Al/C/Fe复合电极电絮凝法同时除氟除砷(Ⅴ)

齐学谦, 李泽唐, 周雅芳, 张旭. Al/C/Fe复合电极电絮凝法同时除氟除砷(Ⅴ)[J]. 环境工程学报, 2014, 8(2): 525-530.
引用本文: 齐学谦, 李泽唐, 周雅芳, 张旭. Al/C/Fe复合电极电絮凝法同时除氟除砷(Ⅴ)[J]. 环境工程学报, 2014, 8(2): 525-530.
Qi Xueqian, Li Zetang, Zhou Yafang, Zhang Xu. Simultaneous removal of fluoride and arsenic(Ⅴ) via Al/C/Fe combination electro-coagulation process[J]. Chinese Journal of Environmental Engineering, 2014, 8(2): 525-530.
Citation: Qi Xueqian, Li Zetang, Zhou Yafang, Zhang Xu. Simultaneous removal of fluoride and arsenic(Ⅴ) via Al/C/Fe combination electro-coagulation process[J]. Chinese Journal of Environmental Engineering, 2014, 8(2): 525-530.

Al/C/Fe复合电极电絮凝法同时除氟除砷(Ⅴ)

  • 基金项目:

    国家“水体污染控制与治理”科技重大专项(2009ZX07425-006)

    环保公益性行业科研专项(201009009-003)

  • 中图分类号: X703

Simultaneous removal of fluoride and arsenic(Ⅴ) via Al/C/Fe combination electro-coagulation process

