高级搜索

邻苯二甲酸及丙二酸对方解石吸附四环素的影响

,  ,  ,  ,  , 

downloadPDF

上一篇

下一篇

孙晓雯, 李振炫, 黄利东, 刘大刚, 于飞, 潘德勤. 邻苯二甲酸及丙二酸对方解石吸附四环素的影响[J]. 环境化学, 2019, (12): 2746-2756. doi: 10.7524/j.issn.0254-6108.2019011506
引用本文: 孙晓雯, 李振炫, 黄利东, 刘大刚, 于飞, 潘德勤.

邻苯二甲酸及丙二酸对方解石吸附四环素的影响

[J]. 环境化学, 2019, (12): 2746-2756. doi: 10.7524/j.issn.0254-6108.2019011506
shu
SUN Xiaowen, LI Zhenxuan, HUANG Lidong, LIU Dagang, YU Fei, PAN Deqin. Effect of organic dicarboxylic acid on the adsorption of tetracycline by calcite[J]. Environmental Chemistry, 2019, (12): 2746-2756. doi: 10.7524/j.issn.0254-6108.2019011506
Citation: SUN Xiaowen, LI Zhenxuan, HUANG Lidong, LIU Dagang, YU Fei, PAN Deqin.

Effect of organic dicarboxylic acid on the adsorption of tetracycline by calcite

[J]. Environmental Chemistry, 2019, (12): 2746-2756. doi: 10.7524/j.issn.0254-6108.2019011506
shu

邻苯二甲酸及丙二酸对方解石吸附四环素的影响

  • 1. 江苏省大气环境与装备技术协同创新中心, 江苏省大气环境监测与污染控制高技术重点实验室, 南京信息工程大学, 南京, 210044;

  • 2. 南京信息工程大学应用气象学院, 南京, 210044;

  • 3. 南京乐翼环境科技有限公司, 南京, 211135;

  • 4. 扬州松泉环保科技有限公司, 扬州, 225600

    • 通讯作者: 李振炫, E-mail: zhenxuan325@163.com ; 
  • 基金项目:

    国家自然科学基金（41303096，41201515），江苏省研究生科研与实践创新计划（KYCX18_1030），教育部留学回国科研启动基金（S131304001）和国家水体污染控制与治理科技重大专项（2015ZX07204-002）资助.

Effect of organic dicarboxylic acid on the adsorption of tetracycline by calcite

  • 1. Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment Technology, Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Nanjing University of Information Science & Technology, Nanjing, 210044, China;

  • 2. School of applied meteorology, Nanjing University of Information Science & Technology, Nanjing, 210044, China;

  • 3. Nanjing Leyi Environmental Technology Co., Ltd., Nanjing, 211135, China;

  • 4. Yangzhou Songquan Environmental Protection Technology Co., Ltd., Yangzhou, 225600, China

    • Corresponding author: LI Zhenxuan, zhenxuan325@163.com ; 
  • Fund Project: Supported by the National Natural Science Foundation of China (41303096,41201515), Postgraduate Research and Practical Innovation Plan of Jiangsu Province (KYCX18_1030), Scientific Research Starting Foundation for the Returned Overseas Chinese Scholars, Ministry of Education of China (S131304001), Major National Science and Technology Project for Water Pollution Control and Treatment (2015ZX07204-002).

  • 摘要:

    通过批量平衡法，研究丙二酸及邻苯二甲酸对方解石吸附四环素的影响.结果表明，初始pH值为7.7时，随丙二酸和邻苯二甲酸浓度升高，它们的吸附竞争作用逐渐增强，四环素的吸附率不断下降.初始pH值为8.3时，丙二酸浓度为0-0.001 mmol·L-1时，它的竞争作用较弱，而溶液pH值的变化（8.3-8.5）有利于四环素吸附，所以四环素吸附率上升；丙二酸浓度为0.001-0.03 mmol·L-1时，它的竞争作用较强，且溶液pH值的变化（8.5-8.9）不利于四环素吸附，所以四环素吸附率下降.邻苯二甲酸浓度为0-1.8 mmol·L-1时，它的竞争作用较弱，而溶液pH值的变化（8.3-8.5）有利于四环素吸附，因而四环素吸附率不断上升.初始pH值为8.9时，丙二酸与邻苯二甲酸大部分都参与到溶液中的配位络合反应，对四环素的吸附影响不大.以上两种二羧酸在不同的实验条件下对四环素吸附分别产生了不同的影响结果，为今后研究其他二羧酸对四环素吸附的影响提供借鉴作用.

