室内空气中装饰和建筑材料VOCs迁移释放和暴露模型研究进展
Research Progress of Release Migration and Exposure Assessment Models for Indoor VOCs in Decorative and Building Materials
-
摘要: 随着城市建设的发展，现代建筑的高密闭性以及大量装饰材料的应用，导致室内空气污染日趋严重，室内空气质量是当前环境与公共卫生领域关注的热点问题之一。室内污染源以挥发性有机物为主，这些有机物会对人体健康造成危害，迁移释放过程耗时时间长，且受产品、环境、使用者、有机物本身多个维度的因素影响，实验室很难全面开展其迁移规律的研究，因此需要建立相应的迁移释放模型。本文综述了室内挥发性有机物迁移释放模型建立的基本流程，从模型传播途径和建立机理对模型进行分类汇总，讨论了模型中包括分配系数、扩散系数、初始释放浓度等重要参数的求解方法，并列举了一些具有代表性的传质模型、经验模型和人体暴露模型。同时，本文对现有模型的适用性和缺陷进行分析讨论，以期为未来挥发性有机物人体暴露风险评估的研究提供理论基础和研究方向。Abstract: With the development of urban construction, the high airtightness of modern buildings and the extensive use of decorative materials have led to increasingly serious indoor air pollution. Indoor air quality has become a focal issue in the fields of environmental and public health. Indoor pollution sources are primarily volatile organic compounds (VOCs), which pose health risks to humans. The migration and release processes of VOCs are prolonged processes influenced by multiple factors, including the product itself, environmental conditions, user behaviors, and the properties of the organic compounds. It is challenging for laboratories to comprehensively study the migration patterns of VOCs, highlighting the need for the establishment of corresponding migration and release models. This paper reviews the basic process of establishing indoor VOC migration and release models, categorizing and summarizing models based on their transmission pathways and establishment mechanisms. It discusses the methods for determining key parameters in the models, such as partition coefficients, diffusion coefficients, and initial release concentrations, and provides examples of representative mass transfer models, empirical models, and human exposure models. Furthermore, this paper analyzes and discusses the applicability and limitations of existing models, aiming to provide a theoretical foundation and research directions for future studies on human exposure risk assessment of VOCs.
-
Key words:
- volatile organic compounds /
- indoor air quality /
- migration model /
- exposure assessment
-
-
YANG D L, ZHANG Z N, LIU H, et al. Indoor air pollution and human ocular diseases:associated contaminants and underlying pathological mechanisms[J]. Chemosphere, 2023, 311:137037. TAYAL A, KABRA S K. Indoor air pollution-Not the lesser evil![J]. Indian journal of pediatrics, 2023, 90(9):849-850. BHOONAH R, MAURY-MICOLIER A, JOLLIET O. Integrated empirical and modelled determination of the human health impacts of building material VOCs[J]. Building and environment, 2023, 242:110523. PATRICK J M. A review of "Indoor air pollutants:exposure and health effects; Euro Reports and Studies 78" (1983)[J]. Ergonomics, 1985, 28(10):1504-1505. KIM Y M, HARRAD S, HARRISON R. Concentrations and sources of volatile organic compounds in urban domestic and public microenvironments[J]. Indoor and built environment, 2001, 10(3/4):147-153. HUANG L H, WEI Y R, ZHANG L Y, et al. Estimates of emission strengths of 43 VOCs in wintertime residential indoor environments, Beijing[J]. Science of the total environment, 2021, 793:148623. 李崇磊,王凡,刘薇,等. VOCs、细菌及颗粒物混合暴露致小鼠学习记忆障碍机制研究[J].生态毒理学报, 2013, 8(5):778-784. LI C L, WANG F, LIU W, et al. Mechanisms of dysfunction on learning and memory capacity induced by VOCs, bacteria and particulate matter[J]. Asian journal of ecotoxicology, 2013, 8(5):778-784.
尉立华,李桂晓,彭晓辉,等.儿童雨衣中苯系物迁移特性影响因素分析[J].印染, 2024, 50(8):78-82. YU L H, LI G X, PENG X H, et al. Analysis of factors affecting migration features of benzene series in children's raincoat[J]. China dyeing&finishing, 2024, 50(8):78-82.
李桂晓,尉立华,贺祥珂,等.儿童地垫产品中5种VOCs暴露及健康风险评估[J].生态毒理学报, 2024, 19(4):360-367. LI G X, YU L H, HE X K, et al. Exposure and health risk assessment of 5 VOCs in children's play mats[J]. Asian journal of ecotoxicology, 2024, 19(4):360-367.
崔进,刘成鑫,陈姗,等.气袋采样/热脱附-气相色谱-质谱法检测儿童地垫中35种挥发性有机物[J].分析试验室, 2020, 39(6):700-705. CUI J, LIU C X, CHEN S, et al. Determination of 35 volatile organic compounds in children playmat by bag sampling/thermodesorption-gas chromatography-mass spectrometry[J]. Chinese journal of analysis laboratory, 2020, 39(6):700-705.
GRIPPO A, ZHU K X, YEUNG E H, et al. Indoor air pollution exposure and early childhood development in the Upstate KIDS Study[J]. Environmental research, 2023, 234:116528. JIANG N, BAO W W, GUI Z H, et al. Findings of indoor air pollution and childhood obesity in a cross-sectional study of Chinese schoolchildren[J]. Environmental research, 2023, 225:115611. LI S X, XU J, JIANG Z G, et al. Correlation between indoor air pollution and adult respiratory health in Zunyi City in Southwest China:situation in two different seasons[J]. BMC public health, 2019, 19(1):723. GHARAIBEH N S. Effects of indoor air pollution on lung function of primary school children in Jordan[J]. Annals of tropical paediatrics, 1996, 16(2):97-102. DWIVEDI S, TAUSHIBA A, ZEHRA F, et al. Revelations to indoor air pollutants and health risk assessment on women:a case study[J]. Hygiene and environmental health advances, 2023, 5:100038. 秦华鹏,刘阳生.室内环境中挥发性有机物释放过程的数学模型[J].环境污染与防治, 2006, 28(2):96-99. QIN H P, LIU Y S. Review of volatile organic compounds emission models for indoor environment[J]. Environmental pollution&control, 2006, 28(2):96-99.
赵胜男,丁从阳,林勤保,等.用于食品包装材料成分迁移数学模型的研究进展[J].包装工程, 2020, 41(13):63-71. ZHAO S N, DING C Y, LIN Q B, et al. Progress in mathematic model for the migration of food packaging material components[J]. Packaging engineering, 2020, 41(13):63-71.
CHANG T, REN D X, SHEN Z X, et al. Indoor air pollution levels in decorated residences and public places over Xi'an, China[J]. Aerosol and air quality research, 2017, 17(9):2197-2205. BRAISH T, TINEL L, DEPELCHIN L, et al. Evaluation of the seasonal variation of VOC surface emissions and indoor air concentrations in a public building with bio-based insulation[J]. Building and environment, 2023, 238:110312. SZCZEPAŃSKA N, MARĆ M, KUDŁAK B, et al. Assessment of ecotoxicity and total volatile organic compound (TVOC) emissions from food and children's toy products[J]. Ecotoxicology and environmental safety, 2018, 160:282-289. GUO Z S. Review of indoor emission source models. Part 2. Parameter estimation[J]. Environmental pollution, 2002, 120(3):551-564. GUO Z S. Review of indoor emission source models. Part 1. overview[J]. Environmental pollution, 2002, 120(3):533-549. ZHANG Y, HOPKE P K, MANDIN C. Handbook of indoor air quality. Part 3.Volatile organic compounds[M]. Singapore:Springer, 2022:84-94. JOHN D, SPENGLER J F M E. Indoor air quality handbook. Chapter 58. Indoor air quality modeling[M]. Columbus:McGraw-Hill Professional, 2000:11-22. LITTLE J C, HODGSON A T, GADGIL A J. Modeling emissions of volatile organic compounds from new carpets[J]. Atmospheric environment, 1994, 28(2):227-234. LIU Z, YE W, LITTLE J C. Predicting emissions of volatile and semivolatile organic compounds from building materials:a review[J]. Building and environment, 2013, 64:7-25. 刘杨.有机模拟物从食品包装纸传质到空气中迁移行为的研究[D].