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黄山景观区域氮、硫湿沉降来源与地球化学过程

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江用彬, 黄燕军, 金相雷, 汪晓云, 董俐香, 张海英, 黄学文, 季宏兵, 李维, 缪鹏. 黄山景观区域氮、硫湿沉降来源与地球化学过程[J]. 环境化学, 2019, (11): 2610-2618. doi: 10.7524/j.issn.0254-6108.2018122001
引用本文: 江用彬, 黄燕军, 金相雷, 汪晓云, 董俐香, 张海英, 黄学文, 季宏兵, 李维, 缪鹏. 黄山景观区域氮、硫湿沉降来源与地球化学过程[J]. 环境化学, 2019, (11): 2610-2618. doi: 10.7524/j.issn.0254-6108.2018122001
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JIANG Yongbin, HUANG Yanjun, JIN Xianglei, WANG Xiaoyun, DONG Lixiang, ZHANG Haiying, HUANG Xuewen, JI Hongbing, LI Wei, MIAO Peng. Sources and geochemical processes of nitrogen and sulfur wet deposition in mount Huangshan landscape[J]. Environmental Chemistry, 2019, (11): 2610-2618. doi: 10.7524/j.issn.0254-6108.2018122001
Citation: JIANG Yongbin, HUANG Yanjun, JIN Xianglei, WANG Xiaoyun, DONG Lixiang, ZHANG Haiying, HUANG Xuewen, JI Hongbing, LI Wei, MIAO Peng. Sources and geochemical processes of nitrogen and sulfur wet deposition in mount Huangshan landscape[J]. Environmental Chemistry, 2019, (11): 2610-2618. doi: 10.7524/j.issn.0254-6108.2018122001
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黄山景观区域氮、硫湿沉降来源与地球化学过程

  • 1. 安徽工业大学环境科学与工程系, 马鞍山, 243002;

  • 2. 生物膜法水质净化及利用技术教育部工程研究中心, 马鞍山, 243002;

  • 3. 中国科学院地球化学研究所环境地球化学国家重点实验室, 贵阳, 550081;

  • 4. 黄山风景区管理委员会, 黄山, 242700

    • 通讯作者: 江用彬, E-mail: yongbin_jiang@163.com ; 
  • 基金项目:

    安徽省自然科学基金（1608085MD82）和国家自然科学基金（41203055）资助.

Sources and geochemical processes of nitrogen and sulfur wet deposition in mount Huangshan landscape

  • 1. Department of Environment and Engineering, Anhui University of Technology, Ma'anshan, 243002, China;

  • 2. Engineering Research Center of Biomembrane Water Purification and Utilization Technology, Ma'anshan, 243002, China;

  • 3. State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, 550081, China;

  • 4. Huangshan Scenic Area Administration Committee, Huangshan, 242700, China

    • Corresponding author: JIANG Yongbin, yongbin_jiang@163.com ; 
  • Fund Project: Supported by the Natural Science Foundation of Anhui Province (1608085MD82) and the National Natural Science Foundation of China (41203055).

  • 摘要: 黄山是世界著名的地质公园，近年来该地区酸雨频率增加，威胁着景区的地质生态环境.本研究通过长期降水化学观测与氮、氧、硫同位素地球化学分析，探讨黄山景区氮、硫湿沉降来源与地球化学过程，以期揭示酸雨成因.结果表明，研究期间酸雨频率为62.5%.SO42-和NO3-为主要致酸离子.[SO42-]/[NO3-]当量比均值为1.7，主要受早期氮排放和移动源递增贡献影响.氮、氧、硫同位素组成和分异数据表明，降水中SO42-和NO3-主要来源为移动源（燃油）释放，工业源（燃煤）贡献次之，降水硝酸、硫酸的形成主要为燃油燃烧及其氧化物氧化过程.Ca2+和NH4+为酸雨的主要中和因子.我国逐渐增加的移动源化石燃料排放已经对黄山景区大气环境产生显著影响.
    Abstract: Mount Huangshan is a famous geological park in the world. Recently the acid rain has arisen with increased frequency in this area, threatening the geological and ecological environment. To reveal the cause of acid rain, the geochemical processes and sources of nitrate and sulfate wet deposition were discussed, based on precipitation chemistry characteristics together with the geochemical analysis of nitrogen, oxygen and sulfur isotopes. Results show that the acid rain frequency is 62.5% during the study period, wherein SO42- and NO3- are the major acidic anions. The average equivalent ratio of[SO42-]/[NO3-] is 1.7, suggesting the acidity of rainwater is greatly affected by NOx emissions and the increasing in vehicles. The data analyses of nitrogen, oxygen and sulfur isotopic composition and their fractionation indicate that SO42- and NO3- are mainly derived from mobile sources (burning oil), followed by industrial sources (burning coal). The fuel combustion and oxidation process of oxide are the main contributor in the appearance of nitric and sulfuric acid precipitation. Ca2+ and NH4+ are dominant neutralization factors for the acidity of rainwater. In summary, the increased fossil fuel emission from mobile sources has a significant impact on the atmospheric environment of Mount Huangshan Scenic Area.
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  • 收稿日期:  2018-12-20

黄山景观区域氮、硫湿沉降来源与地球化学过程

    通讯作者: 江用彬, E-mail: yongbin_jiang@163.com ; 
  • 1. 安徽工业大学环境科学与工程系, 马鞍山, 243002;
  • 2. 生物膜法水质净化及利用技术教育部工程研究中心, 马鞍山, 243002;
  • 3. 中国科学院地球化学研究所环境地球化学国家重点实验室, 贵阳, 550081;
  • 4. 黄山风景区管理委员会, 黄山, 242700
  • 收稿日期:  2018-12-20
基金项目:

安徽省自然科学基金（1608085MD82）和国家自然科学基金（41203055）资助.

摘要: 黄山是世界著名的地质公园，近年来该地区酸雨频率增加，威胁着景区的地质生态环境.本研究通过长期降水化学观测与氮、氧、硫同位素地球化学分析，探讨黄山景区氮、硫湿沉降来源与地球化学过程，以期揭示酸雨成因.结果表明，研究期间酸雨频率为62.5%.SO42-和NO3-为主要致酸离子.[SO42-]/[NO3-]当量比均值为1.7，主要受早期氮排放和移动源递增贡献影响.氮、氧、硫同位素组成和分异数据表明，降水中SO42-和NO3-主要来源为移动源（燃油）释放，工业源（燃煤）贡献次之，降水硝酸、硫酸的形成主要为燃油燃烧及其氧化物氧化过程.Ca2+和NH4+为酸雨的主要中和因子.我国逐渐增加的移动源化石燃料排放已经对黄山景区大气环境产生显著影响.

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