挥发性氯代烃类新污染物的环境特性、水平、行为与风险
Environmental Characteristics, Levels, Behavior, and Risks of Emerging Volatile Chlorinated Hydrocarbons
-
摘要: 根据国内外污染物管控清单和国内环境质量标准等文件，共筛选出24种挥发性氯代烃(VCHs)。这些VCHs的理化性质相近，饱和蒸气压均大于20 Pa (20℃)且微溶于水，主要用于溶剂、清洗剂、冷冻机和化工原料等。这24种VCHs中，有19种具有PMT或者vPvM特性，有22种具有高淋溶迁移性，有11种、12种和17种被列入国内的地表水、地下水和土壤环境质量标准，有13种属于危险废物鉴别标准中的判定指标。环境水平分析显示，大气环境中以二氯甲烷和氯甲烷等低氯代烃为主，三氯甲烷、四氯化碳、三氯乙烯和四氯乙烯是地表水中VCHs特征污染物，土壤和地下水的检测结果来看，值得关注的VCHs包括三氯甲烷、二氯甲烷、四氯乙烯、1,2-二氯乙烷、三氯乙烯、1,2-二氯丙烷和1,1,2-三氯乙烷。风险评估结果显示，在呼吸吸入暴露途径，大气环境中非致癌风险值最高的VCHs为1,2-二氯乙烷、1,2-二氯丙烷和三氯甲烷，最大值分别为0.209、0.102和0.040；致癌风险值最高的VCHs为三氯甲烷、1,2-二氯丙烷和四氯化碳，最大值分别为2.76×10-5、1.50×10-5和3.72×10-5。在饮水摄入暴露途径，地表水源中非致癌风险值最高的VCHs为三氯乙烯、三氯甲烷和四氯化碳，最大值分别为0.555、0.152和0.077；致癌风险值最高的VCHs为四氯化碳、三氯乙烯和四氯乙烯，最大值分别为2.16×10-5、1.27×10-5和7.12×10-7。对VCHs的风险管控提出了对策和建议。Abstract: According to domestic and international pollutant control lists and domestic environmental quality standards, a total of 24 volatile chlorinated hydrocarbons (VCHs) were selected in this study. These VCHs share similar physical and chemical properties, including saturated vapor pressures greater than 20 Pa (20 ℃) and low water solubility. They are mainly used as solvents, cleaning agents, refrigerants, and chemical intermediates. Among these VCHs, 19 exhibit PMT (persistent, mobile, toxic) or vPvM (very persistent, very mobile) characteristics, 22 show high leachability, and 11, 12, and 17 are regulated under domestic surface water, groundwater, and soil environmental quality standards, respectively. Additionally, 13 are listed in the hazardous waste identification standards. Environmental monitoring reveals that low chlorinated hydrocarbons, such as dichloromethane and monochloromethane, dominate atmospheric VCHs, whereas trichloromethane, tetrachloromethane, trichloroethene and tetrachloroethene are prominent in surface water. In soil and groundwater, key VCHs of concern include trichloromethane, dichloromethane, tetrachloromethane, 1,2-dichloroethane, trichloroethene, 1,2-dichloropropane and 1,1,2-trichloroethane. Risk assessments indicate that, for inhalation exposure, 1,2-dichloroethane, 1,2-dichloropropane, and trichloromethane in the atmosphere pose the highest non-carcinogenic risks, with maximum values of 0.209, 0.102, and 0.040, respectively; the highest carcinogenic risks stem from trichloromethane, 1,2-dichloropropane, and tetrachloromethane, with maximum values of 2.76×10-5, 1.50×10-5, and 3.72×10-5, respectively. For drinking water exposure, trichloroethene, trichloromethane, and tetrachloromethane in surface water present the highest non-carcinogenic risks, with maximum values of 0.555, 0.152, and 0.077, respectively; the highest carcinogenic risks are associated with tetrachloromethane, trichloroethene, and tetrachloroethene, with maximum values of 2.16×10-5, 1.27×10-5, and 7.12×10-7, respectively. This study provides targeted recommendations to enhance the management and control of VCH-related environmental risks.
