高级搜索

永定河上覆水、间隙水和沉积物中重金属的分布特征

,  ,  ,  ,  , 

downloadPDF

上一篇

下一篇

时春景, 李红霞, 张言, 徐翔宇, 冯金国, 季宏兵. 永定河上覆水、间隙水和沉积物中重金属的分布特征[J]. 环境化学, 2017, 36(1): 48-61. doi: 10.7524/j.issn.0254-6108.2017.01.2016061401
引用本文: 时春景, 李红霞, 张言, 徐翔宇, 冯金国, 季宏兵. 永定河上覆水、间隙水和沉积物中重金属的分布特征[J]. 环境化学, 2017, 36(1): 48-61. doi: 10.7524/j.issn.0254-6108.2017.01.2016061401
shu
SHI Chunjing, LI Hongxia, ZHANG Yan, XU Xiangyu, FENG Jinguo, JI Hongbing. Distribution characteristics of heavy metals in overlying water-pore water-sediment in the Yongding River[J]. Environmental Chemistry, 2017, 36(1): 48-61. doi: 10.7524/j.issn.0254-6108.2017.01.2016061401
Citation: SHI Chunjing, LI Hongxia, ZHANG Yan, XU Xiangyu, FENG Jinguo, JI Hongbing. Distribution characteristics of heavy metals in overlying water-pore water-sediment in the Yongding River[J]. Environmental Chemistry, 2017, 36(1): 48-61. doi: 10.7524/j.issn.0254-6108.2017.01.2016061401
shu

永定河上覆水、间隙水和沉积物中重金属的分布特征

  • 1.

    北京科技大学能源与环境工程学院, 北京, 100083;

  • 2.

    北京市地质工程设计研究院, 北京, 101500

  • 基金项目:

    国家自然科学基金（41173113）和中国科学院百人计划项目资助.

Distribution characteristics of heavy metals in overlying water-pore water-sediment in the Yongding River

  • 1.

    Energy & Environment Engineering School, University of Science & Technology Beijing, Beijing, 100083, China;

  • 2.

    Beijing Geological Engineering Design and Research Institute, Beijing, 101500, China

  • Fund Project: Supported by the National Natural Science Foundation of China (41173113) and the 100 Talents Program of the Chinese Academy of Sciences.