  • Fund Project:
  • 摘要: 为了同时去除地下水中的氟和砷,提出了Al/C/Fe复合电极电絮凝法和Al/C-Fe/ C依次除氟砷法,并进行效果对比。研究了Al/C/Fe复合电极电絮凝法的影响因素,并对复合电极电絮凝产生的絮体进行了SEM-EDX分析。结果表明,Al/C/Fe复合电极电絮凝法对氟、砷的去除速率分别是Al/C-Fe/C依次除氟砷法的1.43倍和4.73倍;初始氟/砷浓度为4.0/1.0、4.0/0和0/1.0 mg/L 3种条件下,通过铝极板、铁极板的电流密度均为0.10 mA/cm2时,达到最好的除氟除砷效果,与初始氟/砷浓度无关。
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  • [1] 刘昌汉. 地方性氟中毒防治指南. 北京:人民卫生出版社. 1988
    [2] 中华人民共和国卫生部, 中国国家标准化委员会. 生活饮用水卫生标准GB5749-2006. 2006
    [3] Chakraborti D., Mohammed M. R., Paul K., et al. Arsenic calamity in the Indian subcontinent, what lessons have been learned. Talenta, 2002, 58(1): 3-22
    [4] Gomez M. L., Blarasin M. T., Martínez D. E. Arsenic and fluoride in a loess aquifer in the central area of Argentina. Environmental Geology, 2009, 57(1):143-155
    [5] 张强, 丁萍, 安永清, 等. 2005年和2006年青海省部分地区居民生活饮用水氟、砷、硒含量分析. 青海医药杂志, 2009, 39(2):63-66 Zhang Qiang, Ding Ping, An Y. Q., et al. The content analysis of fluorine, arsenic, selenium in residents living and drinking water at parts of Qinghai Province in 2005 and 2006. Qinghai Medical Journal, 2009, 39(2):63-66 (in Chinese)
    [6] 王喜宽, 黄增芳, 赵锁志, 等. 河套地区盐碱化和砷氟中毒问题探讨. 岩矿测试.2007, 26(4):328-330 Wang Xikuan, Huang Zengfang, Zhao Suozhi, et al. A preliminary study on soil salification and arseniasis-fluorosis in hetao area. Rock and Mineral Analysis, 2007, 26(4):328-330 (in Chinese)
    [7] Manuel Pi ón-Miramontes, Raúl G. Bautista-Margulis, Antonino Pérez Hernández. Removal of arsenic and fluoride from drinking water with cake alum and a polymeric anionic flocculent. Fluoride, 2003, 36(2): 122-128
    [8] 崔自敏. 铁铝复合吸附剂共除地下水中砷和氟的研究. 哈尔滨: 哈尔滨工业大学硕士学位论文, 2011 Cui Zimin, Simultaneous removal arsenate and fluoride from groundwater with coprecipitated aluminum-ironhydroxide. Harbin: Master Dissertation of Harbin Institute of Technology, 2011 (in Chinese)
    [9] L.A. Richards, B.S. Richards, H.M.A. Rossiter, et al. Impact of speciation on fluoride, arsenic and magnesium retention by nanofiltration/reverse osmosis in remote Australian communities. Desalination, 2009, 248(1-3): 177-183
    [10] Mohammad Y. A., Schenncah M. R., Paraga J. R., et al. Electrocoagulation (EC) -science and applicat ions. Journal of Hazardous Materials, 2001, B84(1): 29-41
    [11] C. Y. Hua, S. L. Loa, W. H. Kuanb.Effects of the molar ratio of hydroxide and fluoride to Al(Ⅲ) on fluoride removal by coagulation and electrocoagulation. Journal of Colloid and Interface Science, 2005, 283(2): 472-476
    [12] Jun Zhu, Huazhang Zhao, Jinren Ni. Fluoride distribution in electrocoagulation defluoridation process. Separation and Purification Technology, 2007, 56(2): 184-191
    [13] Mohammad M. E., Muttucumaru Sivakumar, Ali Safari Varyani. Analysis and the understanding of fluoride removal mechanisms by an electrocoagulation/flotation (ECF) process. Desalination, 2011, 56(1-3): 102-106
    [14] Case M. van Genuchten, Susan E. A. Addy, Jasquelin Pena, et al. Removing arsenic from synthetic groundwater with iron electrocoagulation: A Fe and As K-Edge EXAFS study. Environ. Sci. & Technol., 2012, 46 (21): 12038-12045
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出版历程
  • 收稿日期:  2013-02-09
  • 刊出日期:  2014-01-27
齐学谦, 李泽唐, 周雅芳, 张旭. Al/C/Fe复合电极电絮凝法同时除氟除砷(Ⅴ)[J]. 环境工程学报, 2014, 8(2): 525-530.
引用本文: 齐学谦, 李泽唐, 周雅芳, 张旭. Al/C/Fe复合电极电絮凝法同时除氟除砷(Ⅴ)[J]. 环境工程学报, 2014, 8(2): 525-530.
Qi Xueqian, Li Zetang, Zhou Yafang, Zhang Xu. Simultaneous removal of fluoride and arsenic(Ⅴ) via Al/C/Fe combination electro-coagulation process[J]. Chinese Journal of Environmental Engineering, 2014, 8(2): 525-530.
Citation: Qi Xueqian, Li Zetang, Zhou Yafang, Zhang Xu. Simultaneous removal of fluoride and arsenic(Ⅴ) via Al/C/Fe combination electro-coagulation process[J]. Chinese Journal of Environmental Engineering, 2014, 8(2): 525-530.

Al/C/Fe复合电极电絮凝法同时除氟除砷(Ⅴ)

  • 1. 清华大学环境学院, 北京 100084
  • 2. 铁岭天信公用事业股份有限公司, 铁岭 112000
基金项目:

国家“水体污染控制与治理”科技重大专项(2009ZX07425-006)

环保公益性行业科研专项(201009009-003)

摘要: 为了同时去除地下水中的氟和砷,提出了Al/C/Fe复合电极电絮凝法和Al/C-Fe/ C依次除氟砷法,并进行效果对比。研究了Al/C/Fe复合电极电絮凝法的影响因素,并对复合电极电絮凝产生的絮体进行了SEM-EDX分析。结果表明,Al/C/Fe复合电极电絮凝法对氟、砷的去除速率分别是Al/C-Fe/C依次除氟砷法的1.43倍和4.73倍;初始氟/砷浓度为4.0/1.0、4.0/0和0/1.0 mg/L 3种条件下,通过铝极板、铁极板的电流密度均为0.10 mA/cm2时,达到最好的除氟除砷效果,与初始氟/砷浓度无关。

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