-
-
孟小燕,黄宝荣.我国新污染物治理的进展、问题及对策[J].环境保护, 2023, 51(7):9-13. MENG X Y, HUANG B R. The progress, problems and countermeasures of new pollutants treatment in China[J]. Environmental protection, 2023, 51(7):9-13.
杨旭,邢志林,张丽杰.填埋场氯代烃生物降解过程的机制转化与调控研究及展望[J].微生物学报, 2017, 57(4):468-479. YANG X, XING Z L, ZHANG L J. Advances in transformation and regulation biodegradation of chorinated hydrocarbons in landfill[J]. Acta microbiologica sinica, 2017, 57(4):468-479.
何洁,王伯光,刘舒乐,等.城市污水处理厂挥发性卤代有机物的排放特征及影响因素研究[J].环境科学, 2011, 32(12):3577-3581. HE J, WANG B G, LIU S L, et al. Source emission characteristics and impact factors of volatile halogenated organic compounds from wastewater treatment plant[J]. Environmental science, 2011, 32(12):3577-3581.
任昶宇,刘强,张璐涛,等.沱江三氯甲烷浓度异常事件中污染物趋势分析[J].中国沼气, 2023, 41(2):59-64. REN C Y, LIU Q, ZHANG L T, et al. Pollution trend analysis of trichloromethane water environmental events in Tuojiang River[J]. China biogas, 2023, 41(2):59-64.
王铁宇,李奇锋,吕永龙.我国VOCs的排放特征及控制对策研究[J].环境科学, 2013, 34(12):4756-4763. WANG T Y, LI Q F, LYU Y L. Characteristics and countermeasures of volatile organic compounds (VOCs) emission in China[J]. Environmental science, 2013, 34(12):4756-4763.
韩方岸,陈钧,蒋兆峰,等.苏、浙、鲁地区主要饮用水地表水源挥发及半挥发有机物调查[J].环境与健康杂志, 2011, 28(10):890-894. HAN F A, CHEN J, JIANG Z F, et al. Investigation of VOCs and SVOCs in surface water source in Jiangsu, Zhejiang, Shandong Province, China[J]. Journal of environment and health, 2011, 28(10):890-894.
李晓萌,唐阔,蒋晶,等.建设用地土壤优先管理有毒有害物质研究[J].生态毒理学报, 2023, 18(2):308-326. LI X M, TANG K, JIANG J, et al. A study on soil priority management of toxic and hazardous substances for development land[J]. Asian journal of ecotoxicology, 2023, 18(2):308-326.
高存荣,王俊桃.中国69个城市地下水挥发性卤代烃污染检测与特征研究[J].地球科学与环境学报, 2012, 34(1):66-71. GAO C R, WANG J T. Investigation and research on volatile halogenated hydrocarbon contamination from groundwater in 69 cities of China[J]. Journal of earth sciences and environment, 2012, 34(1):66-71.
ARP H P H, HALE S E, BORCHERS U, et al. A prioritization framework for PMT/vPvM substances under REACH for registrants, regulators, researchers and the water sector[R]. Dessau-Roβlau, Germany:Umwelt Bundesamt, 2023:21-132. 王昭,石建省,张兆吉,等.我国"水中优先控制有机物"对地下水污染的预警性研究[J].水资源保护, 2009, 25(1):90-94. WANG Z, SHI J S, ZHANG Z J, et al. Groundwater contamination risk assessment:a Chinese list of preferred controlled organic pollutants in water[J]. Water resources protection, 2009, 25(1):90-94.
赵晨妍,孙宇翔,杨莉莉,等.六氯丁二烯的排放源及环境污染特征[J].化学进展, 2023, 35(7):1040-1052. ZHAO C Y, SUN Y X, YANG L L, et al. Source and environmental characteristics of hexachlorobutadiene[J]. Progress in chemistry, 2023, 35(7):1040-1052.
