氯/溴稳定同位素分析技术及其在环境科学研究中的应用
Techniques for stable chlorine/bromine isotope analysis and recent applications in environmental research
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摘要: 稳定同位素分析被认为是环境污染物溯源和转化途径探究的有效工具.针对氯/溴稳定同位素研究已经开发了一些较为可靠的分析技术,被广泛应用于氯乙烯、氯苯、溴酚、多溴二苯醚和有机氯农药等有机污染物的研究.本文综述了近年来氯/溴同位素分析技术的最新进展,介绍了稳定同位素分析技术在含氯/溴有机污染物的溯源分析和降解途径识别等方面的应用实例,分析了现有分析技术在仪器测定、分析策略、理论知识等方面的不足,展望了该技术的发展方向及其在环境科学领域内的应用前景.Abstract: Stable isotope analysis is an effective tool to characterize sources and transformation processes of environmental pollutants. A variety of reliable techniques have been developed for stable chlorine/bromine isotope analysis, which were applied in various organic pollutants, such as chlorinated ethenes, chlorobenzene, bromophenols, polybrominated diphenyl ethers and organic chlorinated pesticides. This paper reviewed the technologies for stable chlorine/bromine isotope analysis in recent years. The applications of those techniques to trace the sources of organic pollutants and identify the degradation pathways of organic pollutants were introduced. The problems of stable chlorine/bromine isotope analysis technologies in instrumental methods, analysis strategies, and theoretical knowledge were discussed, and their development and applications in the field of environmental science were prospected as well.
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Key words:
- chlorine /
- bromine /
- stable isotope analysis /
- organic pollutants
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