填料塔中Na2CO3吸收高浓度H2S的传质特性

罗洋, 盛宇星, 曹宏斌. 填料塔中Na2CO3吸收高浓度H2S的传质特性[J]. 环境工程学报, 2014, 8(4): 1561-1566.
引用本文: 罗洋, 盛宇星, 曹宏斌. 填料塔中Na2CO3吸收高浓度H2S的传质特性[J]. 环境工程学报, 2014, 8(4): 1561-1566.
Luo Yang, Sheng Yuxing, Cao Hongbin. Mass transfer characteristics of absorption of high concentration of H2S by sodium carbonate in packed column[J]. Chinese Journal of Environmental Engineering, 2014, 8(4): 1561-1566.
Citation: Luo Yang, Sheng Yuxing, Cao Hongbin. Mass transfer characteristics of absorption of high concentration of H2S by sodium carbonate in packed column[J]. Chinese Journal of Environmental Engineering, 2014, 8(4): 1561-1566.

填料塔中Na2CO3吸收高浓度H2S的传质特性

  • 基金项目:

    国家“863”高技术研究发展计划项目(2011AA060904)

  • 中图分类号: X511

Mass transfer characteristics of absorption of high concentration of H2S by sodium carbonate in packed column

  • Fund Project:
  • 摘要: 在填料吸收塔中考察了Na2CO3溶液吸收高浓度H2S气体的气液传质特性。通过测量填料塔进出口气体中H2S浓度计算了Na2CO3溶液吸收高浓度H2S气体的总体积传质系数(KGa),并研究了进气流速、吸收液流量、吸收温度和吸收液浓度对KGa的影响。结果表明,KGa随Na2CO3浓度、吸收液流量的增加而增加,随吸收温度、进气流速的升高而降低;在高浓度H2S吸收过程中液相传质阻力不能忽略。
  • 加载中
  • [1] GBZ 2.1-2007.工作场所有害因素职业接触限值第1部分:化学有害因素, 2007
    [2] 周金堂, 杨伟彪, 赵安军, 等.井场硫化氢气体检测方法及防护措施.录井技术, 2004, 15(2):1-5 Zhou Jintang, Yang Weibiao, Zhao Anjun, et al.Detection methods and protection measures of wellsite H2S gas.Mud Logging Engineering, 2004, 15(2):1-5(in Chinese)
    [3] 鄂利海, 栾耕时, 武开军, 等.用Fe3+盐间接电化学氧化法吸收硫化氢制氢工艺.抚顺石油学院学报, 1998, 18(4):9-12 E Lihai, Luan Gengshi, Wu Kaijun, et al.Process of absorbing H2S and production H2 using Fe3+ indirected electrochemical method.Journal of Fushun Petroleum Institute, 1998, 18(4):9-12(in Chinese)
    [4] Anani A.A., Mao Z., White R.E., et al.Electrochemical production of hydrogen and sulfur by low-temperature decomposition of hydrogen sulfide in an aqueous alkaline-solution.Journal of the Electrochemical Society, 1990, 137(9):2703-2709
    [5] 田林钧.高浓度硫化氢废气回收硫磺.农药工业, 1978, (6):10-15
    [6] 朱玉霜, 朱建光.浮选药剂的化学原理.长沙:中南工业大学出版社, 1996
    [7] 姜怡娇, 宁平.硫化氢废气净化进展.云南环境科学, 2002, 21(3):40-44 Jiang Yijiao, Ning Ping.Updates on removing hydrogen sulfide from waste gas.Yunnan Environmental Science, 2002, 21(3):40-44(in Chinese)
    [8] 姜茹.沼气中硫化氢的脱除技术研究.南京:南京大学硕士学位论文, 2011 Jiang Ru.Study on removal technology of H2S in biogas.Nanjing:Master Dissertation of Nanjing University, 2011(in Chinese)
    [9] 杨海梅.LO-CAT硫回收工艺技术及其应用前景.无机盐工业, 2011, 43(10):9-11, 32 Yang Haimei.LO-CAT sulfur recovery technique and application prospect thereof.Inorganic Chemicals Industry, 2011, 43(10):9-11, 32(in Chinese)
    [10] Yih S.M., Lai H.C.Simultaneous absorption of carbon-dioxide and hydrogen-sulfide in hot carbonate solutions in a packed absorber-stripper unit.Chemical Engineering Communications, 1987, 51 (1-6):277-290
    [11] Yih S.M., Sun C.C.Simultaneous absorption of hydrogen-sulfide and carbon-dioxide into patassium carbonate solution with or without amine promoters.Chemical Engineering Journal and the Biochemical Engineering Journal, 1987, 34 (2):65-72
    [12] Garner F.H., Long R., Pennell A.The selective absorption of hydrogen sulphide in carbonate solutions.Journal of Applied Chemistry, 1958, 8(5):325-336
    [13] 尚方毓.用氢氧化钠溶液吸收硫化氢制取硫化钠工业技术.无机盐工业, 2012, 44(2):42-43 Shang Fangyu.Industrial technology of preparing sodium sulfide from absorption of hydrogen sulfide with sodium hydroxide solution.Inorganic Chemicals Industry, 2012, 44(2):42-43(in Chinese)
    [14] 杨宏远, 齐永红, 刘彦婷.碱吸收法对酸性气体的处理效能研究.山西化工, 2012, 32(4):34-35, 58 Yang Hongyuan, Qi Yonghong, Liu Yanting.The research of treatment efficiency on acid gas with alkali absorption method.Shanxi Chemical Industry, 2012, 32(4):34-35, 58(in Chinese)