JI Y Y, XU L H, LI H, et al. Pollution characteristics and health risk assessment of summertime atmospheric volatile halogenated hydrocarbons in a typical urban area of Beijing, China[J]. Atmosphere, 2020, 11(10):1021. 张博韬,景宽,王琴,等.北京城区夏季VOCs初始体积分数特征及来源解析[J].环境科学, 2024, 45(1):81-92. ZHANG B T, JING K, WANG Q, et al. Characteristics and source apportionment of VOCs initial mixing ratio in Beijing during summer[J]. Environmental science, 2024, 45(1):81-92.
金丹.上海城郊夏季大气VOCs在臭氧生成中的作用[J].环境科学, 2022, 43(1):132-139. JIN D. Role of atmospheric VOCs in ozone formation in summer in Shanghai suburb[J]. Environmental science, 2022, 43(1):132-139.
南淑清,张霖琳,梁晶,等.郑州市环境空气中挥发性卤代烃污染特征与健康风险评价[J].环境污染与防治, 2016, 38(10):72-78. NAN S Q, ZHANG L L, LIANG J, et al. Pollution characters and health risk assessment of VHCs in ambient air in Zhengzhou[J]. Environmental pollution&control, 2016, 38(10):72-78.
邓拓宇,陈鸿展,张金谱.广州市大气VOCs污染特征及O3生成潜势分析[J].中国环境监测, 2023, 39(1):51-59. DENG T Y, CHEN H Z, ZHANG J P. Analysis on pollution characteristics and O3 formation potential of ambient VOCs in Guangzhou[J]. Environmental monitoring in China, 2023, 39(1):51-59.
张良瑜,母应锋,朱志锋,等.南京市大气VOCs污染特征及来源解析[J].环境监控与预警, 2023, 15(5):128-133. ZHANG L Y, MU Y F, ZHU Z F, et al. Pollution characteristics and source apportionment of atmospheric VOCs in Nanjing[J]. Environmental monitoring and forewarning, 2023, 15(5):128-133.
高亢,章慧,刘梦迪,等.芜湖市大气挥发性有机物污染特征、大气反应活性及源解析[J].环境科学, 2020, 41(11):4885-4894. GAO K, ZHANG H, LIU M D, et al. Characteristics, atmospheric reactivity, and source apportionment of ambient volatile organic compounds in Wuhu[J]. Environmental science, 2020, 41(11):4885-4894.
徐晨曦,陈军辉,韩丽,等.成都市2017年夏季大气VOCs污染特征、臭氧生成潜势及来源分析[J].环境科学研究, 2019, 32(4):619-626. XU C X, CHEN J H, HAN L, et al. Analyses of pollution characteristics, ozone formation potential and sources of VOCs atmosphere in Chengdu City in summer 2017[J]. Research of environmental sciences, 2019, 32(4):619-626.
王成辉,陈军辉,韩丽,等.成都市城区大气VOCs季节污染特征及来源解析[J].环境科学, 2020, 41(9):3951-3960. WANG C H, CHEN J H, HAN L, et al. Seasonal pollution characteristics and analysis of the sources of atmospheric VOCs in Chengdu urban area[J]. Environmental science, 2020, 41(9):3951-3960.
赵乐,刘新军,范莉茹,等.石家庄夏季典型时段臭氧污染特征及来源解析[J].中国环境监测, 2019, 35(4):78-84. ZHAO L, LIU X J, FAN L R, et al. Pollution characteristic and source apportionment of VOCs during summer typical periods in Shijiazhuang[J]. Environmental monitoring in China, 2019, 35(4):78-84.
高素莲,闫学军,刘光辉,等.济南市夏季臭氧重污染时段VOCs污染特征及来源解析[J].生态环境学报, 2020, 29(9):1839-1846. GAO S L, YAN X J, LIU G H, et al. Characteristics and source apportionment of ambient VOCs in serious ozone pollution period of summer in Ji'nan[J]. Ecology and environmental sciences, 2020, 29(9):1839-1846.
