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全二维气相色谱-飞行时间质谱(GC×GC/TOFMS)对比研究不同燃料油中烷烃和芳烃的图谱特征

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押淼磊, 李昱茜, 王怡程, 陈宇, 郑少艳, 李永玉, 王新红. 全二维气相色谱-飞行时间质谱(GC×GC/TOFMS)对比研究不同燃料油中烷烃和芳烃的图谱特征[J]. 环境化学, 2016, 35(5): 933-940. doi: 10.7524/j.issn.0254-6108.2016.05.2015113006
引用本文: 押淼磊, 李昱茜, 王怡程, 陈宇, 郑少艳, 李永玉, 王新红. 全二维气相色谱-飞行时间质谱(GC×GC/TOFMS)对比研究不同燃料油中烷烃和芳烃的图谱特征[J]. 环境化学, 2016, 35(5): 933-940. doi: 10.7524/j.issn.0254-6108.2016.05.2015113006
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YA Miaolei, LI Yuqian, WANG Yicheng, CHEN Yu, ZHENG Shaoyan, LI Yongyu, WANG Xinhong. Comparative research on the spectral characteristic of alkane and aromatic hydrocarbon in different fuel oil by GC×GC/TOFMS[J]. Environmental Chemistry, 2016, 35(5): 933-940. doi: 10.7524/j.issn.0254-6108.2016.05.2015113006
Citation: YA Miaolei, LI Yuqian, WANG Yicheng, CHEN Yu, ZHENG Shaoyan, LI Yongyu, WANG Xinhong. Comparative research on the spectral characteristic of alkane and aromatic hydrocarbon in different fuel oil by GC×GC/TOFMS[J]. Environmental Chemistry, 2016, 35(5): 933-940. doi: 10.7524/j.issn.0254-6108.2016.05.2015113006
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全二维气相色谱-飞行时间质谱(GC×GC/TOFMS)对比研究不同燃料油中烷烃和芳烃的图谱特征

  • 1.

    厦门大学近海海洋环境科学国家重点实验室, 厦门大学环境与生态学院环境科学与工程系, 厦门, 361005

  • 基金项目:

    国家自然科学基金(41276066),福建省科技厅对外合作项目(2016I0014)资助.

Comparative research on the spectral characteristic of alkane and aromatic hydrocarbon in different fuel oil by GC×GC/TOFMS

  • 1.

    State Key Laboratory of Marine Environmental Science, Department of Environmental Science & Engineering, College of the Environment & Ecology, Xiamen University, Xiamen, 361005, China

  • Fund Project: Supported by the National Natural Science Foundation of China (41276066), the Fujian Provincial Department of Science & Technology (2016I0014).

  • 摘要: 采用全二维气相色谱-飞行时间质谱(GC×GC-TOFMS)方法对比研究不同沸程燃料油(93号和97号汽油、0号柴油和重柴油)中烃类组分的全二维谱图特征,经过对色谱和质谱条件的优化,较好地实现了不同汽油和柴油中烷烃、规则类异戊二烯烃、十氢化萘系、四氢化萘系、萘系、菲系等族组分分离和目标化合物分离,各族化合物均呈现显著的"瓦片效应"的特征.4类燃料油的烃类碳骨架分布、正构烷烃与姥鲛烷和植烷的比值以及不同族化合物的相对丰度等存在较显著的差异.
    Abstract: Comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometry (GC×GC-TOFMS) was employed to compare and analyze the group-type separation characteristics of alkane, rule-type isoprenoids, decalin, tetralin, naphthalene and phenanthrene in 0# diesel, heavy diesel, 93# and 97# gasoline with different boiling ranges. Group composition and target compounds separation of different gasoline and diesel were achieved by optimizing the chromatographic and mass spectral conditions. There significant differences in carbon distribution of n-alkanes, (pristane) Pr/nC17 and (phytane) Ph/nC18, and relative abundance of different group-type compounds among the four fuel oils. The group-type compounds showed the obvious "tile effects".
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  • 收稿日期:  2015-11-30
  • 刊出日期:  2016-05-15

全二维气相色谱-飞行时间质谱(GC×GC/TOFMS)对比研究不同燃料油中烷烃和芳烃的图谱特征

  • 1. 厦门大学近海海洋环境科学国家重点实验室, 厦门大学环境与生态学院环境科学与工程系, 厦门, 361005
  • 收稿日期:  2015-11-30
基金项目:

国家自然科学基金(41276066),福建省科技厅对外合作项目(2016I0014)资助.

摘要: 采用全二维气相色谱-飞行时间质谱(GC×GC-TOFMS)方法对比研究不同沸程燃料油(93号和97号汽油、0号柴油和重柴油)中烃类组分的全二维谱图特征,经过对色谱和质谱条件的优化,较好地实现了不同汽油和柴油中烷烃、规则类异戊二烯烃、十氢化萘系、四氢化萘系、萘系、菲系等族组分分离和目标化合物分离,各族化合物均呈现显著的"瓦片效应"的特征.4类燃料油的烃类碳骨架分布、正构烷烃与姥鲛烷和植烷的比值以及不同族化合物的相对丰度等存在较显著的差异.

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