环境中短链和中链氯化石蜡的来源、污染特征及环境行为研究进展
Chlorinated paraffins in the environment: A review on their sources, levels and fate
-
摘要: 短链氯化石蜡(SCCPs)是持久性有机污染物,已于2017年5月被正式列入《关于持久性有机污染物的斯德哥尔摩公约》附件A的受控名单.中链氯化石蜡(MCCPs)具有相似的性质.由于氯化石蜡(CPs)大量生产以及广泛应用,其在环境介质中的含量处于较高水平.本文综述了SCCPs和MCCPs的生产和排放,以及2016年以后文献报道的SCCPs和MCCPs在不同环境介质中的研究进展,包括在大气、水体、土壤和沉积物中的赋存、分布特征,探讨了SCCPs和MCCPs的环境行为,同时指出环境中CPs的溯源、界面过程及区域传输是未来的主要研究方向.Abstract: Short-chain chlorinated paraffins (SCCPs) are persistent organic pollutants. In May 2017, they were added to Annex A to the Stockholm Convention. The properties of medium-chain chlorinated paraffins (MCCPs) are similar to those of SCCPs. Because they are produced in large quantities industrially and widely applied, high concentrations of SCCPs and MCCPs have been found in different environmental matrices. This paper reviews the production and emission inventories of SCCPs and MCCPs. Studies on the occurrences, distributions and fates of SCCPs and MCCPs in various environmental matrices, including ambient air, water, soil, and sediments, conducted since 2016 are also summarized. The environmental behaviors of SCCPs and MCCPs are discussed. Future studies should focus on source identification, environmental processes and regional transport of CPs.
-
Key words:
- short-chain chlorinated paraffins /
- medium-chain chlorinated paraffins /
- ambient air /
- soil /
- sediment
-
[1] JACOB D B, EI-SAYED A T, FIEDLER H, et al. The handbook of environment chemistry[M]. Berlin:Springer-Verlag Press, 2010. [2] TOMY G T, FISK A T, WESTMORE J B, et al. Environmental chemistry and toxicology of polychlorinated n-alkanes[J]. Reviews of Environmental Contamination and Toxicology, 1998, 158:53-128. [3] HILGER B, FROMME H, VöLKEL W, et al. Occurrence of chlorinated paraffins in house dust samples from Bavaria, Germany[J]. Environmental Pollution, 2013, 175:16-21. [4] 王坤然. 氯化石蜡的检测技术及其环境行为研究[D]. 北京:中国科学院大学, 2020. WANG K R. Detection technology and environmental behavior of chlorinated paraffins[D].Beijing:University of Chinese Academy of Sciences,2020(in Chinese). [5] VAN MOURIK L M, GAUS C, LEONARDS P E G, et al. Chlorinated paraffins in the environment:A review on their production, fate, levels and trends between 2010 and 2015[J]. Chemosphere, 2016, 155:415-428. [6] WEI G L, LIANG X L, LI D Q, et al. Occurrence, fate and ecological risk of chlorinated paraffins in Asia:A review[J]. Environment International, 2016, 92/93:373-387. [7] 徐淳, 徐建华, 张剑波. 中国短链氯化石蜡排放清单和预测[J]. 北京大学学报(自然科学版), 2014, 50(2):369-378. XU C, XU J H, ZHANG J B. Emission inventory prediction of short chain chlorinated paraffins (SCCPs) in China[J]. Acta Scientiarum Naturalium Universitatis Pekinensis, 2014, 50(2):369-378(in Chinese). [8] 黄慧婷. 短链和中链氯化石蜡的人体外暴露水平研究[D]. 北京:中国科学院大学, 2017. HUANG H T.Human exposure to short-and medium-chain chlorinated paraffins in China[D]. Beijing:University of Chinese Academy of Sciences,2017(in Chinese). [9] CHEN L, HUANG Y, HAN S, et al. Sample pretreatment optimization for the analysis of short chain chlorinated paraffins in soil with gas chromatography-electron capture negative ion-mass spectrometry[J]. Journal of Chromatography A, 2013, 1274:36-43. [10] ZENG L, WANG T, RUAN T, et al. Levels and distribution patterns of short chain chlorinated paraffins in sewage sludge of wastewater treatment plants in china[J]. Environmental Pollution, 2012, 160:88-94. [11] GLUGE J, WANG Z, BOGDAL C, et al. Global production, use, and emission volumes of short-chain chlorinated paraffins-a minimum scenariol[J]. Science of the Total Environment, 2016, 573:1132-1146. [12] CHAEMFA C, XU Y, LI J, et al. Screening of atmospheric short- and medium-chain chlorinated paraffins in India and Pakistan using polyurethane foam based passive air sampler[J]. Environmental Science&Technology, 2014, 48(9):4799-4808. [13] 王亚韡, 王莹, 江桂斌. 