曹方方,王文雷,李玉华,等.山东省环境空气中挥发性卤代烃污染状况研究[J].中国测试, 2023, 49(4):60-67. CAO F F, WANG W L, LI Y H, et al. Pollution characteristics of ambient halocarbons in Shandong Province[J]. China measurement&test, 2023, 49(4):60-67.
宋晗睿,徐勃,王健,等.我国典型工业城市夏冬季卤代烃来源解析与致癌风险[J].环境科学研究, 2022, 35(11):2527-2537. SONG H R, XU B, WANG J, et al. Halogenated hydrocarbon source apportionment and carcinogenic risks in summer and winter in a typical industrial city of China[J]. Research of environmental sciences, 2022, 35(11):2527-2537.
ZHENG P G, CHEN T S, DONG C, et al. Characteristics and sources of halogenated hydrocarbons in the Yellow River Delta Region, Northern China[J]. Atmospheric research, 2019, 225:70-80. 杨丽蓉,许萌,徐学哲,等.银川市大气臭氧生成敏感性与VOCs来源解析[J].环境科学, 2024, 45(8):4419-4431. YANG L R, XU M, XU X Z, et al. Sensitivity analysis of atmospheric ozone and source apportionment of volatile organic compounds in Yinchuan City[J]. Environmental science, 2024, 45(8):4419-4431.
罗达通,张青梅,刘湛,等.长株潭城区8月VOCs污染特征及来源分析[J].环境科学, 2022, 43(7):3463-3472. LUO D T, ZHANG Q M, LIU Z, et al. Characteristics and source apportionment of volatile organic compounds in August in the Chang-Zhu-Tan urban area[J]. Environmental science, 2022, 43(7):3463-3472.
连世泽,邓萌杰,陈楠,等.黄冈市大气挥发性有机物污染特征、来源及对臭氧生成的影响[J].环境科学, 2023, 44(10):5410-5417. LIAN S Z, DENG M J, CHEN N, et al. Characteristics, sources, and contributions to ozone formation of ambient volatile organic compounds in Huanggang, China[J]. Environmental science, 2023, 44(10):5410-5417.
BARLETTA B, MEINARDI S, SIMPSON I J, et al. Ambient halocarbon mixing ratios in 45 Chinese cities[J]. Atmospheric environment, 2006, 40(40):7706-7719. 万译文,康天放,周忠亮,等.北京官厅水库水体中挥发性有机物健康风险评价[J].环境科学研究, 2009, 22(2):150-154. WAN Y W, KANG T F, ZHOU Z L, et al. Health risk assessment of volatile organic compounds in water of Beijing Guanting Reservoir[J]. Research of environmental sciences, 2009, 22(2):150-154.
高秋生,赵永辉,焦立新,等.白洋淀水体挥发性有机物污染特征与风险评价[J].环境科学, 2018, 39(5):2048-2055. GAO Q S, ZHAO Y H, JIAO L X, et al. Pollution characteristics and health risk assessment of volatile organic compounds in Baiyangdian Lake[J]. Environmental science, 2018, 39(5):2048-2055.
谢轶.辽河流域水体中挥发性有机物(VOCs)污染状况调查[J].农业与技术, 2014, 34(2):253-254. 程云轩,高秋生,李捷,等.淮河流域南四湖可挥发性有机物污染特征及风险评价[J].环境科学, 2021, 42(4):1820-1829. CHENG Y X, GAO Q S, LI J, et al. Characteristics of volatile organic compounds pollution and risk assessment of Nansi Lake in Huaihe River Basin[J]. Environmental science, 2021, 42(4):1820-1829.
黄韵竹,隋倩,王佳琦,等.太湖流域城镇地表水中挥发性卤代烃污染特征[J].中国环境科学, 2020, 40(5):2174-2179. HUANG Y Z, SUI Q, WANG J Q, et al. Pollution characteristics of volatile halogenated hydrocarbons in the surface water of a typical town in Taihu Basin[J]. China environmental science, 2020, 40(5):2174-2179.
