杂原子掺杂碳材料用于电合成过氧化氢的研究进展

王以恒; 赵尔卓; 夏广森; 管少华; 展巨宏

doi:10.7524/j.issn.0254-6108.2022061202

[1]

MYERS R L. The 100 most important chemical compounds a reference guide[M]. Westport, Conn. : Greenwood Press, 2007

[2]

CAMPOS-MARTIN J M, BLANCO-BRIEVA G, FIERRO J L G. Hydrogen peroxide synthesis: An outlook beyond the anthraquinone process [J]. Angewandte Chemie International Edition, 2006, 45(42): 6962-6984. doi: 10.1002/anie.200503779

[3]

刘淼, 钱美荣, 苏荣梅, 等. 羟基自由基氧化处理垃圾渗滤液中高浓度氨氮 [J]. 水处理技术, 2007, 33(11): 79-81,88. doi: 10.16796/j.cnki.1000-3770.2007.11.022 LIU M, QIAN M R, SU R M, et al. High strength nh₃-n removal in landfill leachate by hydroxy radical oxidation [J]. Technology of Water Treatment, 2007, 33(11): 79-81,88(in Chinese). doi: 10.16796/j.cnki.1000-3770.2007.11.022

[4]

DOLL M, MORGAN D J, ANDERSON D, et al. Touchless technologies for decontamination in the hospital: A review of hydrogen peroxide and UV devices [J]. Current Infectious Disease Reports, 2015, 17(9): 498.

[5]

潘智勇, 邢定峰. 过氧化氢市场现状和技术发展趋势 [J]. 现代化工, 2021, 41(4): 11-16. doi: 10.16606/j.cnki.issn0253-4320.2021.04.003 PAN Z Y, XING D F. Market status and technology development trend of hydrogen peroxide [J]. Modern Chemical Industry, 2021, 41(4): 11-16(in Chinese). doi: 10.16606/j.cnki.issn0253-4320.2021.04.003

[6]

ZHANG Z H, MENG H S, WANG Y J, et al. Fabrication of graphene@graphite-based gas diffusion electrode for improving H₂O₂ generation in Electro-Fenton process [J]. Electrochimica Acta, 2018, 260: 112-120. doi: 10.1016/j.electacta.2017.11.048

[7]

陈君伟, 孙绍晖. 工业制过氧化氢的研究进展 [J]. 河南化工, 2017, 34(12): 12-17. doi: 10.14173/j.cnki.hnhg.2017.12.004 CHEN J W, SUN S H. Research progress of industrial hydrogen peroxide [J]. Henan Chemical Industry, 2017, 34(12): 12-17(in Chinese). doi: 10.14173/j.cnki.hnhg.2017.12.004

[8]

何峰, 张静静, 陈奕君, 等. 电化学氧还原反应合成H₂O₂碳基催化剂研究进展 [J]. 储能科学与技术, 2021, 10(6): 1963-1976. HE F, ZHANG J J, CHEN Y J, et al. Recent progress on carbon-based catalysts for electrochemical synthesis of H₂O₂ via oxygen reduction reaction [J]. Energy Storage Science and Technology, 2021, 10(6): 1963-1976(in Chinese).

[9]

CHAI G L, HOU Z F, IKEDA T, et al. Two-electron oxygen reduction on carbon materials catalysts: Mechanisms and active sites [J]. The Journal of Physical Chemistry C, 2017, 121(27): 14524-14533. doi: 10.1021/acs.jpcc.7b04959

[10]

闫啸, 石文武, 王新中. 碳基电催化材料选择性合成过氧化氢研究进展 [J]. 新型炭材料, 2022, 37(1): 223-236. doi: 10.1016/S1872-5805(22)60582-1 YAN X, SHI W W, WANG X Z. Carbon based electrocatalysts for selective hydrogen peroxide conversion [J]. New Carbon Materials, 2022, 37(1): 223-236(in Chinese). doi: 10.1016/S1872-5805(22)60582-1

[11]

ZHOU Y, CHEN G, ZHANG J J. A review of advanced metal-free carbon catalysts for oxygen reduction reactions towards the selective generation of hydrogen peroxide [J]. Journal of Materials Chemistry A, 2020, 8(40): 20849-20869. doi: 10.1039/D0TA07900F

[12]

BU Y F, WANG Y B, HAN G F, et al. Carbon-based electrocatalysts for efficient hydrogen peroxide production [J]. Advanced Materials, 2021, 33(49): e2103266. doi: 10.1002/adma.202103266

