催化臭氧氧化去除水中PPCPs的作用机制及工艺研究进展

彭嘉运

doi:10.16803/j.cnki.issn.1004-6216.202209003

[1]

YAN Z, YANG H, DONG H, et al. Occurrence and ecological risk assessment of organic micropollutants in the lower reaches of the Yangtze River, China: A case study of water diversion[J]. Environmental Pollution, 2018, 239: 223 − 232. doi: 10.1016/j.envpol.2018.04.023

[2]

DE BARROS A L C, SCHMIDT F F, DE AQUINO S F, et al. Determination of nine pharmaceutical active compounds in surface waters from Paraopeba River Basin in Brazil by LTPE-HPLC-ESI-MS/MS[J]. Environmental Science Pollution Research, 2018, 25(20): 19962 − 19974. doi: 10.1007/s11356-018-2123-y

[3]

K O, KANDIE F J, VERGEYNST L, et al. Occurrence, fate and removal of pharmaceuticals, personal care products and pesticides in wastewater stabilization ponds and receiving rivers in the Nzoia Basin, Kenya[J]. Science of the Total Environment, 2018, 637-638: 336 − 348. doi: 10.1016/j.scitotenv.2018.04.331

[4]

SOMENSI C A, SIMIONATTO E L, BERTOLI S L, et al. Use of ozone in a pilot-scale plant for textile wastewater pre-treatment: physico-chemical efficiency, degradation by-products identification and environmental toxicity of treated wastewater[J]. Journal of Hazardous Materials, 2010, 175(1-3): 235 − 240. doi: 10.1016/j.jhazmat.2009.09.154

[5]

LIU X, YANG Y, LI H, et al. Visible light degradation of tetracycline using oxygen-rich titanium dioxide nanosheets decorated by carbon quantum dots, Chemical Engineering Journal [J]. 2021, 408: 127259-127271.

[6]

AMILDON R I, PAIVA V A B, PANIAGUA C E S, et al. Chloramphenicol photo-Fenton degradation and toxicity changes in both surface water and a tertiary effluent from a municipal wastewater treatment plant at near-neutral conditions[J]. Chemical Engineerring Journal, 2018, 347: 763 − 770. doi: 10.1016/j.cej.2018.04.169

[7]

CAO Y, QIU W, ZHAO Y, et al. The degradation of chloramphenicol by O₃/PMS and the impact of O₃-based AOPs pre-oxidation on dichloroacetamide generation in post-chlorination[J]. Chemical Engineering Journal, 2020, 401: 126146 − 126155. doi: 10.1016/j.cej.2020.126146

[8]

LIU X, YANG Z, ZHU W, et al. Catalytic ozonation of chloramphenicol with manganese-copper oxides/maghemite in solution: Empirical kinetics model, degradation pathway, catalytic mechanism, and antibacterial activity[J]. Journal of Environmental Management, 2022, 302: 114043 − 114053. doi: 10.1016/j.jenvman.2021.114043

[9]

WANG J, CHEN H. Catalytic ozonation for water and wastewater treatment: Recent advances and perspective [J]. Science of the Total Environment, 2020, 704 : 135249-135266.

[10]

VANAKEN R V d B P, DEGREVE J, DEWIL R. The effect of ozonation on the toxicity and biodegradability of 2, 4-dichlorophenol-containing wastewater[J]. Chemical Engineerring Journal, 2015, 280: 728 − 736.

[11]

SKOUMAL M, CABOT P L, CENTELLAS F, et al. Mineralization of paracetamol by ozonation catalyzed with Fe²⁺, Cu²⁺ and UVA light[J]. Applied Catalysis B:Environmental, 2006, 66: 228 − 240. doi: 10.1016/j.apcatb.2006.03.016

[12]

GUO Y, WANG H, WANG B, et al. Prediction of micropollutant abatement during homogeneous catalytic ozonation by a chemical kinetic model[J]. Water Research, 2018, 142: 383 − 395. doi: 10.1016/j.watres.2018.06.019

[13]

BELTRAN F J, RIVAS F J. MONTERO-DE-ESPINOSA R, Ozone-enhanced oxidation of oxalic acid in water with cobalt catalysts. 1. homogeneous catalytic ozonation[J]. Industrial & Engineering Chemistry Research, 2003, 42: 3210 − 3217.

