粉煤灰基陶瓷微滤膜处理水中悬浮物的抗污染特性

秦国彤, 吕永慧, 马琳, 魏微. 粉煤灰基陶瓷微滤膜处理水中悬浮物的抗污染特性[J]. 环境工程学报, 2015, 9(6): 2555-2562. doi: 10.12030/j.cjee.20150604
引用本文: 秦国彤, 吕永慧, 马琳, 魏微. 粉煤灰基陶瓷微滤膜处理水中悬浮物的抗污染特性[J]. 环境工程学报, 2015, 9(6): 2555-2562. doi: 10.12030/j.cjee.20150604
Qin Guotong, Lü Yonghui, Ma Lin, Wei Wei. Anti-fouling performance of fly-ash based ceramic microfiltration membrane in treatment of suspension in water[J]. Chinese Journal of Environmental Engineering, 2015, 9(6): 2555-2562. doi: 10.12030/j.cjee.20150604
Citation: Qin Guotong, Lü Yonghui, Ma Lin, Wei Wei. Anti-fouling performance of fly-ash based ceramic microfiltration membrane in treatment of suspension in water[J]. Chinese Journal of Environmental Engineering, 2015, 9(6): 2555-2562. doi: 10.12030/j.cjee.20150604

粉煤灰基陶瓷微滤膜处理水中悬浮物的抗污染特性

  • 基金项目:

    国家自然科学基金资助项目(50478001)

  • 中图分类号: X773

Anti-fouling performance of fly-ash based ceramic microfiltration membrane in treatment of suspension in water

