河套平原地下水环境质量研究综述及展望
Research progress of groundwater environment in Hetao Plain
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摘要: 河套平原位于内蒙古自治区的西部,是我国最大的引黄灌区,也是内蒙古自治区重要的粮食生产地区之一.地下水是河套平原广大居民主要供水来源,但是地下水环境质量特别是地下水中砷元素的富集问题,成为制约地区经济、社会发展的重要因素,同时影响当地居民的身体健康和生活水.本文针对河套平原高砷地下水分布特征及演化机制进行重点分析,结合研究区如水化学特征、高铁、高氟、高碘地下水、灌溉区地下水质量和地下水数值模拟等地下水其他研究,对河套平原地下水环境质量研究进展进行系统论述.通过对比分析发现,人类活动对各元素释放的影响程度的相关研究较为缺乏;先进的研究方法和手段如水文地球化学模拟和环境同位素的应用在地下水环境质量研究中应用较少;对高砷、高氟等地下水的水化学特征的研究较为片面,当前研究集中在各离子浓度之间的相关分析,对地下水形成过程中所发生的水文地球化学过程研究较少.针对以上问题,本文提出了以下展望:1.选择合适的典型地质断面从时间和空间角度相结合来研究高砷、高氟等地下水的形成和演化机理;2.针对地下水环境质量开展宏观和微观机制的综合研究;3.可利用同位素技术对于地下水系统中水动力场和水化学场的指示作用以便于清楚地认识系统中发生的地球化学过程;4.运用水文地球化学模拟手段识别研究内蒙古河套平原地区开展高砷地下水演化机理,深入探讨该地区地下水中水化学特征形成演化机制.本文为进一步研究地区地下水环境提供了思路,对指导地下水环境研究及改良、防治砷对环境和人类的危害具有重要意义.Abstract: Hetao Plain which is located in the west of Inner Mongolia Autonomous Region, is the largest irrigation area of Yellow River diversion in China and one of the important grain production areas in this area. Groundwater is the main source of water supply for the majority of residents in Hetao Plain; However the quality of groundwater, especially the accumulation of arsenic in it, seriously affects the health and living standards of local residents, and is also one of the important factors restricting the economic and social development of the region. This paper focuses on the distribution characteristics and evolution mechanism of high arsenic groundwater in Hetao Plain. Combined with other researches on groundwater such as hydrochemical characteristics, high iron, high fluorine, high iodine groundwater in the research area, groundwater quality in irrigation area and groundwater numerical simulation, the research progress of groundwater environmental quality in Hetao Plain is systematically analyzed and discussed. Through comparative analysis, it is found that there is a lack of relevant research on the extent to which human activities affect the release of various elements. Advanced research methods and means such as hydrogeochemical simulation and environmental isotopes are seldom used in groundwater environmental quality studies. The understanding of hydrochemical characteristics of groundwater with high arsenic and fluorine is not comprehensive enough. Most studies were limited to the correlation analysis of ion concentrations, and lack of the systematic analysis of hydrogeochemical processes that occur during the formation of groundwater. On the basis of previous discussion this paper presents the following suggestions. First, one can select suitable typical geological sections to study the formation and evolution mechanism of high arsenic and fluorine groundwater from the perspective of time and space. Second, comprehensive studies need to be conducted on the macro and micro mechanism of groundwater environmental quality. The isotope technique can be used to indicate the hydrodynamic and hydrochemical fields in groundwater system, which is helpful to get a clearer understanding of the geochemical processes occurring in the system. Lastly, hydrogeochemical simulation method can be used to identify the evolution mechanism of high arsenic groundwater in the Hetao Plain area of inner Mongolia, and further explore the formation and evolution mechanism of the hydrochemical characteristics in the groundwater in this area. This study provides new ideas for further study of the groundwater environment in the region, and is of great significance for guiding the research and improvement of the groundwater environment, and preventing the damage of arsenic to the environment and humans.
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[1] 高存荣, 刘文波, 冯翠娥, 等. 内蒙古河套平原地下咸水与高砷水分布特征[J]. 地球学报,2014,35(2):139-148. GAO C R, LIU W B, FENG C E, et al. Distribution characteristics of saline groundwater and high-arsenic groundwater in the Hetao Plain, Inner Mongolia[J]. Acta Geoscientica Sinica,2014,35(2):139-148(in Chinese).
