高级搜索

铁碳微电解预处理TNT红水

,  ,  ,  ,  ,  , 

downloadPDF

上一篇

下一篇

张默贺, 叶正芳, 赵泉林, 华刚, 马金明, 王延庆, 张德龙. 铁碳微电解预处理TNT红水[J]. 环境工程学报, 2012, 6(9): 3115-3120.
引用本文: 张默贺, 叶正芳, 赵泉林, 华刚, 马金明, 王延庆, 张德龙. 铁碳微电解预处理TNT红水[J]. 环境工程学报, 2012, 6(9): 3115-3120.
shu
Zhang Mohe, Ye Zhengfang, Zhao Quanlin, Hua Gang, Ma Jinming, Wang Yanqing, Zhang Delong. Pretreatment of TNT red water by iron-carbon micro-electrolysis process[J]. Chinese Journal of Environmental Engineering, 2012, 6(9): 3115-3120.
Citation: Zhang Mohe, Ye Zhengfang, Zhao Quanlin, Hua Gang, Ma Jinming, Wang Yanqing, Zhang Delong. Pretreatment of TNT red water by iron-carbon micro-electrolysis process[J]. Chinese Journal of Environmental Engineering, 2012, 6(9): 3115-3120.
shu

铁碳微电解预处理TNT红水

  • 1.

    北京大学环境工程系,水沙科学教育部重点实验室,北京 100871

  • 2.

    五洲工程设计研究院,北京 100053

  • 3.

    湖北东方化工有限公司,宜城 441404

  • 4.

    山西北方兴安化学工业有限公司,太原 030008

  • 基金项目:

    国防科工委"十一五"重大专项资金项目

  • 中图分类号: X703.1

Pretreatment of TNT red water by iron-carbon micro-electrolysis process

  • 1.

    The Key Laboratory of Water and Sediment Sciences, Ministry of Education, Department of Environmental Engineering, Peking University, Beijing 100871, China

  • 2.

    Wuzhou Engineering Design and Research Institute, Beijing 100053, China

  • 3.

    Hubei Dongfang Chemical Industry Limited Company, Yicheng 441404, China

  • 4.

    Shanxi North Xingan Chemical Industry Limited Company, Taiyuan 030008, China

  • Fund Project:

  • 摘要: 为了寻求经济有效的TNT红水处理技术,对铁碳微电解工艺预处理TNT红水进行了研究。结果表明,当pH值为3,铁碳质量比0.25∶1,曝气3 h时,COD去除率达到10.1%,2,4-二硝基甲苯-3-磺酸(2,4-dinitrotoluene-3-sulfonic acid, 2,4-DNT-3-SA)和2,4-二硝基甲苯-5-磺酸(2,4-dinitrotoluene-5-sulfonic acid, 2,4-DNT-5-SA)的去除率分别可达到10.4%和12.0%;铁碳微电解可以将TNT红水中部分有机物进行转化或去除,经过铁碳微电解后,红水中的有机物从原来的11种变为16种。大部分有机物得到了不同程度的转化,其中1,3,5-三硝基甲苯相对含量降低得最多。
    Abstract: To investigate the cost-effective pretreatment technology of TNT red water, iron-carbon micro-electrolysis process was studied. When pH was 3 and the mass ratio of iron and carbon was 0.25∶1 with the aeration for 3 h, the removal efficiency of COD reached 10.1%, and the removal efficiencies of 2,4-dinitrotoluene-3-sulfonic acid (2,4-DNT-3-SA) and 2,4-dinitrotoluene-5-sulfonic acid (2,4-DNT-5-SA) were 10.4% and 12.0%, respectively. After the iron-carbon microelectrolysis, the number of the compounds in TNT red water was changed from 11 to 16 species. Most organic compounds were transformed to some extent, especially 1,3,5-trinitrotoluene.
  • 加载中
  • [1] 周军,郭新超,金奇庭,等. 生化法处理炸药废水研究进展. 中国给水排水,2006,16(9):50-52 Zhou Jun,Guo Xinchao,Jin Qiting,et al. Research review on biochemical treatment for explosives wastewater. China Water & Wastewater,2006,16(9):50-52 (in Chinese)
    [2] Jehuda Y.,Shmuel Z. Modern Methods and Applications in Analysis of Explosives. England: John Wiley & Sons Ltd.,1996.212-214
    [3] 孙荣康,魏运洋. 硝基化合物炸药化学与工艺学. 兵器工业出版社,1992.300-303
    [4] 肖忠良,胡双启,吴晓青,等. 火炸药的安全与环保技术. 北京: 北京理工大学出版社,2006,268
    [5] Janda V.,Vasek P.,Bizova J.,et al. Kinetic models for volatile chlorinated hydrocarbons removal by zero-valent iron. Chemosphere,2004,54(7):917-925
    [6] Feitz A.J.,Joo S.H.,Guan J.,et al. Oxidative transformation of contaminants using colloidal zero-valent iron. Colloids and Surfaces a-Physicochemical and Engineering Aspects,2005,265(1-3):88-94
    [7] 李德生,王宝山. 曝气铁炭微电解工艺预处理高浓有机化工废水. 中国给水排水,2003,19(10):58-60 Li Desheng,Wang Baoshan. Pretreatment on high concentrations of organic chemical wastewater using iron-carbon micro-electrolysis process with aeration. China Water & Wastewater,2003,19(10):58-60 (in Chinese)
    [8] 余宗学. 微电解处理间二硝基苯生产废水的研究. 环境科学与技术,2004,27(3):68-70 Yu Zongxue. Research on the treatment of m-dinitrobenzene wastewater by micro-electrolysis. Environmental Science and Technology,2004,27(3):68-70 (in Chinese)
    [9] 丁军委,江秀华. 微电解-催化氧化-吸附法处理二硝基苯废水. 工业安全与环保,2004,32(6):20-23 Ding Junwei,Jiang Xiuhua. Treat diaitrobenzene wastewater by micro-electrolysis-catalyzed oxidation-absorption process. Industrial Safety and Environmental Protection,2004,32(6):20-23 (in Chinese)
    [10] 俞飞,赵克强. 微电解法对硝化废水的预处理研究. 安全与环境学报,2004,4(Sup):90-92 Yu Fei,Zhao Keqiang. Research on the pretreatment of nitrification wastewater by micro-electrolysis. Journal of Safety and Environment,2004,4(Sup):90-92 (in Chinese)
    [11] 石金晔,王三反,高晓东. 铁碳微电解法预处理炸药生产废水. 中国给水排水,2009,25(7):59-61 Shi Jinye,Wang Sanfan,Gao Xiaodong. Pretreatment of wastewater from explosive production by iron-carbon micro-electrolysis process. China Water & Wastewater,2009,25(7):59-61 (in Chinese)
    [12] 顾炳林,钟梅英,陈慧娣,等. 铁炭微电解-Fenton组合工艺处理炸药废水. 水处理技术,2009,35(9):101-113 Gu Binglin,Zhong Meiying,Chen Huidi,et al. Treatment of explosives wastewater by ferric-carbon micro-electrolysis combined Fenton oxidation process. Technology of Water Treatment,2009,35(9):101-113 (in Chinese)
    [13] 叶正芳,王中友,牟敬海,等. 微电解与I-BAF组合工艺处理硝基甲苯废水中试. 环境工程,2008,26(4):73-75 Ye Zhengfang,Wang Zhongyou,Mou Jinghai,et al. Pilot scale of nitrotoluene wastewater by micro-electrolysis combined I-BAF process. Environment Engineering,2008,26(4):73-75 (in Chinese)
    [14] 徐东辉,李德生,姚智文. 铁炭曝气微电解对炸药废水的试验研究. 环境科学与技术,2006,29(11):79-81 Xu Donghui,Li Desheng,Yao Zhiwen. Research on explosives wastewater by iron-carbon micro-electrolysis with aeration. Environmental Science and Technology,2006,29(11):79-81 (in Chinese)
    [15] Nam S.,Tratnyek P.G. Reduction of azo dyes with zero-valent iron. Water Research,2000,34(6):1837-1845
    [16] Ghauch A. Degradation of benomyl,picloram,and dicamba in a conical apparatus by zero-valent iron powder. Chemosphere,2001,43(8):1109-1117
    [17] Keum Y.S.,Li Q.X. Reduction of nitroaromatic pesticides with zero-valent iron. Chemosphere,2004,54(3):255-263
    [18] Preiss A.,Bauer A.,Berstermann H.M.,et al. Advanced high-performance liquid chromatography method for highly polar nitroaromatic compounds in ground water samples from ammunition waste sites. Journal of Chromatography A,2009,1216(25):4968-4975
    [19] 胡玉洁,华兆哲,王璋,等. 黄姜废水的铁炭微电解-混凝预处理研究. 环境污染治理技术与设备,2004,5(9):44-47 Hu Yujie,Hua Zhaozhe,Wang Zhan,et al. Study on the Dioscorea zingiberensis C. H. wright wastewater pretreatment of iron-carbon micro-electrolysis-coagulation. Techniques and Equipment for Environmental Pollution Control,2004,5(9):44-47 (in Chinese)
  • 加载中
WeChat 点击查看大图
计量
  • 文章访问数:  2546
  • HTML全文浏览数:  1302
  • PDF下载数:  2179
  • 施引文献:  0
出版历程
  • 收稿日期:  2011-07-20
  • 刊出日期:  2012-09-14
张默贺, 叶正芳, 赵泉林, 华刚, 马金明, 王延庆, 张德龙. 铁碳微电解预处理TNT红水[J]. 环境工程学报, 2012, 6(9): 3115-3120.
引用本文: 张默贺, 叶正芳, 赵泉林, 华刚, 马金明, 王延庆, 张德龙. 铁碳微电解预处理TNT红水[J]. 环境工程学报, 2012, 6(9): 3115-3120.
shu
Zhang Mohe, Ye Zhengfang, Zhao Quanlin, Hua Gang, Ma Jinming, Wang Yanqing, Zhang Delong. Pretreatment of TNT red water by iron-carbon micro-electrolysis process[J]. Chinese Journal of Environmental Engineering, 2012, 6(9): 3115-3120.
Citation: Zhang Mohe, Ye Zhengfang, Zhao Quanlin, Hua Gang, Ma Jinming, Wang Yanqing, Zhang Delong. Pretreatment of TNT red water by iron-carbon micro-electrolysis process[J]. Chinese Journal of Environmental Engineering, 2012, 6(9): 3115-3120.
shu