[13]

VERDAGUER-CASADEVALL A, DEIANA D, KARAMAD M, et al. Trends in the electrochemical synthesis of H₂O₂: Enhancing activity and selectivity by electrocatalytic site engineering [J]. Nano Letters, 2014, 14(3): 1603-1608. doi: 10.1021/nl500037x

[14]

FORTUNATO G V, PIZZUTILO E, MINGERS A M, et al. Impact of palladium loading and interparticle distance on the selectivity for the oxygen reduction reaction toward hydrogen peroxide [J]. The Journal of Physical Chemistry C, 2018, 122(28): 15878-15885. doi: 10.1021/acs.jpcc.8b04262

[15]

LEDENDECKER M, PIZZUTILO E, MALTA G, et al. Isolated Pd sites as selective catalysts for electrochemical and direct hydrogen peroxide synthesis [J]. ACS Catalysis, 2020, 10(10): 5928-5938. doi: 10.1021/acscatal.0c01305

[16]

LEE S, CHUNG Y M. Direct synthesis of H₂O₂ over acid-treated Pd/C catalyst derived from a Pd-Co core-shell structure [J]. Catalysis Today, 2020, 352: 270-278. doi: 10.1016/j.cattod.2019.09.038

[17]

CHOI C H, KWON H C, YOOK S, et al. Hydrogen peroxide synthesis via enhanced two-electron oxygen reduction pathway on carbon-coated Pt surface [J]. The Journal of Physical Chemistry C, 2014, 118(51): 30063-30070. doi: 10.1021/jp5113894

[18]

CHOI C H, KIM M, KWON H C, et al. Tuning selectivity of electrochemical reactions by atomically dispersed platinum catalyst [J]. Nature Communications, 2016, 7: 10922. doi: 10.1038/ncomms10922

[19]

PIZZUTILO E, KASIAN O, CHOI C H, et al. Electrocatalytic synthesis of hydrogen peroxide on Au-Pd nanoparticles: From fundamentals to continuous production [J]. Chemical Physics Letters, 2017, 683: 436-442. doi: 10.1016/j.cplett.2017.01.071

[20]

SIAHROSTAMI S, VERDAGUER-CASADEVALL A, KARAMAD M, et al. Enabling direct H₂O₂ production through rational electrocatalyst design [J]. Nature Materials, 2013, 12(12): 1137-1143. doi: 10.1038/nmat3795

[21]

周伟. H₂O₂的电催化合成及·OH产用效能提升[D]. 哈尔滨: 哈尔滨工业大学, 2019. ZHOU W. H₂O₂ electrocatalytic synthesis and the enhancement of generation and utilization efficiency of ·OH[D]. Harbin: Harbin Institute of Technology, 2019(in Chinese).

[22]

LIU H, CHENG S A, LOGAN B E. Power generation in fed-batch microbial fuel cells as a function of ionic strength, temperature, and reactor configuration [J]. Environmental Science & Technology, 2005, 39(14): 5488-5493.

[23]

da POZZO A, PALMA L D, MERLI C, et al. An experimental comparison of a graphite electrode and a gas diffusion electrode for the cathodic production of hydrogen peroxide [J]. Journal of Applied Electrochemistry, 2005, 35(4): 413-419. doi: 10.1007/s10800-005-0800-2

[24]

SALARI D, NIAEI A, KHATAEE A, et al. Electrochemical treatment of dye solution containing C. I. Basic Yellow 2 by the peroxi-coagulation method and modeling of experimental results by artificial neural networks [J]. Journal of Electroanalytical Chemistry, 2009, 629(1/2): 117-125.

[25]

ÖZCAN A, ŞAHIN Y, SAVAŞ KOPARAL A, et al. Carbon sponge as a new cathode material for the electro-Fenton process: Comparison with carbon felt cathode and application to degradation of synthetic dye basic blue 3 in aqueous medium [J]. Journal of Electroanalytical Chemistry, 2008, 616(1/2): 71-78.

[26]

WANG A M, QU J H, RU J, et al. Mineralization of an azo dye Acid Red 14 by electro-Fenton's reagent using an activated carbon fiber cathode [J]. Dyes and Pigments, 2005, 65(3): 227-233. doi: 10.1016/j.dyepig.2004.07.019

[27]

SANG Z Y, HOU F, WANG S H, et al. Research progress on carbon-based non-metallic nanomaterials as catalysts for the two-electron oxygen reduction for hydrogen peroxide production [J]. New Carbon Materials, 2022, 37(1): 136-151. doi: 10.1016/S1872-5805(22)60583-3

[28]

YU F K, ZHOU M H, YU X M. Cost-effective electro-Fenton using modified graphite felt that dramatically enhanced on H₂O₂ electro-generation without external aeration [J]. Electrochimica Acta, 2015, 163: 182-189. doi: 10.1016/j.electacta.2015.02.166

[29]

SHENG Y P, ZHAO Y, WANG X L, et al. Electrogeneration of H₂O₂ on a composite acetylene black-PTFE cathode consisting of a sheet active core and a dampproof coating [J]. Electrochimica Acta, 2014, 133: 414-421. doi: 10.1016/j.electacta.2014.04.071

[30]

YANG W L, ZHOU M H, CAI J, et al. Ultrahigh yield of hydrogen peroxide on graphite felt cathode modified with electrochemically exfoliated graphene [J]. Journal of Materials Chemistry A, 2017, 5(17): 8070-8080. doi: 10.1039/C7TA01534H

[31]

FELLINGER T P, HASCHÉ F, STRASSER P, et al. Mesoporous nitrogen-doped carbon for the electrocatalytic synthesis of hydrogen peroxide [J]. Journal of the American Chemical Society, 2012, 134(9): 4072-4075. doi: 10.1021/ja300038p

[32]

LEE Y H, LI F, CHANG K H, et al. Novel synthesis of N-doped porous carbons from collagen for electrocatalytic production of H₂O₂ [J]. Applied Catalysis B:Environmental, 2012, 126: 208-214. doi: 10.1016/j.apcatb.2012.06.031

[33]

ZHONG R S, QIN Y H, NIU D F, et al. Effect of carbon nanofiber surface functional groups on oxygen reduction in alkaline solution [J]. Journal of Power Sources, 2013, 225: 192-199. doi: 10.1016/j.jpowsour.2012.10.043

[34]

HASCHÉ F, OEZASLAN M, STRASSER P, et al. Electrocatalytic hydrogen peroxide formation on mesoporous non-metal nitrogen-doped carbon catalyst [J]. Journal of Energy Chemistry, 2016, 25(2): 251-257. doi: 10.1016/j.jechem.2016.01.024

[35]

LU Z Y, CHEN G X, SIAHROSTAMI S, et al. High-efficiency oxygen reduction to hydrogen peroxide catalysed by oxidized carbon materials [J]. Nature Catalysis, 2018, 1(2): 156-162. doi: 10.1038/s41929-017-0017-x

[36]

ZHOU L, ZHOU M H, ZHANG C, et al. Electro-Fenton degradation of p-nitrophenol using the anodized graphite felts [J]. Chemical Engineering Journal, 2013, 233: 185-192. doi: 10.1016/j.cej.2013.08.044

[37]

MIAO J, ZHU H, TANG Y, et al. Graphite felt electrochemically modified in H₂SO₄ solution used as a cathode to produce H₂O₂ for pre-oxidation of drinking water [J]. Chemical Engineering Journal, 2014, 250: 312-318. doi: 10.1016/j.cej.2014.03.043

[38]

ZHAO K, QUAN X, CHEN S, et al. Enhanced electro-Fenton performance by fluorine-doped porous carbon for removal of organic pollutants in wastewater [J]. Chemical Engineering Journal, 2018, 354: 606-615. doi: 10.1016/j.cej.2018.08.051

[39]

ZHAO K, SU Y, QUAN X, et al. Enhanced H₂O₂ production by selective electrochemical reduction of O₂ on fluorine-doped hierarchically porous carbon [J]. Journal of Catalysis, 2018, 357: 118-126. doi: 10.1016/j.jcat.2017.11.008

[40]

LIU L, ZHANG J, MA W J, et al. Co/N co-doped graphene-like nanocarbon for highly efficient oxygen reduction electrocatalyst [J]. Science China Materials, 2019, 62(3): 359-367. doi: 10.1007/s40843-018-9322-y

[41]

ZHANG W M, CHU J J, LI S F, et al. CoN_xC active sites-rich three-dimensional porous carbon nanofibers network derived from bacterial cellulose and bimetal-ZIFs as efficient multifunctional electrocatalyst for rechargeable Zn-air batteries [J]. Journal of Energy Chemistry, 2020, 51: 323-332. doi: 10.1016/j.jechem.2020.04.067

