城市生活垃圾焚烧处理过程中重金属迁移规律研究

张厚坚, 刘海娟, 黄世清, 温晓兰, 李兴坛, 赵付一. 城市生活垃圾焚烧处理过程中重金属迁移规律研究[J]. 环境工程学报, 2013, 7(11): 4569-4574.
引用本文: 张厚坚, 刘海娟, 黄世清, 温晓兰, 李兴坛, 赵付一. 城市生活垃圾焚烧处理过程中重金属迁移规律研究[J]. 环境工程学报, 2013, 7(11): 4569-4574.
Zhang Houjian, Liu Haijuan, Huang Shiqing, Wen Xiaolan, Li Xingtan, Zhao Fuyi. Study on the migration rule of heavy metal in waste incineration[J]. Chinese Journal of Environmental Engineering, 2013, 7(11): 4569-4574.
Citation: Zhang Houjian, Liu Haijuan, Huang Shiqing, Wen Xiaolan, Li Xingtan, Zhao Fuyi. Study on the migration rule of heavy metal in waste incineration[J]. Chinese Journal of Environmental Engineering, 2013, 7(11): 4569-4574.

城市生活垃圾焚烧处理过程中重金属迁移规律研究

  • 基金项目:

    厦门市科技计划项目(3502Z20111039)