铁碳微电解预处理TNT红水

  • 1.  北京大学环境工程系,水沙科学教育部重点实验室,北京 100871
  • 2.  五洲工程设计研究院,北京 100053
  • 3.  湖北东方化工有限公司,宜城 441404
  • 4.  山西北方兴安化学工业有限公司,太原 030008
  • 收稿日期:  2011-07-20
基金项目:

国防科工委"十一五"重大专项资金项目

摘要: 为了寻求经济有效的TNT红水处理技术,对铁碳微电解工艺预处理TNT红水进行了研究。结果表明,当pH值为3,铁碳质量比0.25∶1,曝气3 h时,COD去除率达到10.1%,2,4-二硝基甲苯-3-磺酸(2,4-dinitrotoluene-3-sulfonic acid, 2,4-DNT-3-SA)和2,4-二硝基甲苯-5-磺酸(2,4-dinitrotoluene-5-sulfonic acid, 2,4-DNT-5-SA)的去除率分别可达到10.4%和12.0%;铁碳微电解可以将TNT红水中部分有机物进行转化或去除,经过铁碳微电解后,红水中的有机物从原来的11种变为16种。大部分有机物得到了不同程度的转化,其中1,3,5-三硝基甲苯相对含量降低得最多。

English Abstract

    全文HTML

参考文献 (19)

返回顶部

目录

/

返回文章
返回

Copyright © 2019 中国科学院生态环境研究中心