铜仁市土壤-玉米重金属含量及其健康风险
Concentrations and health risk assessments of heavy metal contents in soil-corn system of Tongren, China
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摘要: 为了解铜仁市玉米地土壤和玉米籽粒重金属的含量分布特征,并评估当地居民通过玉米籽粒摄入重金属的健康风险.于2018年7月采集了铜仁市自然土壤样品65个、玉米地土壤样品122个和玉米样品100个,并分析其Cd、Pb、Cu、Zn、Ni、As、Hg含量,通过重金属摄入量评价居民膳食暴露的健康风险.结果表明,自然土壤Cd、Pb、Cu、Zn、Ni、As和Hg的含量均值分别为0.148、23.09、29.60、103.6、37.73、16.43、0.144 mg·kg-1;玉米地土壤Cd、Pb、Cu、Zn、Ni、As和Hg的含量均值分别为0.273、30.00、27.79、103.4、29.89、13.58、1.037 mg·kg-1.以《土壤环境质量农用地土壤污染风险管控标准》(GB 15618—2018)中的风险筛选值作为限量标准,玉米地土壤Cd、As和Hg超标率分别为18.9%、19.7%和17.2%;以风险管制值为限量标准,玉米地土壤Hg超标率为10.7%.依据GB 2762—2017《食品中污染物限量》,玉米籽粒Cd和Pb超标率分别为7.0%和44%.人体健康风险评价表明,居民通过食用玉米籽粒的重金属健康风险THQ值均小于1,表明食用当地玉米对居民的健康不会造成明显影响.Abstract: In order to understand the distribution of heavy metal in soil-corn system of Tongren City and evaluate the health risk of the exposure of typical local residents to heavy metals through consumption of corn. A total of 65 natural soil samples,122 soil samples from corn fields and 100 corn samples were collected in July 2018 and then analysis the contents of Cd, Pb, Cu, Zn, Ni, As and Hg. And furthermore, the potential health risk of the dietary exposure of residents was assessed through the intake of heavy metals. Results showed that the mean contents of Cd, Pb, Cu, Zn, Ni, As and Hg in the natural soil samples were 0.148, 23.09, 29.60, 103.6, 37.73, 16.43 and 0.144 mg·kg-1; the mean contents of Cd, Pb, Cu, Zn, Ni, As and Hg in the soil samples from corn fields were 0.273, 30.00, 27.79, 103.4, 29.89, 13.58 and 1.037 mg·kg-1. The over-standard rate of Cd, As and Hg in soil samples from corn fields was calculated to be 18.9%, 19.7% and 17.2% respectively, by risk screening values for soil contamination of GB 15618—2018 "Risk control standard for soil contamination of agricultural land". The over-standard rate of Hg in soil samples from corn fields was calculated to be 10.7%, by risk intervention values for soil contamination. The over-standard rate of Cd and Pb in corn samples was calculated to be 7.0% and 44%, by GB 2762—2017 "Thresholds for pollutants in food". Human health risk assessment showed that the THQ of heavy metals of corn was below 1, which indicate that ingestion of locally produced corn would not have any significant health risk.
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Key words:
- Tongren City /
- soil /
- corn /
- heavy metals /
- health risk
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[1] CAI L, XU Z, REN M, et al. Source identification of eight hazardous heavy metals in agricultural soils of Huizhou, Guangdong Province, China[J]. Ecotoxicology and Environmental Safety, 2012, 78:2-8. [2] 朱宇恩, 赵烨, 李强,等. 北京城郊污灌土壤-小麦(Triticum aestivum)体系重金属潜在健康风险评价[J]. 农业环境科学学报, 2011, 30(2):263-270. ZHU Y E, ZHAO Y, LI Q, et al. Potential infiluences of heavy metal in "soil-wheat (Triticum aestivum)" system on human health:A case study of sewage irrigation area in Beijing, China[J]. Journal of Agro-Environment Science,2011,30(2):263-270(in Chinese).
