堆肥+零价铁可渗透反应墙修复黄土高原地下水中铬铅复合污染

李雅, 张增强, 沈锋, 汪葵. 堆肥+零价铁可渗透反应墙修复黄土高原地下水中铬铅复合污染[J]. 环境工程学报, 2014, 8(1): 110-115.
引用本文: 李雅, 张增强, 沈锋, 汪葵. 堆肥+零价铁可渗透反应墙修复黄土高原地下水中铬铅复合污染[J]. 环境工程学报, 2014, 8(1): 110-115.
Li Ya, Zhang Zengqiang, Shen Feng, Wang Kui. Remediation of Cr-Pb polluted groundwater using a mixed zero-valent iron-compost permeable reactive barrier in Loess Plateau aera[J]. Chinese Journal of Environmental Engineering, 2014, 8(1): 110-115.
Citation: Li Ya, Zhang Zengqiang, Shen Feng, Wang Kui. Remediation of Cr-Pb polluted groundwater using a mixed zero-valent iron-compost permeable reactive barrier in Loess Plateau aera[J]. Chinese Journal of Environmental Engineering, 2014, 8(1): 110-115.

堆肥+零价铁可渗透反应墙修复黄土高原地下水中铬铅复合污染

  • 基金项目:

    陕西省科技攻关项目(2010k01-01)

    西安航空学院校级研究课题(12XQ306)

    江西省科技支撑计划项目(20132-BBG70026)

  • 中图分类号: X523

Remediation of Cr-Pb polluted groundwater using a mixed zero-valent iron-compost permeable reactive barrier in Loess Plateau aera

  • Fund Project:
  • 摘要: 为了研究堆肥+零价铁混合可渗透反应墙(PRB)修复黄土高原地下水中铬铅复合污染的可行性,分别用堆肥、零价铁、堆肥+ 零价铁、堆肥+ 零价铁+活性炭为反应介质,通过模拟柱实验考察PRB修复铬铅复合污染黄土高原地下水的效果。结果表明,在实验进行30 d后当反应柱1和2对六价铬的去除率接近于零,而且对二价铅的去除率迅速下降时,反应柱3对2种污染物仍保持较高的去除率;反应介质质量比为10:2:1的反应柱4和质量比为10:1:2的反应柱5对污染物的去除效果均优于质量比为10:1:1的反应柱3;反应50 d后,添加活性炭的反应柱6对2种污染物的去除率仍在90%。这说明使用堆肥+零价铁混合可渗透反应墙修复黄土高原地下水中铬铅复合污染是可行的;且以堆肥+零价铁作为介质的反应柱去除效果优于单独以堆肥或铁粉为介质的反应柱;增加铁粉或堆肥的用量有利于铬铅复合污染的去除;且同时添加活性炭更有助于污染物的去除。
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  • [1] 彭利群, 张澄博, 李洪艺, 等. 介质材料在可渗透反应墙中的应用进展. 环境科学与管理, 2011, 36(10): 47-52 Peng Liqun,Zhang Chengbo,Li Hongyi,et al. Application progress of reactive media materials in permeable reactive barrier.Environmental Science and Management, 2011, 36(10): 47-52 (in Chinese)
    [2] Phillips D. H., Nooten T. V., Bastiaens L., et al. Ten year performance evaluation of a field-scale zero-valent iron permeable reactive barrier installed to remediate trichloroethene contaminated groundwater. Environ. Sci. Technol., 2010, 44 (10): 3861-3869
    [3] Moraci N., Calabrò P. S. Heavy metals removal and hydraulic performance in zero-valent iron/pumice permeablereactive barriers.Journal of Environmental Management,2010, 91(10): 2336-2341
    [4] 骆其金, 谌建宇, 许振成, 等. 适用于污染河水修复的可渗透反应墙材料筛选. 水处理技术, 2010,36(3):55-58 Luo Qijin, Chen Jianyu, Xu Zhencheng, et al. Screening of there active media of the permeable reactive barriers(PRB) for remediation of polluted river water. Technology of Water Treatment, 2010, 36(3):55-58 (in Chinese)
    [5] 熊玲, 张瑞雪, 吴攀, 等. 碳酸盐岩处理煤矿酸性废水的试验研究. 水处理技术, 2010, 36(8):45-48 Xiong Ling, Zhang Ruixue, Wu Pan, et al. Experimental study on acid coal mine drainage treatment with carbonate. Technology of Water Treatment, 2010, 36(8):45-48 (in Chinese)
    [6] Walker D. J., Bernal M. P. The effects of olive mill waste compost and poultry manure on the availability and plant uptake of nutrients in a highly saline soil. Bioresource Technology, 2008, 99(2): 396-403
    [7] Brown S. L., Chaney R. L., Angle J. S., et al. Phyto remediation potential of thlaspicaerulescens and bladder campion for zinc and cadmium contaminated soil. Journal of Environmental Quality, 1994, 23(6): 1151-1157
    [8] 范建军,张华,谢震震.堆肥在土壤生物修复和污染控制中的应用. 环境卫生工程, 2005, 13(3): 46-49 Fan Jianjun, Zhang Hua, Xie Zhenzhen. Use of compost in bioremediation and pollution prevention. Enviromental Sanitation Engineering, 2005,13 (3):46-49 (in Chinese)
    [9] Martin A. J., Jones K. D., Ren Jianhong,et al. Compost product optimization for surface water nitrate treatment in biofiltration applications. Bioresource Technology, 2009, 100(17): 3991-3996
    [10] Fordham W. Yard trimmings composting in the air force. Biocycle, 1995, 36 (1): 36-44
    [11] Ergas S. J., Schroeder E. D., Chang D. P. Y., et al. Control of volatile organic compound emissions using a compost biofilter. Water Environment Research, 1995, 679(5): 816-821
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    [13] Ludwig R. D., Smyth D. J. A., Blowes D. W., et al.Treatment of arsenic, heavy metals, and acidity using mixed ZVI-compost PRB. Environ. Sci. Technol., 2009, 43 (6):1970-1976
    [14] 李雅, 张增强, 邵淼. 堆肥-零价铁混合PRB处理铬污染地下水. 农业机械学报, 2010, 41(9): 110-113 Li Ya, Zhang Zengqiang, Shao Miao. Treatment of Cr-polluted groundwater using a mixed ZVI-compost PRB. Transactions of the Chinese society for Agricultutal Machinery, 2010, 41(9): 110-113 (in Chinese)
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    [17] Dickinson M., Scott T. B. The application of zero-valent iron nanoparticles for the remediation of a uranium-contaminated waste effluent. Journal of Hazardous Materials, 2010, 178(1-3): 171-179
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出版历程
  • 收稿日期:  2013-01-08
  • 刊出日期:  2014-01-03
李雅, 张增强, 沈锋, 汪葵. 堆肥+零价铁可渗透反应墙修复黄土高原地下水中铬铅复合污染[J]. 环境工程学报, 2014, 8(1): 110-115.
引用本文: 李雅, 张增强, 沈锋, 汪葵. 堆肥+零价铁可渗透反应墙修复黄土高原地下水中铬铅复合污染[J]. 环境工程学报, 2014, 8(1): 110-115.
Li Ya, Zhang Zengqiang, Shen Feng, Wang Kui. Remediation of Cr-Pb polluted groundwater using a mixed zero-valent iron-compost permeable reactive barrier in Loess Plateau aera[J]. Chinese Journal of Environmental Engineering, 2014, 8(1): 110-115.
Citation: Li Ya, Zhang Zengqiang, Shen Feng, Wang Kui. Remediation of Cr-Pb polluted groundwater using a mixed zero-valent iron-compost permeable reactive barrier in Loess Plateau aera[J]. Chinese Journal of Environmental Engineering, 2014, 8(1): 110-115.

