乙醇水蒸气重整制氢催化剂的研究进展

梅占强; 何素芳; 陈柯臻; 陈然; 陆继长; 罗永明

doi:10.7524/j.issn.0254-6108.2017030702

[1]

DEBABRATA D, NEJAT V. Hydrogen production by biological processes:A survey of literature[J]. International Journal of Hydrogen Energy, 2001, 26(1):13-28.

[2]

TRANE R, DAHL S, SKJфTH-RASMUSSEN M S, et al. Catalytic steam reforming of bio-oil[J]. International Journal of Hydrogen Energy, 2012, 37(8):6447-6472.

[3]

CAI W J, PISCINA P R, GABROWSKA K, et al. Hydrogen production from oxidative steam reforming of bio-butanol over CoIr-based catalysts[J]:Effect of the support. Bioresource Technology, 2013, 128(128C):467-471.

[4]

TANKSALE A, BELTRAMINI J N, LU G Q M. A review of catalytic hydrogen production processes from biomass[J]. Renewable & Sustainable Energy Reviews, 2010, 14(1):166-182.

[5]

MARIANA N B, MANUEL F G, LUIS A A, et al. Co catalysts modified by rare earths (La, Ce or Pr) for hydrogen production from ethanol[J]. International Journal of Hydrogen Energy, 2014, 39(16):8712-8719.

[6]

AUGUSTO B L, COSTA L O O, NORONHA F B, et al. Ethanol reforming over Ni/CeGd catalysts with low Ni content[J]. International Journal of Hydrogen Energy], 2012, 37(17):12258-12270.

[7]

MATTOS L V, JACOBS G, DAVIS B H, et al. Production of hydrogen from ethanol:Review of reaction mechanism and catalyst deactivation[J]. Chemical Reviews, 2012, 112(7):4094-4123.

[8]

HARYANTO A, FERNANDO S, MURALI N, et al. Current status of hydrogen production techniques by steam reforming of ethanol:A review[J]. Energy Fuels, 2005, 19(5), 2098-2106.

[9]

VAIDYA P D, RODRIGUES A E. Insight into steam reforming of ethanol to produce hydrogen for fuel cells[J]. Chemical Engineering Journal, 2006, 117(1):39-49.

[10]

HE S Y, HE S F, ZHANG L, et al. Hydrogen production by ethanol steam reforming over Ni/SBA-15 mesoporous catalysts:Effect of Au addition[J]. Catalysis Today, 2015, 258:162-168.

[11]

MENG NI, LEUNG D Y C, LEUNG M K H. A review on reforming bio-ethanol for hydrogen production[J]. International Journal of Hydrogen Energy, 2007, 32(15):3238-3247.

[12]

王倩, 徐新, 郭芳林, 等. 乙醇重整制氢催化剂的国内研究进展[J]. 中外能源, 2008, 13(2):23-29. WANG Q, XU X, GUO F L, et al. Domestic research progress in catalyst for hydrogen manufacture from ethanol reforming[J]. Sino-Global Energy, 2008, 13(2):23-29(in Chinese).

[13]

[14]

毛晓明, 王鹏宇. Ni系催化剂上乙醇水蒸气重整制氢研究进展[J]. 商丘师范学院学报, 2009, 25(12):70-74. MAO X M, WANG P Y. The development of catalysts in ethanol steam reforming for fuel cells[J]. Journal of Shangqiu Normal University, 2009, 25(12):70-74(in Chinese).

[15]

[16]

吴川, 张华民, 衣宝廉. 化学制氢技术研究进展[J]. 化学进展, 2005, 17(3):423-429. WU C, ZHANG H M, YI B L. Recent Advances in hydrogen generation with chemical methods[J]. Progress in Chemistry, 2005, 17(3):423-429(in Chinese).

