我国省会城市土壤重金属含量分布与健康风险评价
Spatial distribution and health risk assessment of heavy metals in provincial capital cities, China
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摘要: 收集了我国31个省会城市城区表层土壤重金属数据,探讨了我国省会城市土壤重金属含量分布特征和健康风险. 结果表明,我国省会城市重金属Cd、Pb、Cr、Ni、Cu、Zn、Hg和As平均含量分别为0.43、44.75、66.85、32.48、39.59、116.15、0.21、12.44 mg·kg-1.土壤重金属具有4种分布类型,大部分重金属(Cd、Pb、Ni、Cu和Zn)含量较高城市分布在西南和南方沿海及东北长春等区域. 健康风险评价表明,所有省会城市土壤重金属对儿童和成年人的非致癌风险是可以忽略的;除南宁外经口摄入As对儿童为不可接受风险外(>10-4),其余经口摄入致癌风险对儿童和成年人均介于可以接受范围内(10-6-10-4).Abstract: Heay metal concentrations in the urban soils of 31 provincial capital cities in China were collected based on the published papers to explore patterns of spatial distribution and evaluate human health risks. The results demonstrated that the average metal concentrations were 0.43 (Cd), 44.75 (Pb), 66.85 (Cr), 32.48 (Ni), 39.59 (Cu), 116.15 (Zn), 0.21 (Hg), 12.44 (As) mg·kg-1. Four patterns of spatial distribution were found, and the cities with relatively high concentrations of metals (Cd, Pb, Ni, Cu, and Zn) were distributed in the southwestern and southern coastal regions as well as Changchun region in northeastern China. Hazard Quotient value for each metal and Hazard Index values for all the metals indicated no significant risk of non-carcinogenic effects to children and adults in urban soils of 31 provincial capital cities in China. The probabilities of As posing carcinogenic risks to children were not accpetable in Nanning (>10-4), but were accpetable (10-6-10-4) to children and adults in the other cities.
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Key words:
- urban soil /
- heavy metals /
- spatial distribution /
- health risk
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[1] GU Y G, LIN Q, GAO Y P. Metals in exposed-lawn soils from 18 urban parks and its human health implications in southern China's largest city, Guangzhou[J]. Journal of Cleaner Production, 2016, 115:122-129. [2] 郭伟, 孙文惠, 赵仁鑫, 等. 呼和浩特市不同功能区土壤重金属污染特征及评价[J]. 环境化学, 2013, 34(4):1561-1567. GUO W, SUN W H, ZHAO R X, et al. Characteristic and evaluation of soil pollution by heavy metal in different functional zones of Hohhot[J]. Environmental Chemistry, 2013, 34(4):1561-1567(in Chinese).
[3] LUO X S, YU S, ZHU Y G, et al. Trace metal contamination in urban soils of China[J]. Science of the Total Environment, 2012, 421-422:17-30. [4] CHEN H Y, TENG Y G, LU S J, et al. Contamination features and health risk of soil heavy metals in China[J]. Science of The Total Environment, 2015, 512-513:143-153. [5] 王莹, 陈玉成, 李章平. 我国城市土壤重金属的污染格局分析[J]. 环境化学, 2012, 31(6):763-770. WANG Y, Chen Y C, LI Z P. Contamination pattern of heavy metals in Chinese urban soils[J]. Environmental Chemistry, 2012, 31(6):763-770(in Chinese).
[6] HAO L B, TIAN M, ZHAO X Y, et al. Spatial distribution and sources of trace elements in surface soils, Changchun, China:Insights from stochastic models and geostatistical analyses[J]. Geoderma, 2016, 273:54-63. [7] WEI B G, YANG L S. A review of heavy metal contaminations in urban soils, urban road dusts and agricultural soils from China[J]. Microchemical Journal, 2010, 94(2):99-107. [8] 和莉莉, 李冬梅, 吴钢. 我国城市土壤重金属污染研究现状和展望[J]. 土壤通报, 2008, 39(5):1210-1216. HE L L, LI D M, WU G. Heavy metal contamination of urban soils in China:State and prospect[J]. Chinese Journal of Soil Science, 2008, 39(5):1210-1216(in Chinese).
[9] GU Y G, GAO Y P, QIN L. Contamination, bioaccessibility and human health risk of heavy metals in exposed-lawn soils from 28 urban parks in southern China's largest city, Guangzhou[J]. Applied Geochemistry, 2016, 67:52-58. [10] CHENG H X, LI M, ZHAO C D, et al. Overview of trace metals in the urban soil of 31 metropolises in China[J]. Journal of Geochemical Exploration, 2014, 139:31-52. [11] CHEN H Y, TENG Y G, LU S J, et al. Source apportionment and health risk assessment of trace metals in surface soils of Beijing metropolitan, China[J]. Chemosphere, 2016, 144:1002-1011. [12] 何玉生. 海口城市土壤重金属污染特征与生态风险评估[J]. 生态学杂志, 2014, 33(2):421-428. HE Y S. Pollution characteristics and ecological risk assessment of heavy metals in Haikou urban soils[J]. Chinese Journal of Ecology, 2014, 33(2):421-428(in Chinese).
