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阴离子黏土处理增强型地热系统返排液的研究

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余正艳, 郭清海, 曹耀武, 庄亚芹, 张灿海, 朱明成. 阴离子黏土处理增强型地热系统返排液的研究[J]. 环境化学, 2018, 37(2): 335-346. doi: 10.7524/j.issn.0254-6108.2017050902
引用本文: 余正艳, 郭清海, 曹耀武, 庄亚芹, 张灿海, 朱明成. 阴离子黏土处理增强型地热系统返排液的研究[J]. 环境化学, 2018, 37(2): 335-346. doi: 10.7524/j.issn.0254-6108.2017050902
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YU Zhengyan, GUO Qinghai, CAO Yaowu, ZHUANG Yaqin, ZHANG Canhai, ZHU Mingcheng. Treat of the fracturing fluid from Enhanced Geothermal Systems by using selected anion clays[J]. Environmental Chemistry, 2018, 37(2): 335-346. doi: 10.7524/j.issn.0254-6108.2017050902
Citation: YU Zhengyan, GUO Qinghai, CAO Yaowu, ZHUANG Yaqin, ZHANG Canhai, ZHU Mingcheng. Treat of the fracturing fluid from Enhanced Geothermal Systems by using selected anion clays[J]. Environmental Chemistry, 2018, 37(2): 335-346. doi: 10.7524/j.issn.0254-6108.2017050902
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阴离子黏土处理增强型地热系统返排液的研究

  • 1.

    中国地质大学(武汉)环境学院, 武汉, 430074;

  • 2.

    国家电力投资集团黄河上游水电开发有限责任公司, 西宁, 810008

  • 基金项目:

    国家自然科学基金（41572335）和国家电力投资集团公司科技项目（2015-138-HHS-KJ-X）资助.

Treat of the fracturing fluid from Enhanced Geothermal Systems by using selected anion clays

  • 1.

    School of Environmental Studies, China University of Geosciences, Wuhan, 430074, China;

  • 2.

    Huanghe Hydropower Development Co., Ltd., State Power Investment Corporation, Xining, 810008, China

  • Fund Project: Supported by the National Natural Science Foundation of China(41572335)and the Science and Technology Project of State Power Investment Corporation(2015-138-HHS-KJ-X).

  • 摘要: 增强型地热系统返排液中一般存在多种有害组分.利用不同类型阴离子黏土（焙烧后水铝钙石、焙烧后水氯铁镁石、焙烧后水滑石和CO32-插层水滑石）开展了实验室配制或基于化学刺激实验所获返排液样品中氟、砷、硼、氯等有害阴离子组分的去除实验研究.结果表明，CO32-插层水滑石可用于有效处理以氟化物和/或氯化物为主要有害组分的青海扎仓寺样品和法国Soultz-sous-Forêts样品；而对于以氟、砷、硼为主要有害组分的美国Fenton Hill样品，焙烧后水铝钙石、水氯铁镁石和水滑石的混合物（质量比为1∶1∶4）为处理效果最佳的阴离子黏土组合.
    Abstract: Fracturing liquid from Enhanced Geothermal Systems usually contains a variety of harmful constituents. Different anion clays (calcined hydrocalumite,calcined iowaite,calcined hydrotalcite and hydrotalcite with CO32- as interlayer anions) were used to remove the harmful constituents (fluoride,arsenic,boride,chloride and so on) in the fracturing liquid either prepared in the laboratory or obtained by chemical stimulation experiments. Experimental results showed that hydrotalcite with CO32- as interlayer anions effectively treated the fracturing liquid sample from Zhacangsi in Qinghai province and Soultz-sous-Forêts in France with fluoride and/or chloride as main components.A mixture of calcined hydrocalumite,iowaite and hydrotalcite (mass tatio is 1:1:4) optimally treated the sample from Fenton Hill in Ameirica with fluoride,arsenic and boride as main components.
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  • 收稿日期:  2017-05-09
  • 刊出日期:  2018-02-15

阴离子黏土处理增强型地热系统返排液的研究

  • 1.  中国地质大学(武汉)环境学院, 武汉, 430074;
  • 2.  国家电力投资集团黄河上游水电开发有限责任公司, 西宁, 810008
  • 收稿日期:  2017-05-09
基金项目:

国家自然科学基金（41572335）和国家电力投资集团公司科技项目（2015-138-HHS-KJ-X）资助.

摘要: 增强型地热系统返排液中一般存在多种有害组分.利用不同类型阴离子黏土（焙烧后水铝钙石、焙烧后水氯铁镁石、焙烧后水滑石和CO32-插层水滑石）开展了实验室配制或基于化学刺激实验所获返排液样品中氟、砷、硼、氯等有害阴离子组分的去除实验研究.结果表明，CO32-插层水滑石可用于有效处理以氟化物和/或氯化物为主要有害组分的青海扎仓寺样品和法国Soultz-sous-Forêts样品；而对于以氟、砷、硼为主要有害组分的美国Fenton Hill样品，焙烧后水铝钙石、水氯铁镁石和水滑石的混合物（质量比为1∶1∶4）为处理效果最佳的阴离子黏土组合.

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