短链氯化石蜡的分析方法、污染现状与毒性效应[J]. 化学进展, 2017, 29(9):919-929. WANG Y W,WANG Y,JINAG G B. Analytical methods,environmental pollutions and toxicity of short chain chlorinated paraffins[J]. Progress in Chemistry, 2017, 29(9):919-929(in Chinese).
[14] POPRC. Short-chained chlorinated paraffins revised draft risk profile. Stockholm convention on persistent organic pollutants.[EB/OL].[2020-8-18]. Http://www.Pops.Int/theconvention/conferenceoftheparties/meetings/cop7/tabid/4251/mctl/viewdetails/eventmodid/870/eventid/543/xmid/13075/default.Aspx. [15] EU. Technical guidance document on risk assessment, part Ⅱ[EB/OL].[2020-8-18].Https://www.Ecdc.Europa.Eu/en/publications-data/technical-guidance-risk-assessment-guidelines-diseases-transmitted-aircraft [16] EU. Risk assessment of alkanes, C14-C17, chloro[EB/OL].[2020-8-18].Https://echa.Europa.Eu/documents/10162/d317126f-75bc-4ba6-a8be-7ecaa2a96656 [17] ZHANG B Y, ZHAO B, XU C, et al. Emission inventory and provincial distribution of short-chain chlorinated paraffins in China[J]. Science of the Total Environment, 2017, 581:582-588. [18] WANG T, HAN S, YUAN B, et al. Summer-winter concentrations and gas-particle partitioning of short chain chlorinated paraffins in the atmosphere of an urban setting[J]. Environmental Pollution 2012, 171:38-45. [19] ZHU X, BAI H, GAO Y, et al. Concentrations and inhalation risk assessment of short-chain polychlorinated paraffins in the urban air of Dalian, China[J]. Environmental Science and Pollution Research, 2017, 24(26):21203-21212. [20] WANG P, ZHAO N, CUI Y, et al. Short-chain chlorinated paraffin (SCCP) pollution from a CP production plant in china:Dispersion, congener patterns and health risk assessment[J]. Chemosphere, 2018, 211:456-464. [21] LI Q, LI J, WANG Y. Atmospheric short-chain chlorinated paraffins in China, Japan, and South Korea[J]. Environmental Science & Technology, 2012, 46(21):11948-11954. [22] DIEFENBACHER P S, BOGDAL C, GERECKE A C, et al. Short-chain chlorinated paraffins in Zurich, Switzerland-atmospheric concentrations and emissions[J]. Environmental Science & Technology, 2015, 49(16):9778-9786. [23] GILLETT R W, GALBALLY I E, KEYWOOD M D, et al. Atmospheric short-chain-chlorinated paraffins in Melbourne, Australia-first extensive Southern Hemisphere observations[J]. Environmental Chemistry, 2017, 14(2):106-114. [24] MA X D, ZHANG H J, ZHOU H Q, et al. Occurrence and gas/particle partitioning of short- and medium-chain chlorinated paraffins in the atmosphere of Fildes Peninsula of Antarctica[J]. Atmospheric Environment, 2014, 90:10-15. [25] BORGEN A R, SCHLABACH M, GUNDERSEN H. Polychlorinated alkanes in arctic air[J]. Organohalogen Compd, 2000, 47:272-274. [26] WANG Y, LI J, CHENG Z, et al. Short- and medium-chain chlorinated paraffins in air and soil of subtropical terrestrial environment in the Pearl River Delta, South China:Distribution, composition, atmospheric deposition fluxes, and environmental fate[J]. Environmental Science & Technology, 2013, 47(6):2679-2687. [27] ZHUO M H, MA S T, LI G Y, et al. Chlorinated paraffins in the indoor