[14]

PERA-TITUS M, GARCIA-MOLINA V, BANOS M A, et al. Degradation of chlorophenols by means of advanced oxidation processes: a general review[J]. Applied Catalysis B:Environmental, 2004, 47: 219 − 256. doi: 10.1016/j.apcatb.2003.09.010

[15]

SAULEDA R, BRILLAS E. Mineralization of aniline and 4-chlorophenol in acidic solution by ozonation catalyzed with Fe²⁺ and UVA light [J]. Applied Catalysis B: Environmental, 2001, 29: 135-145.

[16]

MA J, GRAHAM N J D. Degradation of atrazine by manganese-catalysed ozonation: Influence of humic substances [J]. Water Research, 1999, 33: 785-793.

[17]

TRAPIDO M, VERESSININA Y, MUNTER R, et al. Catalytic ozonation of m-dinitrobenzene[J]. Ozone:Science & Engineering, 2005, 27: 359 − 363.

[18]

WU C H, KUO C Y, CHANG C L. Homogeneous catalytic ozonation of C. I. Reactive Red 2 by metallic ions in a bubble column reactor[J]. Journal of Hazardous Materials, 2008, 154: 748 − 755. doi: 10.1016/j.jhazmat.2007.10.087

[19]

PINES D S, RECKHOW D A. Effect of dissolved cobalt(II) on the ozonation of oxalic acid [J]. Environment Science & Technology, 2002, 36(19): 4046-4051.

[20]

韩帮军. 臭氧催化氧化除污染特性及其生产应用研究 [D]. 哈尔滨: 哈尔滨工业大学, 2007.

[21]

MA J, GRAHAM N J D. Preliminary investigation of manganese-catalyzed ozonation for the destruction of atrazine[J]. Ozone: Science & Engineering, 1997, 19: 227 − 240.

[22]

TONG S P, LIU W P, LENG W H, et al. Characteristics of MnO₂ catalytic ozonation of sulfosalicylic acid and propionic acid in water[J]. Chemosphere, 2003, 50: 1359 − 1364. doi: 10.1016/S0045-6535(02)00761-0

[23]

NAWAZ F, CAO H, XIE Y, et al. Selection of active phase of MnO₂ for catalytic ozonation of 4-nitrophenol[J]. Chemosphere, 2017, 168: 1457 − 1466. doi: 10.1016/j.chemosphere.2016.11.138

[24]

PARK J S, CHOI H, AHN K H, et al. Removal mechanism of natural organic matter and organic acid by ozone in the presence of goethite[J]. Ozone:Science & Engineering, 2004, 26: 141 − 151.

[25]

PARK J S, CHOI H, CHO J. Kinetic decomposition of ozone and para-chlorobenzoic acid (p-CBA) during catalytic ozonation [J]. Water Research, 2004, 38: 2284-2291.

[26]

YIN R, GUO W, ZHOU X, et al. Enhanced sulfamethoxazole ozonation by noble metal-free catalysis based on magnetic Fe₃O₄ nanoparticles: Catalytic performance and degradation mechanism[J]. RSC Advances, 2016, 6: 19265 − 19270. doi: 10.1039/C5RA25994K

[27]

CHEN J N, NI C H. Heterogeneous catalytic ozonation of 2-chlorophenol queous solution with alumina as a catalyst [J]. Water Science and Technology, 2001, 43: 213-220.

[28]

KASPRZYK B, AWROCKI J N. Preliminary results on ozonation enhancement by a perfluorinated bonded alumina phase [J]. Ozone: Science & Engineering, 2007, 24: 63-68.

[29]

KASPRZYK-HORDEM B, ANDRZEJEWSKI P, DABROWSKA A, et al. MTBE, DIPE, ETBE and TAME degradation in water using perfluorinated phases as catalysts for ozonation process[J]. Applied Catalysis B:Environmental, 2004, 51: 51 − 66. doi: 10.1016/j.apcatb.2004.02.004

[30]

CHEN L, QI F, XU B, et al. The efficiency and mechanism of γ-alumina catalytic ozonation of 2-methylisoborneol in drinking water[J]. Water Supply, 2006, 6: 43 − 51.