    [15] 张永, 王学谦, 宁平, 等.碳酸钠溶液吸收处理硫化氢实验研究.云南化工, 2006, 33(2):32-34 Zhang Yong, Wang Xueqian, Ning Ping, et al.Study on the absorption of hydrogen sulfide by sodium carbonate solution.Yunnan Chemical Technology, 2006, 33(2):32-34(in Chinese)
    [16] Wallin M., Olausson S.Simultaneous absorption of H2S and CO2 into a solution of sodium carbonate.Chemical Engineering Communications, 1993, 123(1):43-59
    [17] Bontozoglou V., Karabelas A.J.Numerical-calculation of simultaneous absorption of H2S and CO2 in aqueous hydroxide solutions.Industrial & Engineering Chemistry Research, 1991, 30(12):2598-2603
    [18] Park K.Y., Kang T.W.Computer-simulation of H2S and CO2 absorption processes.Korean Journal of Chemical Engineering, 1995, 12(1):29-35
    [19] AI-Wohoush M.H., Van Heiningen A.R.P., Kubes G.J.Selective absorption of H2S from a CO2 containing gas in a solution of sodium carbonate.AICHE Symposium Series, 1996, 92(311):106-112
    [20] Dubois L., Thomas D.Comparison of various alkaline solutions for H2S/CO2-selective absorption applied to biogas purification.Chemical Engineering & Technology, 2010, 33(10):1601-1609
    [21] Brettschneider O., Thiele R., Faber R., et al.Experimental investigation and simulation of the chemical absorption in a packed column for the system NH3-CO2-H2S-NaOH-H2O.Separation and Purification Technology, 2004, 39(3):139-159
    [22] Faiz R., Al-Marzouqi M.H2S absorption via carbonate solution in membrane contactors:Effect of species concentrations.Journal of Membrane Science, 2010, 350(1-2):200-210
    [23] GB/T 14678-93.空气质量硫化氢、甲硫醇、甲硫醚和二甲二硫的测定气相色谱法, 1993
    [24] GB/T 11060.1-2010.天然气含硫化合物的测定第1部分:用碘量法测定硫化氢含量, 2010
    [25] Onda K., Sada E., Takeuchi H.Gas absorption with chemical reaction in packed columns.Journal of Chemical Engineering of Japan, 1968, 1(1):62-66
    [26] Ooi S.M.P.Development and demonstration of a new non-equilibrium rate-based process model for the hot potassium carbonate process.Adelaide:Doctor Dissertation of the University of Adelaide, 2009
    [27] Onda K., Takeuchi H., Okumoto Y.Mass transfer coefficients between gas and liquid phases in packed columns.Journal of Chemical Engineering of Japan, 1968, 1(1):56-62
    [28] Danckwerts P.V., Lannus A.Gas-liquid reactions.Journal of the Electrochemical Society, 1970, 117(10):369C-370C
    [29] Seinfeld J.H., Pandis S.N.Atmospheric Chemistry and Physics:From Air Pollution to Climate Change (2nd Edition).John Wiley & Sons, 2006
    [30] 《化学工程手册》编辑委员会.化学工程手册.北京:化学工业出版社, 1989
    [31] 李阳初, 刘雪暖.石油化学工程原理.北京:中国石化出版社, 2008
  • 加载中
计量
  • 文章访问数:  2241
  • HTML全文浏览数:  1506
  • PDF下载数:  993
  • 施引文献:  0
出版历程
  • 收稿日期:  2013-09-13
  • 刊出日期:  2014-03-28
罗洋, 盛宇星, 曹宏斌. 填料塔中Na2CO3吸收高浓度H2S的传质特性[J]. 环境工程学报, 2014, 8(4): 1561-1566.
引用本文: 罗洋, 盛宇星, 曹宏斌. 填料塔中Na2CO3吸收高浓度H2S的传质特性[J]. 环境工程学报, 2014, 8(4): 1561-1566.
Luo Yang, Sheng Yuxing, Cao Hongbin. Mass transfer characteristics of absorption of high concentration of H2S by sodium carbonate in packed column[J]. Chinese Journal of Environmental Engineering, 2014, 8(4): 1561-1566.
Citation: Luo Yang, Sheng Yuxing, Cao Hongbin. Mass transfer characteristics of absorption of high concentration of H2S by sodium carbonate in packed column[J]. Chinese Journal of Environmental Engineering, 2014, 8(4): 1561-1566.

填料塔中Na2CO3吸收高浓度H2S的传质特性

  • 1.  中国科学院过程工程研究所绿色过程与工程重点实验室, 北京 100190
  • 2.  中国科学院大学, 北京 100049
基金项目:

国家“863”高技术研究发展计划项目(2011AA060904)

摘要: 在填料吸收塔中考察了Na2CO3溶液吸收高浓度H2S气体的气液传质特性。通过测量填料塔进出口气体中H2S浓度计算了Na2CO3溶液吸收高浓度H2S气体的总体积传质系数(KGa),并研究了进气流速、吸收液流量、吸收温度和吸收液浓度对KGa的影响。结果表明,KGa随Na2CO3浓度、吸收液流量的增加而增加,随吸收温度、进气流速的升高而降低;在高浓度H2S吸收过程中液相传质阻力不能忽略。

English Abstract

参考文献 (31)

返回顶部

目录

/

返回文章
返回