[13] 孟紫强. 环境毒理学[M]. 中国环境科学出版社, 2000. MENG Z Q. Environmental Toxicology[M]. China Environmental Science Press, 2000(in Chinese). [14] GRANERO S, DOMINGO J L. Levels of metals in soils of Alcalá de Henares, Spain:Human health risks[J]. Environment International, 2002, 28(3):159-164. [15] XIA X H, CHEN X, LIU R M, et al. Heavy metals in urban soils with various types of land use in Beijing, China[J]. Journal of Hazardous Materials, 2011, 186(2-3):2043-2050. [16] GUO P, XIE Z L, LI J, et al. Relationships between fractionations of Pb, Cd, Cu, Zn and Ni and Soil properties in urban soils of Changchun, China[J]. Chinese Geographical Science, 2005, 15(2):179-185. [17] 杨忠平, 卢文喜, 刘新荣, 等. 长春市城区表层土壤重金属污染来源解析[J]. 城市环境与城市生态, 2009, 22(5):29-33. YANG Z P, LU W X, LIU X R, et al. Sources identification of heavy metals in urban soil of Changchun base on principal component analysis[J]. Urban Environment & Urban Ecology, 2009, 22(5):29-33(in Chinese).
[18] 周涛, 息朝庄, 戴塔根, 等. 湖南长沙城市土壤地质环境综合评价[J]. 广东微量元素科学, 2008, 15(6):32-38. ZHOU T, XI Z Z, DAI T G, et al. Comprehensive assessmentof urban geological environment in ChangshaCity[J]. Guangdong Trace Elements Science, 2008, 15(6):32-38(in Chinese).
[19] 龙永珍, 戴塔根, 邹海洋. 长沙、株洲、湘潭地区土壤重金属污染现状及评价[J]. 地球与环境, 2008, 36(3):231-236. LONG Y Z, DAI T G, ZOU H Y. The status quo and evaluation of heavy metal pollution of soils in the Changsha, Zhuzhou and Xiangtan areas[J]. Earth and Environment, 2008, 36(3):231-236(in Chinese).
[20] YANG Z P, LU W X, LONG Y Q, et al. Assessment of heavy metals contamination in urban topsoil from Changchun City, China[J]. Journal of Geochemical Exploration, 2011, 108(1):27-38. [21] 李章平, 陈玉成, 杨学春, 等. 重庆市主城区土壤重金属的潜在生态危害评价[J]. 西南农业大学学报, 2006, 28(2):227-230. LI Z P, CHEN Y C, YANG X C, et al. Assessment of potential ecological hazard of heavy metals in urban soils in Chongqing City[J]. Jounal of Southwest Agriculture University (Natural Science), 2006, 28(2):227-230(in Chinese).
[22] 陈华英. 福州城市土壤中铜等13种元素的分布特征[J]. 福建地质, 2008, 27(2):211-218. CHEN H Y. The distributional characteristics of Cu and else 13 kinds of elements in city soil of Fuzhou[J]. Geology of Fujian, 2008, 27(2):211-218(in Chinese).
[23] CAI Q Y, MO C H, LI H Q, et al. Heavy metal contamination of urban soils and dusts in Guangzhou, South China[J]. Environmental Monitoring and Assessment, 2013, 185(2):1095-1106. [24] 尹伟, 卢瑛, 李军辉, 等. 广州城市土壤汞的分布特征及污染评价[J]. 土壤通报, 2009, 40(5):1185-1188. YIN W, LU Y, LI J H, et al. Distribution characteristics and pollution assessment of mercury in urban soils of Guangzhou[J]. Chinese Journal of Soil Science, 2009, 40(5):1185-1188(in Chinese).
[25] 卢瑛, 尹伟, 张波, 等. 广州市土壤砷的含量及其污染评价[J]. 安全与环境学报, 2010, 10(1):110-113. LU Y, YIN W, ZHANG B, et al. Concentration of As in the urban soil in Guangzhou and its contamination assessment[J]. Journal of Safety and Environment, 2010, 10(1):110-113(in Chinese).