范美娟,季鹏,程芳菲.长江(南京段)水源水中有机污染物的GC/MS分析[J].广州化工, 2014, 42(4):128-130. FAN M J, JI P, CHENG F F. GC/MS analysis of organic pollutants in Yangtze River in Nanjing[J]. Guangzhou chemical industry, 2014, 42(4):128-130.
李琰,周志俊,宁文吉,等.上海市闵行区居民供水系统中挥发性有机物分析[J].复旦学报(医学版), 2017, 44(5):644-651. LI Y, ZHOU Z J, NING W J, et al. Analysis of volatile organic compounds in water supply system of Minhang District of Shanghai[J]. Fudan university journal of medical sciences, 2017, 44(5):644-651. 李永珍,何更生,詹铭,等.上海市水源水及出厂水中卤甲烷、卤乙酸、卤乙腈类消毒副产物含量及健康风险评估[J].环境与职业医学, 2021, 38(5):460-466. LI Y Z, HE G S, ZHAN M, et al. Levels and health risk assessments of halomethanes, haloacetic acids, and haloacetonitriles disinfection by-products in source and finished water in Shanghai[J]. Journal of environmental and occupational medicine, 2021, 38(5):460-466.
袁宇,谭璐,舒倩,等.集中式饮用水源地水环境质量变化及健康风险评估--以湘潭市某水厂为例[J].环境保护科学, 2022, 48(3):132-139. YUAN Y, TAN L, SHU Q, et al. Water environmental quality analysis and health risk assessment of centralized drinking water sources-Taking a waterworks in Xiangtan City as an example[J]. Environmental protection science, 2022, 48(3):132-139.
饶志,储小东,颜春,等.鄱阳湖平原浅层地下水有机污染物含量特征与健康风险评价[J].地球与环境, 2019, 47(5):662-670. RAO Z, CHU X D, YAN C, et al. Characteristics and health risk assessment of organic pollutants in groundwater of the Poyang Lake Plain[J]. Earth and environment, 2019, 47(5):662-670.
郭永丽,全洗强,吴庆.北方喀斯特地区地下水VOCs污染特征及健康风险--以山东省淄博市临淄区为例[J].广西师范大学学报(自然科学版), 2020, 38(6):102-113. GUO Y L, QUAN X Q, WU Q. Pollution characteristics and health risk assessment of volatile organic compounds of typical Karst groundwater source in North China[J]. Journal of Guangxi Normal University (natural science edition), 2020, 38(6):102-113. 成世才,董妍,刘凯丽.山东济南市先行区浅层地下水有机污染特征[J].矿产勘查, 2020, 11(12):2749-2756. CHENG S C, DONG Y, LIU K L. Characteristics of organic pollution in the shallow groundwater, Jinan pilot area, Shandong Province[J]. Mineral exploration, 2020, 11(12):2749-2756.
李丽君,王海娇,马健生.下辽河平原地下水中挥发性有机物的污染特征及健康风险评价[J].岩矿测试, 2021, 40(6):930-943. LI L J, WANG H J, MA J S. Pollution characteristics and health risk assessment of volatile organic compounds in groundwater in the lower Liaohe River Plain[J]. Rock and mineral analysis, 2021, 40(6):930-943.
张坤锋,昌盛,赵少延,等.克鲁伦河流域地下水饮用水水源中挥发性有机物的污染特征与风险评价[J].环境工程技术学报, 2021, 11(6):1083-1091. ZHANG K F, CHANG S, ZHAO S Y, et al. Pollution characteristics and risk assessment of volatile organic compounds in groundwater drinking water sources in Klulun River Basin[J]. Journal of environmental engineering technology, 2021, 11(6):1083-1091.
王超,张立川,王应强,等.莱芜地区地下水污染研究[J].地下水, 2021, 43(6):21-24 , 229. WANG C, ZHANG L C, WANG Y Q, et al. Study on groundwater pollution in Laiwu Region[J]. Ground water, 2021, 43(6):21-24, 229.
