铅-镉-锌-汞稳定同位素在重金属污染源解析中的研究进展
Applications of lead-cadmium-zinc-mercury stable isotopes in source identification of heavy metal pollutions
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摘要: 随着重金属稳定同位素指纹分析中样品前处理方法、测定方法的建立与完善，以及质谱技术的飞速发展，重金属稳定同位素溯源技术研究与应用进入高速发展阶段.本文系统总结了铅-镉-锌-汞稳定同位素指纹分析在重金属污染源解析中的基本原理、优势，以及国内外利用稳定同位素指纹技术在重金属污染源定性、定量解析方面的研究进展.在此基础上，提出了今后的研究重点和方向，为农田和农作物重金属污染源解析理论、技术的研究与应用提供借鉴，推进农产品重金属污染防控措施的建立与完善，保障人体健康.Abstract: Heavy metal stable isotope traceability was increasingly applied based on the improvement of sample pretreatment and measuring technique of heavy metal stable isotopes. This review scientifically summaries the tracing principle and advantages of Pb, Cd, Zn and Hg stable isotopic fingerprinting and its applications in qualitative and quantitative analysis of heavy metal pollution sources. Besides, the focal point and direction was proposed to provide theoretical and technical reference for the pollution source identification of heavy metals in farmland and crops and promote the measurement of preventing and controlling the heavy metal pollution for ensuring human health.
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[1] WEI B G,YANG L S. A review of heavy metal contaminations in urban soils,urban road dusts and agricultural soils from China[J]. Microchemical Journal,2010,94(2):99-107. [2] WONG C S C,WU S C,DUZGOREN-AYDIN N S,et al. Trace metal contamination of sediments in an e-waste processing village in China[J]. Environmental Pollution,2007,145(2):434-442. [3] WANG Y R,WANG R M,FAN L Y,et al. Assessment of multiple exposure to chemical elements and health risks among residents near Huodehong lead-zinc mining area in Yunnan,Southwest China[J]. Chemosphere,2017,174:613-627. [4] ZHANG X W,WEI S,SUN Q Q,et al. Source identification and spatial distribution of arsenic and heavy metals in agricultural soil around Hunan industrial estate by positive matrix factorization model,principle components analysis and geo statistical analysis[J]. Ecotoxicology and Environmental Safety,2018,159:354-362. [5] TAO C,LIU X M, ZHU M Z,et al. Identification of trace element sources and associated risk assessment in vegetable soils of the urban-rural transitional area of Hangzhou, China[J]. Environmental Pollution,2008. 151(1):67-78. [6] CHEN J B,LOUVAT P,GAILLARDET J,et al. Direct separation of Zn from dilute aqueous solutions for isotope composition determination using multi-collector ICP-MS[J]. Chemical Geology,2009. 259(3/4):120-130. [7] 郭波莉,魏益民,SIMON K D,等. 稳定性氢同位素分析在牛肉产地溯源中的应用[J]. 分析化学,2009,37(9):1333-1336. GUO B L,WEI Y M,SIMON K D, et al. Application of stable hydrogen isotope analysis in beef origin traceability[J].Analytical Chemistry, 2009,37(9):1333-1336(in Chinese).
[8] 王绍清,武士奎,穆同娜,等. 扫描电镜和稳定碳同位素比质谱法鉴别马铃薯淀粉中的掺假玉米淀粉[J]. 食品科学,2010,31(22):332-335. WANG S Q,WU S K,MU T N,et al. Identification of adulterated corn starch in potato starch by scanning electron microscopy and stable carbon isotope ratio mass spectrometry[J].Food Science,2010,31(22):332-335(in Chinese).
[9] 孙境蔚,于瑞莲,胡恭任,等. 应用铅锶同位素示踪研究泉州某林地垂直剖面土壤中重金属污染及来源解析[J]. 环境科学,2017,38(4):1566-1575. SUN J W,YU R L,HU G R,et al. Using lead-strontium isotope tracer to study heavy metal pollution and source analysis in vertical profile soil of a forest land in Quanzhou[J].Environmental Science,2017,38(4):1566-1575(in Chinese).