[17]

王卫平, 吕功煊. 乙醇催化制氢研究进展[J]. 化学进展, 2003, 15(1):74-78. WANG W P, LU G X. Advances in catalytic generation of hydrogen from ethanol[J]. Progress in Chemistry, 2003, 15(1):74-78(in Chinese).

[18]

ZHANG T, HE J, ZHAO Y, et al. Precious metal-support interaction in automotive exhaust catalysts[J]. Journal of Rare Earths, 2014, 32(2):97-107.

[19]

FURTADO A C, ALONSO C G, CANTAO M P, et al. Support influence on Ni-Cu catalysts behavior under ethanol oxidative reforming reaction[J]. International Journal of Hydrogen Energy, 2011, 36(16):9653-9662.

[20]

HAN S J, BANG Y J, SEO J G, et al. Hydrogen production by steam reforming of ethanol over mesoporous Ni-Al₂O₃-ZrO₂ xerogel catalysts:Effect of Zr/Al molar ratio[J]. International Journal of Hydrogen Energy], 2013, 38(3):1376-1383.

[21]

SHENG P Y, YEE A, BOWMAKER G A, et al. H₂ production from ethanol over Rh-Pt/CeO₂ catalysts:The role of Rh for the efficient dissociation of the carbon-carbon bond[J]. Journal of Catalysis, 2002, 208(2):393-403.

[22]

HUANG L, CHOONG C, CHEN L W, et al. Oxide-supported Rh catalysts for H₂ generation from low-temperature ethanol steam reforming:Effects of support, Rh precursor and Rh loading on catalytic performance[J]. Rsc Advances, 2015, 5(120):99461-99482.

[23]

ROH H, WANG Y, KING D, et al. Low temperature and H₂ selective catalysts for ethanol steam reforming[J]. Catalysis Letters, 2006, 108(1-2):15-19.

[24]

BUNLUESIN T, GORTE R J AND GRAHAM G W. Studies of the water-gas-shift reaction on ceria-supported Pt, Pd, and Rh:Implications for oxygen-storage properties[J]. Applied Catalysis B:Environmental, 1998, 15(1-2):107-l14.

[25]

LIGURAS D K, KONDARIDES D I, VERYKIOS X E. Production of hydrogen for fuel ceils by steam reforming of ethanol over supported noble metal catalysts[J]. Applied Catalysis B Environmental, 2003, 43(4):345-354.

[26]

BREEN J P, BURCH R, COLEMAN H M. Metal-catalysed steam reforming of ethanol in the production of hydrogen for fuel cell applications[J]. Applied Catalysis B Environmental, 2002, 39(1):65-74.

[27]

PARASKEVI P, XENOPHON E V. Mechanistic aspects of the low temperature steam reforming of ethanol over supported Pt catalysts[J]. International Journal of Hydrogen Energy, 2012, 37(21):16333-16345.

[28]

CAN F, VALANT A L, BION N, et al. New active and selective Rh-REOx-Al₂O₃ catalysts for ethanol steam reforming[J]. Journal of Physical Chemistry C, 2008, 112(36):14145-14153.

[29]

PAULA O V, CAMPOS C H, NAVARRO R M, et al. Improved ethanol steam reforming on Rh/Al₂O₃ catalysts doped with CeO₂ or/and La₂O₃:Influence in reaction pathways including coke formation[J]. Applied Catalysis A:General, 2015, 505(1):159-172.

[30]

PAULA O V, CAMPOS C H, NAVARRO R M, et al. Rh/Al₂O₃-La₂O₃ catalysts promoted with CeO₂ for ethanol steam reforming reaction[J]. Journal of Molecular Catalysis A:Chemical, 2015, 407:169-181.

[31]

刘承伟, 石秋杰, 李彬等. 不同载体对钌基催化剂催化乙醇水蒸气重整制氢性能的影响[J]. 中国稀土学报, 2009, 27(1):19-24. LIU C W,SHI Q J, LI B, et al. Effects of different supports on properties of ruthenium catalyst for hydrogen production from steam reforming of ethanol[J]. Journal of the Chinese Society of Rare Earths, 2009, 27(1):19-24(in Chinese).