[42]

ZHANG J Y, ZHANG G, JIN S Y, et al. Graphitic N in nitrogen-Doped carbon promotes hydrogen peroxide synthesis from electrocatalytic oxygen reduction [J]. Carbon, 2020, 163: 154-161. doi: 10.1016/j.carbon.2020.02.084

[43]

SUN Y Y, LI S, JOVANOV Z P, et al. Structure, activity, and faradaic efficiency of nitrogen-doped porous carbon catalysts for direct electrochemical hydrogen peroxide production [J]. ChemSusChem, 2018, 11(19): 3388-3395. doi: 10.1002/cssc.201801583

[44]

WAN J, ZHANG G Q, JIN H R, et al. Microwave-assisted synthesis of well-defined nitrogen doping configuration with high centrality in carbon to identify the active sites for electrochemical hydrogen peroxide production [J]. Carbon, 2022, 191: 340-349. doi: 10.1016/j.carbon.2022.01.061

[45]

HU Y Z, ZHANG J J, SHEN T, et al. Efficient electrochemical production of H₂O₂ on hollow N-doped carbon nanospheres with abundant micropores [J]. ACS Applied Materials & Interfaces, 2021, 13(25): 29551-29557.

[46]

KIM H W, ROSS M B, KORNIENKO N, et al. Efficient hydrogen peroxide generation using reduced graphene oxide-based oxygen reduction electrocatalysts [J]. Nature Catalysis, 2018, 1(4): 282-290. doi: 10.1038/s41929-018-0044-2

[47]

MATSUBARA K, WAKI K. The effect of O-functionalities for the electrochemical reduction of oxygen on MWCNTs in acid media [J]. Electrochemical and Solid-State Letters, 2010, 13(8): F7. doi: 10.1149/1.3428472

[48]

SUN X J, SONG P, ZHANG Y W, et al. A class of high performance metal-free oxygen reduction electrocatalysts based on cheap carbon blacks [J]. Scientific Reports, 2013, 3: 2505. doi: 10.1038/srep02505

[49]

LI X Y, WANG X P, XIAO G Z, et al. Identifying active sites of boron, nitrogen co-doped carbon materials for the oxygen reduction reaction to hydrogen peroxide [J]. Journal of Colloid and Interface Science, 2021, 602: 799-809. doi: 10.1016/j.jcis.2021.06.068

[50]

QIN M C, FAN S Y, WANG L, et al. Oxygen and nitrogen co-doped ordered mesoporous carbon materials enhanced the electrochemical selectivity of O₂ reduction to H₂O₂ [J]. Journal of Colloid and Interface Science, 2020, 562: 540-549. doi: 10.1016/j.jcis.2019.11.080

[51]

BIEMOLT J, van der VEEN K, GEELS N J, et al. Efficient oxygen reduction to H₂O₂ in highly porous Manganese and nitrogen co-doped carbon nanorods enabling electro-degradation of bulk organics [J]. Carbon, 2019, 155: 643-649. doi: 10.1016/j.carbon.2019.09.034

[52]

魏家崴, 李平, 强富强, 等. 杂原子掺杂碳材料用于氧还原反应催化剂的研究 [J]. 功能材料, 2021, 52(2): 2098-2108. WEI J W, LI P, QIANG F Q, et al. Review of heteroatom-doped carbon materials as catalysts for oxygen reduction reaction [J]. Journal of Functional Materials, 2021, 52(2): 2098-2108(in Chinese).

[53]

李宇明, 刘梓烨, 张启扬, 等. 氮掺杂碳材料的制备及其在催化领域中的应用 [J]. 化工学报, 2021, 72(8): 3919-3932. LI Y M, LIU Z Y, ZHANG Q Y, et al. Preparation of nitrogen-doped carbon materials and their applications in catalysis [J]. CIESC Journal, 2021, 72(8): 3919-3932(in Chinese).

