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原油和燃料油多环芳烃特征组分差异性分析

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鲁英, 马启敏, 丁慧平. 原油和燃料油多环芳烃特征组分差异性分析[J]. 环境化学, 2020, (2): 542-551. doi: 10.7524/j.issn.0254-6108.2019031901
引用本文: 鲁英, 马启敏, 丁慧平. 原油和燃料油多环芳烃特征组分差异性分析[J]. 环境化学, 2020, (2): 542-551. doi: 10.7524/j.issn.0254-6108.2019031901
shu
LU Ying, MA Qimin, DING Huiping. Analysis on the differences of characteristic components of polycyclic aromatic hydrocarbons between crude oil and fuel oil[J]. Environmental Chemistry, 2020, (2): 542-551. doi: 10.7524/j.issn.0254-6108.2019031901
Citation: LU Ying, MA Qimin, DING Huiping. Analysis on the differences of characteristic components of polycyclic aromatic hydrocarbons between crude oil and fuel oil[J]. Environmental Chemistry, 2020, (2): 542-551. doi: 10.7524/j.issn.0254-6108.2019031901
shu

原油和燃料油多环芳烃特征组分差异性分析

  • 中国海洋大学, 环境科学与工程学院, 青岛, 266100

    • 通讯作者: 鲁英, E-mail: 1294746412@qq.com ; 

Analysis on the differences of characteristic components of polycyclic aromatic hydrocarbons between crude oil and fuel oil

  • College of Environmental Science and Engineering, Ocean University of China, Qingdao, 266100, China

    • Corresponding author: LU Ying, 1294746412@qq.com ; 

  • 摘要: 本文采用气相色谱/质谱方法（GC-MS），并结合文献数据，分析研究了未风化或风化程度很小的原油和燃料油多环芳烃（PAHs）不同系列组分相对含量的差异性.结果表明，原油萘系列化合物相对含量明显高于燃料油，菲系列和系列化合物相对含量明显低于燃料油，二苯并噻吩和芴系列化合物相对含量无明显差异性.油品萘系列化合物相对含量高于57.0%时，油品可能为原油，含量低于48.9%时，油品可能为燃料油；菲系列化合物相对含量小于21.7%时，油品可能为原油，含量大于22.6%时，油品可能为燃料油；系列化合物相对含量大于5.4%时，油品可能为燃料油.基于16种多环芳烃，原油中苯并蒽和蒽的相对含量低于燃料油，油品中蒽的相对含量大于3.8%，油品可能为燃料油，油品中苯并蒽的相对含量大于5.9%时，油品可能为燃料油.
    Abstract: In this paper,gas chromatography/mass spectrometry(GC-MS) is used to analyze the relative content of different components of crude oil and fuel oil polycyclic aromatic hydrocarbons(PAHs) with little weathering or weathering in combination with literature data. The results show that the relative content of crude naphthalene series compounds is significantly higher than that of fuel oil. The relative content of phenanthrene series and chrysene series compounds is lower than that of fuel oil. The relative content of dibenzothiophene and the fluorene series components are not significantly different. When the relative content of the naphthalene component of the oil naphthalene series is higher than 57.0%, the oil may be crude oil, and when the content is less than 48.9%, the oil may be fuel oil; When the relative content of phenanthrene series is less than 21.7%, the oil may be crude oil. When the content is more than 22.6%, the oil may be fuel oil; when the relative content of chrysene series component is more than 5.4%, the oil may be fuel oil. Based on 16 polycyclic aromatic hydrocarbons, the relative content of benz(a)anthracene and anthracene in crude oil is lower than that of fuel oil. The relative content of anthracene in the oil is more than 3.8%. The oil may be fuel oil. When the relative content of benz(a)anthracene in the oil is more than 5.9%, the oil may be fuel oil.
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  • [1] 韩彬, 郑立, 宋转玲,等. 渤海相近石油平台原油指纹鉴别规律初探[J]. 环境化学, 2012, 31(2):195-201.

    HAN B, ZHENG L, SONG Z L, et al. Preliminary study on fingerprint identification of crude oil in similar oil platforms in bohai sea[J]. Environmental Chemistry, 2012, 31(2):195-201(in Chinese).