and outdoor atmospheric particles from the Pearl River Delta:Characteristics, sources, and human exposure risks[J]. Science of the Total Environment, 2019, 650:1041-1049. [28] ZHOU W, SHEN M, LAM J C W, et al. Size-dependent distribution and inhalation exposure characteristics of particle-bound chlorinated paraffins in indoor air in Guangzhou, China[J]. Environment International, 2018, 121:675-682. [29] BARBER J L, SWEETMAN A J, THOMAS G O, et al. Spatial and temporal variability in air concentrations of short-chain (C10-C13) and medium-chain (C14-C17) chlorinated n-alkanes measured in the UK atmosphere[J]. Environmental Science & Technology, 2005, 39(12):4407-4415. [30] FRIDEN U E, MCLACHLAN M S, BERGER U. Chlorinated paraffins in indoor air and dust:Concentrations, congener patterns, and human exposure[J]. Environment International, 2011, 37(7):1169-1174. [31] SAKHI A K, CEQUIER E, BECHER R, et al. Concentrations of selected chemicals in indoor air from Norwegian homes and schools[J]. Science of the Total Environment, 2019, 674:1-8. [32] GAO W, CAO D, WANG Y, et al. External exposure to short- and medium-chain chlorinated paraffins for the general population in Beijing, China[J]. Environmental Science & Technology, 2018, 52:32-39. [33] HUANG H T, GAO L R, XIA D, et al. Characterization of short- and medium-chain chlorinated paraffins in outdoor/indoor PM10/PM2.5/PM1.0 in Beijing, China[J]. Environmental Pollution, 2017, 225:674-680. [34] SHANG H, FAN X, KUBWABO C, et al. Short-chain and medium-chain chlorinated paraffins in Canadian house dust and NIST SRM 2585[J]. Environmental Science and Pollution Research, 2019, 26(8):7453-7462. [35] KERSTEN W, REICH T. Non-volatile organic substances in Hamburg indoor dust[J]. Gefahrstoffe Reinhaltung der Luft, 2003, 63(3):85-91. [36] HE C, BRANDSMA S H, JIANG H, et al. Chlorinated paraffins in indoor dust from Australia:Levels, congener patterns and preliminary assessment of human exposure[J]. Science of the Total Environment, 2019, 682:318-323. [37] CHEN H, LAM J C W, ZHU M, et al. Combined effects of dust and dietary exposure of occupational workers and local residents to short- and medium-chain chlorinated paraffins in a mega e-waste recycling industrial park in South China[J]. Environmental Science & Technology, 2018, 52(20):11510-11519. [38] CAO Z, XU F, COVACI A, et al. Distribution patterns of brominated, chlorinated, and phosphorus flame retardants with particle size in indoor and outdoor dust and implications for human exposure[J]. Environmental Science & Technology, 2014, 48(15):8839-8846. [39] LIU L H, MA W L, LIU L Y, et al. Occurrence, sources and human exposure assessment of SCCPs in indoor dust of Northeast China[J]. Environmental Pollution, 2017, 225:232-243. [40] SHI L, GAO Y, ZHANG H, et al. Concentrations of short- and medium-chain chlorinated paraffins in indoor dusts from malls in China:Implications for human exposure[J]. Chemosphere, 2017, 172:103-110. [41] ZENG L, WANG T, WANG P, et al. Distribution and trophic transfer of short-chain chlorinated paraffins in an aquatic ecosystem receiving effluents from a sewage treatment plant[J]. Environmental Science & Technology, 2011, 45(13):5529-5535. [42] ZENG L X, LI H J, WANG T, et al. Behavior, fate, and mass loading of short chain chlorinated paraffins in an advanced municipal sewage treatment plant[J]. Environmental Science & Technology, 2013, 47:732-740. [43] ⅡNO F, TAKASUGA T, SENTHILKUMAR