  • Fund Project:
  • 摘要: 粉煤灰基陶瓷微滤膜是一种新型的廉价无机膜,为研究其抗污染性能,研究了自制的管式膜在处理几种典型料液中的分离性能和渗透性能.考察了过滤不同料液过程中的阻力构成和膜的抗污染特性,并且和文献报道的同类过程中其他膜材料的性能进行了比较.实验进行了2~45 h无反冲、无清洗的连续运行.在过滤粉煤灰悬浮液、高龄土悬浮液和斜生栅藻悬浮液过程中,截留率可以达到100%,过滤阻力低于类似条件下的其他膜材料,在长时间运行后仍能保持较高的通量,表现出良好的抗污染性能.在过滤活性污泥时,截留率达到99.8%,单位压力下过滤通量达到1 170 L/(m·h·MPa).和其他膜材料相比,单位压力下的过滤通量表现出明显的优势.
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  • [1] Fang Jing, Qin Guotong, Wei Wei, et al. Preparation and characterization of tubular supported ceramic microfiltration membranes from fly ash. Separation and Purification Technology, 2011, 80(3): 585-591
    [2] Fang Jing, Qin Guotong, Wei Wei, et al. Elaboration of new ceramic membrane from spherical fly ash for microfiltration of rigid particle suspension and oil-in-water emulsion. Desalination, 2013, 311: 113-126
    [3] 时均, 袁权, 高从揩. 膜技术手册. 北京: 化学工业出版社, 2001: 92-94
    [4] 赵宜江, 钟憬, 李红, 等. 陶瓷微滤膜处理钛白生产废水研究. 化学工程, 1998, 26(4): 56-60 Zhao Yijiang, Zhong Jing, Li Hong, et al. The investigation of microfiltration process using ceramic membrane to be used in the treatment of wastewater produced by sulfuric acid process in TiO2 plant. Chemical Engineering (China), 1998, 26(4): 56-60(in Chinese)
    [5] 岳宇. 炭膜处理二氧化钛悬浮液的研究. 大连: 大连理工大学硕士学位论文, 2006 Yue Yu. Research on separation titanium dioxide dispersion with carbon membrane. Dalian: Dissertation for Master Degree of Dalian University of Technology, 2006 (in Chinese)
    [6] 何晓媛, 辛海虹, 李锦蓉. 大亚湾藻类赤潮的TOC浓度动态分析. 海洋环境科学, 2002, 21(2): 6-9 He Xiaoyuan, Xin Haihong, Li Jinrong. Variations of total organic carbon during red tide event in Daya Bay. Marine Environmental Science, 2002, 21(2): 6-9(in Chinese)
    [7] 顾丁锡. 湖泊富营养化评价方法. 环境污染与防治, 1982, (3): 14-17
    [8] 顾国维, 何义亮. 膜生物反应器:在污水处理中的研究和应用. 北京: 化学工业出版社, 2002
    [9] 赵京东. 陶瓷微滤膜回收钛白粉厂煅烧尾气洗涤废水中TiO2颗粒的工艺研究. 成都: 四川大学硕士学位论文, 2003 Zhao Jingdong. Study onTiO2 recovery by ceramic membrane from the wastewater of flue gas scrubber process, Chengdu: Dissertation for Master Degree of Sichuan University, 2003 (in Chinese)
    [10] 柏文静, 薛晓波, 唐礼升, 等. 陶瓷膜在制备超纯超细粉体中的应用. 中国粉体技术, 2005, (5): 28-30 Bai Wenjing, Xue Xiaobo, Tang Lishen, et al. Application of ceramic filtration membrane in preparation of super-pure and superfine powder. China Powder Science and Technology, 2005, (5): 28-30(in Chinese)
    [11] 李庆华, 曹智, 李小红. 陶瓷膜分离技术在纳米SiO2工业生产中的应用. 化学研究, 2006, 17(2): 77-79 Li Qinghua, Cao Zhi, Li Xiaohong. Application of ceramic membrane separation technology in nanosilica industrial production. Chemical Research, 2006, 17(2): 77-79(in Chinese)
    [12] 沈丽明, 金江, 陈悦. 酵母菌悬浊液污染陶瓷膜的清洗. 南京工业大学学报, 2002, 24(3): 74-77 Shen Liming, Jin Jiang, Chen Yue. Cleaning of polluted ceramic membrane in microzyme separation. Journal of Nanjing University of Technology, 2002, 24(3): 74-77(in Chinese)
    [13] 范广璞, 陆正清. 陶瓷膜在生啤酒酿造过程中的应用研究. 中国酿造, 2005, (9): 43-45 Fang Guangpu, Lu Zhengqing. Application of ceramic membrane in the draft beer brewing. China Brewing, 2005, (9): 43-45(in Chinese)
    [14] 李景明, 吴军, 王树生, 等. 微孔膜在红葡萄酒过滤澄清中的应用研究. 农业工程学报, 2004, 20(1): 222-225 Li Jingming, Wu Jun, Wang Shusheng, et al. Clarification of red wine by cross microflow filtration. Transactions of the Chinese Society of Agricultural Engineering, 2004, 20(1): 222-225(in Chinese)
    [15] 史红文, 李晓湘, 唐东秀, 等. 无机膜超过滤技术在白酒除浊中的应用. 过滤与分离, 2002, 12(1): 32-33 Shi Hongwen, Li Xiaoxiang, Tang Dongxiu, et al. The application of inorganic ultrafiltration membrane in removal of turbid materials in distilled spirit. Journal of Filtration & Separation, 2002, 12(1): 32-33(in Chinese)
