高级搜索

北京市典型垃圾填埋场渗滤液中PFASs污染水平研究

,  ,  ,  ,  ,  ,  , 

downloadPDF

上一篇

下一篇

崔毓莹, 牛夏梦, 唐佳伟, 孙鹤, 杨晨, 陈薇, 周兆伦, 张春晖. 北京市典型垃圾填埋场渗滤液中PFASs污染水平研究[J]. 环境化学, 2019, (9): 2038-2046. doi: 10.7524/j.issn.0254-6108.2018120601
引用本文: 崔毓莹, 牛夏梦, 唐佳伟, 孙鹤, 杨晨, 陈薇, 周兆伦, 张春晖. 北京市典型垃圾填埋场渗滤液中PFASs污染水平研究[J]. 环境化学, 2019, (9): 2038-2046. doi: 10.7524/j.issn.0254-6108.2018120601
shu
CUI Yuying, NIU Xiameng, TANG Jiawei, SUN He, YANG Chen, CHEN Wei, ZHOU Zhaolun, ZHANG Chunhui. Distribution and pollution level of PFASs in leachate from typical refuse landfills in Beijing[J]. Environmental Chemistry, 2019, (9): 2038-2046. doi: 10.7524/j.issn.0254-6108.2018120601
Citation: CUI Yuying, NIU Xiameng, TANG Jiawei, SUN He, YANG Chen, CHEN Wei, ZHOU Zhaolun, ZHANG Chunhui. Distribution and pollution level of PFASs in leachate from typical refuse landfills in Beijing[J]. Environmental Chemistry, 2019, (9): 2038-2046. doi: 10.7524/j.issn.0254-6108.2018120601
shu

北京市典型垃圾填埋场渗滤液中PFASs污染水平研究

  • 中国矿业大学(北京)化学与环境工程学院, 北京, 100083

    • 通讯作者: 张春晖, E-mail: zchcumtb@hotmail.com
  • 基金项目:

    国家重点研发计划资助（2018YFC0406400）资助.

Distribution and pollution level of PFASs in leachate from typical refuse landfills in Beijing

  • School of Chemical & Environmental Engineering, China University of Mining and Technology(Beijing), Beijing, 100083, China

    • Corresponding author: ZHANG Chunhui, zchcumtb@hotmail.com
  • Fund Project: Supported by National Key Research and Development Program(2018YFC0406400).

  • 摘要: 全氟及多氟类化合物（Perfluoroalkyl and polyfluoroalkyl substances）作为一类新型污染物近年来已开始受到人们的广泛关注.本研究应用高效液相色谱-质谱联用的方法对北京市4个典型垃圾填埋场垃圾渗滤液中全氟化合物（PFASs）的含量进行研究分析，并着重对六里屯垃圾填埋场产生的垃圾渗滤液及其周边河流、底泥以及土壤进行监测取样，分析PFASs污染程度.结果显示，北京市垃圾渗滤液的PFASs总浓度在407.10-2982.25 ng·L-1之间，主要的污染物为PFPeA（Perfluoropentanoic acid，全氟戊酸）、PFOA（Perfluorooctanoic acid，全氟辛酸）和PFOS（Perfluorooctane sulphonate，全氟辛烷磺酸盐），另对六里屯垃圾填埋场渗滤液中PFASs进行为期两年的分析，PFASs检出率为100%，总浓度为407.10-4275.53 ng·L-1，主要的污染因子为PFOA，浓度范围在132.87-431.00 ng·L-1.六里屯垃圾填埋场周围环境介质均检出PFASs，受纳河流与土壤污染程度较高，河流PFASs总浓度在5.33-176.05 ng·L-1之间，土壤PFASs总浓度在0.10-169.05 ng·g-1之间，河水底泥污染程度较低，平均PFASs浓度为1.91 ng·g-1，表明经处理的垃圾填埋场渗滤液排放会对周围环境造成PFASs污染.
    Abstract: As an emerging type of pollutants, Perfluoroalkyl and polyfluoroalkyl substances (PFASs) have begun to receive considerable attention in recent years. With the help of high performance liquid chromatography-mass spectrometry (HPLC-MS), this paper analyzed the contents of PFASs in the landfill leachate collected from four typical landfills in Beijing. The leachate from Liulitun landfill and the surrounding rivers, sediments, and soils samples were collected and PFASs were analyzed emphatically. The research showed that the total concentration of PFASs in the four landfills in Beijing ranged from 407.10 to 2982.25 ng·L-1, and the main pollutants were perfluoropentanoic acid(PFPeA), perfluorooctanoic acid (PFOA) and perfluorooctane sulphonate (PFOS). In addition, PFASs in leachate of Liulitun landfill was analyzed for two years. The detection rate of PFASs was 100%, and the total concentration was 407.10-4275.53 ng·L-1. and the main pollutant was PFOA, with the concentration ranging from 132.87 to 431.00 ng·L-1. PFASs were detected in the surrounding environmental media of Liulitun landfill, which severely polluted the nearby rivers and soil, with the concentration from 5.33 to 176.05 ng·L-1 and 0.10 to 169.05 ng·L-1 respectively. Nevertheless, the average concentration of PFASs in sediments was on low level of 1.91 ng·L-1, which indicated that discharge and leakage of landfill leachate will definitely cause PFASs pollution to the surrounding environment.
  • 加载中
  • [1] EGGEN T, MOEDER M, ARUKWE A. Municipal landfill leachates:A significant source for new and emerging pollutants[J]. Science of the Total Environment, 2010,408(21):5147-5157.
    [2] REBECCA R. The long and the short of perfluorinated replacements[J]. Environmental Science & Technology, 2006, 40(1):12-13.
    [3] RITTER S K. Fluorochemicals go short[J]. Chem Eng News, 2010, 88(5):12-17.
    [4] MCLAUGHLIN C L, BLAKE S, Co-operation on existing chemicals. Hazard assessment of perfluorooctane sulfonate(PFOS)and its salts[R]. Environment Directorate Joint Meeting of the Chemicals Committee and the Working Party on Chemicals. Pesticides and Biotechnology, Paris, 2002
    [5] 高燕, 傅建捷, 王亚韡, 等.全氟化工厂土芯中全氟化合物的分布规律[J].环境化学, 2014, 33(10):1686-1691.

    GAO Y, FU J J, WANG Y W, et al. Spatial and vertical distribution of perfluoroalkyl substances in soil cores around manufacturing facilities in China[J]. Environmental Chemistry, 2014, 33(10):1686-1691(in Chinese).

    [6] HEKSTER F M, LAANE R W P M, DEVOOGT P. Environmental and toxicity effects of perfluoroalkylated substances[J]. Rev Environ Cont Toxicol, 2003, 179:99-121.
    [7] BUSCH J, AHRENS L, STURM R, et al. Polyfluoroalkyl compounds in landfill leachates[J]. Environmental Pollution, 2010, 158(5):1467-1471.
    [8] AHRENS L, SHOEIB M, HARNER T, et al. Wastewater treatment plant and landfills as sources of polyfluoroalkyl compounds to the atmosphere[J]. Environmental Science & Technology, 2011, 45(19):8098-8105.
    [9] WEINBERG I, DREYER A, EBINGHAUS R. Landfills as sources of polyfluorinated compounds, polybrominated diphenyl ethers and musk fragrances to ambient air[J]. Atmospheric Environment, 2011, 45(4):935-941.
    [10] HUSET C A, BARLAZ M A, BAROFSKY D F, et al. Quantitative determination of fluorochemicals in municipal landfill leachates[J]. Chemosphere, 2011, 82:1380-1386.
    [11] ANDREAS W, MIKAEL R. Results from the National Swedish Screening Programme[R]. 2008, IVL Swedish Environmental Research Institute:Stockholm.
    [12] BOSSI R, STRAND J, SORTKJAER O. Perfluorinated compounds in danish wastewater treatment plants and aquatic environments[J]. Environment International, 2008, 34(4):1-450.
    [13] BUCK R C, FRANKLIN J, BERGER U, et al. Perfluoroalkyl and polyfluoroalkyl substances in the environment:Terminology, classification, and origins[J]. Integr Environ Assess Manag, 2011, 7(4):513-541.
    [14] 3M. Environmental Monitoring-multi-city-study Water, Sluge, Sediment, POTW Effluent and Landfill Leachate Samples[R]. 3M Environmental Laboratory, 2001:78-82.
    [15] LI B, DANON-SCHAFFER M N, LI L Y, et al. Occurrence of PFCs and PBDEs in landfill leachates from across Canada[J]. Water Air and Soil Pollution, 2012, 223(6):3365-3372.
    [16] HUSET C A, BARLAZ M A, BAROFSKY D F, et al. Quantitative determination of fluorochemicals in municipal landfill leachates[J]. Chemosphere, 2011, 82(10):1380-1386.
    [17] 杨琳,李敬光.全氟化合物前体物质生物转化与毒性研究进展[J].环境化学,2015,34(4):649-655.

    YANG L, LI J G. Perfluorinated compound precursors:Biotransformation and toxicity[J]. Environmental Chemistry, 2015, 34(4):649-655(in Chinese).

    [18] 周珍, 胡宇宁, 史亚利, 等. 武汉地区水环境中全氟化合物污染水平及其分布特征[J].生态毒理学报,2017,12(3):425-433.

    ZHOU Z, HU Y N, SHI Y L, et al. Occurrence and distribution of per-and polufluoroalkyl substances in waste water and surfacewater samples in Wuhan[J] Asian Journal of Ecotoxicology,2017,12(3):425-433(in Chinese).