K, et al. Risk assessment of short-chain chlorinated paraffins in Japan based on the first market basket study and species sensitivity distributions[J]. Environmental Science & Technology, 2005, 39(3):859-866. [44] RUBIROLA A, SANTOS F, BOLEDA M, et al. Routine method for the analysis of short-chain chlorinated paraffins in surface water and wastewater[J]. Clean-Soil Air Water, 2018, 46:1600151. [45] COELHAN M. Levels of chlorinated paraffins in water[J]. Clean-Soil Air Water, 2010, 38(5/6):452-456. [46] GANDOLFI F, MALLERET L, SERGENT M, et al. Parameters optimization using experimental design for headspace solid phase micro-extraction analysis of short-chain chlorinated paraffins in waters under the European water framework directive[J]. Journal of Chromatography A, 2015, 1406:59-67. [47] HOUDE M, MUIR D C G, TOMY G T, et al. Bioaccumulation and trophic magnification of short- and medium-chain chlorinated paraffins in food webs from Lake Ontario and Lake Michigan[J]. Environmental Science & Technology, 2008, 42(10):3893-3899. [48] WANG X, XU S, WANG X, et al. Occurrence, homologue patterns and source apportionment of short- and medium-chain chlorinated paraffins in suburban soils of Shanghai, China[J]. Chemosphere, 2017, 180:302-311. [49] 王迎军, 王亚韡, 江桂斌. 固相萃取法测定水中短链氯化石蜡[J]. 分析化学, 2018, 46(7):1102-1108. WANG Y J,WANG Y W,JIANG G B. Solid-phase extraction for analysis of short-chain chlorinated paraffins in water samples[J]. Chinese Journal of Analytical Chemistry, 2018, 46(7):1102-1108(in Chinese).
[50] HUANG Y M, CHEN L G, JIANG G, et al. Bioaccumulation and biomagnification of short-chain chlorinated paraffins in marine organisms from the Pearl River Estuary, South China[J]. Science of the Total Environment, 2019, 671:262-269. [51] 于国龙. 海洋环境短链氯化石蜡分析方法及应用研究[D]. 大连:大连海事大学, 2012. YU G L. Study on method and application for analysis of short chain chlorinated paraffins in marine environment[D]. Dalian:Dalian Maritime University,2012(in Chinese). [52] MA X, ZHANG H, WANG Z, et al. Bioaccumulation and trophic transfer of short chain chlorinated paraffins in a marine food web from Liaodong Bay, North China[J]. Environ Sci Technol, 2014, 48(10):5964-5971. [53] SUN R, LUO X, TANG B, et al. Bioaccumulation of short chain chlorinated paraffins in a typical freshwater food web contaminated by e-waste in South China:Bioaccumulation factors, tissue distribution, and trophic transfer[J]. Environmental Pollution, 2017, 222:165-174. [54] WANG X T, ZHANG Y, MIAO Y, et al. Short-chain chlorinated paraffins (SCCPs) in surface soil from a background area in China:Occurrence, distribution, and congener profiles[J]. Environmental Science and Pollution Research, 2013, 20(7):4742-4749. [55] ZENG L X, ZHAO Z S, LI H J, et al. Distribution of short chain chlorinated paraffins in marine sediments of the East China Sea:Influencing factors, transport and implications[J]. Environmental Science & Technology, 2012, 46(18):9898-9906. [56] BRANDSMA S H, VAN MOURIK L, O'BRIEN J W, et al. Medium-chain chlorinated paraffins (CPs) dominate in Australian sewage sludge[J]. Environmental Science & Technology, 2017, 51(6):3364-3372. [57] NICHOLLS C R, ALLCHIN C R, LAW R J. Levels of short and medium chain length polychlorinated n-alkanes in environmental samples from selected industrial areas in England and Wales[J]. Environmental Pollution, 2001, 114(3):415-430. [58] STEVENS J L, NORTHCOTT G L, STERN G A, et al. PAHs, PCBs, PCNs, organochlorine