钛基SnO2、Cr2O3、SnO2/Co催化电极的制备和性能比较

周元祥, 沈浩. 钛基SnO2、Cr2O3、SnO2/Co催化电极的制备和性能比较[J]. 环境化学, 2010, 29(6): 1027-1031.
引用本文: 周元祥, 沈浩. 钛基SnO2、Cr2O3、SnO2/Co催化电极的制备和性能比较[J]. 环境化学, 2010, 29(6): 1027-1031.
ZHOU Yuanxiang, SHEN Hao. PREPARATION AND PERFORMANCE COMPARISON OF TITANIUM MATRIX (SnO2, Cr2O3, SnO2/Co) CATALYTIC ELECTRODE[J]. Environmental Chemistry, 2010, 29(6): 1027-1031.
Citation: ZHOU Yuanxiang, SHEN Hao. PREPARATION AND PERFORMANCE COMPARISON OF TITANIUM MATRIX (SnO2, Cr2O3, SnO2/Co) CATALYTIC ELECTRODE[J]. Environmental Chemistry, 2010, 29(6): 1027-1031.

钛基SnO2、Cr2O3、SnO2/Co催化电极的制备和性能比较

  • 基金项目:

    国家重大水专项(2008ZX07316-003)

PREPARATION AND PERFORMANCE COMPARISON OF TITANIUM MATRIX (SnO2, Cr2O3, SnO2/Co) CATALYTIC ELECTRODE

  • Fund Project:
  • 摘要: 以涂覆热分解法制备的DSA阳极(Ti/SnO2,Ti/Cr2O3,Ti/Co/SnO2),表面晶体颗粒饱满,分布均匀致密,覆盖度好,裂缝较少,催化活化性能明显增加;电极寿命和未经过涂覆的钛基体相比也有显著提高.NH4-N和COD去除率提高了20%—40%.电极寿命与未经过涂覆的钛基体相比提高到50%—119.2%.Ti/SnO2电极的COD去除效率较高,Ti/Cr2O3电极的NH4-N去除效率较高.
  • 加载中
  • [1] 邹启光,周恭明.电催化氧化处理有机废水的应用现状和展望[J].福建环境,2003,20(3):35-36
    [2] 吴伟,吴春笃.电催化氧化技术处理硝基苯废水的试验研究[J].环境科学与技术,2006,29(11):82-85
    [3] 刘占孟,向速林,张琦,等. 染料废水电催化氧化及降解动力学研究[J].环境科学与技术,2006,29(7):23-25
    [4] Wang Bo, Kong Wuping, Ma Hongzhu. Electrochemical treatment of paper mill wastewater using three-dimensional electrodes with Ti/Co/SnO2-Sb2O5 anode[J].Journal of Hazardous Materials, 2007,146: 295-301
    [5] Fockedey E, Lierde Van A. Coupling of anodic and cathodic reaction of phenol electro-oxidation using three dimensional electrodes [J]. Water Research,2002, 36(16):4169-4175
    [6] Drogui P, Elmaleh S, Rumeau M, et al. Oxidizing and disinfection by hydrogen peroxide produced in a two-electrode cell [J]. Water Research, 2001,35(13):3235-3241
    [7] Lipp L, Pletcher D. Preparation and characterization of tin dioxide coated titanium electrodes [J]. Electrochimica, Acta, 1997, 42(7):1091-1099
    [8] De Pauli C P, Trasatti S. Composite materials for electrocatalysis of O2 evolution:IrO2+SnO2 in acid solution[J]. Journal of Electroanalytical Chemistry, 2002,538-539:145-151
    [9] Comninellis C. Electrocatalysis in the electrochemical conversion/combussion of organic pollutants for waste watertreatment [J]. Electrochemica Acta,1994,39(11-12):1857-1862
    [10] 赵国华,胡惠康,李楹,等. 氧化物修饰电极降解有机污染物的电催化特性[J]. 中国环境科学,2003,23(4):385-389
  • 加载中
计量
  • 文章访问数:  941
  • HTML全文浏览数:  917
  • PDF下载数:  630
  • 施引文献:  0
出版历程
  • 收稿日期:  2010-01-07

钛基SnO2、Cr2O3、SnO2/Co催化电极的制备和性能比较

  • 1. 合肥工业大学资源与环境工程学院, 合肥, 230009
基金项目:

国家重大水专项(2008ZX07316-003)

摘要: 以涂覆热分解法制备的DSA阳极(Ti/SnO2,Ti/Cr2O3,Ti/Co/SnO2),表面晶体颗粒饱满,分布均匀致密,覆盖度好,裂缝较少,催化活化性能明显增加;电极寿命和未经过涂覆的钛基体相比也有显著提高.NH4-N和COD去除率提高了20%—40%.电极寿命与未经过涂覆的钛基体相比提高到50%—119.2%.Ti/SnO2电极的COD去除效率较高,Ti/Cr2O3电极的NH4-N去除效率较高.

English Abstract

参考文献 (10)

目录

/

返回文章
返回