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Vis/Co-TiO2/KHSO5体系Fenton-光催化协同降解苯酚

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陈晴空, 谢志刚, 吉芳英, 郭倩, 刘亭役, 徐璇. Vis/Co-TiO2/KHSO5体系Fenton-光催化协同降解苯酚[J]. 环境工程学报, 2014, 8(5): 1749-1754.
引用本文: 陈晴空, 谢志刚, 吉芳英, 郭倩, 刘亭役, 徐璇. Vis/Co-TiO2/KHSO5体系Fenton-光催化协同降解苯酚[J]. 环境工程学报, 2014, 8(5): 1749-1754.
shu
Chen Qingkong, Xie Zhigang, Ji Fangying, Guo Qian, Liu Tingyi, Xu Xuan. Synergistic effect of Fenton-photocatalysis through degradation of phenol by Vis/Co-TiO2/KHSO5 reaction system[J]. Chinese Journal of Environmental Engineering, 2014, 8(5): 1749-1754.
Citation: Chen Qingkong, Xie Zhigang, Ji Fangying, Guo Qian, Liu Tingyi, Xu Xuan. Synergistic effect of Fenton-photocatalysis through degradation of phenol by Vis/Co-TiO2/KHSO5 reaction system[J]. Chinese Journal of Environmental Engineering, 2014, 8(5): 1749-1754.
shu

Vis/Co-TiO2/KHSO5体系Fenton-光催化协同降解苯酚

  • 1.

    重庆大学三峡库区生态环境教育部重点实验室, 重庆 400045

  • 2.

    重庆文理学院材料与化工学院, 重庆 402160

  • 3.

    林同棪国际工程咨询(中国)有限公司, 重庆 401121

  • 基金项目:

    国家自然科学基金资助项目（51108483）

    中央高校基本科研业务费专项资金项目（CDJXS12210002）

    教育部科技创新工程重大项目培育资金项目（708071）

    重庆市自然科学基金资助项目（cstcjjA20002）

  • 中图分类号: X703

Synergistic effect of Fenton-photocatalysis through degradation of phenol by Vis/Co-TiO2/KHSO5 reaction system

  • 1.

    Key Laboratory of Three Gorges Reservoir Region's Eco-Environment, Ministry of Education, Chongqing University, Chongqing 400045, China

  • 2.

    College of Materials and Chemical Engineering, Chongqing University of Arts and Sciences, Chongqing 402160, China

  • 3.

    T. Y. Lin International Engineering Consulting (China) Co. Ltd., Chongqing 401121, China

  • Fund Project:

  • 摘要: 通过溶胶-凝胶法制备了同时具有可见光（Vis）光催化和Fenton催化双重活性的Co-TiO2催化剂。通过对比Vis/Co-TiO2/KHSO5、Co-TiO2/KHSO5和Vis/Co-TiO2 3种体系对苯酚的降解效果，Vis/Co-TiO2/KHSO5表现出明显的Fenton-光催化协同作用。进一步研究pH值、KHSO5与苯酚摩尔比（nKHSO5：nC6H6O）和Co-TiO2投加量（mCo-TiO2）对Fenton-光催化协同降解苯酚效果的影响。结果表明，pH=6.9、nKHSO5：nC6H6O=10：1、mCo-TiO2=1.0 g/L时，降解率达100%。最后，结合XRD、XPS和UV-DRS等手段和催化活性实验数据分析了Vis/Co-TiO2/KHSO5体系的催化机理。
    Abstract: The Co-TiO2 catalyst, which has both Fenton and visible light phocatalytic activities, was prepared by the sol-gel method. Its catalytic activities were measured by the degradation of phenol through comparative experiments of Vis/Co-TiO2/KHSO5, Co-TiO2/KHSO5 and Vis/Co-TiO2 reaction systems. The Vis/Co-TiO2/KHSO5 process represented the obvious synergistic effect of Fenton and photocatalysis, and the results showed that when the pH=6.9, nKHSO5:nC6H6O=10:1 and mCo-TiO2=1.0 g/L, the degradation rate of phenol reached 100%. Finally, the catalytic mechanism was also studied through XRD, UV-DRS, XPS and phenol degradation tests.
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出版历程
  • 收稿日期:  2013-08-17
  • 刊出日期:  2014-05-06
陈晴空, 谢志刚, 吉芳英, 郭倩, 刘亭役, 徐璇. Vis/Co-TiO2/KHSO5体系Fenton-光催化协同降解苯酚[J]. 环境工程学报, 2014, 8(5): 1749-1754.
引用本文: 陈晴空, 谢志刚, 吉芳英, 郭倩, 刘亭役, 徐璇. Vis/Co-TiO2/KHSO5体系Fenton-光催化协同降解苯酚[J]. 环境工程学报, 2014, 8(5): 1749-1754.
shu
Chen Qingkong, Xie Zhigang, Ji Fangying, Guo Qian, Liu Tingyi, Xu Xuan. Synergistic effect of Fenton-photocatalysis through degradation of phenol by Vis/Co-TiO2/KHSO5 reaction system[J]. Chinese Journal of Environmental Engineering, 2014, 8(5): 1749-1754.
Citation: Chen Qingkong, Xie Zhigang, Ji Fangying, Guo Qian, Liu Tingyi, Xu Xuan. Synergistic effect of Fenton-photocatalysis through degradation of phenol by Vis/Co-TiO2/KHSO5 reaction system[J]. Chinese Journal of Environmental Engineering, 2014, 8(5): 1749-1754.
shu

Vis/Co-TiO2/KHSO5体系Fenton-光催化协同降解苯酚

  • 1. 重庆大学三峡库区生态环境教育部重点实验室, 重庆 400045
  • 2. 重庆文理学院材料与化工学院, 重庆 402160
  • 3. 林同棪国际工程咨询(中国)有限公司, 重庆 401121
  • 收稿日期:  2013-08-17
基金项目:

国家自然科学基金资助项目（51108483）

中央高校基本科研业务费专项资金项目（CDJXS12210002）

教育部科技创新工程重大项目培育资金项目（708071）

重庆市自然科学基金资助项目（cstcjjA20002）

摘要: 通过溶胶-凝胶法制备了同时具有可见光（Vis）光催化和Fenton催化双重活性的Co-TiO2催化剂。通过对比Vis/Co-TiO2/KHSO5、Co-TiO2/KHSO5和Vis/Co-TiO2 3种体系对苯酚的降解效果，Vis/Co-TiO2/KHSO5表现出明显的Fenton-光催化协同作用。进一步研究pH值、KHSO5与苯酚摩尔比（nKHSO5：nC6H6O）和Co-TiO2投加量（mCo-TiO2）对Fenton-光催化协同降解苯酚效果的影响。结果表明，pH=6.9、nKHSO5：nC6H6O=10：1、mCo-TiO2=1.0 g/L时，降解率达100%。最后，结合XRD、XPS和UV-DRS等手段和催化活性实验数据分析了Vis/Co-TiO2/KHSO5体系的催化机理。

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