溶胶凝胶法制备磷钨酸掺杂TiO2薄膜及其光催化性能

盛雪; 余足玲; 刘士荣; 陈明清

环境工程学报

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盛雪, 余足玲, 刘士荣, 陈明清. 溶胶凝胶法制备磷钨酸掺杂TiO2薄膜及其光催化性能[J]. 环境工程学报, 2008, 2(8): 1026-1030.

引用本文:

盛雪, 余足玲, 刘士荣, 陈明清. 溶胶凝胶法制备磷钨酸掺杂TiO2薄膜及其光催化性能[J]. 环境工程学报, 2008, 2(8): 1026-1030.

Sheng Xue, Yu Zuling, Liu Shirong, Chen Mingqing. Preparation and photocatalytic performance of PW doped TiO2 film via the sol-gel method[J]. Chinese Journal of Environmental Engineering, 2008, 2(8): 1026-1030.

Citation:

Sheng Xue, Yu Zuling, Liu Shirong, Chen Mingqing. Preparation and photocatalytic performance of PW doped TiO2 film via the sol-gel method[J]. Chinese Journal of Environmental Engineering, 2008, 2(8): 1026-1030.

溶胶凝胶法制备磷钨酸掺杂TiO2薄膜及其光催化性能

1.
江南大学化学与材料工程学院，无锡 214000
基金项目:
国家自然科学基金资助项目（20671043）
中图分类号: X703

Preparation and photocatalytic performance of PW doped TiO2 film via the sol-gel method

1.
School of Chemical & Material Engineering of Jiangnan University，Wuxi 214000
Fund Project:

摘要: 以钛酸四丁酯为前驱物，采用溶胶凝胶法制备了磷钨酸掺杂的二氧化钛薄膜。通过XRD、FT-TR对该薄膜进行了表征，研究了薄膜在对氯苯酚光降解中的催化活性。结果表明，当磷钨酸与二氧化钛摩尔比为0.01∶1、薄膜烧结温度600℃、对氯苯酚溶液浓度30 mg/L（pH＝5）、光催化8 h的条件下，对氯苯酚的降解率超过90%，且薄膜可以重复使用。磷钨酸对二氧化钛的光催化活性具有明显的促进作用。
- 磷钨酸 /
- 掺杂二氧化钛薄膜 /
- 溶胶凝胶法 /
- 光催化 /
- 对氯苯酚
Abstract: Tungstophosphate acid (PW) doped TiO2 film (PW/TiO2) was prepared by sol-gel method using tetrabutyl titanate (TBOT) as a precursor,and was characterized by XRD, FT-IR.The photocatalysis degradation of p-chlorophnol with PW/TiO2 film was investigated to study the catalytic activities of the film.The result indicated that, when the ratio of tungstophosphate acid and titania was 0.01∶1, the sintering temperature was 600℃ and the concentration of the p-chlorophnol was 30 mg/L (pH=5), after 8 h time of catalysis, the degradati on rate was more than 90%,and the film could be reutilized.The doped of PW can enhance the catalytic actvities of the TiO2 film.
- tungstophosphate acid /
- TiO2 film /
- sol-gel /
- photocatalysis /
- p-chlorophnol

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盛雪, 余足玲, 刘士荣, 陈明清. 溶胶凝胶法制备磷钨酸掺杂TiO2薄膜及其光催化性能[J]. 环境工程学报, 2008, 2(8): 1026-1030.

引用本文:

盛雪, 余足玲, 刘士荣, 陈明清. 溶胶凝胶法制备磷钨酸掺杂TiO2薄膜及其光催化性能[J]. 环境工程学报, 2008, 2(8): 1026-1030.

Citation:

溶胶凝胶法制备磷钨酸掺杂TiO2薄膜及其光催化性能

1. 江南大学化学与材料工程学院，无锡 214000

收稿日期: 2008-02-22

基金项目:

国家自然科学基金资助项目（20671043）

关键词:

摘要: 以钛酸四丁酯为前驱物，采用溶胶凝胶法制备了磷钨酸掺杂的二氧化钛薄膜。通过XRD、FT-TR对该薄膜进行了表征，研究了薄膜在对氯苯酚光降解中的催化活性。结果表明，当磷钨酸与二氧化钛摩尔比为0.01∶1、薄膜烧结温度600℃、对氯苯酚溶液浓度30 mg/L（pH＝5）、光催化8 h的条件下，对氯苯酚的降解率超过90%，且薄膜可以重复使用。磷钨酸对二氧化钛的光催化活性具有明显的促进作用。

English Abstract

Preparation and photocatalytic performance of PW doped TiO2 film via the sol-gel method

1. School of Chemical & Material Engineering of Jiangnan University，Wuxi 214000

Received Date: 2008-02-22

Fund Project:

Keywords:

Abstract: Tungstophosphate acid (PW) doped TiO2 film (PW/TiO2) was prepared by sol-gel method using tetrabutyl titanate (TBOT) as a precursor,and was characterized by XRD, FT-IR.The photocatalysis degradation of p-chlorophnol with PW/TiO2 film was investigated to study the catalytic activities of the film.The result indicated that, when the ratio of tungstophosphate acid and titania was 0.01∶1, the sintering temperature was 600℃ and the concentration of the p-chlorophnol was 30 mg/L (pH=5), after 8 h time of catalysis, the degradati on rate was more than 90%,and the film could be reutilized.The doped of PW can enhance the catalytic actvities of the TiO2 film.

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溶胶凝胶法制备磷钨酸掺杂TiO2薄膜及其光催化性能

Preparation and photocatalytic performance of PW doped TiO2 film via the sol-gel method

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溶胶凝胶法制备磷钨酸掺杂TiO2薄膜及其光催化性能

English Abstract

Preparation and photocatalytic performance of PW doped TiO2 film via the sol-gel method

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