北京市部分地区降雪中溶解性有机物的光谱性能表征
Spectroscopic characterization of dissolved organic matter in snow samples from some typical regions of Beijing
-
摘要: 为了解降雪中溶解性有机物（DOM）的特征，采集了北京市不同地区两场降雪，对降雪样品中的DOM进行了紫外-可见光谱、三维荧光光谱、同步荧光光谱表征.结果表明，不同区域降雪中溶解性有机碳（DOC）浓度变化规律不同，这可能与降雪所在区域的下垫面性质不同有关；降雪样品中DOM的芳香性和分子量较低，含有类色氨酸、类富里酸和类蛋白质类物质，腐殖化程度较低，受生物过程影响较大；同步荧光光谱表明，DOM为类蛋白类物质和芳香性化合物，其中存在苯环和具有共轭系统的多环芳烃，含有少量胡敏酸类物质.研究降雪中DOM光谱性质将有助于进一步研究DOM与共存污染物之间的相互作用，为有效利用降雪提供基础性数据.Abstract: To investigate the characteristics of dissolved organic matter (DOM) in snow, snow samples collected during two snow eventy at typical sites in different districts of Beijing were characterized by UV-vis spectroscopy, three-dimensional fluorescence spectroscopy and synchronous fluorescence spectroscopy. The results revealed that the concentrations of dissolved organic carbon (DOC) at different sites varied widely, which might be attributed to the different nature of underlying surface materials. DOM in snow samples was composed of organic compounds with lower molecular weight and less aromatic structures, which can be possibly attributed to small amount of fulvic acid produced by biological activity. The information obtained from synchronous fluorescence spectra showed that some protein material and aromatic compounds were also found in the DOM. The investigation of spectroscopic properties can facilitate further insight into the interaction between DOM and co-existing pollutants, and also can provide basic information on the efficient utilizations of snow.
-
-
[1] SANTOS P S, SANTOS E B, DUARTE A C. First spectroscopic study on the structural features of dissolved organic matter isolated from rainwater in different seasons[J]. Science of the Total Environment, 2012,426:172-179. [2] HOWE K J, CLARK M M. Fouling of microfiltration and ultrafiltration membranes by natural waters[J]. Environmental Science & Technology, 2002,36(16):3571-3576. [3] BENNER R, PAKULSKI J, MCCARTHY M. Chemical characteristics of dissolved organic matter in the ocean[J]. Science, 1998,255(5051):1561-1564. [4] QUALLS R G, HAINES B L. Geochemistry of dissolved organic nutrients in water percolating through a forest ecosystem[J]. Soil Science Society of America Journal, 1991,55(4):1112-1123. [5] THURMAN E M. Organic geochemistry of natural waters[M]. Springer Science & Business Media, 2012. [6] KAISER K, ZECH W. Rates of dissolved organic matter release and sorption in forest soils[J]. Soil Science,1998,163(9):714-725. [7] YAMASHITA Y, JAFFÉ R. Characterizing the interactions between trace metals and dissolved organic matter using excitation-emission matrix and parallel factor analysis[J]. Environmental Science & Technology, 2008,42(19):7374-7379. [8] KUITERS A, MULDER W. Water-soluble organic matter in forest soils[J]. Plant and Soil, 1993,152(2):225-235. [9] WANG M, LIU C P, SHEU B H. Characterization of organic matter in rainfall, throughfall, stemflow, and streamwater from three subtropical forest ecosystems[J]. Journal of Hydrology, 2004,289(1):275-285. [10] DECESARI S, FACCHINI M, FUZZI S, et al. The water-soluble organic component of size-segregated aerosol, cloud water and wet depositions from Jeju Island during ACE-Asia[J]. Atmospheric Environment, 2005,39(2):211-222. [11] KIEBER R J, WHITEHEAD R F, REID S N, et al. Chromophoric dissolved organic matter (CDOM) in rainwater, southeastern North Carolina, USA[J]. Journal of Atmospheric Chemistry, 2006,54(1):21-41. [12] MILLER C, GORDON K G, KIEBER R J, et al. Chemical characteristics of chromophoric dissolved organic matter in rainwater[J]. Atmospheric Environment, 2009,43(15):2497-2502. [13] SANTOS P S, OTERO M, DUARTE R M, et al. Spectroscopic characterization of dissolved organic matter isolated from rainwater[J]. Chemosphere, 2009,74(8):1053-1061. [14] MULLER C L, BAKER A, HUTCHINSON R, et al. Analysis of rainwater dissolved organic carbon compounds using fluorescence spectrophotometry[J]. Atmospheric Environment, 2008,42(34):8036-8045. [15] KIEBER R, SKRABAL S, SMITH B, et al. Organic complexation of Fe (Ⅱ) and its impact on the redox cycling of iron in rain[J]. Environmental Science & Technology, 2005,39(6):1576-1583. [16] SEATON P J, KIEBER R J, WILLEY J D, et al. Seasonal and temporal characterization of dissolved organic matter in rainwater by proton nuclear magnetic resonance spectroscopy[J]. Atmospheric Environment, 2013,65:52-60. [17] ZHAO C, WANG C C, LI J Q, et al. Dissolved organic matter in urban stormwater runoff at three typical regions in Beijing:chemical composition, structural characterization and source identification[J]. RSC Advances, 2015,5(90):73490-73500. [18] STEDMON C A, BRO R. Characterizing dissolved organic matter fluorescence with parallel factor analysis:a tutorial[J]. Limnology and Oceanography:Methods, 2008,6(11):572-579. [19] LEENHEER J A, CROUÉ J P. Peer reviewed:Characterizing aquatic dissolved organic matter[J]. Environmental Science & Technology, 2003,37(1):18A-26A. [20] 赵劲松, 张旭东. 土壤溶解性有机质的特性与环境意义[J]. 应用生态学报, 2003,14(1):126-130. ZHAO J S, ZHANG X D. Characteristics and environmental significance of soil dissolved organic matter[J]. Chinese Journal of Applied Ecology, 2003, 14(1):126-130(in Chinese).
