聚合硅酸钛铝复合絮凝剂的结构及性能

宋敏娟; 刘红; 刘娟; 黄青; 宋卫坤

环境工程学报

聚合硅酸钛铝复合絮凝剂的结构及性能

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宋敏娟, 刘红, 刘娟, 黄青, 宋卫坤. 聚合硅酸钛铝复合絮凝剂的结构及性能[J]. 环境工程学报, 2012, 6(8): 2661-2665.

引用本文:

宋敏娟, 刘红, 刘娟, 黄青, 宋卫坤. 聚合硅酸钛铝复合絮凝剂的结构及性能[J]. 环境工程学报, 2012, 6(8): 2661-2665.

Song Minjuan, Liu Hong, Liu Juan, Huang Qing, Song Weikun. Structure and performance of composite flocculant poly-titanium-aluminum-silicate[J]. Chinese Journal of Environmental Engineering, 2012, 6(8): 2661-2665.

Citation:

Song Minjuan, Liu Hong, Liu Juan, Huang Qing, Song Weikun. Structure and performance of composite flocculant poly-titanium-aluminum-silicate[J]. Chinese Journal of Environmental Engineering, 2012, 6(8): 2661-2665.

聚合硅酸钛铝复合絮凝剂的结构及性能

1.
武汉科技大学冶金矿产资源高效利用与造块湖北省重点实验室，武汉430081
2.
黄石理工学院环境科学与工程学院，黄石435000
3.
武汉科技大学耐火材料与高温陶瓷国家重点实验室培育基地，武汉430081
4.
中国水利水电科学研究院水利研究所，北京100048
基金项目:
湖北省武汉市科技计划项目(200861113462)
中图分类号: X703.1

Structure and performance of composite flocculant poly-titanium-aluminum-silicate

1.
Hubei Key Laboratory for Efficient Utilization and Agglomeration of Metallurgic Mineral Resources， Wuhan University of Science and Technology， Wuhan 430081， China
2.
Environmental Science and Engineering College， Huangshi Institute of Technology， Huangshi 435000， China
3.
Cultivation Base for State Key Laboratory of Refractories and High-Temperature Ceramics， Wuhan University of Science and Technology， Wuhan 430081， China
4.
Department of Irrigation and Drainage， China Institute of Water Resources and Hydropower Research， Beijing 100048， China
Fund Project:

摘要: 为了克服有机絮凝剂的二次投加及有毒性的缺点，以硅酸钠、硫酸钛、硫酸铝为原料，制备了聚合硅酸钛铝(PTAS)无机高分子复合絮凝剂处理模拟江水。结果表明，在n(Ti+Al)∶n (Si)=1∶3，n (Ti)∶n (Al)=1∶5，模拟江水pH值为5～9.3，絮凝剂投加量为0.3 mmol/L(以金属离子计)时， PTAS对模拟江水的混凝效果最好，除浊率达到92.5%以上。此外，通过X-射线衍射说明聚硅酸与硫酸铝、硫酸钛不是单纯的原料复合；红外吸收光谱显示钛、铝离子及其水解聚合产物可与共存的聚硅酸生成Si—O—Al键和Ti—O—Si键；激光粒度分析表明PTAS在聚合过程中粒度并没有明显变化，但均比聚硅酸粒径大。
- 聚合硅酸钛铝 /
- 絮凝 /
- 结构 /
- 模拟江水
Abstract: Inorganic polymeric composite flocculant， poly-titanium-aluminum-silicate(PTAS)， was prepared by using sodium silicate， titanium sulfate， aluminum sulfate as raw materials which could avoid secondary dosing and toxicity produced by organic flocculants in treating synthetic river water. The results showed that PTAS exhibited the best turbidity removal rate， up to 92.5% when the n (Ti+Al)∶n (Si) was 1∶3， the n (Ti)∶n (Al) was 1∶5， the pH value of synthetic river water was from 5 to 9.3， the dosage of flocculant was 0.3 mmol/L. In addition， it was speculated from X-ray diffraction that PTAS was not a simple compound of raw materials. The infrared spectrums indicated that Si—O—Al bond and Ti—O—Si bond could be formed by titanium， aluminum ions as well as their hydrolysis aggregated product with coexisted polysilicic acid. The laser particle size showed that PTAS particle size was not changed obviously in aggregation process， but larger than polysilicic acid.
- poly-titanium-aluminum-silicate(PTAS) /
- flocculation /
- structure /
- synthetic river water

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宋敏娟, 刘红, 刘娟, 黄青, 宋卫坤. 聚合硅酸钛铝复合絮凝剂的结构及性能[J]. 环境工程学报, 2012, 6(8): 2661-2665.