[3] 湛天丽, 黄阳, 何腾兵,等. 贵州铜仁汞矿区主要农产品重金属污染及其健康风险评估[J]. 安全与环境学报, 2017, 17(4):1524-1529. ZHAN T L, HUANG Y, HE T B, et al. Heavy metal pollution and health risk in major agricultural products in Tongren mercury mine area, Guizhou[J]. Journal of Safety and Environment, 2017, 17(4):1524-1529(in Chinese).
[4] 包丹丹. 污染源周边农田重金属污染风险评价与控制技术试验[D]. 南京:南京农业大学, 2011. BAO D D. Risk Analysis and mitigation experiment of heavy metal pollution in croplands in vicinity of pollution sources[D]. Nanjing:Nanjing Agriculture University, 2011(in Chinese). [5] 湛天丽, 黄阳, 何腾兵,等. 贵州万山汞矿区某农田土壤重金属污染特征及来源解析[J]. 土壤通报, 2017, 48(2):474-480. ZHAN T L, HUANG Y, HE T B, et al. Pollution characteristics and sources of heavy metals in farmland soil in Wanshan mining areas, Guizhou Province[J]. Chinese Journal of Soil Science, 2017, 48(2):474-480(in Chinese).
[6] WANG X, LI Y F, LI B, et al. Multielemental contents of foodstuffs from the Wanshan (China) mercury mining area and the potential health risks[J]. Applied Geochemistry, 2011, 26(2):182-187. [7] 余元元, 黄宇妃, 宋波,等. 南丹县矿区周边土壤与农产品重金属含量调查及健康风险评价[J]. 环境化学, 2015, 34(11):2133-2135. YU Y Y, HUANG Y F, SONG B, et al. Investigation and health risk assessment of heavy metal content in surrounding soil and agricultural products of mining area in Nan- dan County[J]. Environmental Chemistry, 2015, 34(11):2133-2135(in Chinese).
[8] 李晓红,王良平. 贵州省铜仁市玉米主推品种选择探析[J]. 园艺与种苗, 2014(11):26-28. LI X H, WANG L P. Discussion on selection of maize varieties in Tongren City of Guizhou Province[J]. Horticulture & Seed, 2014 (11):26-28(in Chinese).
[9] RAHMAN A K M R, HOSSAIN S M, AKRAMUZZAMAN M M. Distribution of heavy metals in rice plant cultivated in industrial effluent receiving soil[J]. Environmentasia, 2010, 3(2):15-19. [10] USEPA. Risk-based concentration table, in Philadelphia[M]. Washington DC:United States Environmental Protection Agency, 2000:165. [11] CHENG J L, SHI Z, ZHU Y W. Assessment and mapping of environmental quality in agricultural soils of Zhejiang Province, China[J]. Journal of Environmental Sciences, 2007, 19(1):50-54. [12] HAN B C, JENG W L, CHEN R Y. Estimation of target hazard quotients and potential health risks for metals by consumption of seafood in Taiwan[J]. Archives of Environmental Contamination and Toxicology, 1998, 35(4):711-720. [13] 甘国娟. 土壤-水稻系统重金属迁移特征与区域污染风险评价[D]. 长沙:中南林业科技大学, 2013. GAN G J. Transfer characteristic of heavy metals in soil-rice system and regional pollution risk assessment[D]. Changsha:Central South University of Forestry & Technology, 2013(in Chinese). [14] 祝滔, 江长胜, 郝庆菊,等. 重庆秀山锰矿区土壤和植物锰污染调查与评价[J]. 环境科学与技术, 2012, 35(9):167-172. ZHU T, JANG C S, HAO Q J, et al. Investigation and assessment of contaminated soils and plant by Mn in manganese mining area in Xiushan autonomous County of Chongqing[J]. Environmental Science & Technology, 2012, 35(9):167-172(in Chinese).
[15] 陆素芬, 张云霞, 余元元,等. 广西南丹土壤-玉米重金属积累特征及其健康风险[J]. 生态与农村环境学报, 2017, 33(8):706-714. LU S F, ZHANG Y X, YU Y Y, et al. Characteristics of heavy metal accumulation in soil-corn system contents and their health risks in Nandan, Guangxi[J]. Journal of Ecology and Rural Environment, 2017, 33(8):706-714(in Chinese).