[21] COOK B D, ALLAN D L. Dissolved organic carbon in old field soils:Compositional changes during the biodegradation of soil organic matter[J]. Soil Biology and Biochemistry, 1992,24(6):595-600. [22] DOMINÉ F, SHEPSON P B. Air-snow interactions and atmospheric chemistry[J]. Science, 2002, 297(5586):1506-1510. [23] 贺润升, 徐荣华, 韦朝海. 焦化废水生物出水溶解性有机物特性光谱表征[J]. 环境化学, 2015, 34(1):129-136. HE R S,XU R H,WEI C H. Spectral characterization of dissolved organic matter in bio-treated effluent of coking wastewater[J]. Environmental Chemistry, 2015,34(1):129-136(in Chinese).
[24] SALVE P, LOHKARE H, GOBRE T, et al. Characterization of chromophoric dissolved organic matter (CDOM) in rainwater using fluorescence spectrophotometry[J]. Bulletin of Environmental Contamination and Toxicology, 2012,88(2):215-218. [25] DEL VECCHIO R, BLOUGH N V. Spatial and seasonal distribution of chromophoric dissolved organic matter and dissolved organic carbon in the Middle Atlantic Bight[J]. Marine Chemistry, 2004,89(1):169-187. [26] DUARTE R M, DURATE A C. Application of non-ionic solid sorbents (XAD resins) for the isolation and fractionation of water-soluble organic compounds from atmospheric aerosols[J]. Journal of Atmospheric Chemistry, 2005,51(1):79-93. [27] SENESI N, MIANO T, PROVENZANO M, et al. Spectroscopic and compositional comparative characterization of IHSS reference and standard fulvic and humic acids of various origin[J]. Science of the Total Environment, 1989,81:143-156. [28] SANTOS P S, DUARTE R M, DUARTE A C. Absorption and fluorescence properties of rainwater during the cold season at a town in Western Portugal[J]. Journal of Atmospheric Chemistry, 2009,62(1):45-57. [29] PEURAVUORI J, PIHLAJA K. Molecular size distribution and spectroscopic properties of aquatic humic substances[J]. Analytica Chimica Acta, 1997,337(2):133-149. [30] HU Z, SHI Y, NIU H, et al. Synthetic musk fragrances and heavy metals in snow samples of Beijing urban area, China[J]. Atmospheric Research, 2012, 104:302-305. [31] HELMS J R, STUBBINS A, RITCHIE J D, et al. Absorption spectral slopes and slope ratios as indicators of molecular weight, source, and photobleaching of chromophoric dissolved organic matter[J]. Limnology and Oceanography, 2008,53(3):955-969. [32] WEISHAAR JL, AIKEN GR, BERGAMASCHI B A, et al. Evaluation of specific ultraviolet absorbance as an indicator of the chemical composition and reactivity of dissolved organic carbon[J]. Environmental Science & Technology, 2003,37(20):4702-4708. [33] QUARANTA M L, MENDES M D, MACKAY A A. Similarities in effluent organic matter characteristics from Connecticut wastewater treatment plants[J]. Water Research, 2012,46(2):284-294. [34] MCELMURRY S P, LONG D T, VOICE T C. Stormwater dissolved organic matter:Influence of land cover and environmental factors[J]. Environmental Science & Technology, 2013,48(1):45-53. [35] CHIN Y P, AIKEN G, O'LOUGHLIN E. Molecular weight, polydispersity, and spectroscopic properties of aquatic humic substances[J]. Environmental Science & Technology, 1994,28(11):1853-1858. [36] ZHAO C, WANG C C, LI J Q, et al. Chemical characteristics of chromophoric dissolved organic matter in stormwater runoff of a typical residential area, Beijing[J]. Desalination and Water Treatment, 2015:DOI:10.1080/19443994 [37] MATTSSON T, KORTELAINEN P, RAIKE A. Export of DOM from boreal catchments:Impacts of land use cover and climate[J]. Biogeochemistry, 2005,76(2):373-394. [38] 朱大伟, 武道吉, 孙翠珍, 等.三维荧光光谱(3DEEM)技术在溶解性有机质(DOM)分析中的应用[J]. 净水技术, 2015,34(1):14-17. ZHU D W,WU D J,SUN C Z,et al. Application of Three-dimensional excitation-emission matrix(3D-EEM) fluorescence spectrum technology in analysis of dissolved organic matter(DOM)[J]. Water Purification Technology, 2015, 34(1):14-17(in Chinese).
[39] STEDMON C A, MARKAGER S. Resolving the variability in dissolved organic matter fluorescence in a temperate estuary and its catchment using PARAFAC analysis[J]. Limnology and Oceanography, 2005,50(2):686-697. [40] 傅平青, 刘丛强, 吴丰昌. 溶解有机质的三维荧光光谱特征研究[J]. 光谱学与光谱分析, 2006,25(12):2024-2028. FU P Q, LIU C Q, WU F C. Dissolved organic matter in the three dimensional fluorescence spectrum characteristic research[J]. Spectroscopy and Spectral Analysis, 2005, 25(12):2024-2028(in Chinese).
[41] MURPHY K R, RUIZ G M, DUNSMUIR W T, et al. Optimized parameters for fluorescence-based verification of ballast water exchange by ships[J]. Environmental Science & Technology, 2006,40(7):2357-2362. [42] MCKNIGHT D M, BOYER E W, WESTERHOFF P K, et al. Spectrofluorometric characterization of dissolved organic matter for indication of precursor organic material and aromaticity[J]. Limnology and Oceanography, 2001,46(1):38-48. [43] 程远月, 郭卫东, 胡明辉. 近岸沉积物再悬浮期间所释放溶解有机物的荧光特征[J]. 地球化学, 2008,37(1):51-58. CHENG Y Y,GUO W D,HU M H. Fluorescence characteristics of dissolved organic matter released from estuarine sediments during resuspension[J]. Geochimica, 2008, 37(1):51-58(in Chinese).
[44] HUGUET A, VACHER L, RELEXANS S, et al. Properties of fluorescent dissolved organic matter in the Gironde Estuary[J]. Organic Geochemistry, 2009,40(6):706-719. [45] 肖隆庚, 陈文松, 陈国丰, 等. 中国南海CDOM三维荧光光谱特征研究[J]. 环境科学学报, 2014,34(1):160-167. XIAO L G,CHEN W S,CHEN G F,et al. Fluorescence excitation-emission matrix spectroscopy of chromophoric dissolved organic matter in the South China Sea[J]. Acta Scientiae Circumstantiae, 2014,34(1):160-167(in Chinese).
[46] SENESI N. Molecular and quantitative aspects of the chemistry of fulvic acid and its interactions with metal ions and organic chemicals:Part Ⅱ. The fluorescence spectroscopy approach[J]. Analytica Chimica Acta, 1990,232:77-106. [47] DOS SANTOS L M, SIMOES M L, DE MELO W J, et al. Application of chemometric methods in the evaluation of chemical and spectroscopic data on organic matter from Oxisols in sewage sludge applications[J]. Geoderma, 2010,155(1):121-127. [48] PEURAVUORI J, PIHLAJA K. Isolation and characterization of natural organic matter from lake water:Comparison of isolation with solid adsorption and tangential membrane filtration[J]. Environment International, 1997,23(4):441-451. [49] PAASO N, PEURAVUORI J, LEHTOMEN T, et al. Sediment-dissolved organic matter equilibrium partitioning of pentachlorophenol:The role of humic matter[J]. Environment International, 2002,28(3):173-183. [50] KALBITZ K, GEYER W, GEYER S. Spectroscopic properties of dissolved humic substances:A reflection of land use history in a fen area[J]. Biogeochemistry, 1999, 47(2):219-238. -
点击查看大图
计量
- 文章访问数: 970
- HTML全文浏览数: 910
- PDF下载数: 369
- 施引文献: 0
下载:
