H2O和SO2对V2O5-WO3/TiO2催化剂催化氧化NO的影响

秦旭东; 张俊丰; 颜斌; 王娇

环境工程学报

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秦旭东, 张俊丰, 颜斌, 王娇. H2O和SO2对V2O5-WO3/TiO2催化剂催化氧化NO的影响[J]. 环境工程学报, 2011, 5(5): 1137-1141.

引用本文:

秦旭东, 张俊丰, 颜斌, 王娇. H2O和SO2对V2O5-WO3/TiO2催化剂催化氧化NO的影响[J]. 环境工程学报, 2011, 5(5): 1137-1141.

Qin Xudong, Zhang Junfeng, Yan Bin, Wang Jiao. Effects of H2O and SO2 on catalytic oxidation of NO by V2O5-WO3/TiO2 catalyst[J]. Chinese Journal of Environmental Engineering, 2011, 5(5): 1137-1141.

Citation:

Qin Xudong, Zhang Junfeng, Yan Bin, Wang Jiao. Effects of H2O and SO2 on catalytic oxidation of NO by V2O5-WO3/TiO2 catalyst[J]. Chinese Journal of Environmental Engineering, 2011, 5(5): 1137-1141.

H2O和SO2对V2O5-WO3/TiO2催化剂催化氧化NO的影响

1.
湘潭大学环境科学与工程系，湘潭 411105
基金项目:
教育部新教师基金资助项目(200805301004)
中图分类号: X511

Effects of H2O and SO2 on catalytic oxidation of NO by V2O5-WO3/TiO2 catalyst

1.
Department of Environmental Engineering， Xiangtan University， Xiangtan 411105，China
Fund Project:

摘要: 研究了在120℃的反应温度下，H2O和SO2对V2O5-WO3/TiO2催化剂选择性催化氧化(SCO)NO的影响。结果表明，在H2O和SO2存在的情况下催化剂失活很快，停止通入H2O和SO2后活性不能恢复，但在加热到250℃后催化活性基本恢复。FT-IR分析表明，催化剂表面形成了金属硝酸盐和Ti的硫酸盐，对催化活性有一定影响，但不影响催化剂在250℃下催化活性的恢复。SO2、H2O和NO的竞争吸附与SO2和NO2的铅室反应是影响催化剂活性的主要原因。
- H2O /
- SO2 /
- 催化氧化 /
- 竞争吸附
Abstract: A catalyst of vanadium pentoxide-tungsten trioxide supported on TiO2 was prepared and applied for selective catalytic oxidation (SCO) of NO in the presence of excessive oxygen at 120℃. The effects of H2O and SO2 on the catalyst were studied. The results showed that H2O and SO2 had negative impact on the activity， and the deactivated catalyst can’t recovery when H2O and SO2 were stopped. The FT-IR spectra showed that the metal nitrates and Ti sulfates formed during SCO reaction. The catalyst was deactivated gradually， but its activity could almost be recovered to the initial level after heat treatment at 250℃. The major causes that affect the catalyst activity are the competitive adsorption of SO2，H2O，NO and the reaction of SO2，NO2.
- H2O /
- SO2 /
- catalytic oxidization /
- competitive adsorption

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秦旭东, 张俊丰, 颜斌, 王娇. H2O和SO2对V2O5-WO3/TiO2催化剂催化氧化NO的影响[J]. 环境工程学报, 2011, 5(5): 1137-1141.

引用本文:

秦旭东, 张俊丰, 颜斌, 王娇. H2O和SO2对V2O5-WO3/TiO2催化剂催化氧化NO的影响[J]. 环境工程学报, 2011, 5(5): 1137-1141.

Qin Xudong, Zhang Junfeng, Yan Bin, Wang Jiao. Effects of H2O and SO2 on catalytic oxidation of NO by V2O5-WO3/TiO2 catalyst[J]. Chinese Journal of Environmental Engineering, 2011, 5(5): 1137-1141.

Citation:

Qin Xudong, Zhang Junfeng, Yan Bin, Wang Jiao. Effects of H2O and SO2 on catalytic oxidation of NO by V2O5-WO3/TiO2 catalyst[J]. Chinese Journal of Environmental Engineering, 2011, 5(5): 1137-1141.

H2O和SO2对V2O5-WO3/TiO2催化剂催化氧化NO的影响

1. 湘潭大学环境科学与工程系，湘潭 411105

收稿日期: 2011-01-29

基金项目:

教育部新教师基金资助项目(200805301004)

关键词:

H2O /
SO2 /
催化氧化 /
竞争吸附

摘要: 研究了在120℃的反应温度下，H2O和SO2对V2O5-WO3/TiO2催化剂选择性催化氧化(SCO)NO的影响。结果表明，在H2O和SO2存在的情况下催化剂失活很快，停止通入H2O和SO2后活性不能恢复，但在加热到250℃后催化活性基本恢复。FT-IR分析表明，催化剂表面形成了金属硝酸盐和Ti的硫酸盐，对催化活性有一定影响，但不影响催化剂在250℃下催化活性的恢复。SO2、H2O和NO的竞争吸附与SO2和NO2的铅室反应是影响催化剂活性的主要原因。

English Abstract

Effects of H2O and SO2 on catalytic oxidation of NO by V2O5-WO3/TiO2 catalyst

1. Department of Environmental Engineering， Xiangtan University， Xiangtan 411105，China

Received Date: 2011-01-29

Fund Project:

Keywords:

Abstract: A catalyst of vanadium pentoxide-tungsten trioxide supported on TiO2 was prepared and applied for selective catalytic oxidation (SCO) of NO in the presence of excessive oxygen at 120℃. The effects of H2O and SO2 on the catalyst were studied. The results showed that H2O and SO2 had negative impact on the activity， and the deactivated catalyst can’t recovery when H2O and SO2 were stopped. The FT-IR spectra showed that the metal nitrates and Ti sulfates formed during SCO reaction. The catalyst was deactivated gradually， but its activity could almost be recovered to the initial level after heat treatment at 250℃. The major causes that affect the catalyst activity are the competitive adsorption of SO2，H2O，NO and the reaction of SO2，NO2.

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H2O和SO2对V2O5-WO3/TiO2催化剂催化氧化NO的影响

Effects of H2O and SO2 on catalytic oxidation of NO by V2O5-WO3/TiO2 catalyst

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H2O和SO2对V2O5-WO3/TiO2催化剂催化氧化NO的影响

English Abstract

Effects of H2O and SO2 on catalytic oxidation of NO by V2O5-WO3/TiO2 catalyst

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