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Tessier法和BCR法对比磷酸二氢钠处置含铅污染土壤形态分析

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高焕方, 曹园城, 何炉杰, 许桂英, 严欢, 李聪, 白薇扬, 陈志. Tessier法和BCR法对比磷酸二氢钠处置含铅污染土壤形态分析[J]. 环境工程学报, 2017, 11(10): 5751-5756. doi: 10.12030/j.cjee.201611189
引用本文: 高焕方, 曹园城, 何炉杰, 许桂英, 严欢, 李聪, 白薇扬, 陈志. Tessier法和BCR法对比磷酸二氢钠处置含铅污染土壤形态分析[J]. 环境工程学报, 2017, 11(10): 5751-5756. doi: 10.12030/j.cjee.201611189
shu
GAO Huanfang, CAO Yuancheng, HE Lujie, XU Guiying, YAN Huan, LI Cong, BAI Weiyang, CHEN Zhi. Speciation analysis of lead-contaminated soil treated with sodium dihydrogen phosphate using Tessier and BCR[J]. Chinese Journal of Environmental Engineering, 2017, 11(10): 5751-5756. doi: 10.12030/j.cjee.201611189
Citation: GAO Huanfang, CAO Yuancheng, HE Lujie, XU Guiying, YAN Huan, LI Cong, BAI Weiyang, CHEN Zhi. Speciation analysis of lead-contaminated soil treated with sodium dihydrogen phosphate using Tessier and BCR[J]. Chinese Journal of Environmental Engineering, 2017, 11(10): 5751-5756. doi: 10.12030/j.cjee.201611189
shu

Tessier法和BCR法对比磷酸二氢钠处置含铅污染土壤形态分析

  • 1.

    重庆理工大学化学化工学院, 重庆 400054

  • 2.

    重庆汇亚环保工程有限公司, 重庆 400041

  • 基金项目:

    重庆市社会民生科技创新专项（cstc2015shmszx20005）

    国家自然科学基金资助项目（21406023）

    重庆市教委基金资助项目（KJ1400901）

    重庆市基础科学与前沿技术研究专项（cstc2014jcyjA20008）

    重庆市科委自然科学基金资助项目（cstc2013jcyjA20008）

  • 中图分类号: X131.3

Speciation analysis of lead-contaminated soil treated with sodium dihydrogen phosphate using Tessier and BCR

  • 1.

    College of Chemistry and Chemical Engineering, Chongqing University of Technology, Chongqing 400054, China

  • 2.

    Chongqing Hui Ya Environmental Protection Engineering Co. Ltd., Chongqing 400041, China

  • Fund Project:

  • 摘要: 应用Tessier与BCR（Bureau Community of Reference）形态分析方法以及固体废物浸出毒性浸出法-醋酸缓冲溶液法（HJ/T300-2007）研究了磷酸二氢钠（MSP）对土壤中铅赋存形态以及浸出浓度的影响。研究表明：Tessier法和BCR法均能证实随着磷酸二氢钠的施加，实验土壤中铅从活泼态向稳定态转化；Tessier法测定的生物活性系数（MF）值较BCR法更为保守；通过线性回归分析发现BCR法测定的MF值相关系数为0.988，优于Tessier法的相关系数0.895；Tessier法与BCR法对污染土壤中铅形态的提取均具有较高的回收率；磷酸二氢钠能有效降低实验土壤中铅的浸出浓度可达98.62%。
    Abstract: The effects of sodium dihydrogen phosphate (MSP) on lead speciation and its leaching concentration in soil were studied by Tessier, BCR sequential extraction method and Solid waste-Extraction method for leaching toxicity-acetic acid buffer solution method (HJ/T300-2007). The results of both Tessier and BCR demonstrate that the lead in the experimental soil is changed from the active state to the steady state with the application of sodium dihydrogen phosphate, and the MF value measured by Tessier method is more conservative than that of BCR. It is shown from Linear regression analysis that the MF correlation coefficient measured by BCR method was 0.988, which is better than that by Tessier method as 0.895.It also can be seen that BCR and Tessier methods have a high recovery rate of lead in the polluted soil. Lastly, it is found that sodium dihydrogen phosphate can reduce the leaching concentration of lead in soil effectively with the reduction of 98.62%.
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  • [1] 章海波, 骆永明, 李志博, 等. 土壤环境质量指导值与标准研究Ⅲ.污染土壤的生态风险评估[J]. 土壤学报, 2007,44(2):338-349
    [2] RAO C R M, SAHUQUILLO A, SANCHEZ J F L. A review of the different methods applied in environmental geochemistry for single and sequential extraction of trace elements in soils and related materials[J]. Water, Air, & Soil Pollution, 2008,189(1):291-333
    [3] YANG K, CATTLE S R. Bioaccessibility of lead in urban soil of Broken Hill, Australia:A study based on in vitro digestion and the IEUBK model[J]. Science of the Total Environment, 2015, 538:922
    [4] 郑顺安. 我国典型农田土壤中重金属的转化与迁移特征研究[D]. 杭州:浙江大学, 2010
    [5] TESSIER A, CAMPBELL P G C, BISSON M. Sequential extraction procedure for the speciation of particulate trace metals[J]. Analytical Chemistry, 1979, 51(7):844-851
    [6] QUEVAUVILLER Ph, RAURET G, GRIEPINK B. Single and sequential extraction in sediments and soils[J]. International Journal of Environmental Analytical Chemistry, 1993, 51(1/2/3/4):231-235
    [7] SHUMAN L. Fractionation method for soil microelements[J]. Soil Science, 1985, 140(1):11-22
    [8] GIBSON M J, FARMER J G. Multi-step sequential chemical extraction of heavy metals from urban soils[J]. Environmental Pollution, 1986, 11(2):117-135
    [9] MILLER W P, MARTENS D C, ZELAZNY L W. Effect of sequence in extraction of trace metals from soils1[J]. Soil Science Society of America Journal, 1986, 50(3):598-601
    [10] MAIZ I, ESNAOLA M V, MILLÁN E. Evaluation of heavy metal availability in contaminated soils by a short sequential extraction procedure[J]. Science of the Total Environment, 1997, 206(2/3):107-115
    [11] WANG Y M, CHEN T C, YEH K J, et al. Stabilization of an elevated heavy metal contaminated site[J]. Journal of Hazardous Materials, 2001, 88(1):63
    [12] 曹俊, 向斌, 高焕方,等. 磷酸盐稳定化处理铅污染土壤及铅的形态分析[J]. 环境工程学报, 2016, 10(10):6015-6020
    [13] VANDENHOVE H, VANHOUDT N, DUQUÈNE L, et al. Comparison of two sequential extraction procedures for uranium fractionation in contaminated soils[J]. Journal of Environmental Radioactivity, 2014, 137C:1-9
    [14] BRAZAUSKIENE D M, PAULAUSKAS V, SABIENE N. Speciation of Zn, Cu, and Pb in the soil depending on soil texture and fertilization with sewage sludge compost[J]. Journal of Soils and Sediments, 2008, 8(3):184-192
    [15] 何茂.磷酸盐固定重金属污染土壤中Pd和Cd的研究[D]. 西安:西安建筑科技大学, 2013
    [16] ANJU M, BANERJEE D K. Comparison of two sequential extraction procedures for heavy metal partitioning in mine tailings[J]. Chemosphere, 2010,78(11):1393-1402
    [17] KABALA C, SINGH B R. Fractionation and mobility of copper, lead, and zinc in soil profiles in the vicinity of a copper smelter.[J]. Journal of Environmental Quality, 2001, 30(2):485
    [18] PARK J H, BOLAN N, MEGHARAJ M, et al. Comparative value of phosphate sources on the immobilization of lead, and leaching of lead and phosphorus in lead contaminated soils.[J]. Science of the Total Environment, 2011, 409(4):853
    [19] YANG Z, FANG Z, ZHENG L, et al. Remediation of lead contaminated soil by biochar-supported nano-hydroxyapatite[J]. Ecotoxicology & Environmental Safety, 2016, 132:224
    [20] 宋波,曾炜铨,陆素芬,等.含磷材料在铅污染土壤修复中的应用[J]. 环境工程学报,2015,12(9):5649-5658
    [21] 王碧玲.含磷物质修复铅锌矿污染土壤的机理和技术[D]. 杭州:浙江大学, 2008
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出版历程
  • 收稿日期:  2017-04-14
  • 刊出日期:  2017-10-12
高焕方, 曹园城, 何炉杰, 许桂英, 严欢, 李聪, 白薇扬, 陈志. Tessier法和BCR法对比磷酸二氢钠处置含铅污染土壤形态分析[J]. 环境工程学报, 2017, 11(10): 5751-5756. doi: 10.12030/j.cjee.201611189
引用本文: 高焕方, 曹园城, 何炉杰, 许桂英, 严欢, 李聪, 白薇扬, 陈志. Tessier法和BCR法对比磷酸二氢钠处置含铅污染土壤形态分析[J]. 环境工程学报, 2017, 11(10): 5751-5756. doi: 10.12030/j.cjee.201611189
shu
GAO Huanfang, CAO Yuancheng, HE Lujie, XU Guiying, YAN Huan, LI Cong, BAI Weiyang, CHEN Zhi. Speciation analysis of lead-contaminated soil treated with sodium dihydrogen phosphate using Tessier and BCR[J]. Chinese Journal of Environmental Engineering, 2017, 11(10): 5751-5756. doi: 10.12030/j.cjee.201611189
Citation: GAO Huanfang, CAO Yuancheng, HE Lujie, XU Guiying, YAN Huan, LI Cong, BAI Weiyang, CHEN Zhi. Speciation analysis of lead-contaminated soil treated with sodium dihydrogen phosphate using Tessier and BCR[J]. Chinese Journal of Environmental Engineering, 2017, 11(10): 5751-5756. doi: 10.12030/j.cjee.201611189
shu

Tessier法和BCR法对比磷酸二氢钠处置含铅污染土壤形态分析

  • 1. 重庆理工大学化学化工学院, 重庆 400054
  • 2. 重庆汇亚环保工程有限公司, 重庆 400041
  • 收稿日期:  2017-04-14
基金项目:

重庆市社会民生科技创新专项（cstc2015shmszx20005）

国家自然科学基金资助项目（21406023）

重庆市教委基金资助项目（KJ1400901）

重庆市基础科学与前沿技术研究专项（cstc2014jcyjA20008）

重庆市科委自然科学基金资助项目（cstc2013jcyjA20008）

摘要: 应用Tessier与BCR（Bureau Community of Reference）形态分析方法以及固体废物浸出毒性浸出法-醋酸缓冲溶液法（HJ/T300-2007）研究了磷酸二氢钠（MSP）对土壤中铅赋存形态以及浸出浓度的影响。研究表明：Tessier法和BCR法均能证实随着磷酸二氢钠的施加，实验土壤中铅从活泼态向稳定态转化；Tessier法测定的生物活性系数（MF）值较BCR法更为保守；通过线性回归分析发现BCR法测定的MF值相关系数为0.988，优于Tessier法的相关系数0.895；Tessier法与BCR法对污染土壤中铅形态的提取均具有较高的回收率；磷酸二氢钠能有效降低实验土壤中铅的浸出浓度可达98.62%。

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