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基于两种前处理对苹果叶片中虫酰肼残留的液相分析方法

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寇弘儒, 刘士峰, 孙艳超, 杨柳, 王进忠, 张志勇. 基于两种前处理对苹果叶片中虫酰肼残留的液相分析方法[J]. 环境化学, 2020, (1): 179-187. doi: 10.7524/j.issn.0254-6108.2019061201
引用本文: 寇弘儒, 刘士峰, 孙艳超, 杨柳, 王进忠, 张志勇. 基于两种前处理对苹果叶片中虫酰肼残留的液相分析方法[J]. 环境化学, 2020, (1): 179-187. doi: 10.7524/j.issn.0254-6108.2019061201
shu
KOU Hongru, LIU Shifeng, SUN Yanchao, YANG Liu, WANG Jinzhong, ZHANG Zhiyong. Liquid phase analysis of tebufenozide residues in apple leaves based on two pretreatments[J]. Environmental Chemistry, 2020, (1): 179-187. doi: 10.7524/j.issn.0254-6108.2019061201
Citation: KOU Hongru, LIU Shifeng, SUN Yanchao, YANG Liu, WANG Jinzhong, ZHANG Zhiyong. Liquid phase analysis of tebufenozide residues in apple leaves based on two pretreatments[J]. Environmental Chemistry, 2020, (1): 179-187. doi: 10.7524/j.issn.0254-6108.2019061201
shu

基于两种前处理对苹果叶片中虫酰肼残留的液相分析方法

  • 农业应用新技术北京市重点实验室, 北京, 102206

    • 通讯作者: 张志勇, E-mail: zzy@bua.edu.cn
  • 基金项目:

    国家重点研发计划课题（2017YFD0200307）和北京市科技创新服务能力建设-高精尖学科建设项目（PXM2019_014207_000032）资助.

Liquid phase analysis of tebufenozide residues in apple leaves based on two pretreatments

  • Beijing Key Laboratory of New Technology in Agricultural Application, Beijing, 102206, China

    • Corresponding author: ZHANG Zhiyong, zzy@bua.edu.cn
  • Fund Project: Supported by the National Key R&D Program of China (2017YFD0200307) and the Construction of Beijing Science and Technology Innovation and Service Capacity in Top Subjects (CEFF-PXM2019_014207_000032).

  • 摘要: 为进一步研究虫酰肼在苹果树冠层的递释规律，分别采用QuEChERS法和Florisil固相萃取法建立虫酰肼在苹果叶片上的液相分析检测方法.结果显示，QuEChERS法虫酰肼的均添加回收率为80.34%—99.20%，变异系数为5.3%—17.9%，最小检出量均为0.1 ng，最低检出质量浓度均为0.01 mg·L-1；Florisil固相萃取法虫酰肼的均添加回收率为78.45%—88.24%，变异系数为7.8%—10.9%，最小检出量均为0.1 ng，最低检出质量浓度均为0.02 mg·L-1.两种方法均满足农药残留分析的要求.
    Abstract: In order to further study the regularity of tebufenozide release in apple canopy, the liquid phase analysis method of tebufenozide on apple leaves was established by QuEChERS and Florisil solid phase extraction. The results showed that the recovery of tebufenozide with QuEChERS method was 80.34%-99.20%, the coefficient of variation was 5.3%-17.9%, the LOD was 0.1 ng, and the LOQ was 0.01 mg·L-1; the recovery of tebufenozide with Florisil solid phase extraction method was 78.45%-88.24%, the coefficient of variation was 7.8%-10.9%, the LOD was 0.1 ng, and the LOQ was 0.02 mg·L-1. Both methods could meet the requirements of pesticide residue analysis.
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  • 收稿日期:  2019-06-12
  • 刊出日期:  2020-01-01
寇弘儒, 刘士峰, 孙艳超, 杨柳, 王进忠, 张志勇. 基于两种前处理对苹果叶片中虫酰肼残留的液相分析方法[J]. 环境化学, 2020, (1): 179-187. doi: 10.7524/j.issn.0254-6108.2019061201
引用本文: 寇弘儒, 刘士峰, 孙艳超, 杨柳, 王进忠, 张志勇. 基于两种前处理对苹果叶片中虫酰肼残留的液相分析方法[J]. 环境化学, 2020, (1): 179-187. doi: 10.7524/j.issn.0254-6108.2019061201
shu
KOU Hongru, LIU Shifeng, SUN Yanchao, YANG Liu, WANG Jinzhong, ZHANG Zhiyong. Liquid phase analysis of tebufenozide residues in apple leaves based on two pretreatments[J]. Environmental Chemistry, 2020, (1): 179-187. doi: 10.7524/j.issn.0254-6108.2019061201
Citation: KOU Hongru, LIU Shifeng, SUN Yanchao, YANG Liu, WANG Jinzhong, ZHANG Zhiyong. Liquid phase analysis of tebufenozide residues in apple leaves based on two pretreatments[J]. Environmental Chemistry, 2020, (1): 179-187. doi: 10.7524/j.issn.0254-6108.2019061201
shu

基于两种前处理对苹果叶片中虫酰肼残留的液相分析方法

    通讯作者: 张志勇, E-mail: zzy@bua.edu.cn
  • 农业应用新技术北京市重点实验室, 北京, 102206
  • 收稿日期:  2019-06-12
  • 网络出版日期:  2020-01-01
基金项目:

国家重点研发计划课题（2017YFD0200307）和北京市科技创新服务能力建设-高精尖学科建设项目（PXM2019_014207_000032）资助.

摘要: 为进一步研究虫酰肼在苹果树冠层的递释规律，分别采用QuEChERS法和Florisil固相萃取法建立虫酰肼在苹果叶片上的液相分析检测方法.结果显示，QuEChERS法虫酰肼的均添加回收率为80.34%—99.20%，变异系数为5.3%—17.9%，最小检出量均为0.1 ng，最低检出质量浓度均为0.01 mg·L-1；Florisil固相萃取法虫酰肼的均添加回收率为78.45%—88.24%，变异系数为7.8%—10.9%，最小检出量均为0.1 ng，最低检出质量浓度均为0.02 mg·L-1.两种方法均满足农药残留分析的要求.

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