南宁:广西大学, 2007:24-27. YU L H, HE X K, GAO C L, et al. An emission model for inhalable chemicals from children's play mats based on partition coefficients[J]. Journal of chromatography A, 2024, 1721:464855. XU Y, ZHANG Y P. An improved mass transfer based model for analyzing VOC emissions from building materials[J]. Atmospheric environment, 2003, 37(18):2497-2505. ZHANG Y, XU N, LIU J M, et al. A multisource mass transfer model for simulating VOC emissions from paints[J]. Science of the total environment, 2023, 902:165945. XIONG J Y, ZHANG Y P, WANG X K, et al. Macro-meso two-scale model for predicting the VOC diffusion coefficients and emission characteristics of porous building materials[J]. Atmospheric environment, 2008, 42(21):5278-5290. LIU Z W, YAN Y S, LIU T T, et al. How to predict emissions of volatile organic compounds from solid building materials?A critical review on mass transfer models[J]. Journal of environmental management, 2022, 302:114054. LIU Y F, ZHOU X J, WANG D J, et al. A diffusivity model for predicting VOC diffusion in porous building materials based on fractal theory[J]. Journal of hazardous materials, 2015, 299:685-695. ZHOU X J, LIU Y F, SONG C, et al. Modelling and testing of VOC source suppression effect of building materials modified with adsorbents[J]. Building and environment, 2019, 154:122-131. ZHOU X J, GAO Z, WANG X K, et al. Mathematical model for characterizing the full process of volatile organic compound emissions from paint film coating on porous substrates[J]. Building and environment, 2020, 182:107062. XIONG J Y, CHEN F Q, SUN L H, et al. Characterization of VOC emissions from composite wood furniture:parameter determination and simplified model[J]. Building and environment, 2019, 161:106237. ZHOU X J, LIU Y F, SONG C, et al. A novel method to determine the formaldehyde emission characteristic parameters of building materials at multiple temperatures[J]. Building and environment, 2019, 149:436-445. HUANG S D, XIONG J Y, ZHANG Y P. A rapid and accurate method, ventilated chamber C-history method, of measuring the emission characteristic parameters of formaldehyde/VOCs in building materials[J]. Journal of hazardous materials, 2013, 261:542-549. CHANG J C S, KREBS K A. Evaluation of para-dichlorobenzene emissions from solid moth repellant as a source of indoor air pollution[J]. Journal of the air&waste management association, 1992, 42(9):1214-1217. CHANG J C S, GUO Z S. Characterization of organic emissions from a wood finishing product-wood stain[J]. Indoor air, 1992, 2(3):146-153. BECKETT E M, MILLER E, UNICE K, et al. Evaluation of volatile organic compound (VOC) emissions from memory foam mattresses and potential implications for consumer health risk[J]. Chemosphere, 2022, 303:134945. 李飞,陈轶丹,杨志敏,等. 8:2氟调聚醇(8:2FTOH)厌氧生物降解特性[J].中国环境科学, 2016, 36(11):3295-3303. LI F, CHEN Y D, YANG Z M, et al. Anaerobic biodegradability of 8:2 fluorotelomer alcohol (8:2 FTOH)[J]. China environmental science, 2016, 36(11):3295-3303.
GUO H, MURRAY F, LEE S C. Emissions of total volatile organic compounds from pressed wood products in an environmental chamber[J]. Building and environment, 2002, 37(11):1117-1126. ZHANG J S, SHAW C Y, KANABUS-KAMINSKA J M, et al. Study of air velocity and turbulence effects on organic compound emissions from building materials/furnishings using a new small test chamber[J]. American Society for Testing and Materials, 1996(1287):184-199. 王军,张旭.建筑室内人员污染暴露量及其特征性分析[J].环境科学与技术, 2012, 35(1):13-16. WANG J, ZHANG X. Amount of occupants'exposure to indoor pollutant and its characteristics[J]. Environmental science&technology, 2012, 35(1):13-16.