[31]

QI F, CHEN Z, XU B, et al. Influence of surface texture and acid–base properties on ozone decomposition catalyzed by aluminum (hydroxyl) oxides[J]. Applied Catalysis B:Environmental, 2008, 84: 684 − 690. doi: 10.1016/j.apcatb.2008.05.027

[32]

SULIGOJ A, KETE M, CERNIGOJ U, et al. Synergism in TiO₂ photocatalytic ozonation for the removal of dichloroacetic acid and thiacloprid[J]. Environmental Research. Section A, 2021, 197: 110982. doi: 10.1016/j.envres.2021.110982

[33]

MU J, LI S, WANG J, et al. Efficient catalytic ozonation of bisphenol A by three-dimensional mesoporous CeOx-loaded SBA-16[J]. Chemosphere, 2021, 278: 130412. doi: 10.1016/j.chemosphere.2021.130412

[34]

ZHANG Z, AI H, FU M L, et al. A new insight into catalytic ozonation of ammonia by MgO/Co₃O₄ composite: The effects, reaction kinetics and mechanism[J]. Chemical Engineering Journal, 2021, 418: 129461. doi: 10.1016/j.cej.2021.129461

[35]

ZHANG L H, ZHOU J, LIU Z Q, et al. Mesoporous CeO₂ catalyst synthesized by using cellulose as template for the ozonation of phenol[J]. Ozone:Science & Engineering, 2018, 41: 166 − 174.

[36]

ROSAL R, RODRIGUEZ A, GONZALO M S, et al. Catalytic ozonation of naproxen and carbamazepine on titanium dioxide[J]. Applied Catalysis B:Environmental, 2008, 84: 48 − 57. doi: 10.1016/j.apcatb.2008.03.003

[37]

MESSELE S A, CHELME-AYALA P, GAMAL E M. Catalytic ozonation of naphthenic acids in the presence of carbon-based metal-free catalysts: Performance and kinetic study [J]. Catalysis Today, 2021, 361: 102-108.

[38]

RESTIVO J, ORGE C A, GUEDES G, et al. Nanostructured layers of mechanically processed multiwalled carbon nanotubes for catalytic ozonation of organic pollutants[J]. ACS Applied Nano Materials, 2020, 3: 5271 − 5284. doi: 10.1021/acsanm.0c00662

[39]

XU J, LI Y, QIAN M, et al. Amino-functionalized synthesis of MnO₂-NH₂-GO for catalytic ozonation of cephalexin[J]. Applied Catalysis B:Environmental, 2019, 256: 117797. doi: 10.1016/j.apcatb.2019.117797

[40]

JANS U, HOIGNE J. Activated carbon and carbon black catalyzed transformation of aqueous ozone into OH-radicals [J]. Ozone: Science & Engineering, 1998, 20: 67-90.

[41]

BELTRAN F J, POCOSTALES J P, ALVAREZ P M, et al. Mechanism and kinetic considerations of TOC removal from the powdered activated carbon ozonation of diclofenac aqueous solutions[J]. Journal of Hazardous Materials, 2009, 169: 532 − 538. doi: 10.1016/j.jhazmat.2009.03.127

[42]

YOON Y, OH H, AHN Y T, et al. Evaluation of the O₃/graphene-based materials catalytic process: pH effect and iopromide removal[J]. Catalysis Today, 2017, 282: 77 − 85. doi: 10.1016/j.cattod.2016.03.014

[43]

GONCALVES A G, ORFAO J J, PEREIRA M F. Catalytic ozonation of sulphamethoxazole in the presence of carbon materials: Catalytic performance and reaction pathways [J]. Journal of Hazardous Materials, 2012, 239-240: 167-174.

[44]

BELTRAN F J, RIVAS F J, FERNANDEZ L A, et al. Kinetics of catalytic ozonation of oxalic acid in water with activated carbon[J]. Industrial & Engineering Chemistry Research, 2002, 41: 6510 − 6517.