    [19] YANG L P, ZHU L Y, LIU Z T. Occurrence and partition of perfluorinated compounds in water and sediment from Liao River and Taihu Lake, China[J]. Chemosphere, 2011, 83(6):806-814.
    [20] SHOEIB M, HARNER T,WILFORD BH, et al. Perffluorinated sulfonamides in indoor and outdoor air and indoor and dust:Occurrence, partitioning, and human exposure[J] Environmental Science and Technology, 2005, 39(17):6599-6606.
    [21] FENG X, SIMCIK M F, HALBACH T R, et al. Perfluorooctane sulfonate (PFOS) and perfluorooctanoate (PFOA) in soils and groundwater of a U.S. metropolitan area:Migration and implications for human exposure[J] Water Research, 2015, 72(Sp. Iss. SI):64-74.
    [22] PAN Y Y, SHI Y L, WANG J M. Pilot investigation of perfluorinated compounds in river water, sediment, soil and fish in Tianjin, China[J]. Blletin of Environmental Contamination & Toxicology, 2011, 87(2):152-157.
  • 加载中
WeChat 点击查看大图
计量
  • 文章访问数:  2301
  • HTML全文浏览数:  2301
  • PDF下载数:  135
  • 施引文献:  0
出版历程
  • 收稿日期:  2018-12-06
崔毓莹, 牛夏梦, 唐佳伟, 孙鹤, 杨晨, 陈薇, 周兆伦, 张春晖. 北京市典型垃圾填埋场渗滤液中PFASs污染水平研究[J]. 环境化学, 2019, (9): 2038-2046. doi: 10.7524/j.issn.0254-6108.2018120601
引用本文: 崔毓莹, 牛夏梦, 唐佳伟, 孙鹤, 杨晨, 陈薇, 周兆伦, 张春晖. 北京市典型垃圾填埋场渗滤液中PFASs污染水平研究[J]. 环境化学, 2019, (9): 2038-2046. doi: 10.7524/j.issn.0254-6108.2018120601
shu
CUI Yuying, NIU Xiameng, TANG Jiawei, SUN He, YANG Chen, CHEN Wei, ZHOU Zhaolun, ZHANG Chunhui. Distribution and pollution level of PFASs in leachate from typical refuse landfills in Beijing[J]. Environmental Chemistry, 2019, (9): 2038-2046. doi: 10.7524/j.issn.0254-6108.2018120601
Citation: CUI Yuying, NIU Xiameng, TANG Jiawei, SUN He, YANG Chen, CHEN Wei, ZHOU Zhaolun, ZHANG Chunhui. Distribution and pollution level of PFASs in leachate from typical refuse landfills in Beijing[J]. Environmental Chemistry, 2019, (9): 2038-2046. doi: 10.7524/j.issn.0254-6108.2018120601
shu

北京市典型垃圾填埋场渗滤液中PFASs污染水平研究

    通讯作者: 张春晖, E-mail: zchcumtb@hotmail.com
  • 中国矿业大学(北京)化学与环境工程学院, 北京, 100083
  • 收稿日期:  2018-12-06
基金项目:

国家重点研发计划资助（2018YFC0406400）资助.

摘要: 全氟及多氟类化合物（Perfluoroalkyl and polyfluoroalkyl substances）作为一类新型污染物近年来已开始受到人们的广泛关注.本研究应用高效液相色谱-质谱联用的方法对北京市4个典型垃圾填埋场垃圾渗滤液中全氟化合物（PFASs）的含量进行研究分析，并着重对六里屯垃圾填埋场产生的垃圾渗滤液及其周边河流、底泥以及土壤进行监测取样，分析PFASs污染程度.结果显示，北京市垃圾渗滤液的PFASs总浓度在407.10-2982.25 ng·L-1之间，主要的污染物为PFPeA（Perfluoropentanoic acid，全氟戊酸）、PFOA（Perfluorooctanoic acid，全氟辛酸）和PFOS（Perfluorooctane sulphonate，全氟辛烷磺酸盐），另对六里屯垃圾填埋场渗滤液中PFASs进行为期两年的分析，PFASs检出率为100%，总浓度为407.10-4275.53 ng·L-1，主要的污染因子为PFOA，浓度范围在132.87-431.00 ng·L-1.六里屯垃圾填埋场周围环境介质均检出PFASs，受纳河流与土壤污染程度较高，河流PFASs总浓度在5.33-176.05 ng·L-1之间，土壤PFASs总浓度在0.10-169.05 ng·g-1之间，河水底泥污染程度较低，平均PFASs浓度为1.91 ng·g-1，表明经处理的垃圾填埋场渗滤液排放会对周围环境造成PFASs污染.

English Abstract

    全文HTML

参考文献 (22)

返回顶部

目录

/

返回文章
返回

Copyright © 2019 中国科学院生态环境研究中心