YOON H, KIM T H, LEE B C, et al. Comparison of the exposure assessment of di (2-ethylhexyl) phthalate between the PBPK model-based reverse dosimetry and scenario-based analysis:a Korean general population study[J]. Chemosphere, 2022, 294:133549. LIU Y H, JIN R, LV Q, et al. Screening and evaluation of children's sensitively toxic chemicals in new mosquito repellent products based on a nationwide investigation[J]. Environmental science&technology, 2024, 58(6):2704-2715. 国家市场监督管理总局,国家标准化管理委员会.消费品安全化学危害表征和暴露评估指南:GB/T 41007-2021[S].北京:中国标准出版社, 2021:2-5. U.S. Environmental Protection Agency. Risk assessment guidance for Superfund Volume Ⅰ:human health evaluation manual (Part F, supplemental guidance for inhalation risk assessment)[R]. Washington DC:U.S. Environmental Protection Agency, 2009:17-19. 王志娟,吕庆,王婉,等.消费品中化学物质暴露模型研究概况[J].中国口岸科学技术, 2021, 3(2):19-26. WANG Z J, LV Q, WANG W, et al. A review of researches on chemical exposure models in consumer products[J]. China port science and technology, 2021, 3(2):19-26.
U.S. Environmental Protection Agency. Risk assessment guidance for Superfund Volume Ⅰ human health evaluation manual (Part A)[R]. Washington DC:U.S. Environmental Protection Agency, 1989:43-44. 国家市场监督管理总局,国家标准化管理委员会.消费品安全化学危害风险评估通则:GB/T 41005-2021[S].北京:中国标准出版社, 2021:9-10. 杨彦,张梦迪,陈浩佳,等.中国人群暴露参数研究进展[J].环境科学研究, 2022, 35(9):2205-2215. YANG Y, ZHANG M D, CHEN H J, et al. Research progress in environmental exposure factors of Chinese population[J]. Research of environmental sciences, 2022, 35(9):2205-2215.
仇付国,高始涛,陈顷.健康风险暴露评价研究进展[J].安全与环境学报, 2012, 12(1):126-129. QIU F G, GAO S T, CHEN Q. Review on research advances in health risk exposure assessment[J]. Journal of safety and environment, 2012, 12(1):126-129.
王丽,黄德寅,刘茂,等.蒙特卡洛模拟方法在苯致癌风险评价中的应用[J].安全与环境学报, 2011, 11(5):231-235. WANG L, HUANG D Y, LIU M, et al. Application of Monte-Carlo simulation method in cancer risk assessment for benzene exposure[J]. Journal of safety and environment, 2011, 11(5):231-235.
李思航,丁洋,牛璨,等.保定市新装修室内空气污染特征及人体健康风险评价[J].环境化学, 2023, 42(5):1584-1592. LI S H, DING Y, NIU C, et al. Air pollution characteristics and human health risk assessment of newly decorated indoor in Baoding City[J]. Environmental chemistry, 2023, 42(5):1584-1592.
WU C F, TAN Y J, WEI X Y, et al. Bayesian analysis of physiologically based toxicokinetic (PBTK) modeling for pentachlorophenol exposure in pregnant women[J]. Toxicology in vitro, 2024, 99:105853. 倪雪,许宁,王强.基于贝叶斯时空模型探究中国女性肺癌发病风险及其影响因素[J].环境卫生学杂志, 2022, 12(6):407-414. NI X, XU N, WANG Q. Analysis on the incidence risk and their influence factors of female lung cancer in China based on Bayesian spatio-temporal model[J]. Journal of environmental hygiene, 2022, 12(6):407-414.
-
点击查看大图
计量
- 文章访问数: 295
- HTML全文浏览数: 295
- PDF下载数: 71
- 施引文献: 0
下载:
