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醇-柴油间界面张力及对砂柱柴油去除率的影响

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郑海亮, 陈家军, 杨建, 裴玉梅, 鞠丽萍, 蒋晶. 醇-柴油间界面张力及对砂柱柴油去除率的影响[J]. 环境化学, 2009, 28(3): 422-426.
引用本文: 郑海亮, 陈家军, 杨建, 裴玉梅, 鞠丽萍, 蒋晶. 醇-柴油间界面张力及对砂柱柴油去除率的影响[J]. 环境化学, 2009, 28(3): 422-426.
shu
ZHENG Hai-liang, CHEN Jia-jun, YANG Jian, PEI Yu-mei, JU Li-ping, JIANG Jing . THE EFFECTS OF ALCOHOL ON DIESEL OIL-WATER SURFACE/INTERFACIAL TENSION AND DIESEL OIL REMOVAL EFFICIENCY FROM SAND COLUMN TESTS[J]. Environmental Chemistry, 2009, 28(3): 422-426.
Citation: ZHENG Hai-liang, CHEN Jia-jun, YANG Jian, PEI Yu-mei, JU Li-ping, JIANG Jing . THE EFFECTS OF ALCOHOL ON DIESEL OIL-WATER SURFACE/INTERFACIAL TENSION AND DIESEL OIL REMOVAL EFFICIENCY FROM SAND COLUMN TESTS[J]. Environmental Chemistry, 2009, 28(3): 422-426.
shu

醇-柴油间界面张力及对砂柱柴油去除率的影响

  • 1.

    北京师范大学环境学院, 环境模拟与污染控制国家重点联合实验室, 北京, 100875;

  • 2.

    黑龙江省绥滨县环保局, 绥滨, 156200

  • 基金项目:

    国家自然科学基金(40772148)

    国家自然科学基金(40272107)支持项目

THE EFFECTS OF ALCOHOL ON DIESEL OIL-WATER SURFACE/INTERFACIAL TENSION AND DIESEL OIL REMOVAL EFFICIENCY FROM SAND COLUMN TESTS

  • 1.

    School of Environment, Beijing Normal University, State Key Joint Laboratory of Environmental Simulation and Pollution Control, Beijing, 100875, China;

  • 2.

    Hei Long Jiang Suibin Environment Protection Bureau, Suibin, 156200, China

  • Fund Project:

  • 摘要: 研究了四种醇类助溶剂表面/界面张力随浓度的变化,表面张力与界面张力之间的关系,以及界面张力降低对残油去除率的影响.结果表明,醇的浓度与表面张力之间满足Szyskowski模型,与界面张力间呈对数函数关系,用Fowkes模型计算乙醇溶液的色散力与理论预测具有一致性.四种醇对油水界面降低能力的顺序为:丁醇异丙醇乙醇异丁醇,醇溶液-柴油界面张力基本上不随时间发生变化;乙醇对含油砂柱冲洗试验结果表明除油率与界面张力降低呈指数关系.
    Abstract: The functional relationship of interfacial/surface tension v.s concentration of four alcohols, interfacial tension v.s surface tension and the effect of interfacial tension to residual oil removal efficiency was studied. The results show that surface tension of cosolvent satisfies the Szyskowski model, while interfacial tension of cosolvent solution exhibits an exponent function relationship with the concentration of cosolvent, and the diffusion force calculated by Fowkes model consists with the theoretic prediction. The sequence for interface tesioin decreasing of four alcohols is as: butanolisobutanol ethanolisopropanol. Moreover, no obvious changes in interfacial tension of cosolvent and diesel oil are observed. Exponential function relationship is found between the concentration of ethanol and removal efficiency of diesel oil from diesel oil-containing sand column. The relationshiop between interfacial tension and adhesion work can well explain the experimental result.
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  • 收稿日期:  2008-06-12
郑海亮, 陈家军, 杨建, 裴玉梅, 鞠丽萍, 蒋晶. 醇-柴油间界面张力及对砂柱柴油去除率的影响[J]. 环境化学, 2009, 28(3): 422-426.
引用本文: 郑海亮, 陈家军, 杨建, 裴玉梅, 鞠丽萍, 蒋晶. 醇-柴油间界面张力及对砂柱柴油去除率的影响[J]. 环境化学, 2009, 28(3): 422-426.
shu
ZHENG Hai-liang, CHEN Jia-jun, YANG Jian, PEI Yu-mei, JU Li-ping, JIANG Jing . THE EFFECTS OF ALCOHOL ON DIESEL OIL-WATER SURFACE/INTERFACIAL TENSION AND DIESEL OIL REMOVAL EFFICIENCY FROM SAND COLUMN TESTS[J]. Environmental Chemistry, 2009, 28(3): 422-426.
Citation: ZHENG Hai-liang, CHEN Jia-jun, YANG Jian, PEI Yu-mei, JU Li-ping, JIANG Jing . THE EFFECTS OF ALCOHOL ON DIESEL OIL-WATER SURFACE/INTERFACIAL TENSION AND DIESEL OIL REMOVAL EFFICIENCY FROM SAND COLUMN TESTS[J]. Environmental Chemistry, 2009, 28(3): 422-426.
shu

醇-柴油间界面张力及对砂柱柴油去除率的影响

  • 1.  北京师范大学环境学院, 环境模拟与污染控制国家重点联合实验室, 北京, 100875;
  • 2.  黑龙江省绥滨县环保局, 绥滨, 156200
  • 收稿日期:  2008-06-12
基金项目:

国家自然科学基金(40772148)

国家自然科学基金(40272107)支持项目

摘要: 研究了四种醇类助溶剂表面/界面张力随浓度的变化,表面张力与界面张力之间的关系,以及界面张力降低对残油去除率的影响.结果表明,醇的浓度与表面张力之间满足Szyskowski模型,与界面张力间呈对数函数关系,用Fowkes模型计算乙醇溶液的色散力与理论预测具有一致性.四种醇对油水界面降低能力的顺序为:丁醇异丙醇乙醇异丁醇,醇溶液-柴油界面张力基本上不随时间发生变化;乙醇对含油砂柱冲洗试验结果表明除油率与界面张力降低呈指数关系.

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