  • 摘要: 采集了永定河及其支流清水河水样和表层沉积物各11个，并通过高速离心获得间隙水样10个.利用ICP-MS检测了上覆水中可溶性重金属（Cd、Cr、Cu、Hg、Mn、Ni、Pb、Zn）、间隙水中可溶性重金属（Cd、Cr、Cu、Mn、Ni、Pb、Zn）的含量以及沉积物中重金属（Cd、Cr、Cu、Hg、Mn、Ni、Pb、Zn）的总量；检测了样品的理化性质；分析了水体及沉积物间重金属的分配系数.结果表明，上游采样点水化学类型主要为Ca2+-Mg2+-HCO3--SO42-，而下游采样点水化学类型则主要为Na+-Mg2+-Cl--SO42-，上游和下游的水化学类型呈现明显的差异性；上覆水中Mn在位于下游的7号采样点含量超出生活饮用水卫生标准；间隙水中的重金属普遍高于上覆水含量；采用间隙水标准毒性单位（IWCTU）对间隙水重金属进行评价，发现Zn在大部分采样点（除2、5、11）及Pb在采样点6、7、8存在一定程度的毒性风险；Cd、Pb、Ni等3种重金属在附近有煤矿分布的采样点的上覆水和沉积物中含量都较高，需要特别注意的是Hg的分布也可能与煤矿开采有关.Pb、Cr、Mn等3种重金属在沉积物与上覆水中的分配系数比较大，而Hg、Cd、Zn则分配系数比较小；重金属在上覆水间隙水及沉积物中的分布关系为沉积物 > 间隙水 > 上覆水；分别对上覆水间隙水和沉积物中的重金属进行相关性分析及沉积物的主成分分析，发现Cd和Pb在间隙水和沉积物中均存在显著的相关性，沉积物中的Cd、Pb、Ni、Hg、Cu、Cr在第一主成分中具有较高的载荷值，推断这几种重金属具有相同的来源.
    Abstract: Eleven samples of water and surface sediment were collected in the Yongding River, with ten pore water samples obtained by high-speed centrifugation of the surface sediments. The dissolved heavy metals (Cd, Cr, Cu, Hg, Mn, Ni, Pb and Zn) in these samples were analyzed by Inductively Coupled Plasma-Mass Spectrometry, and relevant physicochemical properties were also determined. The partition coefficients of heavy metals between water and surface sediment were calculated. The results showed that the main hydrochemical type of the upstream part of the river in this research area was Ca2+-Mg2+-HCO3--SO42-, while that of the downstream part of the river was Na+-Mg2+-Cl--SO42-. Only the concentration of Mn in overlying water exceeded the limit for Drinking Water Quality. Concentrations of the heavy metals in pore water were generally higher than those in overlying water. According to assessment of heavy metals in pore water based on interstitial water criteria toxic units (IWCTU), Zn for all sampling sites (except site 2, 5 and 11) and Pb for the three sites (site 6, 7 and 8) had a toxic risk to aquatic organisms. Cd, Pb and Ni showed high concentrations in both overlying water and sediment collected at sampling sites where the coal mining activities were carried out. High concentrations of Hg near the coal mines should also be taken into account. Pb, Cr and Mn showed higher partition coefficient values while the values were lower for the other three heavy metals (Hg, Cd and Zn). The distribution of all heavy metals in overlying water,pore water and sediment was sediment > pore water > overlying water. Among heavy metals in overlying water, pore water and sediment, Cd and Pb in both pore water and sediment were significantly correlated. The principal component analysis (PCA) results for the heavy metals in sediment demonstrated that Cd, Pb, Ni, Hg, Cu and Cr were present in the first principal component, indicating that these heavy metals probably had similar source.
  • 加载中
  • [1] 朱青青,王中良.中国主要水系沉积物中重金属分布特征及来源分析[J]. 地球与环境,2012,40(3):305-313.

    ZHU Q Q, WANG Z L. Distribution and source of heavy metals in main drainage sediment, China[J]. Earth and Environment, 2012, 40(3):305-313(in Chinese).

    [2] 陈莉薇,徐晓春,王军,等. 铜陵相思河流域重金属分布特征研究[J]. 环境科学,2014,35(8):2967-2973.

    CHEN L W, XU X J, WANG J, et al. Distribution of heavy metals in Xiangsi River valley of Tongling, China[J]. Environmental Science, 2014, 35(8):2967-2973(in Chinese).

    [3] 何江,王新伟,李朝生,等. 黄河包头段水-沉积物系统中重金属的污染特征[J]. 环境科学学报, 2003,23(1):53-57.

    HE J, WANG X W, LI C S, et al. Pollution character of heavy metals in the water-sediment system from Baotou section of the Yellow River[J]. Acta Scientiae Circumstantiae, 2003, 23(1):53-57(in Chinese).

    [4] 王沛芳,胡燕,王超,等. 动水条件下重金属在沉积物水之间的迁移规律[J]. 土木建筑与环境工程,2012,34(3):151-158.

    WANG P F, HU Y, WANG C, et al. Analysis on mobility of heavy metals between sediment-water under different hydrodynamic conditions[J]. Journal of Civil, Architecture & Environmental Engineering, 2012, 34(3):151-158(in Chinese).

    [5] 陈小威. 湘江株洲段表层水及沉积物重金属污染研究[D]. 湘潭:湖南科技大学硕士学位论文, 2011. CHEN X W. The study of heavy metal pollution of water and sediments in Zhuzhou section of Xiangjiang River[D]. Xiangtan:Hunan University of Science and Technology, 2011(in Chinese).
    [6] 严睿文,李玉成. 淮河安徽段水及沉积物中重金属的研究[J]. 生物学杂志,2010,27(2):74-75.

    YAN R W, LI Y C. Study on heavy metals of water and sediments of Huaihe River in Anhui section[J]. Journal of Ecology, 2010, 27(2):74-75(in Chinese).

    [7] 黄廷林. 水体沉积物中重金属释放动力学及试验研究[J]. 环境科学学报, 1995,15(4):440-446.