[26] LU Y, ZHU F, CHEN J, et al. Chemical fractionation of heavy metals in urban soils of Guangzhou, China[J]. Environmental Monitoring and Assessment, 2007, 134(1):429-439. [27] 王济. 贵阳市表层土壤重金属污染元素环境地球化学基线研究[D]. 贵阳:中国科学院地球化学研究所, 2004. WANG J. Study of environmental geochemical baseline of pollutional heavy metals in surficial soil of Guiyang, Guizhou[D]. Guiyang:Institute of Geochemistry, Chinese Academy of Sciences, 2004(in Chinese). [28] LI X Y, CAO Y J, QI L, et al. The distribution characteristics of heavy metals in Guiyang urban soils[J]. Chinese Journal of Geochemistry, 2012, 31(2):174-180. [29] 张久明, 迟凤琴, 宿庆瑞, 等. 哈尔滨市城市土壤重金属空间分布特征及相关分析[J]. 东北农业大学学报, 2010, 41(7):56-61. ZHANG J M, CHI F Q, SU Q R, et al. Study on spatial variability of soil heavy metal in Harbin building area[J]. Journal of Northeast Agricultural University, 2010, 41(7):56-61(in Chinese).
[30] 余世清, 杨强. 杭州城市土壤重金属污染研究进展及展望[J]. 环境科学与管理, 2011, 36(4):44-49. YU S Q, YANG Q. Heavy metal contamination of urban soils in Hangzhou:Research and prospect[J]. Environmental Science and Management, 2011, 36(4):44-49(in Chinese).
[31] 李增福, 朱继业, 王腊春. 合肥市城市土壤重金属元素含量及空间分布特征[J]. 城市环境与城市生态, 2009, 22(3):24-27. LI Z F, ZHU J Y, WANG L C. Heavy metal contents and their spatial distribution in urban soil of Hefei City[J]. Urban Environment & Urban Ecology, 2009, 22(3):24-27(in Chinese).
[32] 代杰瑞, 祝德成, 庞绪贵, et al. 济南市土壤元素地球化学特征及环境质量[J]. 中国地质, 2015, 42(1):308-316. DAI R J, ZHU D C, PANG X G, et al. Geochemical characteristics and environmental quality of soil elements in Jinan City[J]. Geology in China, 2015, 42(1):308-316(in Chinese).
[33] 缪瑞琪, 燕永锋, 白燕, 等. 昆明市土壤重金属污染评价[J]. 地球与环境, 2015, 43(5):536-539. MIU R Q, YAN Y F, BAI Y, et al. Assessment of heavy metal contamination of soil in Kunming city, China[J]. Earth and Environment, 2015, 43(5):536-539(in Chinese).
[34] WANG B, XIA D S, YU Y, et al. Magnetic records of heavy metal pollution in urban topsoil in Lanzhou, China[J]. Chinese Science Bulletin, 2013, 58(3):384-395. [35] 黄顺生, 吴新民, 颜朝阳, 等. 南京城市土壤重金属含量及空间分布特征[J]. 城市环境与城市生态, 2007, 20(2):1-4. HUANG S S, WU X M, YAN C Y, et al. Heavy metal concentrations and their spatial distribution in urban soils of Nanjing[J]. Urban Environment & Urban Ecology, 2007, 20(2):1-4(in Chinese).
[36] 刘宝庆. 南宁市城区土壤重金属污染状况研究[D]. 南宁:广西大学, 2004. LIU B Q. Present situation and evaluatin of heavy metal pollution in the soils of Nanning City[D]. Nanning:Guangxi University, 2004(in Chinese). [37] SHI G T, CHEN Z L, XU S Y, et al. Potentially toxic metal contamination of urban soils and roadside dust in Shanghai, China[J]. Environmental Pollution, 2008, 156(2):251-260. [38] JIAO X D, TENG Y G, WU J, et al. Soil heavy metal pollution and risk assessment in Shenyang industrial district, Northeast China[J]. PLoS ONE, 2015, 10(5):e0127736. [39] LI X Y, LIU L J, WANG Y G, et al. Heavy metal contamination of urban soil in an old industrial city (Shenyang) in Northeast China[J]. Geoderma, 2013, 192:50-58. [40] 崔邢涛, 栾文楼, 郭海全, 等. 石家庄城市土壤重金属污染及潜在生态危害评价[J]. 现代地质, 2011, 25(1):169-175. CU X T, LUAN W L, GUO H Q, et al. Assessment of the heavymetal pollution and the potential ecological hazard in urban soil of Shijiazhuang City[J]. Geoscience, 2011, 25(1):169-175(in Chinese).
[41] 刘勇, 岳玲玲, 李晋昌. 太原市土壤重金属污染及其潜在生态风险评价[J]. 环境科学学报, 2011, 31(6):1285-1293. LIU Y, YUE L L, LI J C. Evaluation of heavy metal contamination and its potential ecological risk to the soil in Taiyuan, China[J]. Acta Scientiae Circumstantiae, 2011, 31(6):1285-1293(in Chinese).