[32]

CIFUENTES B, HERNANDEZ M, MONSALVE S, et al. Hydrogen production by steam reforming of ethanol on a RhPt/CeO₂/SiO₂ catalyst:Synergistic effect of the Si:Ce ratio on the catalyst performance[J]. Applied Catalysis A:General, 2016, 523:283-293.

[33]

李键铭,郎林, 杨文申, 等. 生物乙醇重整制氢用ZSM-5催化剂的载体碱改性研究[J]. 可再生能源, 2014, 32(4):537-541. LI J M, LANG L, YANG W S, et al. Alkali modification of ZSM-5 supports for Hydrogen production by ethanol reforming[J]. Renewable Energy Resources, 2014, 32(4):537-541(in Chinese).

[34]

INOKAWA H, NISHIMOTO S, KAMESHIMA Y, et al. Difference in the catalystic activity of transition metals ans their cations loaded in zeolite Y for ethanol steam reforming[J]. International Journal of Hydrogen Energy, 2010, 35(21):11719-11724.

[35]

SONG Y Q, ZHU X X, SONG Y, et al. An effective method to enhance the stability on-stream of butane aromatization:Post-treatment of ZSM-5 by alkali solution of sodium hydroxide[J]. Applied Catalysis A:General, 2006, 302(1):69-77.

[36]

CAMPOS-SKROBOT F C, RIZZO-DOMINGUES R C P, FERNANDES-MACHADO N R C, et al. Novel zeolite-supported rhodium catalysts for ethanol steam reforming[J]. Journal of Power Sources, 2008, 183(2):713-716.

[37]

VARGA O A G, HEREDIA J A R, WANG J A, et al. Hydrogen production over Rh/Ce-MCM-41 catalysts via ethanol steam reforming[J]. International Journal of Hydrogen Energy, 2013, 38(32):13914-13925.

[38]

LANG L, ZHAO S, YIN X, et al. Catalytic activities of K-modified zeolite ZSM-5 supported rhodium catalysts in low-temperature steam reforming of bioethanol[J]. International Journal of Hydrogen Energy, 2015, 40(32):9924-9934.

[39]

杨宇, 吴绯, 马建新. 载体对镍催化剂催化乙醇水蒸气重整制氢反应性能的影响[J].催化学报, 2005, 26(2):131-137. YANG Y, WU F, MA J X. Effect of support on catalytic performance of nickel catalyst for ethanol steam reforming[J]. Chinese Journal of Catalysis, 2005, 26(2):131-137(in Chinese).

[40]

GALETTI A E, GOMEZ M F, ARRUA L A, et al. Ni catalysts supported on modified ZnAl₂O₄ for ethanol steam reforming[J]. Applied Catalysis A General, 2010, 380(1-2):40-47.

[41]

FATSIKOSTAS A N, KONDARIDES D I, VERYKIOS X E. Production of hydrogen for fuel cells by reformation of biomass-derived ethanol[J]. Catalysis Today, 2002, 75(1-4):145-155.

[42]

FATSIKOSTAS A N, VERYKIOS X E. Reaction network of steam reforming of ethanol over Ni-based catalysts[J]. Journal of Catalysis, 2004, 225(2):439-452.

[43]

FRUSTERIA F, FRENIA S, CHIODO V, et al. Steam and auto-thermal reforming of bio-ethanol over MgO and CeO₂ Ni supported catalysts[J]. International Journal of Hydrogen Energy, 2006, 31(15):2193-2199.

[44]

BATISTA M S,SANTOS R K S,ASSAF E M,et al. Characterization of the activity and stability of supported cobalt catalysts for the steam reforming of ethanol[J]. Power Sources, 2003, 124(1):99-103.