[45]

FARIA P C C, ÓRFAO J J M, PEREIRA M F R. Activated carbon catalytic ozonation of oxamic and oxalic acids [J]. Applied Catalysis B: Environmental, 2008, 79 : 237-243.

[46]

LIU Z Q, MA J, CUI Y H, et al. Effect of ozonation pretreatment on the surface properties and catalytic activity of multi-walled carbon nanotube[J]. Applied Catalysis B:Environmental, 2009, 92: 301 − 306. doi: 10.1016/j.apcatb.2009.08.007

[47]

LIU X, LI H, FANG Y, et al. Heterogeneous catalytic ozonation of sulfamethazine in aqueous solution using maghemite-supported manganese oxides[J]. Separation and Purification Technology, 2021, 274: 118945 − 118956. doi: 10.1016/j.seppur.2021.118945

[48]

XIE Y, PENG S, FENG Y, et al. Enhanced mineralization of oxalate by highly active and stable Ce(III)-Doped g-C₃N₄ catalyzed ozonation[J]. Chemosphere, 2019, 239: 124612.

[49]

DONG T, LIU W, MA M, et al. Hierarchical zeolite enveloping Pd-CeO₂ nanowires: An efficient adsorption/catalysis bifunctional catalyst for low temperature propane total degradation[J]. Chemical Engineering Journal, 2020, 393: 124717. doi: 10.1016/j.cej.2020.124717

[50]

CHEN H, WANG J. Catalytic ozonation of sulfamethoxazole over Fe₃O₄/Co₃O₄ composites[J]. Chemosphere, 2019, 234: 14 − 24.

[51]

WEN S, CHEN L, LI W, et al. Insight into the characteristics, removal, and toxicity of effluent organic matter from a pharmaceutical wastewater treatment plant during catalytic ozonation[J]. Scientific Reports, 2018, 8(1): 9581. doi: 10.1038/s41598-018-27921-0

[52]

BING J, HU C, NIE Y, et al. Mechanism of catalytic ozonation in Fe₂O₃/Al₂O₃@SBA-15 aqueous suspension for destruction of ibuprofen[J]. Environmental Science & Technology, 2015, 49: 1690 − 1697.

[53]

SHEN T, ZHANG X, LIN K A, et al. Solid base Mg-doped ZnO for heterogeneous catalytic ozonation of isoniazid: Performance and mechanism[J]. Science of the Total Environment, 2020, 703: 134983 − 134995. doi: 10.1016/j.scitotenv.2019.134983

[54]

LI S, LI X, WU H, et al. Mechanism of synergistic effect on electron transfer over Co-Ce/MCM-48 during ozonation of pharmaceuticals in water[J]. ACS Applied Material Interfaces, 2019, 11: 23957 − 23971. doi: 10.1021/acsami.9b02143

[55]

CHEN W, LI X, PAN Z, et al. Synthesis of MnOx/SBA-15 for norfloxacin degradation by catalytic ozonation[J]. Seperation and Purification Technology, 2017, 173: 99 − 104. doi: 10.1016/j.seppur.2016.09.030

[56]

IAKOVIDES I C, MICHAEL-KORDATOU I, MOREIRA N F F, et al. Continuous ozonation of urban wastewater: Removal of antibiotics, antibiotic-resistant Escherichia coli and antibiotic resistance genes and phytotoxicity[J]. Water Research, 2019, 159: 333 − 347. doi: 10.1016/j.watres.2019.05.025

[57]

TERNES T A, STUBER J, HERRMANN N, et al. Ozonation: a tool for removal of pharmaceuticals, contrast media and musk fragrances from wastewater[J]. Water Research, 2003, 37: 1976 − 1982. doi: 10.1016/S0043-1354(02)00570-5

[58]

DE WITTE B, DEWULF J, DEMEESTERE K, et al. Ozonation and advanced oxidation by the peroxone process of ciprofloxacin in water[J]. Journal of Hazardous Materials, 2009, 161: 701 − 708. doi: 10.1016/j.jhazmat.2008.04.021

[59]

AKMEHMET BALCIOGLU I, ÖTKER M. Treatment of pharmaceutical wastewater containing antibiotics by O₃ and O₃/H₂O₂ processes [J]. Chemosphere, 2003, 50: 85-95.

