被动式甲醛监测器的研制
A PASSIVE PERSONAL FORMALDEHYDE DOSIMETER AND ITS APPLICATION
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摘要: 本文研制的被动式甲醛监测器,以20%二乙醇胺处理过的玻璃棉为吸收介质,并用多聚甲醛在恒温下分解生成甲醛的方法,制备ppb到ppm级的甲醛气源,然后用AHMT比色法测定监测器收集的甲醛量。监测器能准确测定120ppb(取样7d)到20ppm(取样8h)的甲醛,重复性好,变异系数小于16%,平均采样速度为5.0ml/min。Abstract: A passive personal formaldehyde dosimeter he.s been developed for determination of formaldehyde in ambient air. The dosimeter consists of a capped polymethyl methacrylate tube packed with glass wool treated with 20% diethanolamine. The formaldehyde Was analyzed by 4-amino-3-hydra-zino-5-mercapto-1,2,4-triazole(AHMT) colormetric method. The continuous generation of gaseous formaldehyde was accomplished by decomposing para-formaldehyde at 30℃. Results indicated that the dosimeter is suitable over a range of formaldehyde concentrations from 120ppb(7-day sample)to 20ppm (8-h sample). The reproducibility was found to be gcod, with a relative standard deviation of less than 16%.A sampling rate of 5.0ml/min has been obtained.
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