[45]

LLORCA J, PISCINA P R, SALES J, et al. Direct production of hydrogen from ethanolic aqueous solutions over oxide catalysts[J]. Chemical Communications, 2001, 242(7):641-642.

[46]

VIZCAINO A J, CARRERO A, CALLES J A. Pure silica SBA-15 supported Cu-Ni catalysts for hydrogen production by ethanol steam reforming[J]. Applied Catalysis A:General 2007, 327:82-94.

[47]

LINDO M, VIZCAINO A J, CALLES J A, et al. Ethanol steam reforming on Ni/Al-SBA-15 catalysts:Effect of the aluminium content[J]. International Journal of Hydrogen Energy, 2010, 35(11):5895-5901.

[48]

KIM D, KWAK B S, PARK N K, et al. Dynamic hydrogen production from ethanol steamreforming reaction on Ni_xMo_y/SBA-15 catalytic system[J]. International Journal of Energy Research, 2014; 39(2):279-292.

[49]

ZHENG Z L, YANG D H, LI T T, et al. A novel BEA-type zeolite core-shell multiple catalyst for hydrogen-rich gas production from ethanol steam reforming[J]. Catalysis Science & Technology, 2016, 6(14):5427-5439.

[50]

FATSIKOSTAS A N, KONDARIDES D I, Verykios X E. Production of hydrogen for fuel cells by reformation of biomass-derived ethanol[J]. Catalysis Today, 2002, 75(1-4):145-155.

[51]

VIZCAINO A J, CARRERO A, CALLES J A. Hydrogen production by ethanol steam reforming over Cu-Ni supported catalysts[J]. International Journal of Hydrogen Energy, 2007, 32(10/11):1450-1461.

[52]

SANCHEZ-SANCHEZ M C, NAVARRO R M, FIERRO J L G. Ethanol steam reforming over Ni/M_xO_y-Al₂O₃ (M=Ce, La, Zr and Mg) catalysts:Influence of support on the hydrogen production[J]. International Journal of Hydrogen Energy, 2007, 32(s 10-11):1462-1471.

[53]

CAMPOS C H, OSORIO-VARGAS P, FLORES-GONZALEZ N, et al. Effect of Ni loading on lanthanide (La and Ce) promoted γ-Al₂O₃ catalysts applied to ethanol steam reforming[J]. Catalysis Letters, 2016, 146(2):433-441.

[54]

ANJANEYULU C, COSTA L O O, RIBEIRO M, et al. Effect of Zn addition on the performance of Ni/Al₂O₃ catalyst for steam reforming of ethanol[J]. Applied Catalysis A General, 2016, 519(5):85-98.

[55]

SRINIVAS D, SATYANARAYANA C V V, POTDAR H S,et al. Structural studies on NiO-CeO₂-ZrO₂ catalysts for steam reforming of ethanol[J]. Applied Catalysis A General, 2003, 246(2):323-334.

[56]

MA H Y, ZENG L, TIAN H, et al. Efficient hydrogen production from ethanol steam reforming over La-modified ordered mesoporous Ni-based catalysts[J]. Applied Catalysis B Environmental, 2016, 181:321-331.

[57]

BELLIDO J D A, ASSAF E M. Nickel catalysts supported on ZrO₂, Y₂O₃-stabilized ZrO₂ and CaO-stabilized ZrO₂ for the steam reforming of ethanol:Effect of the support and nickel load[J]. Journal of Power Sources, 2008, 177(1):24-32.

[58]

CARRERO A, CALLES J A, VIZCAINO A J. Effect of Mg and Ca addition on coke deposition over Cu-Ni/SiO₂ catalysts for ethanol steam reforming[J].Chemical Engineering Journal, 2010, 163(3):395-402.

[59]

CALLES J A, CARRERO A, VIZCAINO A J. Ce and La modification of mesoporous Cu-Ni/SBA-15 catalysts for hydrogen production through ethanol steam reforming[J]. Microporous and Mesoporous Materials, 2009, 119(1-3):200-207.