[10] IMPERATP M,ADAMO P,NAIMO D,et al. Spatial distribution of heavy metals in urban soils of Naples City (Italy)[J]. Environmental Pollution, 2003, 124(2):247-256. [11] HU W Y, WANG H Y, DONG L R, et al. Source identification of heavy metals in peri-urban agricultural soils of southeast China:An integrated approach[J]. Environmental Pollution, 2018, 237:650-661. [12] GOWD S S, REDDY M R, GOVIL P K. Assessment of heavy metal contamination in soils at Jajmau (Kanpur) and Unnao industrial areas of the Ganga Plain, Uttar Pradesh, India[J]. Journal of Hazardous Materials, 2010, 174:113-121. [13] HERNANDEZ L, PROBST A, PROBST J L, et al. Heavy metal distribution in some French forest soils:Evidence for atmospheric contamination[J]. Science of the Total Environment, 2003, 312(1):195-219. [14] DAVIS H T, AELION C M, MCDERMOTT S, et al. Identifying natural and anthropogenic sources of metals in urban and rural soils using GIS-based data, PCA, and spatial interpolation[J]. Environmental Pollution, 2009, 157(8/9):2378-2385. [15] CHUEINTA W, HOPKE P K, PAATERO P. Investigation of sources of atmospheric aerosol at urban and suburban residential areas in Thailand by positive matrix factorization[J]. Atmospheric Environment, 2000, 34(20):3319-3329. [16] 包贞, 冯银厂, 焦荔,等.杭州市大气PM2.5和PM10污染特征及来源解析[J]. 中国环境监测, 2010, 26(2):44-48. BAO Z, FENG Y C,JIAO L,et al. Pollution characteristics and source analysis of PM2.5 and PM10 in Hangzhou[J].Environmental Monitoring in China,2010, 26(2):44-48(in Chinese).
[17] ZHANG M, SALMON L G, SCHAUER J J, et al. Seasonal trends in PM2.5 source contributions in Beijing, China[J]. Atmospheric Environment, 2005, 39(22):3967-3976. [18] 田福林, 陈景文, 敖江婷. 受体模型应用于典型持久性有毒物质的来源解析研究进展[J]. 环境化学, 2009, 28(3):319-327. TIAN F L,CHEN J W,AO J T. Research progress of receptor model applied to source analysis of typical persistent toxic substances[J].Environmental Chemistry, 2009, 28(3):319-327(in Chinese).
[19] PANDEY B, AGRAWAL M, SINGH S. Ecological risk assessment of soil contamination by trace elements around coal mining area[J]. Journal of Soils and Sediments, 2016, 16(1):159-168. [20] SONG Y, XIE S, ZHANG Y, et al. Source apportionment of PM2.5 in Beijing using principal component analysis/absolute principal component scores and UNMIX[J]. Science of the Total Environment, 2006, 372(1):278-286. [21] 蒲雅丽,涂耀仁,游镇烽,等. Pb-Zn同位素在沉积物重金属污染源解析方面的应用:综述与展望[J]. 环境化学,2017,36(3):581-590. PU Y L,TU Y R,YOU Z F,et al. Application of Pb-Zn isotopes in source analysis of heavy metals in sediments:Review and prospect[J]. Environmental Chemistry,2017,36(3):581-590(in Chinese).
[22] 曹亚澄,张金波,温腾,等.稳定同位素示踪技术与质谱分析:在土壤、生态、环境研究中的应用[M].北京:科学出版社,2018:6-10. CAO Y C,ZHANG J B,WEN T,et al. Stable isotope tracer technology and mass spectrometry:Applications in soil,ecology and environmental studies[M]. Beijing:Science Press,2018:6 -10(in Chinese).
[23] 赵多勇, 郭波莉, 魏益民, 等. 重金属污染源解析研究进展[J]. 安全与环境学报, 2011, 11(4):98-103. ZHAO D Y,GUO B L,WEI Y M,et al. Advances in heavy metal pollution source analysis[J]. Journal of Safety and Environment, 2011, 11(4):98-103.
[24] 何琼,李向阳. 铅同位素地球化学示踪进展[J]. 地质找矿论丛,1998(3):79-82. HE Q,LI X Y. Advances in lead isotope geochemical tracing[J]. Geological Prospecting Theory Cluster,1998 (3):79-82(in Chinese).
[25] 朱赖民,张海生,陈立奇. 铅稳定同位素在示踪环境污染中的应用[J]. 环境科学研究,2002,15(1):27-30. ZHU L M,ZHANG H S,CHEN L Q. Application of lead stable isotopes in tracing environmental pollution[J].Environmental Science Research,2002,15(1):27-30(in Chinese).
