The migration and release characteristics of chlorine during coal combustion in coal-fired power plants

DA Chunnian; WANG Hai; XU Bo; LIU Guijian; LIU Zhuang; WEI Yong; WANG Ruwei

doi:10.7524/j.issn.0254-6108.2020041702

2020 Volume 39 Issue 10

Article Contents

Previous Article Next Article

DA Chunnian, WANG Hai, XU Bo, LIU Guijian, LIU Zhuang, WEI Yong, WANG Ruwei. The migration and release characteristics of chlorine during coal combustion in coal-fired power plants[J]. Environmental Chemistry, 2020, (10): 2833-2839. doi: 10.7524/j.issn.0254-6108.2020041702

Citation:

DA Chunnian, WANG Hai, XU Bo, LIU Guijian, LIU Zhuang, WEI Yong, WANG Ruwei. The migration and release characteristics of chlorine during coal combustion in coal-fired power plants[J]. Environmental Chemistry, 2020, (10): 2833-2839. doi: 10.7524/j.issn.0254-6108.2020041702

The migration and release characteristics of chlorine during coal combustion in coal-fired power plants

1. China Energy Engineering Group Anhui Electric Power Design Institute Co., Ltd., Hefei, 230005, China;
2. School of Biology, Food and Environment, Hefei University, Hefei, 230022, China;
3. Key Laboratory of Crust-Mantle Matter and Environment, Chinese Academy of Sciences, School of Earth and Space Sciences, University of Science and Technology of China, Hefei, 230026, China;
4. Guangdong Key Laboratory of Environmental Pollution and Health, School of Environment, Jinan University, Guangzhou, 511443, China

Corresponding author: LIU Guijian, lgj@ustc.edu.cn ;
Received Date: 17/04/2020

Fund Project: Supported by Anhui Postdoctoral Fund (2019B332), Domestic Visiting and Training Program for Outstanding Young Talents in Colleges and Universities (gxgnfx2019057), Natural Science Foundation of Anhui Province (2008085MD119) and National Key Research and Development Program of China(2016YFC0201600).

Abstract

Based on the contents of chlorine (Cl) determined by ion chromatography, this study systematically investigated the levels, occurrence and transformation of Cl in coal and its combustion products from four coal-fired power plants (CFPPs) in Anhui province. Results indicated that Cl content in coals was low, which positively correlated with the contents of lead, mercury, and total sulfur, whereas weakly correlated with the moisture and ash yield.The releasing rate of Cl during coal combustion was highly correlated with temperature and volatile matter, and most Cl transferred into the flue gas. Dust collector and wet flue gas devices equipped in the CFPPs were robust to remove Cl in particulate phase, and the fabric filter showed higher removal efficiency compared with the electrostatic precipitator.
- coal-fired power plant,
- chlorine,
- release,
- migration