[42] ZHAO L, XU Y F, HOU H, et al. Source identification and health risk assessment of metals in urban soils around the Tanggu chemical industrial district, Tianjin, China[J]. Science of the Total Environment, 2014, 468-469:654-662. [43] 黄敏, 杨海舟, 余萃, 等. 武汉市土壤重金属积累特征及其污染评价[J]. 水土保持学报, 2010, 24(4):135-139. HUANG M, YANG H Z, YU C, et al. Accumulation characteristics and pollution evaluation of heavy metals in soils of Wuhan City[J]. Journal of Soil and Water Conservation, 2010, 24(4):135-139.
[44] ZHANG C T, YANG Y, LI W D, et al. Spatial distribution and ecological risk assessment of trace metals in urban soils in Wuhan, central China[J]. Environmental Monitoring and Assessment, 2015, 187(9):1-16. [45] 闫旭. 西安市大气、土壤、降水中重金属的污染特征研究[D]. 西安:西安建筑科技大学, 2013. YAN X. Pollution characterization of heavy metals in air, soil and precipitation in Xi'an[D]. Xi'an:Xi'an University of Architecture and Technology, 2013(in Chinese). [46] 王幼奇, 白一茹, 王建宇. 基于GIS的银川市不同功能区土壤重金属污染评价及分布特征[J]. 环境科学, 2016, 37(2):710-716. WANG Y Q, BAI Y R, WANG J Y. Distribution of urban soil heavy metal and pollution evaluation in different functional zones of Yinchuan City[J]. Environmental Sciene, 2016, 37(2):710-716(in Chinese).
[47] 余广学, 张金震, 王烨, 等. 郑州市土壤重金属污染状况和质量评价[J]. 岩矿测试, 2015, 34(3):340-345. YU G X, ZHANG J Z, WANG Y, et al. Investigation and evaluation of heavy metal pollution in soil from Zhengzhou City[J]. Rock and Mineral Aanlysis, 2015, 34(3):340-345(in Chinese).
[48] US EPA (US Environmental Protection Agency). Risk Assessment Guidance for Superfund Volume I:Human Health Evaluation Manual[S].//Office of Solid Waste and Emergency Response, Washington. 1989. [49] US EPA (US Environmental Protection Agency). Soil Screening Guidance:Technical Background Document (EPA/540/R-95/128)[S].//Office of Solid Waste and Emergency Response, Washington. 1996. [50] 中华人民共和国环保部. 污染场地风险评估技术导则(HJ 25.3-2014)[S]. 北京:中国环境科学出版社. 2014. [51] US DOE(United States Department of Energy). The Risk Assessment Information System (RAIS)[M].//U.S. Department of Energy's Oak Ridge Operations Office (ORO). 2011. [52] US DE (US Department of Energy). RAIS:Risk Assessment Information System[S].//US Department of Energy, Office of Environmental Management. 2000. [53] FERREIRA-BAPTISTA L, MIGUEL E D. Geochemistry and risk assessment of street dust in Luanda, Angola:A tropical urban environment[J]. Atmospheric Environment, 2005, 39(25):4501-4512. [54] 陈星, 马建华, 李新宁, 等. 基于棕地的居民小区土壤重金属健康风险评价[J]. 环境科学, 2014, 35(3):1068-1074. CHEN X, MA J H, LI X N, et al. Health risk assessment of soil heavy metals in residential communities built on brownfields[J]. Environmental Science, 2014, 35(3):1068-1074(in Chinese).
[55] [56] SUN Y B, ZHOU Q X, XIE X K, et al. Spatial, sources and risk assessment of heavy metal contamination of urban soils in typical regions of Shenyang, China[J]. Journal of Hazardous Materials, 2010, 174(1-3):455-462. [57] NIU L L, YANG F X, XU C, et al. Status of metal accumulation in farmland soils across China:From distribution to risk assessment[J]. Environmental Pollution, 2013, 176:55-62. [58] GU Y G, LI Q S, FANG J H, et al. Identification of heavy metal sources in the reclaimed farmland soils of the Pearl River Estuary in China using a multivariate geostatistical approach[J]. Ecotoxicology and Environmental Safety, 2014, 105:7-12. [59] 谢小进. 上海地区土壤重金属空间分布特征及其成因分析[D]. 上海:上海师范大学, 2010. XIE X J. Spatial distribution and sources of heavy metals in soils of Shanghai city[D]. Shanghai:Shanghai Normal University, 2010(in Chinese). [60] FRYER M, COLLINS C D, FERRIER H, et al. Human exposure modelling for chemical risk assessment:A review of current approaches and research and policy implications[J]. Environmental Science & Policy, 2006, 9(3):261-274. -

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