[60]

FENG M, YAN L, ZHANG X, et al. Fast removal of the antibiotic flumequine from aqueous solution by ozonation: Influencing factors, reaction pathways, and toxicity evaluation[J]. Science of the Total Environment, 2016, 541: 167 − 175. doi: 10.1016/j.scitotenv.2015.09.048

[61]

ROTH J A, SULLIVAN D E. Solubility of ozone in water[J]. Industrial & Engineering Chemistry Fundamentals, 2002, 20: 137 − 140.

[62]

MEIJERS R T, ODERWALD-MULLER E, NUHN P A N M, et al. Degradation of pesticides by ozonation and advanced oxidation[J]. Ozone:Science & Engineering, 1995, 17: 673 − 686.

[63]

HUANG Y, CUI C, ZHANG D, et al. Heterogeneous catalytic ozonation of dibutyl phthalate in aqueous solution in the presence of iron-loaded activated carbon[J]. Chemosphere, 2015, 119: 295 − 301. doi: 10.1016/j.chemosphere.2014.06.060

[64]

QI F, CHU W, XU B. Ozonation of phenacetin in associated with a magnetic catalyst CuFe₂O₄: The reaction and transformation [J]. Chemical Engineering Journal, 2015, 262: 552-562.

[65]

TONG S P, SHI R, ZHANG H, et al. Kinetics of Fe₃O₄-CoO/Al₂O₃ catalytic ozonation of the herbicide 2-(2, 4-dichlorophenoxy) propionic acid[J]. Journal of Hazardous Materials, 2011, 185: 162 − 167. doi: 10.1016/j.jhazmat.2010.09.013

[66]

BAI Z Y, YANG Q, WANG J L. Fe₃O₄/multi-walled carbon nanotubes as an efficient catalyst for catalytic ozonation of p-hydroxybenzoic acid [J]. International Journal of Environmental Science and Technology, 2015, 13: 483-492.

[67]

WU C, LI P, XIA S, et al. The role of interface in microbubble ozonation of aromatic compounds[J]. Chemosphere, 2019, 220: 1067 − 1074. doi: 10.1016/j.chemosphere.2018.12.174

[68]

CHAVEZ A M, QUINONES D H, REY A, et al. Simulated solar photocatalytic ozonation of contaminants of emerging concern and effluent organic matter in secondary effluents by a reusable magnetic catalyst[J]. Chemical Engineering Journal, 2020, 398: 125642. doi: 10.1016/j.cej.2020.125642

[69]

ARAM M, FARHADIAN M, SOLAIMANG N A R, et al. Metronidazole and cephalexin degradation by using of Urea/TiO₂/ZnFe₂O₄/Clinoptiloite catalyst under visible-light irradiation and ozone injection[J]. Journal of Molecular Liquids, 2020, 304: 112764. doi: 10.1016/j.molliq.2020.112764

[70]

KISHIMOTO N, MORITA Y, TSUNO H, et al. Advanced oxidation effect of ozonation combined with electrolysis[J]. Water Research, 2005, 39: 4661 − 4672. doi: 10.1016/j.watres.2005.09.001

[71]

陈思, 钛镀稀有金属电极电催化臭氧降解水中有机药物的效果研究 [D]. 重庆: 重庆大学, 2015.

[72]

ZHAN J, LI Z, YU G, et al. Enhanced treatment of pharmaceutical wastewater by combining three-dimensional electrochemical process with ozonation to in situ regenerate granular activated carbon particle electrodes[J]. Separation and Purification Technology, 2019, 208: 12 − 18. doi: 10.1016/j.seppur.2018.06.030

[73]

YANG L, SHENG M, LI Y, et al. A hybrid process of Fe-based catalytic ozonation and biodegradation for the treatment of industrial wastewater reverse osmosis concentrate[J]. Chemosphere, 2020, 238: 124639. doi: 10.1016/j.chemosphere.2019.124639

[74]

AGHAPOUR A A, MOUSSAVI G, YAGHMAEIAN K. Degradation and COD removal of catechol in wastewater using the catalytic ozonation process combined with the cyclic rotating-bed biological reactor[J]. Journal of Environmental Management, 2015, 157: 262 − 266.