[60]

VIZCAINO A J, CARRERO A, CALLES J A. Ethanol steam reforming on Mg-and Ca-modified Cu-Ni/SBA-15 catalysts[J]. Catalysis Today, 2009, 146(1-2):63-70.

[61]

KWAK B S, LEE J S, LEE J S, et al. Hydrogen-rich gas production from ethanol steam reforming over Ni/Ga/Mg/Zeolite Y catalysts at mild temperature[J]. Applied Energy, 2011, 88(12):4366-4375.

[62]

INOKAWA H, NISHIMOTO S, KAMESHIMA Y, et al. Promotion of H₂ production from ethanol steam reforming by zeolite basicity[J]. International Journal of Hydrogen Energy, 2011, 36(23):15195-15202.

[63]

VIZCAINO A J, CARRERO A, CALLES J A. Comparison of ethanol steam reforming using Co and Ni catalysts supported on SBA-15 modified by Ca and Mg[J]. Fuel Processing Technology, 2016, 146:99-109.

[64]

CAI W J, WANG F G, DANIEL C, et al. Oxidative steam reforming of ethanol over Ir/CeO₂ catalysts:A structure sensitivity analysis[J]. Journal of Catalysis, 2012, 286(2):137-152.

[65]

WANG H Z, LEUNG D Y C, LEUNG M K H, et al. A review on hydrogen production using aluminum and aluminum alloys[J]. Renewable Sustainable Energy Reviews, 2009, 13(4):845-853.

[66]

ERDOHELYI A, RASKO J, KECSKES T, et al. Hydrogen formation in ethanol reforming on supported noble metal catalysts[J]. Catalysis Today, 2006, 116(3):367-376.

[67]

RAMOS I A. C, MONTINI T, LORENZUT B, et al. Hydrogen production from ethanol steam reforming on M/CeO₂/YSZ (M=Ru, Pd, Ag) nanocomposites[J]. Catalysis Today, 2012, 180(1):96-104.

[68]

杨宇, 王荣文, 杨家梦, 等. 金属/MgO上的乙醇水蒸气重整制氢[J]. 石油化工, 2004, 33(增刊):349-351. YANG Y, WANG R W, YANG J M, et al. Hydrogen production for ethanol steam reforming reaction over metal/MgO catalysts[J]. Petrochemical Technology, 2004 , 33(Suppl):349-351(in Chinese).

[69]

KONSOLAKIS M, IOAKIMIDIS Z, KRAIA T, et al. Hydrogen production by ethanol steam reforming (ESR) over CeO₂ supported transition metal (Fe, Co, Ni, Cu) catalysts:insight into the structure-activity relationship[J]. Catalysts, 2016, 6(3):39:1-27.

[70]

毛丽萍, 吕功煊. Ni/Al₂O₃和Fe/Al₂O₃催化剂催化乙醇水蒸气重整制氢的对比研究[J]. 分子催化, 2007, 21(4):365-367. MAO L P, LU G X. Comparative study of Ni/Al₂O₃ and Fe/Al₂O₃ catalysts for ethanol steam reforming[J]. Journal of Molecular Catalysis (China), 2007, 21(4):365-367(in Chinese).

[71]

CHEN L W, CHOONG C K S, ZHONG Z Y, et al. Carbon monoxide-free hydrogen production via low-temperature steam reforming of ethanol over iron-promoted Rh catalyst[J]. Journal of Catalysis, 2010, 276(2):197-200.

[72]

SONG J H, HAN S J, YOO J, et al. Effect of Sr content on hydrogen production by steam reforming of ethanol over Ni-Sr/Al₂O₃-ZrO₂ xerogel catalysts[J]. Journal of Molecular Catalysis A Chemical, 2016, s 418-419:68-77.

[73]

SONG J H, HAN S J, YOO J, et al. Hydrogen production by steam reforming of ethanol over Ni-X/Al₂O₃-ZrO₂ (X=Mg, Ca, Sr, and Ba) xerogel catalysts:Effect of alkaline earth metal addition[J]. Journal of Molecular Catalysis A Chemical, 2016, 415(35):151-159.

[74]

LORENZUT B,MONTINI T, ROGATIS L D, et al. Hydrogen production through alcohol steam reforming on Cu/ZnO-based catalysts[J]. Applied Catalysis B Environmental, 2011, 101(3-4):397-408.

[75]

MARINO F J,CERRELLA E G,DUHALDE S,et al. Hydrogen from steam reforming of ethanol. Characterization and performance ofcopper-nickel supported catalysts[J]. International Journal of Hydrogen Energy, 1998, 23(12):1095-1101.

[76]

MARINO F, BOVERI M, BARONETTI G, et al. Hydrogen production from steam reforming of bioethanol using Cu/Ni/K/γ-Al₂O₃ catalysts. Effect of Ni[J]. International Journal of Hydrogen Energy, 2001, 26(7):665-668.

[77]

MAIA T A, BELLIDO J D A, ASSAF E M. Hydrogen production by ethanol steam reforming using Cu/Ni/gamma-Al₂O₃ catalysts[J]. Quimica Nova Vol, 2007, 30(2):339-345.

[78]

ZHANG L F, LIU J, LI W, et al. Ethanol steam reforming over Ni-Cu/Al₂O₃-M_yO_z(M=Si, La, Mg,and Zn) catalysts[J]. Journal of Natural Gas Chemistry, 2009, 18(1):55-65.

[79]

张利峰, 魏永涛, 邱泽勤等. Ni-Cu/Al₂O₃·SiO₂ 催化剂上乙醇水蒸气重整制氢——燃料电池氢源技术[J]. 天津化工, 2011, 25(3):21-24. ZHANG L F, WEI Y T, QIU Z L, et al. Hydrogen production for fuel cell via ethanol steam reforming reaction over Ni-Cu/Al₂O₃·SiO₂ catalysts[J]. Tianjin Chemical Industry, 2011, 25(3):21-24(in Chinese).

[80]

CHEN L C, LIN S D. The ethanol steam reforming over Cu-Ni/SiO₂ catalysts:Effect of Cu/Ni ratio[J]. Applied Catalysis B Environmental, 2011, 106(3-4):639-649.

[81]

SONG H, BAO X, HADAD C M, et al. Adsorption/desorption behavior of ethanol steam reforming reactants and intermediates over supported cobalt catalysts[J]. Catalysis Letters, 2011, 141(1):43-54.

[82]

ABDELKADER A, DALY H, SAIH Y, et al. Steam reforming of ethanol over Co₃O₄-Fe₂O₃ mixed oxides[J]. International Journal of Hydrogen Energy, 2013, 38(20):8263-8275.

[83]

HAGA F, NAKAJIMA T, MIYA H, et al. Catalytic properties of supported cobalt catalysts for steam reforming of ethanol[J], Catalysis Letters, 1997, 48(1-2):223-227.

[84]

DAI R Q, CHEN Y Z, JIN F,et al. Hydrogen production from ethanol steam reforming over Co-Ni/CeO₂ catalysts prepared by coprecipitation[J]. Advanced Materials Resources, 2013, 2479(724):729-734.

[85]

ZHAO X X, LU G X. Modulating and controlling active species dispersion over Ni-Co bimetallic catalysts for enhancement of hydrogen production of ethanol steam reforming[J]. International Journal of Hydrogen Energy, 2016, 41(5):3349-3362.

[86]

WANG Z J, WANG C X, CHEN S Q, et al. Co-Ni bimetal catalyst supported on perovskite-type oxide for steam reforming of ethanol to produce hydrogen[J]. International Journal of Hydrogen Energy, 2014, 39(11):5644-5652.