GC-MS-DRS快速确证电子电气产品中有毒有害有机物质
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摘要: 自主建立了基于解卷积报告软件的含有110种电子电气中有毒有害有机物质的数据库,作为标准的GC/MS数据库来确证化合物,解卷积报告软件帮助确证谱图中隐藏的上述有毒有害有机物质.该方法已经在电子电气有机化学安全检测项目中得到了充分应用,实践表明,该方法不仅在某检测项目目标化合物如禁用多环芳烃等确证方面优于目前基于GC/MS化学工作站的检测方法,假阳性几率大大减少,同时也能够提供准确的谱图内所含有的其它检测项目目标化合物信息,这非常有利于加强对电子电气产品中所含有的有毒有害有机物质的监控和风险预警.
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关键词:
- 解卷积报告软件数据库 /
- 气相色谱质谱仪 /
- 电子电气产品 /
- 有毒有害有机物质 /
- 风险预警
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[1] Regulation(EC) No 1907/2006 of the european parliament and of the council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) [2] Directive 2002/954 EC of the european parliament and of the council of 27 January 2003 on the restriction of the use of certain hazardous substances in electrical and electronic equipment [3] Directive 2009/425/EC of commission decision amending Council Directive 76/769/EEC as regards restrictions on the marketing and use of organostannic compounds for the purpose of adapting its Annex I to technical progress Notified under document number C(2009) 4084; Text with EEA relevance [4] Directive 2005/84/EC of the european parliament and of the council of 14 December 2005(phthalates in toys and childcare articles) [5] Directive 2002/261/EC of the european parliament and of the council of 19 July 2002 (azocolourants) [6] CEN EN71-9:2005/A1:2007 Safety of toys-Part 9: Organic chemical compounds-Requirements [7] ZEK01.2-08 Testing and Validation of Polycyclic Aromatic Hydrocarbons (PAH) in the course of GS-Mark Certification [8] Directive 2009/48/EC of the european parliament and of the council of 18 June 2009 on the safety of toys [9] Gomez M J,Gomez-Ramos M M,et al.A new gas chromatography/mass spectrometry method for the simultaneous analysis of target and non-target organic contaminants in waters[J].J Chromatogr A,,2009,1216:4071-4082 [10] Jie Chen,Chin-Kai Meng,et al.The use of Deconvolution Reporting Software and backflush improves the speed and accuracy of data processing for urinary organic acid analysis[J].Clinica Chimica Acta,,2009,405:53-59 [11] Nestor Etxebarria,Olatz Zuloaga,et al.Retention-time locked methods in gas chromatography[J].J Chromatogr A,,2009,1216:1624-1629 -
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