张坤锋,赵少延,孙兴滨,等.海拉尔河及傍河地下水饮用水源中挥发性有机物的污染特征与风险[J].河南师范大学学报(自然科学版), 2021, 49(5):74-82. ZHANG K F, ZHAO S Y, SUN X B, et al. Pollution characteristics and risks of volatile organic compounds in drinking water sources of Hailar River and nearby rivers groundwater[J]. Journal of Henan Normal University (natural science edition), 2021, 49(5):74-82. 贾文娟.沈阳市地下水饮用水源挥发性有机物分布特征及风险评价[J].湖南生态科学学报, 2022, 9(3):65-70. JIA W J. Distribution characteristics and risk assessment of volatile organic compounds in groundwater sources in Shenyang[J]. Journal of Hunan ecological science, 2022, 9(3):65-70.
任庆莲,郑瑞文,徐超.济南市深层地下水化学特征及变化规律[J].山东水利, 2023(6):11-15. REN Q L, ZHENG R W, XU C. Chemical characteristics and variation rules of deep groundwater in Jinan[J]. Shandong water resources, 2023 (6):11-15.
刘乾,孟令华.泰安城区地下水中挥发性和半挥发性有机物特征与健康风险评价[J].环境污染与防治, 2024, 46(2):208-215. LIU Q, MENG L H. The characteristics and health risk assessment of volatile and semi-volatile organic pollutants in groundwater in Tai'an urban area[J]. Environmental pollution&control, 2024, 46(2):208-215.
杨俊晨,王琨,黄丽坤,等.污水处理厂芳香烃和氯代烃逸散速率研究[J].中国环境科学, 2012, 32(3):433-439. YANG J C, WANG K, HUANG L K, et al. Emission rates of aromatic hydrocarbons and chlorinated hydrocarbons at a wastewater treatment plant[J]. China environmental science, 2012, 32(3):433-439.
王琨,杨俊晨,黄丽坤,等.污水处理过程中苯系物和氯代烃三相分布规律[J].环境科学研究, 2012, 25(2):186-192. WANG K, YANG J C, HUANG L K, et al. Distributions of BTEX and chlorinated hydrocarbons in three phases during wastewater treatment processing[J]. Research of environmental sciences, 2012, 25(2):186-192.
宋贵生,杨桂朋,陆小兰.东海和南黄海表层海水中几种挥发性卤代烃的分布和通量研究[J].海洋与湖沼, 2013, 44(1):9-14. SONG G S, YANG G P, LU X L. Distributions and sea-to-air fluxes of several volatile halocarbons (VHCs) in the surface seawater of the East China Sea and southern Yellow Sea[J]. Oceanologia et limnologia sinica, 2013, 44(1):9-14.
杨斌,陆小兰,杨桂朋,等.北黄海海水中挥发性卤代烃的分布和海-气通量研究[J].海洋学报, 2010, 32(1):47-55. YANG B, LU X L, YANG G P, et al. Distributions and sea-air fluxes of volatile halocarbons in the seawater of the northern Huanghai Sea[J]. Acta oceanologica sinica, 2010, 32(1):47-55.
何真,陆小兰,杨桂朋.冬季中国东海海水中挥发性卤代烃的分布特征和海-气通量[J].环境科学, 2013, 34(3):849-856. HE Z, LU X L, YANG G P. Distribution characteristics and sea-air fluxes of volatile halocarbons in the East China Sea in winter[J]. Environmental science, 2013, 34(3):849-856.
张苗苗,陆小兰,杨桂朋.夏季北黄海和渤海海水中几种挥发性卤代烃的分布和通量研究[J].中国海洋大学学报(自然科学版), 2013, 43(3):62-69. ZHANG M M, LU X L, YANG G P. Distributions and sea-to-air fluxes of several volatile halocarbons in the north Yellow Sea and the Bohai Sea[J]. Periodical of Ocean University of China, 2013, 43(3):62-69. 柳秋林,何真,杨桂朋.秋季渤海和北黄海海水中挥发性卤代烃的分布与通量[J].海洋环境科学, 2015, 34(4):481-487. LIU Q L, HE Z, YANG G P. Distributions and sea-to-air fluxes of volatile halocarbons in the Bohai Sea and northern Yellow Sea[J]. Marine environmental science, 2015, 34(4):481-487.
