other heavy metals in soils with high geochemical background in the karst region, Southwestern China[J]. Chemosphere, 2020, 245:125620. [30] 胡国成, 张丽娟, 齐剑英, 等.贵州万山汞矿周边土壤重金属污染特征及风险评价[J].生态环境学报,2015,24(5):879-885. HU G C, ZHANG L J, QI J Y, et al. Contaminant characteristics and risk assessment of heavy metals in soils from Wanshan mercury mine area, Guizhou Province[J]. Ecology and Environmental Sciences, 2015, 24(5):879-885(in Chinese).
[31] 冯学仕. 大硐喇汞矿田中寻找(铅)锌矿的可能性探讨[J].贵州地质,1995(3):204-207. FENG X S. Discussion on the possibility of searching (Lead) zinc ore in Datuola mercury ore field[J].Guizhou Geology, 1995 (3):204-207(in Chinese).
[32] 邹灏, 淡永, 张寿庭, 等. 重庆东南部彭水地区重晶石-萤石矿床的成矿物质来源探讨:地球化学证据[J].大地构造与成矿学报, 2016, 40(1):71-85. ZOU H, DAN Y, ZHANG S T, et al. Geochemical evidence for sources of ore-forming material of barite-fluorite deposits in Pengshui area, Southeast Chongqing[J]. Geotectonica et Metallogenia, 2016, 40(1):71-85(in Chinese).
[33] 王飞, 赵立欣, 沈玉君, 等.华北地区畜禽粪便有机肥中重金属含量及溯源分析[J].农业工程学报, 2013, 29(19):202-208. WANG F, ZHAO L X, SHEN Y J, et al. Analysis of heavy metal contents and source tracing in organic fertilizer from livestock manure in North China[J]. Transactions of the Chinese Society of Agricultural Engineering, 2013, 29(19):202-208(in Chinese).
[34] 王美, 李书田, 马义兵, 等. 长期不同施肥措施对土壤和作物重金属累积的影响[J]. 农业环境科学学报, 2014, 33(1):63-74. WANG M, LI S T, MA Y B, et al. Effect of long-term fertilization on heavy metal accumulation in soils and crops[J]. Journal of Agro-Environment Science, 2014, 33(1):63-74(in Chinese).
[35] 余志, 陈凤, 张军方, 等. 锌冶炼区菜地土壤和蔬菜重金属污染状况及风险评价[J].中国环境科学, 2019, 39(5):2086-2094. YU Z, CHEN F, ZHANG J F, et al. Contamination and risk of heavy metals in soils and vegetables from zinc smelting area[J]. China Environmental Science, 2019, 39(5):2086-2094(in Chinese).
[36] 孙厚云, 吴丁丁, 毛启贵, 等. 新疆东天山某铜矿区土壤重金属污染与生态风险评价[J]. 环境化学, 2019, 38(12):2690-2699. SUN H Y, WU D D, MAO Q G, et al. Soil heavy metal pollution and ecological risk assessment in a copper mining area in East Tianshan, Xinjiang[J].Environmental Chemistry, 2019, 38(12):2690-2699(in Chinese).
[37] 赵方杰, 谢婉滢, 汪鹏. 土壤与人体健康[J].土壤学报, 2020, 57(1):1-11. ZHAO F J, XIE W Y, WANG P. Soil and human health[J]. Acta Pedologica Sinica, 2020, 57(1):1-11(in Chinese).
[38] ZHAO F J, MCGRATH S P, MEHARG A A. Arsenic as a foodchain contaminant:Mechanisms of plant uptake and metabolism and mitigation strategies[J].Annual Review of Plant Biology, 2010, 61:535-559. [39] 罗文贱, 张政勤, 陈勇, 等.连续解吸中离子强度对可变电荷土壤和高岭石体系pH的影响[J]. 土壤学报, 2016, 53(1):146-154. LUO W J, ZHANG Z Q, CHEN Y, et al. Effect of ionic-strength change on the system pH of variable charge soils and kaolinite during successive desorption[J]. Acta Pedologica Sinica, 2016, 53(1):146-154(in Chinese).
[40] 刘佳丽, 王祖伟, 张辉. 模拟降水对碱性盐化土壤中镉的淋滤及形态变化的影响[J]. 生态环境学报, 2010, 19(8):1974-1978. LIU J L, WANG Z W, ZHANG H. Simulated rainfall leaching cadmium and cadmium fraction changes in soils[J]. Ecology and Environmental Sciences, 2010, 19(8):1974-1978(in Chinese).
[41] KHAOKAEW S, CHANEY R L, LANDROT G, et al. Speciation and release kinetics of cadmium in an alkaline paddy soil under various flooding periods and draining conditions[J]. Environmental Science & Technology, 2011, 45(10):4249-4255. [42] CAPORALE A G, VIOLANTE A. Chemical processes affecting the mobility of heavy metals and metalloids in soil environments[J]. Current Pollution Reports, 2016, 2(1):15-27. [43] YU H Y, LIU C P, ZHU J S, et al. Cadmium availability in rice paddy fields from a mining area:The effects of soil properties highlighting iron fractions and pH value[J].Environmental Pollution, 2016, 209:38-45. [44] 宋娇艳, 袁林, 杨志丹,等.铁锰复合氧化物对铅离子的吸附特征及影响因素研究[J].西南大学学报(自然科学版), 2014, 36(7):135-142. SONG J Y, YUAN L, YANG Z D, et al. On adsorption of lead ions on Fe-Mn composite oxide and its influencing factorsp[J].Journal of Southwest University(Natural Science Edition), 2014, 36(7):135-142(in Chinese). [45] 金圣圣, 贺纪正, 郑袁明, 等.生物氧化锰矿物对几种重金属的吸附作用[J].环境科学学报, 2009, 29(1):132-139. JIN S S, HE J Z, ZHENG Y M, et al. Adsorption of heavy metals by biogenicmanganeseoxides[J]. Acta Scientiae Circumstantiae, 2009, 29(1):132-139(in Chinese).
[46] ZHAO F J, MA Y, ZHU Y G, et al. Soil contamination in China:Current status and mitigation strategies[J].Environmental Science & Technology, 2015, 49(2):750-759. [47] WU G, KANG H, ZHANG X, et al. A critical review on the bio-removal of hazardous heavy metals from contaminated soils:Issues,progress, eco-environmental concerns and opportunities[J].Journal of Hazardous Materials, 2010, 174(1/3):1-8. [48] HU Y, CHENG H, TAO S. The challenges and solutions for cadmium contaminated rice in China:A critical review[J]. Environment International, 2016, 92:515-532. [49] DING C, ZHANG T, WANG X, et al. Prediction model for cadmium transfer from soil to carrot(Daucus carota L.)and its application to derive soil thresholds for food safety[J]. Journal of Agricultural and Food Chemistry, 2013, 61(43):10273-10282. [50] DING C, MA Y, LI X, et al. Derivation of soil thresholds for lead applying species sensitivity distribution:A case study for root vegetables[J].Journal of Hazardous Materials, 2016, 303:21-27. [51] YANG Y, WANG M, CHEN W, et al. Cadmium accumulation risk in vegetables and rice in southern China:Insights from solid-solution partitioning and plant uptake factor[J]. Journal of Agricultural and Food Chemistry, 2017, 65(27):5463-5469. [52] LI Y, WANG Y B, GOU X, et al. Risk assessment of heavy metalsin soils and vegetables around non-ferrous metals mining and smelting sites, Baiyin, China[J]. China Journal of Environmental Sciences, 2006, 18(6):1124-1134. -

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