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典型磺胺类抗生素在稻田土中的纵向迁移

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汪仙仙, 张洪昌, 沈根祥, 胡双庆, 张玉, 顾海蓉, 袁哲军. 典型磺胺类抗生素在稻田土中的纵向迁移[J]. 环境化学, 2018, 37(8): 1746-1754. doi: 10.7524/j.issn.0254-6108.2018022802
引用本文: 汪仙仙, 张洪昌, 沈根祥, 胡双庆, 张玉, 顾海蓉, 袁哲军. 典型磺胺类抗生素在稻田土中的纵向迁移[J]. 环境化学, 2018, 37(8): 1746-1754. doi: 10.7524/j.issn.0254-6108.2018022802
shu
WANG Xianxian, ZHANG Hongchang, SHEN Genxiang, HU Shuangqing, ZHANG Yu, GU Hairong, YUAN Zhejun. Vertical migration of typical sulfonamide antibiotics in paddy soil[J]. Environmental Chemistry, 2018, 37(8): 1746-1754. doi: 10.7524/j.issn.0254-6108.2018022802
Citation: WANG Xianxian, ZHANG Hongchang, SHEN Genxiang, HU Shuangqing, ZHANG Yu, GU Hairong, YUAN Zhejun. Vertical migration of typical sulfonamide antibiotics in paddy soil[J]. Environmental Chemistry, 2018, 37(8): 1746-1754. doi: 10.7524/j.issn.0254-6108.2018022802
shu

典型磺胺类抗生素在稻田土中的纵向迁移

  • 1.

    东华大学环境科学与工程学院, 上海, 201620;

  • 2.

    上海市环境科学研究院, 上海, 200233;

  • 3.

    华东理工大学资源与环境工程学院, 上海, 200237

  • 基金项目:

    上海市2016年度"科技创新行动计划"社会发展领域项目（16DZ1204700），上海市环保科研项目（2016-3）和长江水环境教育部重点实验室开放课题（YRWEF201803）资助.

Vertical migration of typical sulfonamide antibiotics in paddy soil

  • 1.

    College of Environmental Science and Engineering, Donghua University, Shanghai, 201620, China;

  • 2.

    Shanghai Academy of Environmental Sciences, Shanghai, 200233, China;

  • 3.

    College of Resources and Environmental Engineering, East China University of Science and Technology, Shanghai, 200237, China

  • Fund Project: Supported by Scientific Research Program of Shanghai Science and Technology Committee (16DZ1204700), Scientific Research Program of Shanghai Environmental Protection Bureau, China(2016-3) and Key Laboratory of Yangtze River Water Environment, Ministry of Education (Tongji University), China(YRWEF201803).

  • 摘要: 兽用抗生素的广泛使用以及畜禽粪污还田资源化利用是农田土壤抗生素污染的重要来源，而抗生素在土壤中的迁移特性对生态环境具有潜在风险.为分析典型磺胺类抗生素在土壤中的迁移特征，采用室内土柱淋溶实验研究了磺胺甲基嘧啶（SM）、磺胺二甲基嘧啶（SM2）和甲氧苄啶（TMP）在稻田土中的淋溶规律，模拟了不同淋溶时间、不同污染程度和不同降雨pH对3种磺胺类抗生素在稻田土中纵向迁移的影响.结果表明，在雨水冲刷下，3种磺胺类抗生素的淋溶迁移性为TMP > SM > SM2.随淋溶时间的增长和污染程度增加，磺胺类抗生素纵向迁移能力增强，进而增加其向地下水迁移的风险.3种磺胺类抗生素在酸雨作用下更容易在土壤中吸附.
    Abstract: Agricultural fields worldwide are contaminated by the widespread use of veterinary antibiotics via livestock and poultry manure applied as fertilizers for irrigation. Antibiotics migration results in damages to the terrestrial environments. Batch experiments were conducted to investigate the leaching behavior of sulfamethazine (SM), sulfamethazine (SM2) and trimethoprim (TMP). The aim of this study was to explore the effects of rainfall duration, antibiotics concentrations and rainfall with different pH values on the leaching behavior of three different sulfanilamide antibiotics along the soil column. The results showed that the leaching ability of the three sulfanilamide antibiotics was in the order of TMP > SM > SM2. With the increase of rainfall duration and pollution level, the migration ability of sulfanilamide antibiotics increased, leading to the increasd risk of groundwater contemination. These three sulfanilamide antibiotics were more easily adsorbed by soil under acid rain.
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  • 收稿日期:  2018-02-28
  • 刊出日期:  2018-08-15
汪仙仙, 张洪昌, 沈根祥, 胡双庆, 张玉, 顾海蓉, 袁哲军. 典型磺胺类抗生素在稻田土中的纵向迁移[J]. 环境化学, 2018, 37(8): 1746-1754. doi: 10.7524/j.issn.0254-6108.2018022802
引用本文: 汪仙仙, 张洪昌, 沈根祥, 胡双庆, 张玉, 顾海蓉, 袁哲军. 典型磺胺类抗生素在稻田土中的纵向迁移[J]. 环境化学, 2018, 37(8): 1746-1754. doi: 10.7524/j.issn.0254-6108.2018022802
shu
WANG Xianxian, ZHANG Hongchang, SHEN Genxiang, HU Shuangqing, ZHANG Yu, GU Hairong, YUAN Zhejun. Vertical migration of typical sulfonamide antibiotics in paddy soil[J]. Environmental Chemistry, 2018, 37(8): 1746-1754. doi: 10.7524/j.issn.0254-6108.2018022802
Citation: WANG Xianxian, ZHANG Hongchang, SHEN Genxiang, HU Shuangqing, ZHANG Yu, GU Hairong, YUAN Zhejun. Vertical migration of typical sulfonamide antibiotics in paddy soil[J]. Environmental Chemistry, 2018, 37(8): 1746-1754. doi: 10.7524/j.issn.0254-6108.2018022802
shu

典型磺胺类抗生素在稻田土中的纵向迁移

  • 1.  东华大学环境科学与工程学院, 上海, 201620;
  • 2.  上海市环境科学研究院, 上海, 200233;
  • 3.  华东理工大学资源与环境工程学院, 上海, 200237
  • 收稿日期:  2018-02-28
基金项目:

上海市2016年度"科技创新行动计划"社会发展领域项目（16DZ1204700），上海市环保科研项目（2016-3）和长江水环境教育部重点实验室开放课题（YRWEF201803）资助.

摘要: 兽用抗生素的广泛使用以及畜禽粪污还田资源化利用是农田土壤抗生素污染的重要来源，而抗生素在土壤中的迁移特性对生态环境具有潜在风险.为分析典型磺胺类抗生素在土壤中的迁移特征，采用室内土柱淋溶实验研究了磺胺甲基嘧啶（SM）、磺胺二甲基嘧啶（SM2）和甲氧苄啶（TMP）在稻田土中的淋溶规律，模拟了不同淋溶时间、不同污染程度和不同降雨pH对3种磺胺类抗生素在稻田土中纵向迁移的影响.结果表明，在雨水冲刷下，3种磺胺类抗生素的淋溶迁移性为TMP > SM > SM2.随淋溶时间的增长和污染程度增加，磺胺类抗生素纵向迁移能力增强，进而增加其向地下水迁移的风险.3种磺胺类抗生素在酸雨作用下更容易在土壤中吸附.

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