    Abstract:

    Batch sorption experiments were performed to investigate the effects of malonate and phthalate on tetracycline (TC) sorption by calcite. The results showed that at the initial pH of 7.7, the competitive adsorption of malonate and phthalate gradually increased with the increase of concentrations, resulting in a continuous decrease of TC adsorption rate. At the initial pH of 8.3, TC adsorption rate increased with malonate concentration of 0-0.001 mmol·L-1, as the increase of pH (8.3-8.5) was favorable for TC adsorption. Meanwhile, the inhibition of malonate on TC adsorption was weak. However, TC adsorption rate decreased with malonate concentration of 0.001-0.03 mmol·L-1, due to the incereased inhibition of malonate, and the increase of pH (8.5 to 8.9) which is negative. With phthalate concentration of 0-1.8 mmol·L-1, where the inhibition of phthalate was weak, TC adsorption rate kept increasing since the increase of pH (8.3-8.5) had a positive effect on TC adsorption. At the initial pH of 8.9, most malonate or phthalate took part in complexation reaction in solution, which had little impact on the TC adsorption. These dicarboxylic acids have different effects on TC adsorption under different experimental conditions, which can provide a reference for future studies on the effects of other dicarboxylic acids on TC adsorption.

  • 加载中
  • [1] 陈艳龙. 秸秆还田对石灰性土壤Zn迁移转化及冬小麦Zn吸收的影响[D]. 咸阳:西北农林科技大学,2017. CHEN Y L. Effects of straw mulching on Zn migration and transformation in calcareous soil and Zn absorption in winter wheat[D]. Xianyang:Northwest A&F University, 2017(in Chinese).
    [2] 孟延. 施用氮肥对石灰性土壤碳释放与累积的影响[D]. 咸阳:西北农林科技大学,2015. MENG Y. Effects of nitrogen fertilizer application on carbon release and accumulation in calcareous soil[D]. Xianyang:Northwest A&F University, 2015(in Chinese).
    [3] CHUN B J, LEE S G, CHOI J I, et al. Adsorption of carboxylate on calcium carbonate (1014) surface:Molecular simulation approach[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2015, 474:9-17.
    [4] MARTIN W R, SAYLES F L. CaCO3 dissolution in sediments of the center rise western equatorial Atlantic[J]. Geochimica et Coschimica Acta, 1996, 60:243-263.
    [5] LI Z, HOFMANN A, WOLTHERS M, et al. Reversibility of cadmium sorption to calcite revisited[J]. Journal of Colloid and Interface Science, 2012, 368(1):434-442.
    [6] 詹杰,魏树和. 四环素在土壤和水环境中的分布及其生态毒性与降解[J]. 生态学报,2015,9:2819-2825. ZHAN J, WEI S H. Distribution of tetracycline in soil and water environment and its ecological toxicity and degradation[J]. Journal of Ecology, 2015

    , 9:2819-2825(in Chinese).

    [7] 邹艳丽,黄宏,储鸣,等. 天然及CaCl2改性沸石对四环素的吸附[J]. 环境工程学报,2012,6(8):2612-2618.

    ZOU Y L, HUANG H, CHU M, et al. Adsorption of tetracycline by natural and CaCl2 modified Zeolite[J]. Journal of Environmental Engineering, 2012, 6(8):2612-2618(in Chinese).

    [8] AHMED M J, ISLAM M A, ASIF M, et al. Human hair-derived high surface area porous carbon material for the adsorption isotherm and kinetics of tetracycline antibiotics[J]. Bioresource Technology, 2017, 243:778-784.
    [9] 张宁,李淼,刘翔. 土壤中抗生素抗性基因的分布及迁移转化[J]. 中国环境科学,2018,38(7):2609-2617.

    ZHANG N, LI M, LIU X. Distribution, migration and transformation of antibiotic resistance genes in soil[J]. Chinese Environmental Science, 2018, 38(7):2609-2617(in Chinese).

    [10] 方媛瑗,丁惠君. 抗生素的生态毒性效应研究进展[J]. 环境科学与技术,2018,41(5):102-110.

    FANG Y Y, DING H J. Advances in studies on the ecotoxicity effects of antibiotics[J]. Environmental Science & Technology, 2018, 41(5):102-110(in Chinese).

    [11] 迟荪琳,王卫中,徐卫红,等. 四环素类抗生素对不同蔬菜生长的影响及其富集转运特征[J]. 环境科学,2018,39(2):935-943.

    CHI S L, WANG W Z, XU W H, et al. Effects of tetracycline antibiotics on the growth of different vegetables and their enrichment and transport characteristics[J]. Environmental Science, 2018, 39(2):935-943(in Chinese).

    [12] PAROLO M E, AVENA M J, SAVINI M C, et al. Adsorption and circular dichroism of tetracycline on sodium and calcium-montmorillonites[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2013, 417:57-64.
    [13] LI Z H, SCHULZ L, ACKLEY C, et al. Adsorption of tetracycline on kaolinite with pH-dependent surface charges[J]. Journal of Colloid and Interface Science, 2010, 351(1):254-260.
    [14] 贺婧. 不同碳酸钙含量石灰性土壤对外源污染物的吸附解吸[D]. 沈阳:沈阳农业大学,2012. HE J. Adsorption and desorption of exogenous pollutants by calcareous soils with different contents of calcium carbonate[D]. Shenyang:Shenyang Agricultural University, 2012(in Chinese).
    [15] 李振炫,黄利东,徐佳,等. 开放系统中碳酸盐矿物(方解石)对四环素的吸附[J]. 环境科学与技术,2015,38(12):215-221.

    LI Z X, HUANG L D, XU J, et al. Adsorption of tetracycline on carbonate minerals (calcite) in open systems[J]. Environmental Science & Technology, 2015,38(12):215-221(in Chinese).

    [16] 孔涛,林俊杰,伏虹旭,等. 低分子量有机酸对土壤微生物碳源代谢特征的影响[J]. 环境化学,2017,36(2):365-372.

    KONG T, LIN J J, FU H X, et al. Effects of low molecular weight organic acids on carbon source metabolism characteristics of soil microorganisms[J]. Environmental Chemistry, 2017, 36(2):365-372(in Chinese).

    [17] JAVED M T, STOLTZ E, LINDBERG S, et al. Changes in pH and organic acids in mucilage of Eriophorum angustifolium roots after exposure to elevated concentrations of toxic elements[J]. Environmental Science and Pollution Research, 2013, 20(3):1876-1880.
    [18] XU W H, LIU H, MA Q F, et al. Root exudates, rhizosphere Zn fractions, and Zn accumulation of ryegrass at different soil Zn levels[J]. Pedosphere, 2007, 17(3):389-396.
    [19] 孙瑞莲,周启星,王新. 镉超积累植物龙葵叶片中镉的积累与有机酸含量的关系[J]. 环境科学,2006,27(4):765-769.

    SUN R L, ZHOU Q X, WANG X. Relationship between cadmium accumulation and organic acid content in leaves of anemone japonicus[J]. Environmental Science, 2006, 27(4):765-769(in Chinese).

    [20] GEFFROY C, FOISSY A, PERSELLO J, et al. Surface complexation of calcite by carboxylates in water[J]. Journal of Colloid and Interface Science, 1999, 211(1):45-53.
    [21] COMPTON R G, BROWN C A. The inhibition of calcite dissolution/precipitaion:1,2-dicarboxylic acids[J]. Journal of Colloid and Interface Science, 1995, 170:586-590.
    [22] MANN S, GOLUBEV J M, SANDERSON N P, et al. Morphological influence of functionalized and non-functionalized α, ω -dicarboxylates on calcite crystallization[J]. Journal of the Chemical Society, Faraday Transaction, 1990, 86:1873-1880.
    [23] WADA N, YAMASHITA K, UMEGAKI T. Effects of carboxylic acids on calcite formation in the presence of Mg2+ ions[J]. Journal of Colloid and Interface Science, 1999, 212(1):357-364.
    [24] 王平,周荣. 高效液相色谱法测定植物根系分泌物中的有机酸[J]. 色谱,2006,24(3):239-242.

    WANG P, ZHOU R. Determination of organic acids in root exudates by high performance liquid chromatography[J]. Chromatography, 2006, 24(3):239-242(in Chinese).

    [25] ZHAO Y P, TONG F, GU X Y, et al. Insights into tetracycline adsorption onto goethite:Experiments and modeling[J]. Science of the Total Environment, 2014, 470-471:19-25.
    [26] GAO Y, LI, et al. Adsorption and removal of tetracycline antibiotics from aqueous solution by graphene oxide[J]. Colloid Interface Science, 2012, 368:540-546.
    [27] 王晓蓉. 环境化学[M]. 南京:南京大学出版社,1993,18-36. WANG X R. Environmental Chemistry[M]. Nanjing:Nanjing University Press, 1993, 18

    -36(in Chinese).