引用本文:

宋敏娟, 刘红, 刘娟, 黄青, 宋卫坤. 聚合硅酸钛铝复合絮凝剂的结构及性能[J]. 环境工程学报, 2012, 6(8): 2661-2665.

Citation:

聚合硅酸钛铝复合絮凝剂的结构及性能

1. 武汉科技大学冶金矿产资源高效利用与造块湖北省重点实验室，武汉430081
2. 黄石理工学院环境科学与工程学院，黄石435000
3. 武汉科技大学耐火材料与高温陶瓷国家重点实验室培育基地，武汉430081
4. 中国水利水电科学研究院水利研究所，北京100048

收稿日期: 2011-07-06

基金项目:

湖北省武汉市科技计划项目(200861113462)

关键词:

摘要: 为了克服有机絮凝剂的二次投加及有毒性的缺点，以硅酸钠、硫酸钛、硫酸铝为原料，制备了聚合硅酸钛铝(PTAS)无机高分子复合絮凝剂处理模拟江水。结果表明，在n(Ti+Al)∶n (Si)=1∶3，n (Ti)∶n (Al)=1∶5，模拟江水pH值为5～9.3，絮凝剂投加量为0.3 mmol/L(以金属离子计)时， PTAS对模拟江水的混凝效果最好，除浊率达到92.5%以上。此外，通过X-射线衍射说明聚硅酸与硫酸铝、硫酸钛不是单纯的原料复合；红外吸收光谱显示钛、铝离子及其水解聚合产物可与共存的聚硅酸生成Si—O—Al键和Ti—O—Si键；激光粒度分析表明PTAS在聚合过程中粒度并没有明显变化，但均比聚硅酸粒径大。

English Abstract

Structure and performance of composite flocculant poly-titanium-aluminum-silicate

1. Hubei Key Laboratory for Efficient Utilization and Agglomeration of Metallurgic Mineral Resources， Wuhan University of Science and Technology， Wuhan 430081， China
2. Environmental Science and Engineering College， Huangshi Institute of Technology， Huangshi 435000， China
3. Cultivation Base for State Key Laboratory of Refractories and High-Temperature Ceramics， Wuhan University of Science and Technology， Wuhan 430081， China
4. Department of Irrigation and Drainage， China Institute of Water Resources and Hydropower Research， Beijing 100048， China

Received Date: 2011-07-06

Fund Project:

Keywords:

Abstract: Inorganic polymeric composite flocculant， poly-titanium-aluminum-silicate(PTAS)， was prepared by using sodium silicate， titanium sulfate， aluminum sulfate as raw materials which could avoid secondary dosing and toxicity produced by organic flocculants in treating synthetic river water. The results showed that PTAS exhibited the best turbidity removal rate， up to 92.5% when the n (Ti+Al)∶n (Si) was 1∶3， the n (Ti)∶n (Al) was 1∶5， the pH value of synthetic river water was from 5 to 9.3， the dosage of flocculant was 0.3 mmol/L. In addition， it was speculated from X-ray diffraction that PTAS was not a simple compound of raw materials. The infrared spectrums indicated that Si—O—Al bond and Ti—O—Si bond could be formed by titanium， aluminum ions as well as their hydrolysis aggregated product with coexisted polysilicic acid. The laser particle size showed that PTAS particle size was not changed obviously in aggregation process， but larger than polysilicic acid.

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聚合硅酸钛铝复合絮凝剂的结构及性能

Structure and performance of composite flocculant poly-titanium-aluminum-silicate

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聚合硅酸钛铝复合絮凝剂的结构及性能

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Structure and performance of composite flocculant poly-titanium-aluminum-silicate

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