  • 中图分类号: X705

Study on the migration rule of heavy metal in waste incineration

  • Fund Project:
  • 摘要: 通过采集厦门2个垃圾焚烧发电厂进厂垃圾、渗滤液、飞灰、炉渣和烟气样品,分析垃圾组成成分及各组分的重金属含量,结果表明,垃圾中以厨余、橡塑类和纸类为主,共占到垃圾干基的78.08%,重金属含量大小次序为Zn>Cu>Pb>Cr>Ni>Cd>Hg;垃圾渗滤液中除Zn外,其他金属的含量都较低,一厂渗滤液中重金属Ni、Zn迁移量较大,分别达到24.46%和8.52%。二厂渗滤液中重金属的迁移有相同的趋势,但含量相对较高。垃圾焚烧后其重金属主要分布在飞灰和废渣中,烟气中的含量非常少,不同金属的含量均有差别,这与金属的性质有很大关系;通过浸出毒性分析,飞灰中重金属酸溶态含量多,容易浸出,属于危险废物。同时,不同烟气处理工艺产生的飞灰的重金属浸出量有很大差别。
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  • [1] Kuen S. W.,Kung Y. C.,Chin C. T.,et al. The effects of FeCl3 on the distribution of tile heavy metals Cd,Cu,Cr,and Zn in a simulated multimetal incineration system.Environment International,2001,26(4):257-263
    [2] 罗宇. 垃圾焚烧系统中重金属的分配及处理研究.重庆:重庆大学博士学位论文,2004 Luo Y. Study on heavy metal distribution and treatment in MSW incineration. Chongqing:Doctor Dissertation of Chongqing University, 2004(in Chinese)
    [3] 祝建中,钟雄,梁好. 垃圾焚烧工况对重金属分布特性的研究.苏州大学学报(自然科学版), 2005,21 (1):66-70 Zhu J.Z.,Zhong X., Liang H.,Studies on characteristics of distribution of heavy metals over waste incineration. Journal of Suzhou University(Natural Science), 2005,21 (1):66-70 (in Chinese)
    [4] 张衍国,武俊,李清海,等.垃圾焚烧重金属迁移特性及其影响因素.环境污染治理技术与设备,2005,6 (12): 6-12 Zhang Y.,Wu J.,Li Q.,et al.Migration properties of heavy metals and principal influencing factors on migration.Techniques and Equipment for Environmental Pollution Control,2005,6 (12): 6-12(in Chinese)
    [5] Hasan B.,Hermann M.Factors determing the element behavior in municipal solid incinerators. Environ. Sci. Technol.,2000,34(12):2507-2512
    [6] 辛美静,仲兆平,金保升,等.城市生活垃圾焚烧处理中重金属污染的形成与控制.能源研究与利用,2002,(5):20-23 Xin M.J.,Zhong Z.P.,Jin B.S., et al. The formation and control of heavy metal pollution in waste incineration. Energy Research & Utilization,2002,(5):20-23 (in Chinese)
    [7] 冯素萍,裘娜,沈永.微波消解-AAS测定垃圾焚烧飞灰中重金属.中国测试技术,2008,34(3):91-94 Feng S.P., Qiu N., Shen Y.,et al.Heavy metal determination in waste incineration fly ash by microwave digestion-AAS.China Measurement& Testing Technology,2008,34(3): 91-94(in Chinese)
    [8] 李波,林勤保,宋欢. 微波消解-ICP-AES测定食品塑料包装中钛、铅、铬和镉.化学研究与应用,2011,23(2):252-256 Li B.,Lin Q.B.,Song H.,Determination of titanium,lead,chromium,cadmium in plastics for food packaging by microwave digestion-ICP-AES.Chemical Research and Application,2011,23(2):252-256(in Chinese)
    [9] Tessier A., Campbell P. G. C., Bisson M.Sequential extraction procedure for the speciation of particulate trace metals. Analytical Chemistry, 1979, 51(7): 844-850
    [10] Juan W., Wen H. W., Wei X., et al. Mercury removals by existing pollutants control devices of four coal-fired power plants in China. Journal of Environmental Sciences,2011,23(11): 1839-1844
    [11] Jia S., Marta F. B., Stefaan J. R. S.Kinetic study of accelerated carbonation of municipal solid waste incinerator air pollution control residues for sequestration of flue gas CO2.Energy & Environmental Science, 2008,1(3): 370-377
    [12] 罗宇,杨宏毅.MBR工艺应用于垃圾渗滤液处理的研究.环境工程,2004,24(2):25-38 Luo Y.,Yang H.,Y.,Study on application of MBR process to treatment of refuse leachate.Environmental Engineering,2004,24(2):25-38 (in Chinese)
    [13] 宋立杰.生活垃圾焚烧炉渣特性及其在废水处理中的应用研究.上海:同济大学博士学位论文,2006 Li J.S. Characterizationand recycling of the bottom ash of municipal solid waste incinerator for wastewater treatment.Shanghai:Doctor Dissertation of Tongji University,2006(in Chinese)
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出版历程
  • 收稿日期:  2013-02-12
  • 刊出日期:  2013-11-21
张厚坚, 刘海娟, 黄世清, 温晓兰, 李兴坛, 赵付一. 城市生活垃圾焚烧处理过程中重金属迁移规律研究[J]. 环境工程学报, 2013, 7(11): 4569-4574.
引用本文: 张厚坚, 刘海娟, 黄世清, 温晓兰, 李兴坛, 赵付一. 城市生活垃圾焚烧处理过程中重金属迁移规律研究[J]. 环境工程学报, 2013, 7(11): 4569-4574.
Zhang Houjian, Liu Haijuan, Huang Shiqing, Wen Xiaolan, Li Xingtan, Zhao Fuyi. Study on the migration rule of heavy metal in waste incineration[J]. Chinese Journal of Environmental Engineering, 2013, 7(11): 4569-4574.
Citation: Zhang Houjian, Liu Haijuan, Huang Shiqing, Wen Xiaolan, Li Xingtan, Zhao Fuyi. Study on the migration rule of heavy metal in waste incineration[J]. Chinese Journal of Environmental Engineering, 2013, 7(11): 4569-4574.

城市生活垃圾焚烧处理过程中重金属迁移规律研究

  • 1. 厦门市环境能源投资发展有限公司, 厦门 361004
基金项目:

厦门市科技计划项目(3502Z20111039)

摘要: 通过采集厦门2个垃圾焚烧发电厂进厂垃圾、渗滤液、飞灰、炉渣和烟气样品,分析垃圾组成成分及各组分的重金属含量,结果表明,垃圾中以厨余、橡塑类和纸类为主,共占到垃圾干基的78.08%,重金属含量大小次序为Zn>Cu>Pb>Cr>Ni>Cd>Hg;垃圾渗滤液中除Zn外,其他金属的含量都较低,一厂渗滤液中重金属Ni、Zn迁移量较大,分别达到24.46%和8.52%。二厂渗滤液中重金属的迁移有相同的趋势,但含量相对较高。垃圾焚烧后其重金属主要分布在飞灰和废渣中,烟气中的含量非常少,不同金属的含量均有差别,这与金属的性质有很大关系;通过浸出毒性分析,飞灰中重金属酸溶态含量多,容易浸出,属于危险废物。同时,不同烟气处理工艺产生的飞灰的重金属浸出量有很大差别。

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