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O3/H2O2处理嘧啶废水的研究

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彭人勇, 杨秀娟. O3/H2O2处理嘧啶废水的研究[J]. 环境工程学报, 2011, 5(3): 601-604.
引用本文: 彭人勇, 杨秀娟. O3/H2O2处理嘧啶废水的研究[J]. 环境工程学报, 2011, 5(3): 601-604.
shu
Peng Renyong, Yang Xiujuan. Study on treatment of wastewater containing pyrimidine by O3/H2O2[J]. Chinese Journal of Environmental Engineering, 2011, 5(3): 601-604.
Citation: Peng Renyong, Yang Xiujuan. Study on treatment of wastewater containing pyrimidine by O3/H2O2[J]. Chinese Journal of Environmental Engineering, 2011, 5(3): 601-604.
shu

O3/H2O2处理嘧啶废水的研究

  • 1.

    青岛科技大学环境与安全工程学院，青岛 266042

  • 基金项目:

  • 中图分类号: X787

Study on treatment of wastewater containing pyrimidine by O3/H2O2

  • 1.

    College of Environment and Safety Engineering, Qingdao University of Science & Technology, Qingdao 266042,China

  • Fund Project:

  • 摘要: 采用O3/H2O2法对嘧啶废水进行处理，考察了不同反应条件对嘧啶和COD去除率的影响，并对O3/H2O2降解嘧啶的反应机制和动力学进行了初步探讨。实验结果表明，在pH值为11，反应时间为70 min，O3流量为4 g/h，H2O2投加量为50 mmol/L的条件下，废水的嘧啶和COD的去除率分别达到86.46%和74.97%。嘧啶的去除率随自由基抑制剂叔丁醇增加而降低，说明O3/H2O2降解嘧啶主要为体系中·OH的贡献。同时动力学研究表明，O3/H2O2对嘧啶的降解符合一级反应动力学模型。
    Abstract: The effects of different conditions on removal rates of pyrimidine and COD were investigated. The reaction mechanism and kinetics on degradation of pyrimidine by O3/ H2O2 were also studied. The experimental results showed that the removal rates of pyrimidine and COD were up to 86.46% and 74.97%, respectively, under the conditions including pH 11, 70 min of reaction time, 4 g/h of ozone flow, and 50 mmol/L of H2O2. The removal rate of pyrimidine deceased with the increasing of the tert-butyl alcohol concentration, which suggested that the degradation of pyrimidine was mainly due to hydroxyl free radical reaction from O3/H2O2process. The kinetic study showed that the degradation of pyrimidine by O3/H2O2 was in accordance with the first-order kinetic model.
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  • 收稿日期:  2010-03-17
彭人勇, 杨秀娟. O3/H2O2处理嘧啶废水的研究[J]. 环境工程学报, 2011, 5(3): 601-604.
引用本文: 彭人勇, 杨秀娟. O3/H2O2处理嘧啶废水的研究[J]. 环境工程学报, 2011, 5(3): 601-604.
shu
Peng Renyong, Yang Xiujuan. Study on treatment of wastewater containing pyrimidine by O3/H2O2[J]. Chinese Journal of Environmental Engineering, 2011, 5(3): 601-604.
Citation: Peng Renyong, Yang Xiujuan. Study on treatment of wastewater containing pyrimidine by O3/H2O2[J]. Chinese Journal of Environmental Engineering, 2011, 5(3): 601-604.
shu

O3/H2O2处理嘧啶废水的研究

  • 1. 青岛科技大学环境与安全工程学院，青岛 266042
  • 收稿日期:  2010-03-17
基金项目:

摘要: 采用O3/H2O2法对嘧啶废水进行处理，考察了不同反应条件对嘧啶和COD去除率的影响，并对O3/H2O2降解嘧啶的反应机制和动力学进行了初步探讨。实验结果表明，在pH值为11，反应时间为70 min，O3流量为4 g/h，H2O2投加量为50 mmol/L的条件下，废水的嘧啶和COD的去除率分别达到86.46%和74.97%。嘧啶的去除率随自由基抑制剂叔丁醇增加而降低，说明O3/H2O2降解嘧啶主要为体系中·OH的贡献。同时动力学研究表明，O3/H2O2对嘧啶的降解符合一级反应动力学模型。

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