pesticides, synthetic musks, and polychlorinated n-alkanes in U.K. Sewage sludge:Survey results and implications[J]. Environmental Science & Technology, 2003, 37(3):462-467. [59] BOGDAL C, ALSBERG T, DIEFENBACHER P S, et al. Fast quantification of chlorinated paraffins in environmental samples by direct injection high-resolution mass spectrometry with pattern deconvolution[J]. Analytical Chemistry, 2015, 87(5):2852-2860. [60] XU J, GAO Y, ZHANG H, et al. Dispersion of short- and medium-chain chlorinated paraffins (CPs) from a CP production plant to the surrounding surface soils and coniferous leaves[J]. Environmental Science & Technology, 2016, 50(23):12759-12766. [61] XU C, ZHANG Q, GAO L R, et al. Spatial distributions and transport implications of short- and medium-chain chlorinated paraffins in soils and sediments from an e-waste dismantling area in China[J]. Science of the Total Environment, 2019, 649:821-828. [62] ZENG L X, WANG T, HAN W Y, et al. Spatial and vertical distribution of short chain chlorinated paraffins in soils from wastewater irrigated farmlands[J]. Environmental Science & Technology, 2011, 45(6):2100-2106. [63] HUANG D, GAO L R, QIAO L, et al. Concentrations of and risks posed by short-chain and medium-chain chlorinated paraffins in soil at a chemical industrial park on the southeast coast of China[J]. Environmental Pollution, 2020, 258:113704. [64] HALSE A K, SCHLABACH M, SCHUSTER J K, et al. Endosulfan, pentachlorobenzene and short-chain chlorinated paraffins in background soils from western europe[J]. Environmental Pollution, 2017, 220:1477-1479. [65] BOGDAL C, NIGGELER N, GLVGE J, et al. Temporal trends of chlorinated paraffins and polychlorinated biphenyls in Swiss soils[J]. Environmental Pollution, 2017, 220:891-899. [66] AAMIR M, YIN S, ZHOU Y, et al. Congener-specific C10-C13 and C14-C17 chlorinated paraffins in Chinese agricultural soils:Spatio-vertical distribution, homologue pattern and environmental behavior[J]. Environmental Pollution, 2019, 245:789-798. [67] WANG X, WANG X, ZHANG Y, et al. Short- and medium-chain chlorinated paraffins in urban soils of Shanghai:Spatial distribution, homologue group patterns and ecological risk assessment[J]. Science of the Total Environment, 2014, 490:144-152. [68] WANG K R, GAO L R, ZHU S, et al. Spatial distributions and homolog profiles of chlorinated nonane paraffins, and short and medium chain chlorinated paraffins in soils from Yunnan, China[J]. Chemosphere, 2020, 247:8. [69] LI H J, FU J J, PAN W X, et al. Environmental behaviour of short-chain chlorinated paraffins in aquatic and terrestrial ecosystems of NY-Alesund and London Island, Svalbard, in the Arctic[J]. Science of the Total Environment, 2017, 590:163-170. [70] LI Y, HOU X, CHEN W, et al. Carbon chain decomposition of short chain chlorinated paraffins mediated by pumpkin and soybean seedlings[J]. Environmental Science & Technology, 2019, 53(12):6765-6772. [71] CHEN M Y, LUO X J, ZHANG X L, et al. Chlorinated paraffins in sediments from the Pearl River Delta, South China:Spatial and temporal distributions and implication for processes[J]. Environmental Science & Technology, 2011, 45(23):9936-9943. [72] 陈晨, 马新东, 国文,等. 辽河口海域短链氯化石蜡污染特征及生物富集[J]. 科学通报, 2014, 59(7):578-585. CHEN C, MA X D,GUO W, et al. Congener specific distribution and bioaccumulation of short-chain chlorinated paraffins in Liao Estuary[J]. Chinese Science Bulletin, 2014, 59(7):578-585(in Chinese).