    [28] 闫志为,刘辉利,张志卫. 温度及CO2对方解石、白云石溶解度影响特征分析[J]. 中国岩溶,2009,28(1):7-10.

    YAN Z W, LIU H L, ZHANG Z W. Analysis of the influence of temperature and CO2 on the solubility of calcite and dolomite[J]. Carsologica Sinica, 2009, 28(1):7-10(in Chinese).

    [29] CAPPELLEN P V,CHARLET L,STUMM W,et al. A surface complexation model of the carbonate mineral-aqueous solution interface[J]. Geochimica et Cosmochimica Acta,1993,57(15):3505-3518.
    [30] LI Z X, SUN X W, HUANG L D, et al. Phosphate adsorption and precipitation on calcite under calco-carbonic equilibrium condition[J]. Chemosphere, 2017, 183:419-428.
    [31] 李振炫,黄利东,陈艳芳,等. 开放系统下丙二酸在方解石上的吸附[J]. 环境化学,2015,34(10):1940-1947.

    LI Z X, HUANG L D,CHEN Y F, et al. Adsorption of malonate on calcite in an open system[J]. Environmental Chemistry, 2015, 34(10):1940-1947(in Chinese).

    [32] 李振炫,黄利东,陈艳芳,等. 开放系统下方解石对邻苯二甲酸的吸附[J]. 环境科学,2015,36(7):2547-2553.

    LI Z X, HUANG L D, CHEN Y F, et al. The adsorption of calcite on phthalate in an open system[J]. Environmental Science, 2015, 36(7):2547-2553(in Chinese).

    [33] CHANG P H, LI Z H, YU T L, et al. Sorptive removal of tetracycline from water by palygorskite[J]. Journal of Hazardous Materials, 2009, 165:148-155.
    [34] 林琳,安婧,周启星. 土壤四环素污染对小白菜幼苗生长发育的生态毒性[J]. 环境科学,2011,32(8):2430-2435.

    LIN L, AN J, ZHOU Q X. Ecological toxicity of soil tetracycline pollution on growth and development of young cabbages[J]. Environmental Science, 2011, 32(8):2430-2435(in Chinese).

    [35] 伊丽丽,焦文涛,陈卫平. 不同抗生素在剖面土壤中的吸附特征[J]. 环境化学,2013,32(12):2357-2363.

    YI L L, JIAO W T, CHEN W P. Adsorption characteristics of different antibiotics in soil profile[J]. Environmental Chemistry, 2013, 32(12):2357-2363(in Chinese).

    [36] 赵宁波,魏亮亮,宋旭刚,等. 四环素在典型土壤中的吸附行为-吸附动力学-热力学特征[J]. 安徽农业科学,2017,45(16):57-62.

    ZHAO N B, WEI L L, SONG X G, et al. Adsorption behavior, adsorption kinetics and thermodynamics of tetracycline in typical soils[J]. Journal of Anhui Agricultural Sciences, 2017, 45(16):57-62(in Chinese).

    [37] 蒋代华. 细菌在粘土矿物及土壤颗粒表面的吸附研究[D]. 武汉:华中农业大学,2009. JIANG D H. Adsorption of bacteria on clay minerals and soil particles[D]. Wuhan:Huazhong Agricultural University, 2009(in Chinese).
    [38] 杨丽华,龚道新,袁雅洁,等. 低分子量有机酸对赤铁矿吸附二氯喹啉酸的影响及机理[J]. 农业环境科学学报,2015,34(7):1301-1310.

    YANG L H, GONG D X, YUAN Y J, et al. Effect of low molecular weight organic acids on adsorption of dichloroquinolinic acid by hematite and its mechanism[J]. Journal of Agricultural and Environmental Sciences, 2015, 34(7):1301-1310(in Chinese).

    [39] WU H Y, JIANG D H, CAI P, et al. Effects of low-molecular-weight organic ligands and phosphate on adsorption of Pseudomonas putida by clay minerals and iron oxide[J]. Colloids and Surfaces B:Biointerfaces, 2011, 82:147-151.
    [40] LEE Y J, REEDER R J. The role of citrate and phthalate during Co(Ⅱ) coprecipitation with calcite[J]. Geochimica et Cosmochimica Acta, 2006, 70(9):2253-2263.
    [41] 黄昭先. 凹凸棒土吸附四环素的研究[D]. 无锡:江南大学,2012. HUANG Z X. Study on adsorption of tetracycline by attapulgite[D]. Wuxi:Jiangnan University, 2012(in Chinese).
    [42] WANG J T, HU J, ZHANG S W. Studies on the sorption of tetracycline onto clays and marine sediment from seawater[J]. Journal of Colloid and Interface Science, 2010, 349:578-582.
  • 加载中
WeChat 点击查看大图
计量
  • 文章访问数:  2064
  • HTML全文浏览数:  2064
  • PDF下载数:  34
  • 施引文献:  0
出版历程
  • 收稿日期:  2019-01-15
  • 刊出日期:  2019-12-10
孙晓雯, 李振炫, 黄利东, 刘大刚, 于飞, 潘德勤. 邻苯二甲酸及丙二酸对方解石吸附四环素的影响[J]. 环境化学, 2019, (12): 2746-2756. doi: 10.7524/j.issn.0254-6108.2019011506
引用本文: 孙晓雯, 李振炫, 黄利东, 刘大刚, 于飞, 潘德勤.

邻苯二甲酸及丙二酸对方解石吸附四环素的影响

[J]. 环境化学, 2019, (12): 2746-2756. doi: 10.7524/j.issn.0254-6108.2019011506
shu
SUN Xiaowen, LI Zhenxuan, HUANG Lidong, LIU Dagang, YU Fei, PAN Deqin. Effect of organic dicarboxylic acid on the adsorption of tetracycline by calcite[J]. Environmental Chemistry, 2019, (12): 2746-2756. doi: 10.7524/j.issn.0254-6108.2019011506
Citation: SUN Xiaowen, LI Zhenxuan, HUANG Lidong, LIU Dagang, YU Fei, PAN Deqin.

Effect of organic dicarboxylic acid on the adsorption of tetracycline by calcite

[J]. Environmental Chemistry, 2019, (12): 2746-2756. doi: 10.7524/j.issn.0254-6108.2019011506
shu

邻苯二甲酸及丙二酸对方解石吸附四环素的影响

    通讯作者: 李振炫, E-mail: zhenxuan325@163.com ; 
  • 1. 江苏省大气环境与装备技术协同创新中心, 江苏省大气环境监测与污染控制高技术重点实验室, 南京信息工程大学, 南京, 210044;
  • 2. 南京信息工程大学应用气象学院, 南京, 210044;
  • 3. 南京乐翼环境科技有限公司, 南京, 211135;
  • 4. 扬州松泉环保科技有限公司, 扬州, 225600
  • 收稿日期:  2019-01-15
  • 网络出版日期:  2019-12-10
基金项目:

国家自然科学基金（41303096，41201515），江苏省研究生科研与实践创新计划（KYCX18_1030），教育部留学回国科研启动基金（S131304001）和国家水体污染控制与治理科技重大专项（2015ZX07204-002）资助.

摘要: 

通过批量平衡法，研究丙二酸及邻苯二甲酸对方解石吸附四环素的影响.结果表明，初始pH值为7.7时，随丙二酸和邻苯二甲酸浓度升高，它们的吸附竞争作用逐渐增强，四环素的吸附率不断下降.初始pH值为8.3时，丙二酸浓度为0-0.001 mmol·L-1时，它的竞争作用较弱，而溶液pH值的变化（8.3-8.5）有利于四环素吸附，所以四环素吸附率上升；丙二酸浓度为0.001-0.03 mmol·L-1时，它的竞争作用较强，且溶液pH值的变化（8.5-8.9）不利于四环素吸附，所以四环素吸附率下降.邻苯二甲酸浓度为0-1.8 mmol·L-1时，它的竞争作用较弱，而溶液pH值的变化（8.3-8.5）有利于四环素吸附，因而四环素吸附率不断上升.初始pH值为8.9时，丙二酸与邻苯二甲酸大部分都参与到溶液中的配位络合反应，对四环素的吸附影响不大.以上两种二羧酸在不同的实验条件下对四环素吸附分别产生了不同的影响结果，为今后研究其他二羧酸对四环素吸附的影响提供借鉴作用.

English Abstract

    全文HTML

参考文献 (42)

返回顶部

目录

/

返回文章
返回

Copyright © 2019 中国科学院生态环境研究中心