高级搜索

固相微萃取-气相色谱/质谱联用法测定饮用水中苯类化合物

,  , 

downloadPDF

上一篇

下一篇

周珊, 康君行, 黄骏雄. 固相微萃取-气相色谱/质谱联用法测定饮用水中苯类化合物[J]. 环境化学, 2001, 20(2): 191-195.
引用本文: 周珊, 康君行, 黄骏雄. 固相微萃取-气相色谱/质谱联用法测定饮用水中苯类化合物[J]. 环境化学, 2001, 20(2): 191-195.
shu
Zheu Shan, Kang Junxing, Huang Junxiong. DETERMINATION OF PHENYL COMPOUNDS IN DRINKINGWATER BY SOLID PHASE MICROEXTRACTION COUPLEDWITH CAPILIARY GC/MS[J]. Environmental Chemistry, 2001, 20(2): 191-195.
Citation: Zheu Shan, Kang Junxing, Huang Junxiong. DETERMINATION OF PHENYL COMPOUNDS IN DRINKINGWATER BY SOLID PHASE MICROEXTRACTION COUPLEDWITH CAPILIARY GC/MS[J]. Environmental Chemistry, 2001, 20(2): 191-195.
shu

固相微萃取-气相色谱/质谱联用法测定饮用水中苯类化合物

DETERMINATION OF PHENYL COMPOUNDS IN DRINKINGWATER BY SOLID PHASE MICROEXTRACTION COUPLEDWITH CAPILIARY GC/MS

  • 1.

    Department of Central Instrumental Analysis, Beijing Municiple Center for Hygiene and Dissease Control, Beijing, 100013;

  • 2.

    Research Center for Eco-Environmental Sciences, Chinee Academy of Sciences, Beijing, 100085

  • 摘要: 用固相微萃取(SPME)-气相色谱/质谱联用法测定饮用水中苯类化合物,以100μmPDMS(聚二甲基硅氧烷)萃取针提取、浓缩、分离与测定九种目标化合物。萃取时间经优化选定为8min,而热解析时间设定为2min.本方法的相对标准偏差小于5%,线性范围宽(20ng·ml-1-10000ng·ml-1),多数化合物的检测限低于5μg·l-1.饮用水样品检测显示,样品加标回收率范围在84%至110%内。
    Abstract: This paper presents determination of phenyl compounds in drinking water by solid phase mi-croextraction (SPME) technique coupled with capillary gas chromatography. Headspace system has been used to optimize the extraction parameters. The extraction fiber coated with 100 μm PDMS was selected to extract the related 9 target compounds. Extraction time was optimized and set at 8 min, while 2 min was chosen to be the thermal desorption time. Relative standard deviation (RSD) of the analytical method was found to be less than 5 % , wide linear range was reached and limit of de-tection was less than 5ng·ml-1 for most of the 9 analytes. Drinking water samples were tested, re-covery range for the spiked samples was from 84% to 110%. GC/MSD was employed to finish qualitative study. It ends up with the conclusion that SPME is a fast, simple, solvent-free, sensi-tive and powerful technique to extract and determine phenyl compounds in drinking water.
  • 加载中
  • 加载中
WeChat 点击查看大图
计量
  • 文章访问数:  587
  • HTML全文浏览数:  587
  • PDF下载数:  226
  • 施引文献:  0
出版历程
  • 收稿日期:  2000-09-10
周珊, 康君行, 黄骏雄. 固相微萃取-气相色谱/质谱联用法测定饮用水中苯类化合物[J]. 环境化学, 2001, 20(2): 191-195.
引用本文: 周珊, 康君行, 黄骏雄. 固相微萃取-气相色谱/质谱联用法测定饮用水中苯类化合物[J]. 环境化学, 2001, 20(2): 191-195.
shu
Zheu Shan, Kang Junxing, Huang Junxiong. DETERMINATION OF PHENYL COMPOUNDS IN DRINKINGWATER BY SOLID PHASE MICROEXTRACTION COUPLEDWITH CAPILIARY GC/MS[J]. Environmental Chemistry, 2001, 20(2): 191-195.
Citation: Zheu Shan, Kang Junxing, Huang Junxiong. DETERMINATION OF PHENYL COMPOUNDS IN DRINKINGWATER BY SOLID PHASE MICROEXTRACTION COUPLEDWITH CAPILIARY GC/MS[J]. Environmental Chemistry, 2001, 20(2): 191-195.
shu

固相微萃取-气相色谱/质谱联用法测定饮用水中苯类化合物

  • 收稿日期:  2000-09-10

摘要: 用固相微萃取(SPME)-气相色谱/质谱联用法测定饮用水中苯类化合物,以100μmPDMS(聚二甲基硅氧烷)萃取针提取、浓缩、分离与测定九种目标化合物。萃取时间经优化选定为8min,而热解析时间设定为2min.本方法的相对标准偏差小于5%,线性范围宽(20ng·ml-1-10000ng·ml-1),多数化合物的检测限低于5μg·l-1.饮用水样品检测显示,样品加标回收率范围在84%至110%内。

English Abstract

    全文HTML

参考文献 (0)

返回顶部

目录

/

返回文章
返回

Copyright © 2019 中国科学院生态环境研究中心