[73] 潘晓辉. 莱州湾区域表层沉积物中多氯化萘、多溴联苯醚和氯化石蜡的研究[D]. 北京:中国科学院大学,2010. PAN X H. Polychlorinated naphthalenes, polybrominated diphenyl ethers and polychlorinated paraffins in surface sediments of rivers and marine environment in the laizhou bay area[D]. Beijing:University of Chinese Academy of Sciences, 2010(in Chinese). [74] 高媛, 王成, 张海军,等.HRGC/ECNI-LRMS测定大辽河入海口表层沉积物中短链氯化石蜡[J]. 环境科学,2010,31(8):1904-1908. GAO Y, WANG C, ZHANG H J, et al. Analysis of short-chain chlorinated paraffins in sediment samples from the mouth of the daliao river by HRGC/ECNI-LRMS[J]. Environmental Science, 2010, 31(8):1904-1908(in Chinese).
[75] ZENG L X, CHEN R, ZHAO Z S, et al. Spatial distributions and deposition chronology of short chain chlorinated paraffins in marine sediments across the Chinese Bohai and Yellow Seas[J]. Environmental Science & Technology, 2013, 47(20):11449-11456. [76] IOZZA S, SCHMID P, OEHME M. Development of a comprehensive analytical method for the determination of chlorinated paraffins in spruce needles applied in passive air sampling[J]. Environmental Pollution, 2009, 157(12):3218-3224. [77] WANG T, YU J, HAN S, et al. Levels of short chain chlorinated paraffins in pine needles and bark and their vegetation-air partitioning in urban areas[J]. Environmental Pollution, 2015, 196:309-312. [78] WANG X T, ZHOU J, LEI B L, et al. Atmospheric occurrence, homologue patterns and source apportionment of short- and medium-chain chlorinated paraffins in Shanghai, China:Biomonitoring with Masson pine (Pinus massoniana L.) needles[J]. Science of the Total Environment, 2016, 560-561:92-100. [79] HUANG H, GAO L, XIA D, et al. Bioaccumulation and biomagnification of short and medium chain polychlorinated paraffins in different species of fish from Liaodong Bay, North China[J]. Scientific Reports, 2017, 7(1):10749. [80] ZHOU Y, YIN G, DU X, et al. Short-chain chlorinated paraffins (SCCPs) in a freshwater food web from dianshan lake:Occurrence level, congener pattern and trophic transfer[J]. Science of the Total Environment, 2018, 615:1010-1018. [81] DU B, GE J, YANG R, et al. Altitude-dependent accumulation of short chain chlorinated paraffins in fish from alpine lakes and Lhasa River on the Tibetan Plateau[J]. Environmental Pollution, 2019, 250:594-600. [82] LABADIE P, BLASI C, LE MENACH K, et al. Evidence for the widespread occurrence of short- and medium-chain chlorinated paraffins in fish collected from the Rhône River basin (France)[J]. Chemosphere, 2019, 223:232-239. [83] VORKAMP K, RIGÉT F F, BOSSI R, et al. Endosulfan, short-chain chlorinated paraffins (SCCPs) and octachlorostyrene in wildlife from greenland:Levels, trends and methodological challenges[J]. Archives of Environmental Contamination and Toxicology, 2017, 73(4):542-551. [84] YUAN B, VORKAMP K, ROOS A M, et al. Accumulation of short-, medium-, and long-chain chlorinated paraffins in marine and terrestrial animals from Scandinavia[J]. Environmental Science & Technology, 2019, 53(7):3526-3537. [85] CASÀ M V, VAN MOURIK L M, WEIJS