Tessier法和BCR法对比磷酸二氢钠处置含铅污染土壤形态分析

高焕方, 曹园城, 何炉杰, 许桂英, 严欢, 李聪, 白薇扬, 陈志. Tessier法和BCR法对比磷酸二氢钠处置含铅污染土壤形态分析[J]. 环境工程学报, 2017, 11(10): 5751-5756. doi: 10.12030/j.cjee.201611189
引用本文: 高焕方, 曹园城, 何炉杰, 许桂英, 严欢, 李聪, 白薇扬, 陈志. Tessier法和BCR法对比磷酸二氢钠处置含铅污染土壤形态分析[J]. 环境工程学报, 2017, 11(10): 5751-5756. doi: 10.12030/j.cjee.201611189
GAO Huanfang, CAO Yuancheng, HE Lujie, XU Guiying, YAN Huan, LI Cong, BAI Weiyang, CHEN Zhi. Speciation analysis of lead-contaminated soil treated with sodium dihydrogen phosphate using Tessier and BCR[J]. Chinese Journal of Environmental Engineering, 2017, 11(10): 5751-5756. doi: 10.12030/j.cjee.201611189
Citation: GAO Huanfang, CAO Yuancheng, HE Lujie, XU Guiying, YAN Huan, LI Cong, BAI Weiyang, CHEN Zhi. Speciation analysis of lead-contaminated soil treated with sodium dihydrogen phosphate using Tessier and BCR[J]. Chinese Journal of Environmental Engineering, 2017, 11(10): 5751-5756. doi: 10.12030/j.cjee.201611189

Tessier法和BCR法对比磷酸二氢钠处置含铅污染土壤形态分析

  • 基金项目:

    重庆市社会民生科技创新专项(cstc2015shmszx20005)

    国家自然科学基金资助项目(21406023)

    重庆市教委基金资助项目(KJ1400901)

    重庆市基础科学与前沿技术研究专项(cstc2014jcyjA20008)

    重庆市科委自然科学基金资助项目(cstc2013jcyjA20008)

  • 中图分类号: X131.3

Speciation analysis of lead-contaminated soil treated with sodium dihydrogen phosphate using Tessier and BCR