[2] 杨会峰, 张翼龙, 孟瑞芳. 河套盆地构造控水研究及地下水系统划分[J]. 干旱区资源与环境, 2017,31(3):177-184. YANG H F, ZHANG Y L, MENG R F. Study on water-controlling mechanism of structures and dividing result of groundwater system in Hetao Basin, Inner Mongolia[J]. Journal of Arid Land Resources and Environment, 2017,31(3):177-184(in Chinese).
[3] [4] [5] YU W H, HARVEY C M, HARVEY C F. Arsenic groundwater in bangladesh:A Geostatistical and epidemiological framework for evaluating health effects and potential remedies[J]. Water Resources Research, 2003, 39(6):377-380. [6] DENG Y M, WANG Y X, MA T, et al. Isotope and minor element geochemistry of high arsenic groundwater from Hangjinhouqi, the Hetao Plain, Inner Mongolia[J]. Applied Geochemistry, 2009, 24(4):587-599. [7] 刘文波,高存荣,刘滨,等. 河套平原浅层地下水水化学成分及其相关性分析[J]. 中国地质, 2010, 37(3):816-823. LIU W B, GAO C R, LIU B, et al. Hydro-chemical constituents and correlation analysis of shallow groundwater in the Hetao Plain[J]. Geology in China, 2010, 37(3):816-823(in Chinese).
[8] 刘文波, 冯翠娥, 高存荣. 河套平原地下水环境背景值[J]. 地学前缘, 2014, 21(4):147-157. LIU W B, FENG C E, GAO C R, et al. Background value of groundwater environment in Hetao Plain[J]. Earth Science Frontiers,, 2014, 21(4):147-157(in Chinese).
[9] [10] 郭华明, 唐小惠, 杨素珍, 等. 土著微生物作用下含水层沉积物砷的释放与转化[J]. 现代地质, 2009, 23(1):86-93. GUO H M, TANG X H, YANG S Z, et al. Indigenous bacteria-mediated release and transformation of as in aquifer sediment from the Hetao Basin,Inner Mongolia[J]. Geoscience, 2009, 23(1):86-93(in Chinese).
[11] 高存荣, 冯翠娥, 刘文波, 等. 地壳表层砷的循环与污染地下水模式[J]. 地球学报, 2014, 35(6):741-750. GAO C R, FENG C E, LIU W B, et al. Patterns of arsenic cycle and groundwater arsenic contamination on the earth's surface[J]. Acta Geoscientia Sinica, 2014, 35(6):741-750(in Chinese).
[12] 高存荣, 刘文波, 冯翠娥, 等. 干旱、半干旱地区高砷地下水形成机理研究:以中国内蒙古河套平原为例[J]. 地学前缘, 2014, 21(4):13-29. GAO C R, LIU W B, FENG C E, et al. Research on the formation mechanism of high arsenic groundwater in arid and semi-arid regions:A case study of Hetao Plain in Inner Mongolia, China[J]. Earth Science Frontiers, 2014, 21(4):13-29(in Chinese).
[13] 陈瑄, 李继超. 河套灌区地下咸水环境研究[J]. 内蒙古水利, 2009,120(2):57-58. CHEN X, LI J C. Research on saline groundwater in the Hetao Plain[J]. Inner Mongolia Water Resources, 2009,120(2):57-58(in Chinese).
[14] [15] 郭华明, 倪萍, 贾永锋, 等. 内蒙古河套盆地地表水-浅层地下水化学特征及成因[J]. 现代地质, 2015,29(2):229-237. GUO H M, NI P, JIA Y F, et al. Characteristics and their causes of surface water-groundwater geochemistry in the Hetao Basin,Inner Mongolia[J]. Geoscience, 2015,29(2):229-237(in Chinese).
[16] 汪敬忠, 吴敬禄, 曾海鳌, 等. 内蒙古河套平原水体同位素及水化学特征[J]. 地球科学与环境学报, 2013, 35(4):104-112. WANG J Z, WU J L, ZENG H A, et al. Characteristics of water isotope and hydrochemistry in Hetao Plain of Inner Mongolia[J]. Journal of Earch Sciences and Environment, 2013, 35(4):104-112(in Chinese).