    [2] 孙培艳, 周青, 李光梅,等. 原油中多环芳烃内标法指纹分析[J]. 分析测试学报, 2008, 27(4):344-348.

    SUN P Y, ZHOU Q, LI G M, et al. Fingerprint analysis of polycyclic aromatic hydrocarbons in crude oil by internal standard method[J]. Journal of Analytical Testing, 2008, 27(4):344-348(in Chinese).

    [3] 高振会, 崔文林, 周青,等. 渤海海上原油油指纹库建设[J]. 海洋环境科学, 2006, 25(zl):1-5. GAO Z H, CUI W L, ZHOU Q, et al. Construction of fingerprint oil library of Bohai Sea crude oil[J]. Marine Environmental Science, 2006

    , 25(zl):1-5(in Chinese).

    [4] 丁慧平, 马启敏, 任建新,等. 舟山海域表层海水正构烷烃、甾萜烷特征参数研究[J]. 海洋环境科学, 2018, 37(2):239-244.

    DING H P, MA Q M, REN J X, et al. Study on the characteristic parameters of n-alkanes steroidal terpenes in surface waters of Zhoushan Sea area[J]. Marine Environmental Science, 2018, 37(2):239-244(in Chinese).

    [5] WANG Z D, FINGAS M, SIGOUIN L. Characterization and identification of a "mystery" oil spill from Quebec (1999)[J]. Journal of Chromatography A, 2001, 909(2):155-169.
    [6] ZAKARIA M P, OKUDA T, TAKADA H. Polycyclic aromatic hydrocarbon (PAHs) and hopanes in stranded tar-balls on the coasts of peninsular malaysia:Applications of biomarkers for identifying sources of oil pollution[J]. Marine Pollution Bulletin, 2002, 42(12):1357-1366.
    [7] LIU X, WANG Z, MA X, et al. Distinguishing crude oils from heavy fuel oils by polycyclic aromatic hydrocarbon fingerprints[J]. Environmental Forensics, 2013, 14(1):20-24.
    [8] ZHANG H, WANG C, ZHAO R, et al. New diagnostic ratios based on phenanthrenes and anthracenes for effective distinguishing heavy fuel oils from crude oils[J]. Marine Pollution Bulletin, 2016, 106(1-2):58-61.
    [9] 满庆祥, 孙延伟, 张颖焱,等. 进口原油与燃料油快速鉴别方法探讨[J]. 化学分析计量, 2008, 17(4):74-75.

    MAN Q X, SUN Y W, ZHANG Y Y, et al. Discussion on rapid identification method of imported crude oil and fuel oil[J]. Chemical Analysis, 2008, 17(4):74-75(in Chinese).

    [10] 倪张林, 马启敏, 程海鸥. 重质燃料油中主要芳烃在自然条件下的风化规律[J]. 油气田环境保护, 2007, 17(4):37-39.

    NI Z L, MA Q M, CHENG H O. Weathering law of main aromatic hydrocarbons in heavy fuel oil under natural conditions[J]. Oil and Gas Field Environmental Protection, 2007, 17(4):37-39(in Chinese).

    [11] 赵玉慧, 孙培艳, 王鑫平,等. 多环芳烃指纹用于渤海采油平台原油的鉴别[J]. 色谱, 2008, 26(1):43-49.

    ZHAO Y H, SUN P Y, WANG X P, et al. Polycyclic aromatic hydrocarbon fingerprints for identification of crude oil in bohai oil production platform[J]. Chromatography, 2008, 26(1):43-49(in Chinese).

    [12] 刘星, 王震, 马新东,等. 原油与重质燃料油中多环芳烃分布特征及主成分分析[C]. 海上污染防治及应急技术研讨会, 2009. LIU X, WANG Z, MA X D, et al. Distribution characteristics and principal component analysis of polycyclic aromatic hydrocarbons in crude oil and heavy fuel oil[C]. Marine Pollution Prevention and Emergency Technology Seminar, 2009(in Chinese).
    [13] WANG Z D, HOLLEBONE B P, FINGAS M, et al. Characteristics of spilled oils, fuels, and petroleum products:1. Composition and properties of selected oils[M]. United States Enviromental Protection Agency, 2003.
    [14]
    [15] 林法祥, 郑立. 原油及石油炼制品指纹特征差异性研究[J]. 环境化学, 2018, 37(1):51-59.

    LIN F X, ZHENG L. Study on the differences of fingerprint characteristics of crude oil and petroleum refinery[J]. Environmental Chemistry, 2018, 37(1):51-59(in Chinese).

    [16] 王德高, 杨萌, 贾宏亮,等. 原油及油制品中多环芳烃化学指纹的分布规律研究[J]. 环境污染与防治, 2008, 30(11):62-65.

    WANG D G, YANG M, JIA H L, et al. Study on distribution law of chemical fingerprints of polycyclic aromatic hydrocarbons in crude oil and oil products[J]. Environmental Pollution and Prevention, 2008, 30(11):62-65(in Chinese).

    [17] WANG Z D, FINGAS M. Identification of the source(s) of unknown spilled oils[J]. Environment Canada Arctic & Marine Oil Spill Program Technical Seminar (AMOP) Proceedings, 1999, 1999(1):69-106.
    [18] SHI S B, WANG T G, LI M. Identification and distribution of chrysene, methylchrysenes and their isomers in crude oils and rock extracts[J]. Organic Geochemistry, 2012, 52:55-66.
    [19] EZRA S, FEINSTEIN S, PELLY I, et al. Weathering of fuel oil spill on the east Mediterranean coast, Ashdod, Israel[J]. Organic Geochemistry, 2000, 31(12):1733-1741.
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  • 收稿日期:  2019-03-19
鲁英, 马启敏, 丁慧平. 原油和燃料油多环芳烃特征组分差异性分析[J]. 环境化学, 2020, (2): 542-551. doi: 10.7524/j.issn.0254-6108.2019031901
引用本文: 鲁英, 马启敏, 丁慧平. 原油和燃料油多环芳烃特征组分差异性分析[J]. 环境化学, 2020, (2): 542-551. doi: 10.7524/j.issn.0254-6108.2019031901
shu
LU Ying, MA Qimin, DING Huiping. Analysis on the differences of characteristic components of polycyclic aromatic hydrocarbons between crude oil and fuel oil[J]. Environmental Chemistry, 2020, (2): 542-551. doi: 10.7524/j.issn.0254-6108.2019031901
Citation: LU Ying, MA Qimin, DING Huiping. Analysis on the differences of characteristic components of polycyclic aromatic hydrocarbons between crude oil and fuel oil[J]. Environmental Chemistry, 2020, (2): 542-551. doi: 10.7524/j.issn.0254-6108.2019031901
shu

原油和燃料油多环芳烃特征组分差异性分析

    通讯作者: 鲁英, E-mail: 1294746412@qq.com ; 
  • 中国海洋大学, 环境科学与工程学院, 青岛, 266100
  • 收稿日期:  2019-03-19
  • 网络出版日期:  2020-02-26

摘要: 本文采用气相色谱/质谱方法（GC-MS），并结合文献数据，分析研究了未风化或风化程度很小的原油和燃料油多环芳烃（PAHs）不同系列组分相对含量的差异性.结果表明，原油萘系列化合物相对含量明显高于燃料油，菲系列和系列化合物相对含量明显低于燃料油，二苯并噻吩和芴系列化合物相对含量无明显差异性.油品萘系列化合物相对含量高于57.0%时，油品可能为原油，含量低于48.9%时，油品可能为燃料油；菲系列化合物相对含量小于21.7%时，油品可能为原油，含量大于22.6%时，油品可能为燃料油；系列化合物相对含量大于5.4%时，油品可能为燃料油.基于16种多环芳烃，原油中苯并蒽和蒽的相对含量低于燃料油，油品中蒽的相对含量大于3.8%，油品可能为燃料油，油品中苯并蒽的相对含量大于5.9%时，油品可能为燃料油.

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