十一镍锆钼杂多酸盐的合成、表征及超声强化降解染料废水

张治宏; 薛峰

环境化学

张治宏, 薛峰. 十一镍锆钼杂多酸盐的合成、表征及超声强化降解染料废水[J]. 环境化学, 2012, 31(5): 677-681.

引用本文:

张治宏, 薛峰. 十一镍锆钼杂多酸盐的合成、表征及超声强化降解染料废水[J]. 环境化学, 2012, 31(5): 677-681.

ZHANG Zhihong, XUE Feng. Synthesis, characterization of 11-NiZrMo heteropoly salt and its ultrasonic degradation of dyeing wastewater[J]. Environmental Chemistry, 2012, 31(5): 677-681.

Citation:

ZHANG Zhihong, XUE Feng. Synthesis, characterization of 11-NiZrMo heteropoly salt and its ultrasonic degradation of dyeing wastewater[J]. Environmental Chemistry, 2012, 31(5): 677-681.

十一镍锆钼杂多酸盐的合成、表征及超声强化降解染料废水

张治宏¹,
薛峰²

1.
西安工业大学材料与化工学院, 西安, 710032;
2.
总后勤部建筑工程研究所, 西安, 710032
基金项目:
西安工业大学校基金项目(XAGDXJJ0911)资助.

Synthesis, characterization of 11-NiZrMo heteropoly salt and its ultrasonic degradation of dyeing wastewater

ZHANG Zhihong¹,
XUE Feng²

1.
School of Materials and Chemical Engineering, Xi'an Technological University, Xi'an, 710032, China;
2.
Architecture Engineering Institute, the General Logistic Department of P.L.A, Xi'an, 710032, China
Fund Project:

摘要: 采用水溶液合成法制备了具有Keggin型结构的十一镍锆钼杂多酸盐Na6·20H2O(NiZrMo),并对其进行表征及分析.元素分析表明,镍锆钼之间的物质的量之比满足1:1:11的关系;热重/差热分析说明合成的杂多酸盐具有比较好的热稳定性并带有20个结晶水;红外光谱、X射线衍射及紫外光谱表征充分表明合成的杂多酸盐其阴离子仍保持Keggin型结构;扫描电镜分析表明,具有比较好的大分子化合物的基本特征和比较规则的晶体结构.以NiZrMo杂多酸盐为催化剂降解酸性绿B(AGB)染料废水,降解率最高可达95.72%.
- 杂多酸盐 /
- Keggin结构 /
- 超声降解
Abstract: The heteropoly salt, Na6�20H2O(NiZrMo)with Keggin structure of the 1:1:11series, was synthesized by the aqueous solution method, and characterized and analyzed. The elemental analysis showed that the molar ratio of Ni,Zr and Mo was accord with 1:1:11. The thermogravimetric analysis/differential thermal analysis(TG/DTA) indicated that the NiZrMo had good thermostability and it contained twenty molecules of crystallization water. The characterization by Fourier transform infrared spectroscopy(IR),X-ray powder diffraction analysis(XRD) and the ultraviolet spectrum(UV) showed that the anionic of the NiZrMo heteropoly salt possessed Keggin structure. The analysis of scanning electron microscopy(SEM) showed that it had the basic feature of the macromolecular compound and a regular crystal. The NiZrMo heteropoly salt was used as the catalyst to degrade the acidid-green B(AGB) dyeing wastewater enhanced by the ultrasonic, and the degradation rate could reached 95.72%.
- heteropoly salt /
- Keggin structure /
- ultrasonic degradation

[1]	Cavani F, Mezzogori R, Pigamo A, et al. Combined effects of Sb-doping and of perparation via lacunary persursor for P/Mo-based, Keggin-type polyoxometalates, catalyses for the selective oxidation of isobutene to methacylic acid[J]. Topics in Catalysis, 2003,23:119-124
[2]	施介华,胡玉华,李祥,等.硅胶负载磷钨酸铯(Cs_2.5H_0.5P₁₂W₄₀)催化合成2-乙酰噻吩的研究[J].高等化学工程学报,2008,22(1):128-133
[3]
[4]	张韩鹏,张小明,索继栓,等.固载型杂多酸的合成与表征及催化异丙醇气相脱水反应的活性[J].精细石油化工,2002,1:19-22
[5]	Vesna K, Maja S, Ivanka H, et al. Synthesis, characterization, and biological activity of amino acid derivatives of the heteropolytungstophosphoric acid[J]. Monatsfte fui Chemie,2006,137:803-810
[6]	梁彦秋,邓斌,刘婷婷,等.杂多酸盐K₇·6H₂O与牛血清蛋白相互作用的研究[J].无机化学学报,2007,23(4):688-692
[7]	Antonaraki S, Androulaki E, Dimotikali D, et al. Photolytic degradation of all chlorophenos with polyoxometalates and H₂O₂[J].J Photochem, Photobioa. A:Chemistry,2002,148(1/3):191-197
[8]	杨曦,余刚,孔令仁,等.酸性红3B的杂多酸光催化降解动力学[J].环境科学,2002,23(3):40-43
[9]
[10]	罗茜,简敏,张进,等.硅钼钒和硅钨钒杂多酸的制备及其在苯直接羟基化酯苯酚中的活性研究[J].化学研究与进展,2006,18(6):629-633
[11]	马荣华,王福平.十一钨镍硅酸盐甘氨酸超分子化合物的合成及性质研究[J].化学试剂,2006,28(11):641-644
[12]	张艳红,钟顺和. SiO₂负载H₆PMo₉V₂NbO₄₀杂多酸的制备与表征[J].分子催化,2005,19(4):246-250

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张治宏, 薛峰. 十一镍锆钼杂多酸盐的合成、表征及超声强化降解染料废水[J]. 环境化学, 2012, 31(5): 677-681.

引用本文:

张治宏, 薛峰. 十一镍锆钼杂多酸盐的合成、表征及超声强化降解染料废水[J]. 环境化学, 2012, 31(5): 677-681.

ZHANG Zhihong, XUE Feng. Synthesis, characterization of 11-NiZrMo heteropoly salt and its ultrasonic degradation of dyeing wastewater[J]. Environmental Chemistry, 2012, 31(5): 677-681.

Citation:

ZHANG Zhihong, XUE Feng. Synthesis, characterization of 11-NiZrMo heteropoly salt and its ultrasonic degradation of dyeing wastewater[J]. Environmental Chemistry, 2012, 31(5): 677-681.

十一镍锆钼杂多酸盐的合成、表征及超声强化降解染料废水

张治宏¹,
薛峰²

1. 西安工业大学材料与化工学院, 西安, 710032;
2. 总后勤部建筑工程研究所, 西安, 710032

收稿日期: 2011-09-21

基金项目:

西安工业大学校基金项目(XAGDXJJ0911)资助.

关键词:

摘要: 采用水溶液合成法制备了具有Keggin型结构的十一镍锆钼杂多酸盐Na6·20H2O(NiZrMo),并对其进行表征及分析.元素分析表明,镍锆钼之间的物质的量之比满足1:1:11的关系;热重/差热分析说明合成的杂多酸盐具有比较好的热稳定性并带有20个结晶水;红外光谱、X射线衍射及紫外光谱表征充分表明合成的杂多酸盐其阴离子仍保持Keggin型结构;扫描电镜分析表明,具有比较好的大分子化合物的基本特征和比较规则的晶体结构.以NiZrMo杂多酸盐为催化剂降解酸性绿B(AGB)染料废水,降解率最高可达95.72%.

English Abstract

Synthesis, characterization of 11-NiZrMo heteropoly salt and its ultrasonic degradation of dyeing wastewater

ZHANG Zhihong¹,
XUE Feng²

1. School of Materials and Chemical Engineering, Xi'an Technological University, Xi'an, 710032, China;
2. Architecture Engineering Institute, the General Logistic Department of P.L.A, Xi'an, 710032, China

Received Date: 2011-09-21

Fund Project:

Keywords:

Abstract: The heteropoly salt, Na6�20H2O(NiZrMo)with Keggin structure of the 1:1:11series, was synthesized by the aqueous solution method, and characterized and analyzed. The elemental analysis showed that the molar ratio of Ni,Zr and Mo was accord with 1:1:11. The thermogravimetric analysis/differential thermal analysis(TG/DTA) indicated that the NiZrMo had good thermostability and it contained twenty molecules of crystallization water. The characterization by Fourier transform infrared spectroscopy(IR),X-ray powder diffraction analysis(XRD) and the ultraviolet spectrum(UV) showed that the anionic of the NiZrMo heteropoly salt possessed Keggin structure. The analysis of scanning electron microscopy(SEM) showed that it had the basic feature of the macromolecular compound and a regular crystal. The NiZrMo heteropoly salt was used as the catalyst to degrade the acidid-green B(AGB) dyeing wastewater enhanced by the ultrasonic, and the degradation rate could reached 95.72%.

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十一镍锆钼杂多酸盐的合成、表征及超声强化降解染料废水

Synthesis, characterization of 11-NiZrMo heteropoly salt and its ultrasonic degradation of dyeing wastewater

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十一镍锆钼杂多酸盐的合成、表征及超声强化降解染料废水

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Synthesis, characterization of 11-NiZrMo heteropoly salt and its ultrasonic degradation of dyeing wastewater

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