[16] 中国环境监测总站. 中国土壤元素背景值[M]. 北京:中国环境科学出版社, 1990:330-382. China National Environmental Monitoring Center. The background concentrations of soil elements in China[M]. Beijing:Chinese Environment Science Press, 1990:330 -382(in Chinese).
[17] 田美玲, 钟雪梅, 张云霞,等. 矿业活动影响区稻田土壤和稻米中重金属含量及健康风险[J]. 环境科学, 2018, 39(6):2919-2926. TIAN M L, ZHONG X M, ZHANG Y X, et al. Concentrations and health risk assessments of heavy metal contents in soil and rice of mine contaminated areas[J]. Environmental Science, 2018, 39(6):2919-2926(in Chinese).
[18] OSTAPCZUK P, VALENTA P, RVTZEL H, et al. Application of differential pulse anodic stripping voltammetry to the determination of heavy metals in environmental samples[J]. Science of the Total Environment, 1987, 60:1-16. [19] 尹伊梦, 赵委托, 黄庭,等. 电子垃圾拆解区土壤-水稻系统重金属分布特征及健康风险评价[J]. 环境科学, 2018, 39(2):916-926. YIN Y M, ZHAO W T, HUANG T, et al. Distribution characteristics and health risk assessment of heavy metals in a soil-rice system in an e-waste dismantling area[J]. Environmental Science, 2018, 39(2):916-926(in Chinese).
[20] FERRÉ-HUGUET N, MARTÍ-CID R, SCHUHCHER M, et al. Risk assessment of metals from consuming vegetables, fruits and rice grown on soils irrigated with waters of the ebro river in catalonia, spain[J]. Biological Trace Element Research, 2008, 123(1/3):66-79. [21] 高继军, 张力平, 黄圣彪, 等. 北京市饮用水源水重金属污染物健康风险的初步评价[J]. 环境科学, 2004, 25(2):47-50. GAO W J, ZHANG L P, HUANG S B, et al. Preliminary health risk assessment of heavy metals in drinking waters in Beijing[J]. Environmental Science, 2004, 25(2):47-50(in Chinese).
[22] 李如忠, 潘成荣, 徐晶晶,等. 典型有色金属矿业城市零星菜地蔬菜重金属污染及健康风险评估[J]. 环境科学, 2013, 34(3):1076-1085. LI R Z, PAN C R, XU J J, et al. Contamination and health risk for heavy metals via consumption of vegetables grown in fragmentary vegetable plots from a typical nonferrous metals mine city[J]. Environmental Science, 2013, 34(3):1076-1085(in Chinese).
[23] 胡国成, 张丽娟, 齐剑英,等. 贵州万山汞矿周边土壤重金属污染特征及风险评价[J]. 生态环境学报, 2015, 24(5):879-885. HU G C, ZHANG L J, QI J Y, et al. Contaminant characteristics and risk assessment of heavy metals in soils from Wanshan mercury mine area, Guizhou Province[J]. Ecology and Environmental Sciences, 2015, 24(5):879-885(in Chinese).
[24] 吴洋, 杨军, 周小勇,等. 都安县玉米籽粒重金属累积特征与健康风险评价[J]. 农业环境科学学报, 2015, 34(11):2048-2054. WU Y, YANG J, ZHOU X Y, et al. Accumulation characteristics and health risk assessment of heavy metals in corn kernel in Du'an Yao Autonomous County[J]. Journal of Agro-Environment Science, 2015, 34(11):2048-2054(in Chinese).
[25] 张江华, 徐友宁,吴耀国. 小秦岭金矿区小麦和玉米重金属的健康风险评价[J]. 地质学报, 2019, 93(2):501-508. ZHANG J H, XU Y N, WU Y G, et al. Health risk assessment of heavy metals in wheat and maize in Xiaoqinling gold mining Area[J]. Acta Geologica Sinica, 2019, 93(2):501-508(in Chinese).
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