固相萃取小柱净化-气相色谱法测定土壤和沉积物中有机氯和拟除虫菊酯农药残留

谢湘云; 沈爱斯; 叶江雷; 弓振斌

环境化学

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谢湘云, 沈爱斯, 叶江雷, 弓振斌. 固相萃取小柱净化-气相色谱法测定土壤和沉积物中有机氯和拟除虫菊酯农药残留[J]. 环境化学, 2006, 25(3): 347-350.

引用本文:

谢湘云, 沈爱斯, 叶江雷, 弓振斌. 固相萃取小柱净化-气相色谱法测定土壤和沉积物中有机氯和拟除虫菊酯农药残留[J]. 环境化学, 2006, 25(3): 347-350.

XIE Xiang-yun, SHEN Ai-si, YE Jiang-lei, GONG Zhen-bin. DETERMINATION OF ORGANOCHLORINE AND PYRETHROID PESTICIDE RESIDUES IN SOLID AND SEDIMENT BY CAPILLARY GAS CHROMATOGRAPHY WITH SOLID-PHASE-EXTRACTION PURIFICATION[J]. Environmental Chemistry, 2006, 25(3): 347-350.

Citation:

固相萃取小柱净化-气相色谱法测定土壤和沉积物中有机氯和拟除虫菊酯农药残留

1.
厦门大学近海海洋环境科学国家重点实验室, 厦门, 361005;
2.
厦门大学海洋与环境学院, 厦门, 361005

DETERMINATION OF ORGANOCHLORINE AND PYRETHROID PESTICIDE RESIDUES IN SOLID AND SEDIMENT BY CAPILLARY GAS CHROMATOGRAPHY WITH SOLID-PHASE-EXTRACTION PURIFICATION

1.
State Key Laboratory of Marine Environmental Science, Xiamen University, Xiamen, 361005, China;
2.
College of Oceanography and Environmental Science, Xiamen University, Xiamen, 361005, China

摘要: 建立了毛细管气相色谱法测定土壤和沉积物中α-六六六,β-六六六,γ-六六六,δ-六六六,硫丹,p,p'-DDE,p,p'-DDD,o,p'-DDT,p,p'-DDT,三氯杀螨醇,甲氰菊酯,氯氰菊酯,联苯菊酯,氟氯氰菊酯,氰戊菊酯,溴氰菊酯等16种农药残留量的方法.16种农药的残留组分在25min内能很好分离.标准加入回收率在81.2%-111.9%之间;方法变异系数2.9%-14.9%(0.01-0.1μg·ml-1,n= 6),检出下限在0.08-0.44μg·kg-1之间.
- 土壤 /
- 沉积物 /
- 有机氯 /
- 拟除虫菊酯 /
- 气相色谱 /
- 固相萃取
Abstract: A quantitative method has been developed for measurement of α-BHC,β-BHC,γ-BHC,δ-BHC,(endosulfan),o,p'-DDT,p,p'-DDT,p,p'-DDD,p,p'-DDE,dicofol,cypermethrin,eyfluthrin,bifenthrin,fenpropathin,fenvalerate,deltamethrinin in soil and sediment samples.The recoveries for stan-(dard) spiked sediment sample were in the range of 81.2%—111.9%.The RSDs were 2.9%—14.9%(0.01—0.1μg·ml-1,n= 6) and the detection limits were 0.08—0.44μg·kg-1(dry matter).
- soil /
- sediment /
- pesticide residues /
- gas chromatography /
- solid phase extraction /

[1]

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固相萃取小柱净化-气相色谱法测定土壤和沉积物中有机氯和拟除虫菊酯农药残留

1. 厦门大学近海海洋环境科学国家重点实验室, 厦门, 361005;
2. 厦门大学海洋与环境学院, 厦门, 361005

关键词:

摘要: 建立了毛细管气相色谱法测定土壤和沉积物中α-六六六,β-六六六,γ-六六六,δ-六六六,硫丹,p,p'-DDE,p,p'-DDD,o,p'-DDT,p,p'-DDT,三氯杀螨醇,甲氰菊酯,氯氰菊酯,联苯菊酯,氟氯氰菊酯,氰戊菊酯,溴氰菊酯等16种农药残留量的方法.16种农药的残留组分在25min内能很好分离.标准加入回收率在81.2%-111.9%之间;方法变异系数2.9%-14.9%(0.01-0.1μg·ml-1,n= 6),检出下限在0.08-0.44μg·kg-1之间.

English Abstract

DETERMINATION OF ORGANOCHLORINE AND PYRETHROID PESTICIDE RESIDUES IN SOLID AND SEDIMENT BY CAPILLARY GAS CHROMATOGRAPHY WITH SOLID-PHASE-EXTRACTION PURIFICATION

1. State Key Laboratory of Marine Environmental Science, Xiamen University, Xiamen, 361005, China;
2. College of Oceanography and Environmental Science, Xiamen University, Xiamen, 361005, China

Keywords:

Abstract: A quantitative method has been developed for measurement of α-BHC,β-BHC,γ-BHC,δ-BHC,(endosulfan),o,p'-DDT,p,p'-DDT,p,p'-DDD,p,p'-DDE,dicofol,cypermethrin,eyfluthrin,bifenthrin,fenpropathin,fenvalerate,deltamethrinin in soil and sediment samples.The recoveries for stan-(dard) spiked sediment sample were in the range of 81.2%—111.9%.The RSDs were 2.9%—14.9%(0.01—0.1μg·ml-1,n= 6) and the detection limits were 0.08—0.44μg·kg-1(dry matter).

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固相萃取小柱净化-气相色谱法测定土壤和沉积物中有机氯和拟除虫菊酯农药残留

DETERMINATION OF ORGANOCHLORINE AND PYRETHROID PESTICIDE RESIDUES IN SOLID AND SEDIMENT BY CAPILLARY GAS CHROMATOGRAPHY WITH SOLID-PHASE-EXTRACTION PURIFICATION

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固相萃取小柱净化-气相色谱法测定土壤和沉积物中有机氯和拟除虫菊酯农药残留

English Abstract

DETERMINATION OF ORGANOCHLORINE AND PYRETHROID PESTICIDE RESIDUES IN SOLID AND SEDIMENT BY CAPILLARY GAS CHROMATOGRAPHY WITH SOLID-PHASE-EXTRACTION PURIFICATION

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