  • Fund Project:
  • 摘要: 应用Tessier与BCR(Bureau Community of Reference)形态分析方法以及固体废物浸出毒性浸出法-醋酸缓冲溶液法(HJ/T300-2007)研究了磷酸二氢钠(MSP)对土壤中铅赋存形态以及浸出浓度的影响。研究表明:Tessier法和BCR法均能证实随着磷酸二氢钠的施加,实验土壤中铅从活泼态向稳定态转化;Tessier法测定的生物活性系数(MF)值较BCR法更为保守;通过线性回归分析发现BCR法测定的MF值相关系数为0.988,优于Tessier法的相关系数0.895;Tessier法与BCR法对污染土壤中铅形态的提取均具有较高的回收率;磷酸二氢钠能有效降低实验土壤中铅的浸出浓度可达98.62%。
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  • [1] 章海波, 骆永明, 李志博, 等. 土壤环境质量指导值与标准研究Ⅲ.污染土壤的生态风险评估[J]. 土壤学报, 2007,44(2):338-349
    [2] RAO C R M, SAHUQUILLO A, SANCHEZ J F L. A review of the different methods applied in environmental geochemistry for single and sequential extraction of trace elements in soils and related materials[J]. Water, Air, & Soil Pollution, 2008,189(1):291-333
    [3] YANG K, CATTLE S R. Bioaccessibility of lead in urban soil of Broken Hill, Australia:A study based on in vitro digestion and the IEUBK model[J]. Science of the Total Environment, 2015, 538:922
    [4] 郑顺安. 我国典型农田土壤中重金属的转化与迁移特征研究[D]. 杭州:浙江大学, 2010
    [5] TESSIER A, CAMPBELL P G C, BISSON M. Sequential extraction procedure for the speciation of particulate trace metals[J]. Analytical Chemistry, 1979, 51(7):844-851
    [6] QUEVAUVILLER Ph, RAURET G, GRIEPINK B. Single and sequential extraction in sediments and soils[J]. International Journal of Environmental Analytical Chemistry, 1993, 51(1/2/3/4):231-235
    [7] SHUMAN L. Fractionation method for soil microelements[J]. Soil Science, 1985, 140(1):11-22
    [8] GIBSON M J, FARMER J G. Multi-step sequential chemical extraction of heavy metals from urban soils[J]. Environmental Pollution, 1986, 11(2):117-135
    [9] MILLER W P, MARTENS D C, ZELAZNY L W. Effect of sequence in extraction of trace metals from soils1[J]. Soil Science Society of America Journal, 1986, 50(3):598-601
    [10] MAIZ I, ESNAOLA M V, MILLÁN E. Evaluation of heavy metal availability in contaminated soils by a short sequential extraction procedure[J]. Science of the Total Environment, 1997, 206(2/3):107-115
    [11] WANG Y M, CHEN T C, YEH K J, et al. Stabilization of an elevated heavy metal contaminated site[J]. Journal of Hazardous Materials, 2001, 88(1):63
    [12] 曹俊, 向斌, 高焕方,等. 磷酸盐稳定化处理铅污染土壤及铅的形态分析[J]. 环境工程学报, 2016, 10(10):6015-6020
    [13] VANDENHOVE H, VANHOUDT N, DUQUÈNE L, et al. Comparison of two sequential extraction procedures for uranium fractionation in contaminated soils[J]. Journal of Environmental Radioactivity, 2014, 137C:1-9
    [14] BRAZAUSKIENE D M, PAULAUSKAS V, SABIENE N. Speciation of Zn, Cu, and Pb in the soil depending on soil texture and fertilization with sewage sludge compost[J]. Journal of Soils and Sediments, 2008, 8(3):184-192
    [15] 何茂.磷酸盐固定重金属污染土壤中Pd和Cd的研究[D]. 西安:西安建筑科技大学, 2013
    [16] ANJU M, BANERJEE D K. Comparison of two sequential extraction procedures for heavy metal partitioning in mine tailings[J]. Chemosphere, 2010,78(11):1393-1402
    [17] KABALA C, SINGH B R. Fractionation and mobility of copper, lead, and zinc in soil profiles in the vicinity of a copper smelter.[J]. Journal of Environmental Quality, 2001, 30(2):485
    [18] PARK J H, BOLAN N, MEGHARAJ M, et al. Comparative value of phosphate sources on the immobilization of lead, and leaching of lead and phosphorus in lead contaminated soils.[J]. Science of the Total Environment, 2011, 409(4):853
    [19] YANG Z, FANG Z, ZHENG L, et al. Remediation of lead contaminated soil by biochar-supported nano-hydroxyapatite[J]. Ecotoxicology & Environmental Safety, 2016, 132:224
    [20] 宋波,曾炜铨,陆素芬,等.含磷材料在铅污染土壤修复中的应用[J]. 环境工程学报,2015,12(9):5649-5658
    [21] 王碧玲.含磷物质修复铅锌矿污染土壤的机理和技术[D]. 杭州:浙江大学, 2008
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出版历程
  • 收稿日期:  2017-04-14
  • 刊出日期:  2017-10-12
高焕方, 曹园城, 何炉杰, 许桂英, 严欢, 李聪, 白薇扬, 陈志. Tessier法和BCR法对比磷酸二氢钠处置含铅污染土壤形态分析[J]. 环境工程学报, 2017, 11(10): 5751-5756. doi: 10.12030/j.cjee.201611189
引用本文: 高焕方, 曹园城, 何炉杰, 许桂英, 严欢, 李聪, 白薇扬, 陈志. Tessier法和BCR法对比磷酸二氢钠处置含铅污染土壤形态分析[J]. 环境工程学报, 2017, 11(10): 5751-5756. doi: 10.12030/j.cjee.201611189
GAO Huanfang, CAO Yuancheng, HE Lujie, XU Guiying, YAN Huan, LI Cong, BAI Weiyang, CHEN Zhi. Speciation analysis of lead-contaminated soil treated with sodium dihydrogen phosphate using Tessier and BCR[J]. Chinese Journal of Environmental Engineering, 2017, 11(10): 5751-5756. doi: 10.12030/j.cjee.201611189
Citation: GAO Huanfang, CAO Yuancheng, HE Lujie, XU Guiying, YAN Huan, LI Cong, BAI Weiyang, CHEN Zhi. Speciation analysis of lead-contaminated soil treated with sodium dihydrogen phosphate using Tessier and BCR[J]. Chinese Journal of Environmental Engineering, 2017, 11(10): 5751-5756. doi: 10.12030/j.cjee.201611189

Tessier法和BCR法对比磷酸二氢钠处置含铅污染土壤形态分析

  • 1. 重庆理工大学化学化工学院, 重庆 400054
  • 2. 重庆汇亚环保工程有限公司, 重庆 400041
基金项目:

重庆市社会民生科技创新专项(cstc2015shmszx20005)

国家自然科学基金资助项目(21406023)

重庆市教委基金资助项目(KJ1400901)

重庆市基础科学与前沿技术研究专项(cstc2014jcyjA20008)

重庆市科委自然科学基金资助项目(cstc2013jcyjA20008)

摘要: 应用Tessier与BCR(Bureau Community of Reference)形态分析方法以及固体废物浸出毒性浸出法-醋酸缓冲溶液法(HJ/T300-2007)研究了磷酸二氢钠(MSP)对土壤中铅赋存形态以及浸出浓度的影响。研究表明:Tessier法和BCR法均能证实随着磷酸二氢钠的施加,实验土壤中铅从活泼态向稳定态转化;Tessier法测定的生物活性系数(MF)值较BCR法更为保守;通过线性回归分析发现BCR法测定的MF值相关系数为0.988,优于Tessier法的相关系数0.895;Tessier法与BCR法对污染土壤中铅形态的提取均具有较高的回收率;磷酸二氢钠能有效降低实验土壤中铅的浸出浓度可达98.62%。

English Abstract

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