    HUANG T L. Study on heavy metal release kinetics and experiments in sediment[J]. Acta Scientiae Circumstantiae, 1995, 15(4):440-446(in Chinese).

    [8] ALI M M, ALI M L, ISLAM M S, et al. Preliminary assessment of heavy metals in water and sediment of Karnaphuli River, Bangladesh[J]. Environmental Nanotechnology, Monitoring& Management, 2016, 5:27-35.
    [9] KAMALA-KANNAN S, BATVARI B. P D, LEE K J, et al. Assessment of heavy metals (Cd, Cr and Pb) in water, sediment and seaweed (Ulva lactuca) in the Pulicat Lake, South East India[J]. Chemosphere, 2008, 71(7):1233-1240.
    [10] BARLAS N, AKBULUT N, AYDOĞAN M. Assessment of heavy metal residues in the sediment and water samples of Uluabat Lake, Turkey[J]. Bulletin of Environmental Contamination and Toxicology, 2005, 74(2):286-293.
    [11] 陈明,刘晓端,魏连伟,等.永定河上游水体与底泥中污染物的分布规律[J]. 岩矿测试,2001,20(2):131-135.

    CHEN M,LIU X D,WEI L W, et al. Distribution of pollutants in water and sediment along the upstream of Yongding River[J]. Rock and Mineral Analysis, 2001, 20(2):131-135(in Chinese).

    [12] 安长生. 门头沟区地表水水质现状评价及趋势分析[J]. 环境工程,2010,28(4):115-118.

    AN C S. Surface water quality evaluation and development trends analysis of Men tougou District in Beijing[J]. Environmental Engineering, 2010, 28(4):115-118(in Chinese).

    [13] 梁涛,张秀梅,章申. 官厅水库及永定河枯水期水体氮、磷和重金属含量分布规律[J]. 地理科学进展, 2001, 20(4):341-346.

    LIANG T, ZHANG X M, ZHANG S. Distribution of N,P and heavy metals in drought period of Guanting Reservoir and Yongding River[J]. Progress in Geography, 2001, 20(4):341-346(in Chinese).

    [14] 肖长来. 水文地质学[M]. 北京:清华大学出版社, 2010. XIAO C L. Hydrological geology[M]. Beijing:Tsinghua University Press, 2010(in Chinese).
    [15] 郇环,王金生,翟远征,等.北京平原区永定河冲洪积扇地下水水化学特征与演化规律[J].地球学报, 2011,32(3):357-366.

    HUAN H, WANG J S, ZHAI Y Z, et al. Chemical characteristics and evolution of groundwater in the Yongding River alluvial fan of Beijing Plain[J]. Acta Geoscientica Sinica, 2011, 32(3):357-366(in Chinese).

    [16] 温小虎,仵彦卿,常娟,等.黑河流域水化学空间分异特征分析[J]. 干旱区研究, 2004,21(1):1-6.

    WEN X H, WU Y Q, CHANG J, et al. Analyze on hydro-chemical spatial variation of Hei River drainage[J]. Arid Zone Research, 2004, 21(1):1-6(in Chinese).

    [17] 胡春华,童乐,万齐远,等.环鄱阳湖浅层地下水水化学特征的时空变化[J]. 环境化学,2013,32(6):974-979.

    HU C H, TONG L,WAN Q Y, et al. Hydro-chemical temporal and spatial variation of ground water around Poyang Lake[J]. Environmental Chemistry, 2013, 32(6):974-979(in Chinese).

    [18] 周嘉欣,丁永建,曾国雄,等.疏勒河上游地表水水化学主离子特征及其控制因素[J]. 环境科学,2014,35(9):3315-3324.

    ZHOU J X, DING Y J, ZENG G X, et al. Major ion chemistry of surface water in the upper reach of Shule River Basin and the possible controls[J]. Environmental Science, 2014, 35(9):3315-3324(in Chinese).

    [19] THOMAS J, JOSEPH S, THRIVIKRAMJ K P. Hydrochemical variations of a tropical mountain river system in a rain shadow region of the southern Western Ghats, Kerala, India[J]. Applied Geochemistry, 2015, 63:456-471.
    [20] 马迎群,时瑶,秦延文,等.浑河上游(清原段)水环境中重金属时空分布及污染评价[J]. 环境科学,2014,35(1):108-116.

    MA Y Q, SHI Y, QIN Y W, et al. Temporal-spatial distribution and pollution assessment of heavy metals in the upper reaches of Hunhe River(Qingyuan Section), Northeast China[J]. Environmental Science, 2014, 35(1):108-116(in Chinese).

    [21] 简敏菲,李玲玉,徐鹏飞,等.鄱阳湖-乐安河湿地水土环境中重金属污染的时空分布特征[J]. 环境科学,2014,35(5):1759-1765.

    JIAN M F, LI L Y, XU P F, et al. Spatiotemporal variation characteristics of heavy metals pollution in the water, soil and sediments environment of the lean River-Poyang Lake wetland[J]. Environmental Science, 2014, 35(5):1759-1765(in Chinese).

    [22] ZHANG L, SHI Z, ZHANG J, et al. Spatial and seasonal characteristics of dissolved heavy metals in the east and west Guangdong coastal waters, South China[J]. Marine Pollution Bulletin, 2015, 95(1):419-426.
    [23] PENG S. The nutrient, total petroleum hydrocarbon and heavy metal contents in the seawater of Bohai Bay, China:Temporal-spatial variations, sources, pollution statuses, and ecological risks[J]. Marine Pollution Bulletin, 2015, 95(1):445-451.
    [24] 王心义,杨建,郭慧霞. 矿区煤矸石堆放引起土壤重金属污染研究[J]. 煤炭学报, 2006,31(6):808-812.

    WANG X Y, YANG J, GUO H X. Study on heavy metals in soil contaminated by coal waste rock pile[J]. Journal of China Coal Society, 2006, 31(6):808-812(in Chinese).

    [25] 廖四海,杜勇立,刘振华,等.煤矸石堆放地周围土壤中重金属的污染特性及评价[J]. 环境工程,2014,32(8):118-120.

    LIAO S H, DU Y L, LIU Z H, et al. The pollution characteristics and risk assessment of heavy metals in gangue piling site to surrounding soil[J]. Environmental Engineering, 2014, 32(8):118-120(in Chinese).

    [26] 杨建,陈家军,王心义. 煤矸石堆周围土壤重金属污染空间分布及评价[J]. 农业环境科学学报,2008,27(3):873-878.

    YANG J,CHEN J J,WANG X Y. Spatial distribution of heavy metals in soils around the coal waste rock pile and their environmental pollution assessment[J]. Journal of Agro-Environment Science, 2008, 27(3):873-878(in Chinese).

    [27] 罗莎莎,万国江.云贵高原湖泊沉积物-水界面铁、锰、硫体系的研究进展[J]. 地质地球化学,1999,27(3):47-52.

    LUO S S, WAN G J. Research progress in Iron, manganese and sulfur system at lake sediment-water interface of Yungui plateau[J]. Geology and Geochemistry, 1999, 27(3):47-52(in Chinese).

    [28] 蒋萏芳,郑乐平,孙为民.淀山湖上覆水与沉积物孔隙水中重金属的分布特征[J]. 环境化学, 2003,22(4):318-323.

    JIANG D F, ZHENG L P, SUN W M. Heavy metals distribution in water and sediment of Zhanshan Lake[J]. Environmental Chemistry, 2003, 22(4):318-323(in Chinese).

    [29] 余秀娟,霍守亮,昝逢宇,等.巢湖表层沉积物中重金属的分布特征及其污染评价[J]. 环境工程学报,2013,7(2):439-450.

    YU X J, HUO S L, ZAN F Y, et al. Distribution characteristics and contamination assessment of heavy metals in surface sediments of Chaohu Lake[J]. Journal of Environmental Engineering, 2013, 7(2):439-450(in Chinese).