L, et al. First detection of short-chain chlorinated paraffins (SCCPs) in humpback whales (Megaptera novaeangliae) foraging in Antarctic waters[J]. Environmental Pollution, 2019, 250:953-959. [86] FRIDÉN U, JANSSON B, PARLAR H. Photolytic clean-up of biological samples for gas chromatographic analysis of chlorinated paraffins[J]. Chemosphere, 2004, 54(8):1079-1083. [87] KOH I O, THIEMANN W. Study of photochemical oxidation of standard chlorinated paraffins and identification of degradation products[J]. Journal of Photochemistry and Photobiology A:Chemistry, 2001, 139(2):205-215. [88] MUKHERJEE A B. The use of chlorinated paraffins and their possible effects in the environment[M]. Helsinki:Vesi- ja ympäristöhallitus, 1990. [89] WILLIS B, CROOKES M J, DIMENT J. Environmental hazard assessment:Chlorinated paraffins[R]. London:Toxicsubstances Division Dept of Theenvironmentl, 1994. [90] RIEGER R, BALLSCHMITER K. Semivolatile organic compounds-polychlorinated dibenzo-p-dioxins (PCDD), dibenzofurans (PCDF), biphenyls (PCB), hexachlorobenzene (HCB), 4,4'-dde and chlorinated paraffins (CP)-as markers in sewer films[J]. Fresenius' Journal of Analytical Chemistry, 1995, 352(7):715-724. [91] ATKINSON R, L. C W P. Experimental investigation of the atmospheric chemistry of aromatic hydrocarbons and long-chain alkanes[J]. Abstracts of Papers of the American Chemical Society, 1986, 192:1-10. [92] FISK A T, WIENS S C, WEBSTER G R B, et al. Accumulation and depuration of sediment-sorbed C12- and C16-polychlorinated alkanes by oligochaetes (Lumbriculus variegatus)[J]. Environmental Toxicology and Chemistry 1998, 17(10):2019-2026. [93] SIJM D T H M, SINNIGE T L. Experimental octanol/water partition coefficients of chlorinated paraffins[J]. Chemosphere, 1995, 31(11):4427-4435. [94] DROUILLARD K, TOMY G, MUIR D, et al. Volatility of chlorinated n-alkanes (C10-C12):Vapor pressures and henry's law constants[J]. Environmental Toxicology and Chemistry, 1998, 17(7):1252-1260. [95] THOMPSON R S, MADELEY J R. Toxicity of a chlorinated paraffin (58% chlorination of short chain length n-paraffins) to the marine alga Skeletonema costatum[R]. London:Brixham Laboratory, 1983. [96] FISK A T, BERGMAN A, CYMBALISTY C D, et al. Dietary accumulation of C12- and C16-chlorinated alkanes by juvenile rainbow trout (Oncorhynchus mykiss)[J]. Environmental Toxicology and Chemistry, 1996, 15:1775-1782. [97] FISK A T, CYMBALISTY C D, TOMY G T, et al. Dietary accumulation and depuration of individual C10-, C11- and C14-polychlorinated alkanes by juvenile rainbow trout (Oncorhynchus mykiss)[J]. Aquatic Toxicology, 1998, 43(2):209-221. [98] FISK A T, TOMY G T, CYMBALISTY C D, et al. Dietary accumulation and quantitative structure activity relationships for depuration and biotransformation of short, medium and long carbon chain polychlorinated alkanes by juvenile rainbow trout (Oncorhynchus mykiss)[J]. Environmental Toxicology and Chemistry, 2000, 19(6):1508-1516.
计量
- 文章访问数: 8369
- HTML全文浏览数: 8369
- PDF下载数: 309
- 施引文献: 0