[17] GUO H M, YANG S Z, TANG X H, et al. Groundwater geochemistry and its implications for arsenic mobilization in shallow aquifers of the Hetao Basin, Inner Mongolia[J]. Science of the Total Environment, 2008, 393(1):131-144. [18] GUO H M, TANG X H, YANG S Z. Effect of indigenous bacteria on geochemical behavior of arsenic in aquifer sediments from the Hetao Basin, Inner Mongolia:Evidence from sediment incubations[J]. Applied Geochemistry, 2008, 23(12):3267-3277. [19] DENG Y M, WANG Y X, MA T, et al. Speciation and enrichment of arsenic in strongly reducing shallow aquifers at western Hetao Plain, northern China.[J]. Environmental Geology, 2009, 56(7):1467-1477. [20] GUO H M, ZHANG B, WANG G C, et al. Geochemical controls on arsenic and rare earth elements approximately along a groundwater flow path in the shallow aquifer of the Hetao Basin, Inner Mongolia[J]. Chemical Geology, 2010, 270(1-4):117-125. [21] GUO H M, ZHANG B, LI Y, et al. Hydrogeological and biogeochemical constrains of arsenic mobilization in shallow aquifers from the Hetao basin, Inner Mongolia[J]. Environmental Pollution, 2011, 159(4):876-883. [22] GUO H M, ZHANG B, ZHANG Y. Control of organic and iron colloids on arsenic partition and transport in high arsenic groundwaters in the Hetao basin, Inner Mongolia[J]. Applied Geochemistry, 2011, 26(3):360-370. [23] DENG Y M, WANG Y X, MA T,et al. Arsenic associations in sediments from shallow aquifers of northwestern Hetao Basin, Inner Mongolia[J]. Environmental Earth Sciences, 2011, 64(8):2001-2011. [24] 曹文庚. 河套平原典型剖面地下水砷分布规律及其影响因素研究[D]. 郑州:华北水利水电学院, 2011. CAO W G. Distribution of arsenic in groundwater and its influencing factors in typical sections of Hetao Plain[D]. Zhengzhou:North China University of Water Resources and Electric Power, 2011(in Chinese). [25] BUSBEE M W, KOCAR B D, BENNER S G. Irrigation produces elevated arsenic in the underlying groundwater of a semi-arid basin in Southwestern Idaho[J]. Applied Geochemistry, 2009, 24(5):843-859. [26] LAWSON M, BALLENTINE C J, POLYA D A, et al. The geochemical and isotopic composition of ground waters in West Bengal:Tracing ground-surface water interaction and its role in arsenic release[J]. Environmental Earth Sciences, 2016, 75(3):1-16. [27] NEUMANN R B, ASHFAQUE K N, BADRUZZAMAN A B M, et al. Anthropogenic influences on groundwater arsenic concentrations in Bangladesh[J]. Nature Geoscience, 2009, 3(1):46-52. [28] 王娟, 王圣瑞, 金相灿,等. 长江中下游浅水湖泊表层沉积物对氨氮的吸附特征[J]. 农业环境科学学报, 2007, 26(4):1224-1229. WANG J. WANG S R. JIN X C, et al. Ammonium adsorption char acter istics onto the sediments from shallow lakes in the middle and lower reaches of the Yangtze River[J]. Journal of Agro-Environment Science, 2007, 26(4):1224-1229.(in Chinese).
[29] GONG Z, LU X, WATT C, et al. Speciation analysis of arsenic in groundwater from Inner Mongolia with an emphasis on acid-leachable particulate arsenic[J]. Analytica Chimica Acta, 2006, 555(1):181-187. [30] JIA Y F, GUO H M, JIANG Y X, et al. Hydrogeochemical zonation and its implication for arsenic mobilization in deep groundwaters near alluvial fans in the Hetao Basin, Inner Mongolia[J]. Journal of Hydrology, 2014, 518:410-420. [31] 张翼龙, 曹文庚, 于娟,等. 河套地区典型剖面下地下水砷分布及地质环境特征研究[J]. 干旱区资源与环境, 2010, 24(12):167-171. ZHANG Y L, CAO W G YU J, et al. The geological environment characteristics and distribution of groundwater arsenic in the typical section of Hetao Plain[J]. Journal of Arid Land Resources and Environment, 2010, 24(12):167-171(in Chinese).
[32] 张翼龙, 曹文庚, 于娟,等. 河套平原五原地区地下水Fe-As-H2O体系中砷的吸附释放趋势[J]. 地学前缘, 2010,17(6):67-71. ZHANG Y L, CAO W G YU J, et al. A study of arsenic adsorption and release in Fe-As-H2O system in Wuyuan County, Hetao Plain[J]. Earth Science Frontiers, 2010,17(6):67-71(in Chinese).
[33] GUO H M, LIU C, LU H, et al. Pathways of coupled arsenic and iron cycling in high arsenic groundwater of the Hetao basin, Inner Mongolia, China:An iron isotope approach[J]. Geochimica et Cosmochimica Acta, 2013, 112(Complete):130-145. [34] 汤洁, 林年丰, 卞建民, 等. 内蒙河套平原砷中毒病区砷的环境地球化学研究[J]. 水文地质工程地质, 1996, 23(1):49-54. TANG J, LIN N F, BIAN J M. Environmental geochemistry of arsenic in arsenic poisoning areas of Hetao Plain, Inner Mongolia[J]. Hydrogeology and Engineering Geology, 1996, 23(1):49-54(in Chinese).
[35] 林年丰, 汤洁, 卞建民. 内蒙古砷中毒病区环境地球化学特征研究[J]. 世界地质, 1999,18(2):83-88. LIN N F, TANG J, BIAN J M. The study on environmental Geo-chemical characteristics in arseniasis area in the Inner Mongolia[J]. World Geology, 1999, 18(2):83-88(in Chinese).
[36] 姚心. 硫酸盐废水生物处理强化机理及BP神经网络模型模拟[D]. 天津:天津大学, 2008. YAO X. Strengthening mechanism of biological treatment of sulfate wastewater and Simulation of BP neural network[D]. Tianjin:Tianjin University, 2008(in Chinese). [37] JIANG Y, GUO H, JIA Y, et al. Principal component analysis and hierarchical cluster analyses of arsenic groundwater geochemistry in the Hetao basin, Inner Mongolia[J]. Chemie der Erde - Geochemistry, 2015, 75(2):197-205. [38] 张迪, 郭华明, 倪萍, 等. 氧化还原条件对地下水中砷释放迁移的影响——以通榆县高砷地下水为例[J]. 第四纪研究, 2014,34(5):1072-1081. ZHANG D,GUO H M,NI P, et al. Effect of redox conditions on arsenic release and transport in groundwater systems:A case study in the tongyu county[J]. Quaternary Sciences, 2014,34(5):1072-1081.(in Chinese).
[39] 周殷竹, 郭华明, 逯海.高砷地下水中溶解性有机碳和无机碳稳定同位素特征[J]. 现代地质, 2015,29(2):252-259. ZHOU Y Z, GUO H M,LU H,Stable isotope characteristics of dissolved organic carbon and inorganic carbon in high arsenic groundwater[J]. Geoscience, 2015,29(2):252-259(in Chinese).
[40] 王岩, 吴佳鹏, 关凤杰, 等. 有机物消耗对珠江口沉积物反硝化和厌氧氨氧化过程的影响[J]. 生态科学, 2018, 37(1):27-34. WANG Y,WU J P,GUAN F J, et al. Controls of organic matters on denitrification and anammox in sediments of Pearl River Estuary by mesocosm experiments[J]. Ecological Science, 2018, 37(1):27-34(in Chinese).
[41] [42] GUO H M, ZHANG B, YANG S Z, et al. Role of colloidal particles for hydrogeochemistry in as-affected aquifers of the Hetao Basin, Inner Mongolia[J]. Geochemical Journal, 2009, 43(4):227-234. [43] TONG J T, GUO H M, WEI C. Arsenic contamination of the soil-wheat system irrigated with high arsenic groundwater in the Hetao Basin, Inner Mongolia, China[J]. Science of the Total Environment, 2014, 496:479-487. [44] 金阳, 姜月华, 李云. 地下水砷污染研究进展[J]. 地下水, 2015, 37(1):67-69. JIN Y,JIANG Y H,LI Y. Research Progress of Arsenic Contamination in Groundwater[J]. Underground Water, 2015, 37(1):67-69(in Chinese).
[45] 冯翠娥, 高存荣, 王俊涛,等. 内蒙古河套平原浅层高铁高氟地下水分布与成因[J]. 地球学报, 2015, 36(1):67-76. FENG C E, GAO C R, WANG J T, et al. Distribution and causes of high-iron and high-fluoride shallow groundwater in the Hetao Plain of Inner Mongolia[J]. Acta Geoscientia Sinica, 2015, 36(1):67-76(in Chinese).
[46] 王妍妍, 马腾, 董一慧,等. 内陆盆地区高碘地下水的成因分析:以内蒙古河套平原杭锦后旗为例[J]. 地学前缘, 2014, 21(4):66-73. WANG Y Y, MA T, DONG Y H, et al. The formation of inland-high-iodine groundwater:A case study in Hangjinhouqi, Hetao Plain[J]. Earth Science Frontiers, 2014, 21(4):66-73(in Chinese).
[47] 徐芬, 马腾, 石柳, 等. 内蒙古河套平原高碘地下水的水文地球化学特征[J]. 水文地质工程地质, 2012, 39(5):8-15. XU F, MA T, SHI L, et al.Hydrogeochemical characteristics of high iodine groundwater in the Hetao Plain, Inner Mongolia[J]. Hydrogeology and Engineering Geology, 2012, 39(5):8-15(in Chinese).
[48] 何薪, 马腾, 王焰新,等. 内蒙古河套平原高砷地下水赋存环境特征[J]. 中国地质, 2010, 37(3):781-788. HE X,MA T, WANG Y X, et al. Geochemical characteristics of the As-bearing aquifer in the Hetao plain, Inner Mongolia[J]. Geology in China, 2010, 37(3):781-788(in Chinese).
[49] 毛若愚, 郭华明, 贾永锋, 等. 内蒙古河套盆地含氟地下水分布特点及成因[J]. 地学前缘, 2016, 23(2):260-268. MAO R Y,GUO H M,JIA Y L, et al. Distribution characteristics and genesis of fluoride groundwater in the Hetao basin, Inner Mongolia[J]. Earth Science Frontiers, 2016, 23(2):260-268(in Chinese).
[50] [51] 岳勇, 郝芳华, 马桂芬. 内蒙古河套灌区地下水矿化度的时空变异特征[J]. 环境与发展, 2009, 21(4):87-90. QIU Y, HAO F H, MA G F. The characteristics of mineralization space-time variation of underground water in Hetao Irrigation Area of Inner Mongolia[J]. Inner Mongolia Environmental Sciences, 2009, 21(4):87-90(in Chinese).
[52] 高晶, 郝爱兵, 魏亚杰,等. 河套平原中东部地下水的环境同位素特征分析[J]. 水文地质工程地质, 2009, 36(3):55-58. GAO J, HAO A B, WEI Y J, et al. Interpretation of the environmental isotopes of groundwater in the middle-eastern part of the Hetao Plain[J]. Hydrogeology And Engineering Geology, 2009, 36(3):55-58(in Chinese).
[53] 佟俊婷, 韦超, 郭华明. 内蒙古自治区河套平原砷中毒高发区作物中砷的检测及健康风险评价[J]. 生态毒理学报, 2013, 8(3):426-434. TONG J T,WEI C,GUO H M. Detection and health risk of arsenic species in crops from arsenic-affected areas of Hetao Plain, Inner Mongolia[J]. Asian Journal of Ecotoxicology, 2013, 8(3):426-434(in Chinese).
[54] 李彬, 史海滨, 张建国,等.节水改造前后内蒙古河套灌区地下水水化学特征[J]. 农业工程学报, 2014,30(21):99-110. LI B, SHI H B, ZHANG J G, et al. Hydrochemical characteristics of groundwater before and after water-saving reform in Hetao Irrigation District, Inner Mongolia[J]. Transactions of the Chinese Society of Agricultural Engineering, 2014,30(21):99-110(in Chinese).
[55] 郭娇, 王伟, 叶浩, 等. 河套平原盐渍化土地时空动态变化及影响因子[J]. 南水北调与水利科技, 2014, 12(3):59-64. GUO J, WANG W,YE H, et al. Analysis on spatial and temporal dynamic variations and their impact factors of salinization land in Hetao Plain[J]. South-to-North Water Transfers and Water Science & Technology, 2014, 12(3):59-64(in Chinese).
[56] 邵景力, 徐映雪, 崔亚莉, 等. 变异条件下内蒙古呼包平原地下水演化趋势[J]. 现代地质, 2006,20(3):480-485. SHAO J L, XU Y X,CUI Y L, et al. Study on groundwater change on the aberrance condition in Hubao Plain, Inner Mongolia, China[J]. Geoscience,2006,20(3):480-485(in Chinese).
[57] 徐映雪, 邵景力, 崔亚莉, 等. 连续特枯年份下呼包平原水资源短缺的对策研究[J]. 水文地质工程地质, 2007, 34(3):46-50. XU Y X, SHAO J L, CUI Y L, et al. Countermeasures for water resources shortage in continuous drought years in the Hubao Plain[J]. Hydrogeology & Engineering Geology, 2007,34(3):46-50(in Chinese).
[58] 卢继红. 内蒙河套灌区咸水灌溉方案研究[D]. 武汉:武汉大学, 2005. LU J H. Research on saline-water irrigation scenarios in Hetao Irrigation District[D]. Wuhan:Wuhan University, 2005(in Chinese). [59] 丁雪华, 朝伦巴根. 基于Visual MODFLOW模型的三湖灌域地下水资源评价[J]. 灌溉排水学报, 2007, 26(3):93-96. DING X H, ZHAO L B G. Evaluation of groundwater resources based on Visual MODFLOW model in Sanhu irrigation district[J]. Journal of Irrigation And Drainage, 2007, 26(3):93-96(in Chinese).
[60] 白忠, 徐旭. 河套灌区解放闸灌域地下水数值模拟[J]. 节水灌溉, 2008(2):28-31, 35. BAI Z, XU X. Numerical simulation of the groundwater and salt dynamics in Jiefangzha irrigation scheme of Hetao Irrigation District[J]. Water Saving Irrigation, 2008(2):28-31, 35(in Chinese).
[61] 卢丽, 王喆, 裴建国, 等. 节水规划方案下后套平原环境问题评价[J]. 人民黄河, 2012, 34(10):69-71. LU L, WANG Z, PEI J G, et al. Evaluation of the environmental problems in the Houtao Plain based on water saving plan[J]. Yellow River, 2012, 34(10):69-71(in Chinese).
[62] [63] 王喜宽, 黄增芳, 苏美霞,等. 河套地区土壤基准值及背景值特征[J]. 岩矿测试, 2007, 26(4):287-292. WANG X K, HUANG Z F, SU M X, et al. Characteristics of reference and background values of soils in Hetao Area[J]. Rock And Mineral Analysis, 2007, 26(4):287-292(in Chinese).
[64] 汪敬忠, 吴敬禄, 曾海鳌, 等. 河套平原表层土壤元素含量与空间分布特征[J]. 沉积学报, 2014,32(4):677-683. WANG J Z, WU J L, ZENG H A, et al, Topsoil element contents and its spatial distribution characteristics in Hetao Plain[J]. Acta Sedimentologica Sinica, 2014,32(4):677-683(in Chinese).
[65] 郝芳华,孙铭泽,张璇, 等.河套灌区土壤水和地下水动态变化及水平衡研究[J].环境科学学报,2013,33(3):771-779. HAO F H, SUN M Z, ZHANG X, et al. Dynamic of soil water, groundwater and water balance in Hetao irrigation area[J]. Acta Scientiae Circumstantiae, 2013, 33(3):771-779(in Chinese).
[66] 赵威光, 郭华明, 张莉,等. 河套平原沉积物中铀的赋存形态及其与地下水铀浓度的关系[J]. 水文地质工程地质, 2015, 42(2):24-30. ZHAO W G,GUO H M, ZHANG L, et al. Uranium forms in sediments and their relation with groundwater uranium:A case study in the Hetao basin[J]. Hydrogeology and Engineering Geology, 2015, 42(2):24-30(in Chinese).
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