[54]

GUO D H, SHIBUYA R, AKIBA C, et al. Active sites of nitrogen-doped carbon materials for oxygen reduction reaction clarified using model catalysts [J]. Science, 2016, 351(6271): 361-365. doi: 10.1126/science.aad0832

[55]

XING T, ZHENG Y, LI L H, et al. Observation of active sites for oxygen reduction reaction on nitrogen-doped multilayer graphene [J]. ACS Nano, 2014, 8(7): 6856-6862. doi: 10.1021/nn501506p

[56]

SCARDAMAGLIA M, SUSI T, STRUZZI C, et al. Spectroscopic observation of oxygen dissociation on nitrogen-doped graphene [J]. Scientific Reports, 2017, 7: 7960. doi: 10.1038/s41598-017-08651-1

[57]

WANG W, HU Y C, LIU Y C, et al. Self-powered and highly efficient production of H₂O₂ through a Zn-air battery with oxygenated carbon electrocatalyst [J]. ACS Applied Materials & Interfaces, 2018, 10(38): 31855-31859.

[58]

WANG Y W, QIU W J, SONG E H, et al. Adsorption-energy-based activity descriptors for electrocatalysts in energy storage applications [J]. National Science Review, 2017, 5(3): 327-341.

[59]

GONG K P, DU F, XIA Z H, et al. Nitrogen-doped carbon nanotube arrays with high electrocatalytic activity for oxygen reduction [J]. Science, 2009, 323(5915): 760-764. doi: 10.1126/science.1168049

[60]

XIE L, ZHOU W, QU Z B, et al. Understanding the activity origin of oxygen-doped carbon materials in catalyzing the two-electron oxygen reduction reaction towards hydrogen peroxide generation [J]. Journal of Colloid and Interface Science, 2022, 610: 934-943. doi: 10.1016/j.jcis.2021.11.144

[61]

CHEN S Y, LUO T, CHEN K J, et al. Chemical identification of catalytically active sites on oxygen-doped carbon nanosheet to decipher the high activity for electro-synthesis hydrogen peroxide [J]. Angewandte Chemie, 2021, 60(30): 16607-16614. doi: 10.1002/anie.202104480

[62]

SHENG Y P, SONG S L, WANG X L, et al. Electrogeneration of hydrogen peroxide on a novel highly effective acetylene black-PTFE cathode with PTFE film [J]. Electrochimica Acta, 2011, 56(24): 8651-8656. doi: 10.1016/j.electacta.2011.07.069

[63]

WANG W, LU X Y, SU P, et al. Enhancement of hydrogen peroxide production by electrochemical reduction of oxygen on carbon nanotubes modified with fluorine [J]. Chemosphere, 2020, 259: 127423. doi: 10.1016/j.chemosphere.2020.127423

[64]

LIU Z M, GAO D Z, HU L N, et al. Metal-free boron-rich borocarbonitride catalysts for high-efficient oxygen reduction to produce hydrogen peroxide [J]. ChemistrySelect, 2022, 7(5): e202104203.

[65]

PARSE H, PATIL I M, SWAMI A S, et al. TiO₂-decorated titanium carbide MXene co-doped with nitrogen and sulfur for oxygen electroreduction [J]. ACS Applied Nano Materials, 2021, 4(2): 1094-1103. doi: 10.1021/acsanm.0c02695

[66]

PERAZZOLO V, DURANTE C, GENNARO A. Nitrogen and sulfur doped mesoporous carbon cathodes for water treatment [J]. Journal of Electroanalytical Chemistry, 2016, 782: 264-269. doi: 10.1016/j.jelechem.2016.10.037

[67]

GU Y Y, FU H J, HUANG Z W, et al. O/F co-doped CNTs promoted graphite felt gas diffusion cathode for highly efficient and durable H₂O₂ evolution without aeration [J]. Journal of Cleaner Production, 2022, 341: 130799. doi: 10.1016/j.jclepro.2022.130799

[68]

HUANG X, LIU W, ZHANG J J, et al. Coupling Co-N-C with MXenes yields highly efficient catalysts for H ₂ O₂ production in acidic media [J]. ACS Applied Materials & Interfaces, 2022, 14(9): 11350-11358.

[69]

CHEN J N, YUAN X L, LYU F L, et al. Integrating MXene nanosheets with cobalt-tipped carbon nanotubes for an efficient oxygen reduction reaction [J]. Journal of Materials Chemistry A, 2019, 7(3): 1281-1286. doi: 10.1039/C8TA10574J

[70]

ZHANG T T, LI C, GU Y, et al. Fabrication of novel metal-free “graphene alloy” for the highly efficient electrocatalytic reduction of H₂O₂ [J]. Talanta, 2017, 165: 143-151. doi: 10.1016/j.talanta.2016.12.018