堆肥+零价铁可渗透反应墙修复黄土高原地下水中铬铅复合污染

  • 1.  西北农林科技大学资源环境学院, 杨凌 712100
  • 2.  西安航空学院动力工程系, 西安 710077
  • 3.  江西环境工程职业学院林业与环境学院, 赣州 341000
基金项目:

陕西省科技攻关项目(2010k01-01)

西安航空学院校级研究课题(12XQ306)

江西省科技支撑计划项目(20132-BBG70026)

摘要: 为了研究堆肥+零价铁混合可渗透反应墙(PRB)修复黄土高原地下水中铬铅复合污染的可行性,分别用堆肥、零价铁、堆肥+ 零价铁、堆肥+ 零价铁+活性炭为反应介质,通过模拟柱实验考察PRB修复铬铅复合污染黄土高原地下水的效果。结果表明,在实验进行30 d后当反应柱1和2对六价铬的去除率接近于零,而且对二价铅的去除率迅速下降时,反应柱3对2种污染物仍保持较高的去除率;反应介质质量比为10:2:1的反应柱4和质量比为10:1:2的反应柱5对污染物的去除效果均优于质量比为10:1:1的反应柱3;反应50 d后,添加活性炭的反应柱6对2种污染物的去除率仍在90%。这说明使用堆肥+零价铁混合可渗透反应墙修复黄土高原地下水中铬铅复合污染是可行的;且以堆肥+零价铁作为介质的反应柱去除效果优于单独以堆肥或铁粉为介质的反应柱;增加铁粉或堆肥的用量有利于铬铅复合污染的去除;且同时添加活性炭更有助于污染物的去除。

English Abstract

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