    [16] 谭佩毅, 黄秀锦. 陶瓷膜技术在黄酒生产中的应用. 中国酿造, 2006, (9): 45-48 Tan Peiyi, Huang Xiujin. Application of ceramic membrane technology in the rice wine production. China Brewing, 2006, (9): 45-48(in Chinese)
    [17] 景文珩, 孙友勋, 邢卫红, 等. 陶瓷膜在谷氨酸等电母液除菌过程中的应用. 化工装备技术, 2002, 23(6): 10-14 Jing Wenhang, Sun Youxun, Xing Weihong, et al. Application of ceramic membrane in sterilization of isoelectric supernatant of glutamic acid. Chemical Equipment Technology, 2002, 23(6): 10-14(in Chinese)
    [18] 王焕章, 许赵辉, 邢卫红, 等. 陶瓷膜在谷氨酸发酵液除菌过程中的应用. 食品与发酵工业, 2001, 27(5): 42-46 Wang Huanzhang, Xu Zhaohui, Xing Weihong, et al. Application of ceramic membrane filtration in glutamic acid recovery. Food and Fermentation Industries, 2001, 27(5): 42-46(in Chinese)
    [19] 黄继红, 张鹰, 章勤, 等. 无机膜分离谷氨酸菌体应用技术研究. 发酵科技通讯, 2006, 35(3): 9-12 Huang Jihong, Zhang Ying, Zhang Qin, et al. Application of inorganic membrane in separation of cell mass of glutamate broth. Communication of Fermentation Technology, 2006, 35(3): 9-12(in Chinese)
    [20] 王荫榆, 李存瑞, 吴正钧. 应用陶瓷膜浓缩植物乳酸杆菌发酵液的研究. 乳业科学与技术, 2005, (4): 157-159 Wang Yinyu, Li Cuirui, Wu Zhengjun. The study of ceramic membrane in concentration of lactobacillus plantarum fermentated broth. Journal of Dairy Science and Technology, 2005, (4): 157-159(in Chinese)
    [21] Stec L. Z., Field R. W. The effect of the extracellular matrix on the microfiltration of micro-organisms // Proceedings of Euromembrane'95. Bath, UK: University of Bath, 1995
    [22] Stephenson T. 膜生物反应器污水处理技术. 北京: 化学工业出版社, 2003
    [23] Ueda T., Hata K. Domestic wastewater treatment by a submerged membrane bioreactor with gravitational filtration. Water Research, 1999, 33(12): 2888-2892
    [24] Ghyoot W. Reduced sludge production in a two stage membrane assisted bioreactor. Water Research, 1999, 34(1): 205-215
    [25] Trouve E., Urbain V., Manem J. Treatment of municipal wastewater by a membrane bioreactor: Results of a semi-industrial pilot-scale study. Water Science and Technology, 1994, 30(4): 151-157
    [26] Fakhru'l-Razi A., Noor M. J. M. M. Treatment of palm oil mill effluent (POME) with the membrane anaerobic system (MAS). Water Science and Technology, 1999, 39(10-11): 159-163
    [27] Strohwald N. K. H., Ross W. R. Application of the ADUFR process to brewery effluent on a laboratory scale. Water Science and Technology, 1992, 25(10): 95-105
    [28] Kirmura S. Japan's aqua renaissance'90 project. Water Science and Technology, 1991, 23(7-9): 1573-1592
    [29] Pillay V. L., Townsend B., Buckley C. A. Improving the performance of anaerobic digesters at wastewater treatment works: The coupled cross-flow microfiltration/ digester process. Water Science and Technology, 1994, 30(12): 329-337
    [30] Cadi Z., Huyard H., Manem J., et al. Anaerobic digestion of a synthetic wastewater containing starch by a membrane reactor. Environmental Technology, 1994, 15(11): 1029-1039
    [31] Hogetsu A., Ishikawa T., Yoshikawa M., et al. High rate anaerobic digestion of wool scouring wastewater in a digester combined with membrane filter. Water Science and Technology, 1992, 25(7): 341-350
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出版历程
  • 收稿日期:  2014-06-03
  • 刊出日期:  2015-06-09

粉煤灰基陶瓷微滤膜处理水中悬浮物的抗污染特性

  • 1. 北京航空航天大学化学与环境学院, 北京 100191
  • 2. 北京联合大学应用文理学院, 北京 100191
基金项目:

国家自然科学基金资助项目(50478001)

摘要: 粉煤灰基陶瓷微滤膜是一种新型的廉价无机膜,为研究其抗污染性能,研究了自制的管式膜在处理几种典型料液中的分离性能和渗透性能.考察了过滤不同料液过程中的阻力构成和膜的抗污染特性,并且和文献报道的同类过程中其他膜材料的性能进行了比较.实验进行了2~45 h无反冲、无清洗的连续运行.在过滤粉煤灰悬浮液、高龄土悬浮液和斜生栅藻悬浮液过程中,截留率可以达到100%,过滤阻力低于类似条件下的其他膜材料,在长时间运行后仍能保持较高的通量,表现出良好的抗污染性能.在过滤活性污泥时,截留率达到99.8%,单位压力下过滤通量达到1 170 L/(m·h·MPa).和其他膜材料相比,单位压力下的过滤通量表现出明显的优势.

English Abstract

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