References

[1]	袁晶晶, 笪春年, 王儒威, 等. 淮南燃煤电厂烟气中颗粒相和气相中多环芳烃的赋存特征[J]. 环境化学, 2018,37(6):1382-1390. YUAN J J, DA C N,WANG R W, et al. Occurence of polycyclic aromatic hydrocarbons in PM10-and gaseous phases of flue gases emitted from Huainan coal-fired power plant[J].Environmental Chemistry,2018,37(6):1382-1390(in Chinese). Google Scholar Pub Med
[2]	任德贻,赵峰华,代世峰,等.煤的微量元素地球化学[M].北京:科学出版社,2006. REN D Y, ZHAO F H, DAI S F, et al. Trace element geochemistry of coal[M]. Beijing:Science Press, 2006(in Chinese). Google Scholar Pub Med
[3]	TSUBOUCHI N, MOCHIZUKI Y, WANG Y, et al. Fate of the chlorine in coal in the heating process[J]. Isij International, 2018, 58(2):227-235. Google Scholar Pub Med
[4]	ROWE C L, HOPKINS W A, CONGDON J D. Ecotoxicological implications of aquatic disposal of coal combustion residues in the united states:A review[J]. Environmental Monitoring and Assessment, 2002, 80(3):207-276. Google Scholar Pub Med
[5]	SHARMA R, RAMTEKE S, PATEL K S, et al. Contamination of lead and mercury in coal basin of india[J]. Journal of Environmental Protection, 2015, 6(12):1430-1441. Google Scholar Pub Med
[6]	PENG B, LI X, ZHAO W, et al. Study on the release characteristics of chlorine in coal gangue under leaching conditions of different pH values[J]. Fuel, 2018, 217(1):427-433. Google Scholar Pub Med
[7]	DAI S, REN D, CHOU C L, et al. Geochemistry of trace elements in chinese coals:A review of abundances, genetic types, impacts on human health, and industrial utilization[J]. International Journal of Coal Geology, 2012,94:3-21. Google Scholar Pub Med
[8]	邓双, 张辰, 刘宇, 等. 基于实测的燃煤电厂氯排放特征[J]. 环境科学研究, 2014, 27(2):127-133. DENG S,ZHANG C,LIU Y,et al.A full-scale field study on chlorine emission of pulverized coal-fired power plants in China[J].Research of Environmental Sciences,2014,27(2):127-133(in Chinese). Google Scholar Pub Med
[9]	蒋旭光, 徐旭, 严建华, 等. 煤中氯的分布及燃烧过程中氯析出特性的试验研究[J]. 煤炭学报, 2001, 26(6):667-670. JIANG X G,XU X, YAN J H, et al. Research of chlorine in coal and isolation characteristic of chlorine in coal combustion process[J]. Journal of China Coal Society, 2001, 26(6):667-670(in Chinese). Google Scholar Pub Med
[10]	HUGGINS F E, HUFFMAN G P. Chlorine in coal:An XAFS spectroscopic investigation[J]. Fuel, 1995, 74(4):556-569. Google Scholar Pub Med
[11]	COX J A, LARSON A E, CARLSON R H. Estimation of the inorganic-to-organic chlorine ratio in coal[J]. Fuel, 1984, 63(9):1334-1335. Google Scholar Pub Med
[12]	何杰. 煤燃烧过程中氯化氢的排放特性研究[D]. 杭州:浙江大学, 2002. HE J. Emission characteristics of hydrogen chloride from coal combustion[D]. Hangzhou:Zhejiang University, 2002(in Chinese). Google Scholar Pub Med
[13]	Google Scholar Pub Med
[14]	徐旭,蒋旭光,何杰,等.煤中氯赋存形态的试验研究[J].煤田地质与勘探,2002,30(4):3-6. XU X, JIANG X G, HE J, et al. Experimental study on the occurrence form of chlorine in coal[J]. Coalfield Geology and Exploration, 2002, 30(4):3-6(in Chinese). Google Scholar Pub Med
[15]	范肖南.煤中氯分布的相关分析[J].煤质技术,1997(2):28-30. FAN X N. Correlation analysis of chlorine distribution in coal[J]. Coal Quality Technology, 1997 (2):28-30(in Chinese). Google Scholar Pub Med
[16]	宁坚,靳虎,王泽安,等. 煤中氯的赋存与释放特性研究进展[J].煤炭学报,2019,44(9):2886-2897. NING J,JIN H,WANG Z A,et al. Research advances on the occurrence and release characteristics of chlorine in coal[J].Journal of China Coal Society,2019,44(9):2886-2897(in Chinese). Google Scholar Pub Med
[17]	USEPA.Determination of hydrogen halide and halogen emissions from stationary sources-isokinetic method,26A method[S].Washington DC:USEPA,2018. Google Scholar Pub Med
[18]	CUI J, DUAN L, ZHOU L, et al. Effects of Air pollution control devices on the chlorine emission from 410 t/h circulating fluidized bed boilers Co-firing petroleum coke and coal[J]. Energy & Fuels, 2018,32(4):4410-4416. Google Scholar Pub Med
[19]	ZHANG W, ZHOU R, YANG P, et al. Determination of chlorine with radical emission using laser-induced breakdown spectroscopy coupled with partial least square regression[J]. Talanta, 2019,198:93-96. Google Scholar Pub Med
[20]	RAHIM M U,GAO X,WU H.Determination of chlorine in solid fuels using an improved Eschka method[J].Fuel,2014,129:314-317. Google Scholar Pub Med
[21]	WANG G, LUO Z, ZHANG J, et al. Modes of occurrence of fluorine by extraction and SEM method in a coal-fired power plant from Inner Mongolia, China[J]. Minerals, 2015,5(4):863-869. Google Scholar Pub Med
[22]	VASSILEV S V, ESKENAZY G M, VASSILEVA C G. Contents, modes of occurrence and behaviour of chlorine and bromine in combustion wastes from coal-fired power stations[J]. Fuel, 2000, 79(8):923-937. Google Scholar Pub Med
[23]	LIU J, YANG Z, YAN X, et al. Modes of occurrence of highly-elevated trace elements in superhigh-organic-sulfur coals[J]. Fuel, 2015,156:190-197. Google Scholar Pub Med
[24]	LÓPEZ-VILARIÑO J M, FERNÁNDEZ-MARTÍNEZ G, TURNES-CAROU I, et al. Behavior of fluorine and chlorine in spanish coal fired power plants with pulverized coal boilers and fluidized bed boiler[J]. Environmental Technology, 2003,24(6):687-692. Google Scholar Pub Med
[25]	LI X,LEE J Y,HEALD S. XAFS characterization of mercury captured on cupric chloride-impregnated sorbents[J].Fuel,2012,93:618-624. Google Scholar Pub Med
[26]	CHENG C M, HACK P, CHU P, et al. Partitioning of mercury, arsenic, selenium, boron, and chloride in a full-scale coal combustion process equipped with selective catalytic reduction, electrostatic precipitation, and flue gas desulfurization systems[J]. Energy & Fuels, 2009, 23:4805-4816. Google Scholar Pub Med

Access History

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Export Citation

PDF

XML

Article Metrics

Article views(1957) PDF downloads(36) Cited by(0)

The migration and release characteristics of chlorine during coal combustion in coal-fired power plants

Abstract

References

Access History

通讯作者: 陈斌, bchen63@163.com

Article Metrics

Access History