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全二维气相色谱-飞行时间质谱(GC×GC/TOFMS)对比研究不同燃料油中烷烃和芳烃的图谱特征

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押淼磊, 李昱茜, 王怡程, 陈宇, 郑少艳, 李永玉, 王新红. 全二维气相色谱-飞行时间质谱(GC×GC/TOFMS)对比研究不同燃料油中烷烃和芳烃的图谱特征[J]. 环境化学, 2016, 35(5): 933-940. doi: 10.7524/j.issn.0254-6108.2016.05.2015113006
引用本文: 押淼磊, 李昱茜, 王怡程, 陈宇, 郑少艳, 李永玉, 王新红. 全二维气相色谱-飞行时间质谱(GC×GC/TOFMS)对比研究不同燃料油中烷烃和芳烃的图谱特征[J]. 环境化学, 2016, 35(5): 933-940. doi: 10.7524/j.issn.0254-6108.2016.05.2015113006
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YA Miaolei, LI Yuqian, WANG Yicheng, CHEN Yu, ZHENG Shaoyan, LI Yongyu, WANG Xinhong. Comparative research on the spectral characteristic of alkane and aromatic hydrocarbon in different fuel oil by GC×GC/TOFMS[J]. Environmental Chemistry, 2016, 35(5): 933-940. doi: 10.7524/j.issn.0254-6108.2016.05.2015113006
Citation: YA Miaolei, LI Yuqian, WANG Yicheng, CHEN Yu, ZHENG Shaoyan, LI Yongyu, WANG Xinhong. Comparative research on the spectral characteristic of alkane and aromatic hydrocarbon in different fuel oil by GC×GC/TOFMS[J]. Environmental Chemistry, 2016, 35(5): 933-940. doi: 10.7524/j.issn.0254-6108.2016.05.2015113006
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全二维气相色谱-飞行时间质谱(GC×GC/TOFMS)对比研究不同燃料油中烷烃和芳烃的图谱特征

  • 1.

    厦门大学近海海洋环境科学国家重点实验室, 厦门大学环境与生态学院环境科学与工程系, 厦门, 361005

  • 基金项目:

    国家自然科学基金(41276066),福建省科技厅对外合作项目(2016I0014)资助.

Comparative research on the spectral characteristic of alkane and aromatic hydrocarbon in different fuel oil by GC×GC/TOFMS

  • 1.

    State Key Laboratory of Marine Environmental Science, Department of Environmental Science & Engineering, College of the Environment & Ecology, Xiamen University, Xiamen, 361005, China

  • Fund Project: Supported by the National Natural Science Foundation of China (41276066), the Fujian Provincial Department of Science & Technology (2016I0014).

  • 摘要: 采用全二维气相色谱-飞行时间质谱(GC×GC-TOFMS)方法对比研究不同沸程燃料油(93号和97号汽油、0号柴油和重柴油)中烃类组分的全二维谱图特征,经过对色谱和质谱条件的优化,较好地实现了不同汽油和柴油中烷烃、规则类异戊二烯烃、十氢化萘系、四氢化萘系、萘系、菲系等族组分分离和目标化合物分离,各族化合物均呈现显著的"瓦片效应"的特征.4类燃料油的烃类碳骨架分布、正构烷烃与姥鲛烷和植烷的比值以及不同族化合物的相对丰度等存在较显著的差异.
    Abstract: Comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometry (GC×GC-TOFMS) was employed to compare and analyze the group-type separation characteristics of alkane, rule-type isoprenoids, decalin, tetralin, naphthalene and phenanthrene in 0# diesel, heavy diesel, 93# and 97# gasoline with different boiling ranges. Group composition and target compounds separation of different gasoline and diesel were achieved by optimizing the chromatographic and mass spectral conditions. There significant differences in carbon distribution of n-alkanes, (pristane) Pr/nC17 and (phytane) Ph/nC18, and relative abundance of different group-type compounds among the four fuel oils. The group-type compounds showed the obvious "tile effects".
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  • [1] 许国旺,叶芬,孔宏伟,等. 全二维气相色谱技术及其进展[J]. 色谱,2001,19(2): 132-136

    XU G W,YE F,KONG W H,et al. Technique and advance of comprehensive two-dimensional gas chromatography[J]. Chinese Journal of Chromatography,2001,19(2): 132-136(in Chinese).

    [2] 潘怡,林长青. 全二维气相色谱-质谱法定性分析燃煤飞灰中的多环芳烃及其同源物[J]. 环境化学,2014,33(5): 870-871

    PANG Y,LIN C Q. Qualitative analyze polycyclic aromatic hydrocarbons and their homologs in the coal-fired fly ash using comprehensive two-dimensional gas chromatography/mass spectrometry[J]. Environmental Chemistry,2014,33(5): 870-871(in Chinese).

    [3] ZHANG W,ZHU S,ZHU S,et al.Screening of oil sources by using comprehensive two-dimensional gas chromatography/time-of-flight mass spectrometry and multivariate statistical analysis[J]. Journal of Chromatography A,2015,1380: 162-170
    [4] 花瑞香,阮春海,王京华,等. 全二维气相色谱法用于不同石油馏分的族组成分布研究[J]. 化学学报,2002,60(12): 2185-2191

    HUA R X,RUAN C H,WANG J H,et al. Research of group separation of petroleum fractions by comprehensive two-dimensional gas chromatography[J]. Acta Chimica Sinica,2002,60(12): 2185-2191(in Chinese).