    [30] TANG W Z, DUAN S H, SHAN B Q, et al. Concentrations, diffusive fluxes and toxicity of heavy metals in pore water of the Fuyang River, Haihe Basin[J]. Ecotoxicology and Environmental Safety, 2016, 127:80-86
    [31] 范拴喜.土壤重金属污染与控制[M].北京:中国环境出版社, 2011. FAN S X. Soil heavy metals pollution and control[M]. Beijing:China Environmental Press, 2011(in Chinese).
    [32] 耿頔,杨芬,韦朝阳,等. 风浪扰动对太湖水体中砷在水相-悬浮物相之间分配的影响[J]. 环境科学学报,2015,35(5):1358-1365.

    GENG D, YANG F, WEI C Y, et al. Effects of wind-wave disturbance on the partition of arsenic between the water-suspended solids phase of Lake Taihu[J]. Acta Scientiae Circumstantia, 2015, 35(5):1358-1365(in Chinese).

    [33] 金相灿. 污染物环境化学[M]. 北京:中国环境科学出版社, 1992:376. JIN X C. Pollutants environmental chemistry[M]. Beijing:China Environmental Science Press, 1992:376(in Chinese).
    [34] 李国莲, 刘桂建, 姜萌萌, 等. 巢湖表层沉积物与上覆水体中重金属分配特征及其相关性研究[J]. 中国科学技术大学学报, 2011,41(1):9-15.

    LI G L, LIU G J, JIANG M M, et al. Partition characteristics and correlation of heavy metal between sediment and surface water from Chaohu Lake[J]. Journal of University of Science and Technology of China, 2011, 41(1):9-15(in Chinese).

    [35] 韩超南, 秦延文, 郑丙辉, 等. 应用相平衡分配法建立湘江衡阳段沉积物重金属质量基准[J]. 环境科学, 2013,34(5):1715-1724.

    HAN C N, QIN Y W, ZHENG B H, et al. Application of equilibrium partitioning approach to establish sediment quality criteria for heavy metals in Hengyang section of Xiangjiang River[J]. Environmental Science, 2013, 34(5):1715-1724(in Chinese).

    [36] WU Q H, ZHOU H C, TAM NORA F Y., et al. Contamination, toxicity and speciation of heavy metals in an industrialized urban river:Implications for the dispersal of heavy metals[J]. Marine Pollution Bulletin, 2016, 104(1-2):153-161.
    [37] 高彦鑫, 冯金国, 唐磊, 等. 密云水库上游金属矿区土壤中重金属形态分布及风险评价[J]. 环境科学, 2012,33(5):1707-1717.

    GAO Y X, FENG J G, TANG L, et al. Fraction distribution and risk assessment of heavy metals in iron and gold mine soil of Miyun reservoir upstream[J]. Environmental Science, 2012, 33(5):1707-1717(in Chinese).

    [38] 黄颜珠. 大宝山矿区Mn、Cu、Cd、Pb和As环境地球化学效应研究[D]. 广州:华南理工大学硕士学位论文, 2010. HUANG Y Z. Study on geochemical environmental effects of Mn, Cu, Cd, Pb and As in Dabaoshan Mine, Guangdong Province[D]. Guangzhou:South China University of Technology, 2010(in Chinese).
    [39] HEI L, JIN P W, ZHU X P, et al. Characteristics of speciation of heavy metals in municipal sewage sludge of Guangzhou as fertilizer[J]. Procedia Environmental Sciences, 2016, 31:232-240.
    [40] WOJTKOWSKA M, BOGACKI J, WITESKA A. Assessment of the hazard posed by metal forms in water and sediments[J]. Science of the Total Environment, 2016, 551-552:387-392.
    [41] 樊庆云, 何江, 薛红喜, 等. 南海湖沉积物重金属形态分布及其对水质影响的研究[J]. 沉积学报, 2007,25(4):612-618.

    FAN Q Y, HE J, XUE H X, et al. Study on distribution, speciation and impact on water of heavy metals in sediment of Nanhai Lake[J]. Acta Sedmentologica Sinica, 2007, 25(4):612-618(in Chinese).

    [42] 秦延文,韩超南,张雷,等. 湘江衡阳段重金属在水体、悬浮颗粒物及表层沉积物中的分布特征研究[J]. 环境科学学报,2012,32(11):2836-2844.

    QIN Y W, HAN C N, ZHANG L, et al. Distribution of heavy metals among surface water,suspended solids and surface sediments in Hengyang section of Xiangjiang River[J]. Acta Scientiae Circumstantiae, 2012, 32(11):2836-2844(in Chinese).

  • 加载中
WeChat 点击查看大图
计量
  • 文章访问数:  3412
  • HTML全文浏览数:  3266
  • PDF下载数:  644
  • 施引文献:  0
出版历程
  • 收稿日期:  2016-06-14
  • 刊出日期:  2017-01-15
时春景, 李红霞, 张言, 徐翔宇, 冯金国, 季宏兵. 永定河上覆水、间隙水和沉积物中重金属的分布特征[J]. 环境化学, 2017, 36(1): 48-61. doi: 10.7524/j.issn.0254-6108.2017.01.2016061401
引用本文: 时春景, 李红霞, 张言, 徐翔宇, 冯金国, 季宏兵. 永定河上覆水、间隙水和沉积物中重金属的分布特征[J]. 环境化学, 2017, 36(1): 48-61. doi: 10.7524/j.issn.0254-6108.2017.01.2016061401
shu
SHI Chunjing, LI Hongxia, ZHANG Yan, XU Xiangyu, FENG Jinguo, JI Hongbing. Distribution characteristics of heavy metals in overlying water-pore water-sediment in the Yongding River[J]. Environmental Chemistry, 2017, 36(1): 48-61. doi: 10.7524/j.issn.0254-6108.2017.01.2016061401
Citation: SHI Chunjing, LI Hongxia, ZHANG Yan, XU Xiangyu, FENG Jinguo, JI Hongbing. Distribution characteristics of heavy metals in overlying water-pore water-sediment in the Yongding River[J]. Environmental Chemistry, 2017, 36(1): 48-61. doi: 10.7524/j.issn.0254-6108.2017.01.2016061401
shu

永定河上覆水、间隙水和沉积物中重金属的分布特征

  • 1.  北京科技大学能源与环境工程学院, 北京, 100083;
  • 2.  北京市地质工程设计研究院, 北京, 101500
  • 收稿日期:  2016-06-14
基金项目:

国家自然科学基金（41173113）和中国科学院百人计划项目资助.

摘要: 采集了永定河及其支流清水河水样和表层沉积物各11个，并通过高速离心获得间隙水样10个.利用ICP-MS检测了上覆水中可溶性重金属（Cd、Cr、Cu、Hg、Mn、Ni、Pb、Zn）、间隙水中可溶性重金属（Cd、Cr、Cu、Mn、Ni、Pb、Zn）的含量以及沉积物中重金属（Cd、Cr、Cu、Hg、Mn、Ni、Pb、Zn）的总量；检测了样品的理化性质；分析了水体及沉积物间重金属的分配系数.结果表明，上游采样点水化学类型主要为Ca2+-Mg2+-HCO3--SO42-，而下游采样点水化学类型则主要为Na+-Mg2+-Cl--SO42-，上游和下游的水化学类型呈现明显的差异性；上覆水中Mn在位于下游的7号采样点含量超出生活饮用水卫生标准；间隙水中的重金属普遍高于上覆水含量；采用间隙水标准毒性单位（IWCTU）对间隙水重金属进行评价，发现Zn在大部分采样点（除2、5、11）及Pb在采样点6、7、8存在一定程度的毒性风险；Cd、Pb、Ni等3种重金属在附近有煤矿分布的采样点的上覆水和沉积物中含量都较高，需要特别注意的是Hg的分布也可能与煤矿开采有关.Pb、Cr、Mn等3种重金属在沉积物与上覆水中的分配系数比较大，而Hg、Cd、Zn则分配系数比较小；重金属在上覆水间隙水及沉积物中的分布关系为沉积物 > 间隙水 > 上覆水；分别对上覆水间隙水和沉积物中的重金属进行相关性分析及沉积物的主成分分析，发现Cd和Pb在间隙水和沉积物中均存在显著的相关性，沉积物中的Cd、Pb、Ni、Hg、Cu、Cr在第一主成分中具有较高的载荷值，推断这几种重金属具有相同的来源.

English Abstract

    全文HTML

参考文献 (42)

返回顶部

目录

/

返回文章
返回

Copyright © 2019 中国科学院生态环境研究中心