[26] DE LAETER J R, HEUMANN K G,ROSMAN K J R.et al. Isotopic compositions of the elements, 2001[J]. Journal of Physical and Chemical Reference Data, 1991, 20(6):1327-1337. [27] SHIEL A E,WEIS D,ORIANS K J. Evaluation of zinc,cadmium and lead isotope fractionation during smelting and refining[J]. Science of the Total Environment,2010,408(11):2357-2368. [28] ZHOU L L,YANG B,XUE N D,et al. Ecological risks and potential sources of heavy metals in agricultural soils from Huanghuai Plain,China[J]. Environmental Science and Pollution Research International,2014,21(2):1360-1369. [29] MARECHAL C N. Precise analysis of copper and zinc isotopic compositions by plasma-source mass spectrometry[J]. Chemical Geology,1999,156:251-273. [30] 戴前进, 冯新斌, 唐桂萍. 土壤汞的地球化学行为及其污染的防治对策[J]. 地球与环境, 2002, 30(4):75-79. DAI Q J,FENG X B,TANG G P. Geochemical behavior of soil mercury and its pollution control strategies[J].Earth and Environment, 2002, 30(4):75-79(in Chinese).
[31] KLAUE B,KESLER S E,BLUM J D. Investigation of natural fractionation of stable mercury isotopes by multicollector inductively coupled plasma mass spectormetry[C]//Proceedings of the Annual International Conferenceon Heavy Metals in the Environment 2000,University of Michigan:1101. [32] SONKE J E, BLUM J D. Advances in mercury stable isotope biogeochemistry[J]. Chemical Geology, 2013, 336:1-4. [33] PHILLIPS D. Mixing models in analyses of diet using multiple stable isotopes:A critique[J]. Oecologia,2001,127(2):166-170. [34] PHILLIPS D L,GREGG J W. Source partitioning using stable isotopes:Coping with too many sources[J]. Oecologia (Berlin),2003,136(2):261-269. [35] PHILLIPS D L,NEWSOME S D,GREGG J W. Combining sources in stable isotope mixing models:alternative methods[J]. Oecologia,2005,144(4):520-527. [36] PARNELL A C, INGER R, BEARHOP S, et al. Source partitioning using stable isotopes:coping with too much variation[J]. Plos One, 2010, 5(3):e9672. [37] XUE D, BAETS B D, CLEEMPUT O V, et al. Use of a Bayesian isotope mixing model to estimate proportional contributions of multiple nitrate sources in surface water[J]. Environmental Pollution, 2012, 161:43-49. [38] SIMONETTI A,GARIEPY C,CARIGNAN J. Tracing sources of atmospheric pollution in Western Canada using the Pb isotopic composition and heavy metal abundances of epiphytic lichens[J]. Atmospheric Environment,2003,37(20):2853-2865. [39] CLOQUET C,CARIGNAN J,LIBOUREL G. Isotopic composition of Zn and Pb atmospheric depositions in an Urban/Periurban Area of Northeastern France[J]. Environmental Science & Technology,2006,40(21):6594-6600. [40] CLOQUET C,CARIGNAN J,LIBOUREL G,et al. Tracing source pollution in soils using cadmium and lead isotopes[J]. Environmental Science & Technology,2006,40(8):2525-2530. [41] ZHANG H,YIN R S,FENG X B,et al. Atmospheric mercury inputs in montane soils increase with elevation:Evidence from mercury isotope signatures[J]. Scientific Reports,2013,3(1):809-822. [42] LUCK J M,OTHMAN D B,ALBAREDE F,et al. Pb,Zn and Cu isotopic variations and trace elements in rain[C]//Geochemistry of the Earths Surface International Symposium, 1999:199-203. [43] THAPALIA A,DAVID M B,PETER C V M,et al. Zn and Cu isotopes as tracers of anthropogenic contamination in a sediment core from an Urban Lake[J]. Environmental Science & Technology,2010,44(5):1544-1550. [44] GAO B,ZHOU H,LIANG X,et al. Cd isotopes as a potential source tracer of metal pollution in river sediments[J]. Environmental Pollution,2013,181(Complete):340-343. [45] YIN R,FENG X,CHEN B,et al. Identifying the sources and processes of mercury in subtropical estuarine and ocean sediments using Hg isotopic composition[J]. Environmental Science & Technology,2015,49(3):1347-1355. [46] BI X Y,FENG X B,YANG Y G,et al. Allocation and source attribution of lead and cadmium in maize (Zea mays L.) impacted by smelting emissions[J]. Environmental Pollution,2009,157(3):834-839. [47] WIGGENHAUSER M,BIGALKE M,IMSENG M,et al.,Using isotopes to trace freshly applied cadmium through mineral phosphorus fertilization in soil-fertilizer-plant systems[J]. Science of the Total Environment,2019,648:779-786. [48] FENG L,ZHANG G L, TAN M G, et al. Lead in children's blood is mainly caused by coal-fired ash after phasing out of leaded gasoline in Shanghai[J]. Environmental Science & Technology,2010,44(12):4760-4765. [49] BREWER P A,BIRD G,MACKLIN M G,Isotopic provenancing of Pb in Mitrovica,northern Kosovo:Source identification of chronic Pb enrichment in soils,house dust and scalp hair[J]. Applied Geochemistry,2016,64:164-175. [50] VINCENT P,VLADIMIR N E,MIKHAIL V P,et al. Tracing sources and bioaccumulation of mercury in fish of Lake Baikal- Angara River using Hg isotopic composition[J]. Environmental Science & Technology,2010. 44(21):8030-8037. [51] LI H B,YU S,LI G L,et al. Contamination and source differentiation of Pb in park soils along an urban-rural gradient in Shanghai[J]. Environmental Pollution,2011,159(12):3536-3544. [52] LUO X S,XUE Y,WANG Y L,et al. Source identification and apportionment of heavy metals in urban soil profiles[J]. Chemosphere,2015,127:152-157. [53] SALMANZADEH M,HARTLAND A,STIRLING C H, et al. Isotope tracing of long-term cadmium fluxes in an agricultural soil[J]. Environmental Science & Technology,2017,51(3):7369-7377. [54] 李霞,张慧鸣,徐震,等. 农田Cd和Hg污染的来源解析与风险评价研究[J]. 农业环境科学学报,2016,35(7):1314-1320. LI X,ZHANG H M,XU Z,et al. Source analysis and risk assessment of Cd and Hg pollution in farmland[J].Journal of Agricultural Environmental Sciences,2016,35(7):1314-1320(in Chinese).
[55] HAN L F,GAO B,WEI X,et al.The characteristic of Pb isotopic compositions in different chemical fractions in sediments from Three Gorges Reservoir,China[J]. Environmental Pollution,2015,206:627-635. [56] FOUCHER D,OGRINC N,HINTELMANN H. Tracing mercury contamination from the idrija mining region (slovenia) to the gulf of trieste using hg isotope ratio measurements[J]. Environmental Science & Technology,2009,43(1):33-39. [57] CHEN J B,JEROME GAILLARDET,PASCALE L,et al. Zn isotopes in the suspended load of the Seine River,France:Isotopic variations and source determination[J]. Geochimica Et Cosmochimica Acta,2009,73(14):4060-4076. [58] 赵多勇,魏益民,魏帅,等. 小麦籽粒铅污染来源的同位素解析研究[J]. 农业工程学报,2012,28(8):258-262. ZHAO D Y,WEI Y M,WEI S,et al. Isotope analysis of lead pollution sources in wheat grain[J].Journal of Agricultural Engineering,2012,28(8):258-262(in Chinese).
[59] LIU J,WANG D Q,SONG B, et al. Source apportionment of Pb in a rice-soil system using field monitoring and isotope composition analysis[J]. Journal of Geochemical Exploration, 2019, 204:83-89. [60] GEAGEA M L,STILLE P,GAUTHIER-LAFAYE F,et al. Tracing of industrial aerosol sources in an urban environment using Pb,Sr,and Nd Isotopes[J]. Environmental Science & Technology,2008,42(3):692-698. [61] CHENG H F,HU Y N. Lead (Pb) isotopic fingerprinting and its applications in lead pollution studies in China:A review[J]. Environmental Pollution,2010,158(5):1134-1146. [62] 陈好寿,裴辉东,张霄宇. 杭州市区土壤铅、锶同位素示踪研究[J]. 浙江国土资源,1999(1):43-48. CHEN H S,PEI H D,ZHANG X Y. Isotopic tracing of lead and strontium in soil of Hangzhou City[J].Land and Resources of Zhejiang Province,1999 (1):43-48(in Chinese).
[63] SHIEL A E,WEIS D,COSSA D,et al. Determining provenance of marine metal pollution in French bivalves using Cd,Zn and Pb isotopes[J]. Geochimica et Cosmochimica Acta,2013,121:155-167. [64] WEN H J,ZHANG Y X,CHRISTOPHE C,et al.Tracing sources of pollution in soils from the Jinding Pb-Zn mining district in China using cadmium and lead isotopes[J]. Applied Geochemistry,2015,52(3):147-154. [65] HUANG Y, LI T, WU C, et al. An integrated approach to assess heavy metal source apportionment in peri-urban agricultural soils[J]. Journal of Hazardous Materials, 2015, 299:540-549. [66] LIN C Q,YU R L,HU G R,et al. Contamination and isotopic composition of Pb and Sr in offshore surface sediments from Jiulong River,Southeast China[J]. Environmental Pollution,2016,218:644-650. -
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