    [5] ÁVILA B,AGUIAR A,GOMES A,et al. Characterization of extra heavy gas oil biomarkers using comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometry[J]. Organic Geochemistry,2010,41(9): 863-866
    [6] GAINES R,FRYSINGER G,HENDRICK-SMITH M,et al.Oil spill source identification by comprehensive two-dimensional gas chromatography[J]. Environ Sci Technol,1999,33(12): 2106-2112
    [7] VON MVHLEN C,VON MVHLEN C,ZINI C,et al.Applications of comprehensive two-dimensional gas chromatography to the characterization of petrochemical and related samples[J]. Journal of Chromatography A,2006,1105(1): 39-50
    [8] 杨永坛,王征. 全二维气相色谱分析直馏柴油中含硫化合物[J]. 分析化学,2011,38(12): 1805-1808

    YANG Y T,WANG Z. Determination of sulfur-containing compounds in straight run diesel oil by comprehensive two dimensional gas chromatography[J]. Chinese Journal of Analytical Chemistry,2011,38(12): 1805-1808(in Chinese).

    [9] 李艳艳. 全二维气相色谱用于轻质石油馏分中芳烃含量的测定[J]. 色谱,2006,24(4): 380-384

    LI Y Y. Determination of aromatics in light petroleum products by comprehensive two-dimensional gas chromatography[J]. Chinese Journal of Chromatography,2006,24(4): 380-384(in Chinese).

    [10] FRAGA C,PRAZEN B, SYNOVEC R. Comprehensive two-dimensional gas chromatography and chemometrics for the high-speed quantitative analysis of aromatic isomers in a jet fuel using the standard addition method and an objective retention time alignment algorithm[J]. Analytical chemistry,2000,72(17): 4154-4162
    [11] Phillips J and Xu J. Comprehensive multi-dimensional gas chromatography[J]. Journal of Chromatography A,1995,703(1): 327-334
    [12] AGUIAR A,SILVA A,AZEVEDO D,et al.Application of comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometry to biomarker characterization in Brazilian oils[J]. Fuel,2010,89(10): 2760-2768
    [13] 王汇彤,翁娜,张水昌,等. 全二维气相色谱/飞行时间质谱对饱和烃分析的图谱识别及特征[J]. 质谱学报,2010,31(1): 18-27

    WANG H T,WONG N,ZHANG S C,et al. Characteristics and identification of saturated hydrocarbons by comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometry[J]. Journal of Chinese Mass Spectrometry Society,2010,31(1): 18-27(in Chinese).

    [14] 王汇彤,翁娜,张水昌,等. 全二维气相色谱/飞行时间质谱对原油芳烃分析的图谱识别[J]. 科学通报,2010,55(21): 2129-2135

    WANG H T,WONG N,ZHAGN S C,et al. Identification of petroleum aromatic fraction by comprehensive two-dimensional gas chromatography with time-of flight mass spectrometer[J]. Chinese Science Bulletin,2010,55(21): 2129-2135(in Chinese).

    [15] KIKUCHI T,SUZUKI N,AND SAITO H. Change in hydrogen isotope composition of n-alkanes,pristane,phytane,and aromatic hydrocarbons in Miocene siliceous mudstones with increasing maturity[J]. Organic Geochemistry,2010,41(9): 940-946
    [16] POWELL T. Pristane/phytane ratio as environmental indicator[J]. Nature,1988,333(6174): 604
    [17] HUGHES W,HOLBA A, DZOU I. The ratios of dibenzothiophene to phenanthrene and pristane to phytane as indicators of depositional environment and lithology of petroleum source rocks[J]. Geochimica et Cosmochimica Acta,1995,59(17): 3581-3598
    [18] COLOMBO J,PELLETIER E,BROCHU C,et al.Determination of hydrocarbon sources using n-alkane and polyaromatic hydrocarbon distribution indexes. Case study: Rio de la Plata estuary,Argentina[J]. Environ Sci Technol,1989,23(7): 888-894
    [19] ROMERO-SARMIENTO M,RIBOULLEAU A,VECOLI M,et al. Occurrence of retene in upper Silurian-lower Devonian sediments from North Africa: Origin and implications[J]. Organic Geochemistry,2010,41(3): 302-306
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  • 收稿日期:  2015-11-30
  • 刊出日期:  2016-05-15

全二维气相色谱-飞行时间质谱(GC×GC/TOFMS)对比研究不同燃料油中烷烃和芳烃的图谱特征

  • 1. 厦门大学近海海洋环境科学国家重点实验室, 厦门大学环境与生态学院环境科学与工程系, 厦门, 361005
  • 收稿日期:  2015-11-30
基金项目:

国家自然科学基金(41276066),福建省科技厅对外合作项目(2016I0014)资助.

摘要: 采用全二维气相色谱-飞行时间质谱(GC×GC-TOFMS)方法对比研究不同沸程燃料油(93号和97号汽油、0号柴油和重柴油)中烃类组分的全二维谱图特征,经过对色谱和质谱条件的优化,较好地实现了不同汽油和柴油中烷烃、规则类异戊二烯烃、十氢化萘系、四氢化萘系、萘系、菲系等族组分分离和目标化合物分离,各族化合物均呈现显著的"瓦片效应"的特征.4类燃料油的烃类碳骨架分布、正构烷烃与姥鲛烷和植烷的比值以及不同族化合物的相对丰度等存在较显著的差异.

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