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微波-Fenton氧化-PAFSi絮凝法处理含油废水

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施国飞, 徐晓军, 贾佳, 郑鑫, 管堂珍, 陈晓鸿. 微波-Fenton氧化-PAFSi絮凝法处理含油废水[J]. 环境工程学报, 2014, 8(1): 190-197.
引用本文: 施国飞, 徐晓军, 贾佳, 郑鑫, 管堂珍, 陈晓鸿. 微波-Fenton氧化-PAFSi絮凝法处理含油废水[J]. 环境工程学报, 2014, 8(1): 190-197.
shu
Shi Guofei, Xu Xiaojun, Jia Jia, Zheng Xin, Guan Tangzhen, Chen Xiaohong. Treatment of oily wastewater by microwave-Fenton oxidation-PAFSi flocculation[J]. Chinese Journal of Environmental Engineering, 2014, 8(1): 190-197.
Citation: Shi Guofei, Xu Xiaojun, Jia Jia, Zheng Xin, Guan Tangzhen, Chen Xiaohong. Treatment of oily wastewater by microwave-Fenton oxidation-PAFSi flocculation[J]. Chinese Journal of Environmental Engineering, 2014, 8(1): 190-197.
shu

微波-Fenton氧化-PAFSi絮凝法处理含油废水

  • 1.

    昆明理工大学环境科学与工程学院, 昆明 650500

  • 2.

    浙江环科环境咨询有限公司, 杭州 310007

  • 基金项目:

    青岛市新型环保技术重点实验室项目（02-2-kj-zhj-77）

  • 中图分类号: TQ09

Treatment of oily wastewater by microwave-Fenton oxidation-PAFSi flocculation

  • 1.

    Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China

  • 2.

    Zhejiang Environmental Sciences Limited Company of Environmental Consulting, Hangzhou 310007, China

  • Fund Project:

  • 摘要: 采用微波-Fenton氧化-PAFSi絮凝法处理含油废水，结果表明，200 mL水样先经微波辐射6 min，在pH=2，H2O2（30%）3.5 g/L，Fe2+ 1.3 g/L的条件下氧化4 h后，采用聚硅酸铝铁（Al：Fe：Si=10：2：1）和聚丙烯酰胺在pH=8时进行絮凝实验，处理后废水浊度、SS、COD、含油量和色度分别降低了99.46%、96.66%、91.94%、97.97%和95.00%，且经处理后废水的BOD5/COD由原水的0.04提高到0.53。实验还分析了含油废水的降解机理。
    Abstract: The microwave-Fenton oxidation-flocculation method was investigated to treat the oily wastewater. In this study, 200 mL of wastewater was treated with microwave for 6 min, then oxidated 4 hours under the conditions of pH=2, 3.5 g/L of H2O2 (30%), 1.3 g/L of Fe2 +. Final poly aluminum silicate iron (Fe:Al:Si=10:2:1) and polyacrylamide were used in the flocculation experiment (pH=8). The results showed that the turbidity, SS, COD, oil content and chrominance of effluent decreased by 99.46%, 96.66%, 91.94%, 97.97% and 95.00%,respectively, the value of BOD5/COD changed from 0.04 to 0.53 after treatment, which indicated that the water quality was improved greatly, and the treatment effect was remarkable. The degradation mechanisms of oily wastewater were also analyzed.
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  • [1] 杨冬梅,赵县防.含油废水处理方法综述.洛阳师范学院学报,2007,26(5):104-105 Yang D.M., Zhao F.X. The method of the disposal of wastewater containing oil.Journal of Luoyang Normal University, 2007, 26(5): 104-105(in Chinese)
    [2] 侯士兵,玄雪梅,贾金平,等.含油废水处理技术的研究与应用现状.上海化工,2003,(9):11-14 Hou S.B.,Xuan X.M.,Jia J.P.,et al.Status quo of research and application of the oily wastewater treatment technology. Shanghai Chemical Industry,2003,(9):11-14
    [3] G.Chih-Ju Jou. Application of activated carbon in a microwave radiation field to treat trichloroethylene. Carbon, 1998, 36(11): 1643-1648
    [4] 鞠峰, 胡勇有. 铁屑内电解技术的强化方式及改进措施研究进展. 环境科学学报, 2011, 31(12): 2585-2594 Ju F., Hu Y.Y. Advance in enhanced patterns and improvement measures of iron inner electrolysis. Acta Scientiae Circumstantiate, 2011, 31(12): 2585-2594 (in Chinese)
    [5] 张汉铭. 内电解工艺在废水处理中的研究进展. 广东化工, 2010, 37( 9): 118-122 Zhang H. M. Development of internal-electrolysis technolo-gy for treating wastewater. Guangdong Chemical Industry, 2010, 37(9): 118-122 (in Chinese)
    [6] Lunar L.,Sicilia D. Identification of metal degradation products under Fenton reagent treatment using liquid chromatography-mass spectrometer.Water Res., 2000, 34(13):3400-3401
    [7] Lin S., Peng F. Treatment of textile wastewater by Fenton's reagent. Environ. Sci. Health, 1995, 23(30):77-283
    [8] 常青,薛锦花.絮凝沉降法处理含油废水的絮凝优化复配研究.安全与环境学报, 2006, 6(1):28-33 Chang Q., Xue J.H. Improvement on optimum composition of composition flocculant for oil wastewater treatment by flocculation-sedimentation. Journal of Safety and Environment, 2006,6(1):28-33(in Chinese)
    [9] 曹晓菊.微波和超声波在化学中的应用.实验教学与仪器,2004,12(9):18-19 Cao X. J. On chemistry application of microwave and ultrasonic. Experiment Teaching and Apparatus, 2004,12(9):18-19(in Chinese)
    [10] 孙京国,冯玉铃.微波在化学领域的研究.大学化学,2003,10(2):36-39 Sun J.G., Feng Y.L. Research of microwave in chemistry. University Chemistry, 2003, 10(2):36-39(in Chinese)
    [11] 陈胜兵.Fenton试剂的氧化作用机理及应用.环境科学与技术,2004,27(3):105-108 Chen S.B. Oxidation mechanism and application of Fenton reagent. Environmental Science and Technology, 2004, 27(3):105-108(in Chinese)
    [12] 湛含辉, 胡岳华.混凝机理及其实验研究.矿冶工程,2003,23(5):124-126 Zhan H.H., Hu Y.H. Experimental study of coagulation mechanism. Mining and Metallurgy Engineering, 2003, 23(5):124-126(in Chinese)
    [13] 孙向东,王云祥,常同胜,等.聚硅酸铝铁的性能研究.水处理技术,2001, 2(8):222-224 Sun X.D., Wang Y.X., Chang T.S., et al. Study on the flocculation performance of polysilicate aluminium ferric. Water Treatment Technology, 2001, 2(8):222-224(in Chinese)
    [14] 薛勇,蒋宝军. Fenton法在污水处理中的应用与研究进展.中国资源综合利用,2011,29(8):42-46 Xue Yong,Jiang Baojun. The research progress and application of Fenton method in sewage treatment.China Resources Comprehensive Utilization, 2011,29(8) :42-46(in Chinese)
    [15] Yoon J., Lee Y. Investigation of the reaction pathway of OH radicals produced by Fenton oxidation in the conditions of wastewater treatment. Water Sci. Technol., 2001, 44(5):15~21
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  • 收稿日期:  2012-04-01
  • 刊出日期:  2014-01-03
施国飞, 徐晓军, 贾佳, 郑鑫, 管堂珍, 陈晓鸿. 微波-Fenton氧化-PAFSi絮凝法处理含油废水[J]. 环境工程学报, 2014, 8(1): 190-197.
引用本文: 施国飞, 徐晓军, 贾佳, 郑鑫, 管堂珍, 陈晓鸿. 微波-Fenton氧化-PAFSi絮凝法处理含油废水[J]. 环境工程学报, 2014, 8(1): 190-197.
shu
Shi Guofei, Xu Xiaojun, Jia Jia, Zheng Xin, Guan Tangzhen, Chen Xiaohong. Treatment of oily wastewater by microwave-Fenton oxidation-PAFSi flocculation[J]. Chinese Journal of Environmental Engineering, 2014, 8(1): 190-197.
Citation: Shi Guofei, Xu Xiaojun, Jia Jia, Zheng Xin, Guan Tangzhen, Chen Xiaohong. Treatment of oily wastewater by microwave-Fenton oxidation-PAFSi flocculation[J]. Chinese Journal of Environmental Engineering, 2014, 8(1): 190-197.
shu

微波-Fenton氧化-PAFSi絮凝法处理含油废水

  • 1. 昆明理工大学环境科学与工程学院, 昆明 650500
  • 2. 浙江环科环境咨询有限公司, 杭州 310007
  • 收稿日期:  2012-04-01
基金项目:

青岛市新型环保技术重点实验室项目（02-2-kj-zhj-77）

摘要: 采用微波-Fenton氧化-PAFSi絮凝法处理含油废水，结果表明，200 mL水样先经微波辐射6 min，在pH=2，H2O2（30%）3.5 g/L，Fe2+ 1.3 g/L的条件下氧化4 h后，采用聚硅酸铝铁（Al：Fe：Si=10：2：1）和聚丙烯酰胺在pH=8时进行絮凝实验，处理后废水浊度、SS、COD、含油量和色度分别降低了99.46%、96.66%、91.94%、97.97%和95.00%，且经处理后废水的BOD5/COD由原水的0.04提高到0.53。实验还分析了含油废水的降解机理。

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