李成帅,何真,张婧,等.夏季长江口及其邻近海域海水及大气中挥发性卤代烃的分布与海-气通量研究[J].环境科学学报, 2018, 38(2):761-771. LI C S, HE Z, ZHANG J, et al. Distributions and sea-to-air fluxes of volatile halocarbons in the Yangtze River Estuary and adjacent area in summer[J]. Acta scientiae circumstantiae, 2018, 38(2):761-771.
汪浩,何真,张婧,等.夏季长江口及其邻近海域挥发性卤代烃的分布和海-气通量研究[J].海洋学报, 2018, 40(10):96-109. WANG H, HE Z, ZHANG J, et al. Distribution characteristics and sea-to-air fluxes of volatile halocarbons in the Changjiang River Estuary and its adjacent marine area in summer[J]. Haiyang Xuebao, 2018, 40(10):96-109.
高尚,王磊,龙涛,等.污染地块中高密度非水相液体(DNAPLs)迁移特征及判定调查技术研究进展[J].生态与农村环境学报, 2018, 34(4):289-299. GAO S, WANG L, LONG T, et al. Research progress on migration characteristics and investigation technologies of DNAPLs contaminated sites[J]. Journal of ecology and rural environment, 2018, 34(4):289-299.
谢文逸,姜登登,李旭伟,等.污染地块巨厚含水层典型DNAPLs运移模拟及安全利用深度评估[J].环境工程学报, 2022, 16(7):2287-2295. XIE W Y, JIANG D D, LI X W, et al. Transport simulation of typical DNAPLs in deep aquifer and safe utilization depth evaluation of polluted plot[J]. Chinese journal of environmental engineering, 2022, 16(7):2287-2295.
肖鹏,刘汉乐.饱和砂土中DNAPL污染物迁移过程及数值模拟[J].中国环境科学, 2024, 44(1):386-395. XIAO P, LIU H L. Transport processes and numerical simulation of DNAPL contaminants in saturated sandy soils[J]. China environmental science, 2024, 44(1):386-395.
陆强,李辉,林匡飞,等.上海浦东某氯代烃场地地下水污染现状调查[J].环境科学学报, 2016, 36(5):1730-1737. LU Q, LI H, LIN K F, et al. Investigation of chlorinated hydrocarbons in groundwater from a typical contaminated site in Pudong District, Shanghai[J]. Acta scientiae circumstantiae, 2016, 36(5):1730-1737.
DICKSON S E, THOMSON N R. Dissolution of entrapped DNAPLs in variable aperture fractures:experimental data and empirical model[J]. Environmental science&technology, 2003, 37(18):4128-4137. 胡文庆,邢志林,赵天涛.包气带中氯代烃运移特性及原位生物修复研究进展[J].应用与环境生物学报, 2022, 28(4):1094-1101. HU W Q, XING Z L, ZHAO T T. Migration behavior and in situ bioremediation of chlorinated hydrocarbon solvent in vadose zone:a review[J]. Chinese journal of applied and environmental biology, 2022, 28(4):1094-1101.
赵天涛,杨旭,邢志林,等.填埋场覆盖土对典型氯代烃的吸附特性[J].中国环境科学, 2018, 38(4):1403-1410. ZHAO T T, YANG X, XING Z L, et al. Adsorption of chlorinated hydrocarbons in landfill cover soil[J]. China environmental science, 2018, 38(4):1403-1410.
周林军,邢维龙,张冰,等.国内外化学物质环境暴露评估策略对比及启示[J].生态毒理学报, 2024, 19(5):27-39. ZHOU L J, XING W L, ZHANG B, et al. Comparison and enlightenment of environmental exposure assessment strategies of chemical substances[J]. Asian journal of ecotoxicology, 2024, 19(5):27-39.
-
点击查看大图
计量
- 文章访问数: 279
- HTML全文浏览数: 279
- PDF下载数: 59
- 施引文献: 0
下载:
