湘江下游沉积物重金属污染模糊评价
Assessment of heavy metal pollution using the fuzzy function normalization method for sediments of the lowermost Xiangjiang River
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摘要: 对湘江下游株洲、湘潭和长沙段河床沉积物进行沉积柱取样,利用ICP-MS等技术手段分析沉积物重金属含量.建立随机模拟与三角模糊数的理论耦合模型,修正地累积指数评价的修正系数K值,再利用改进的地累积指数法评价沉积物重金属污染程度.结果表明,湘江株洲段河床沉积物中Pb、Zn为极强污染,Cu为强烈污染;湘潭段和长沙段Zn、Pb、Cu为中度污染.Mn在各河段河床沉积物中分布较均匀,为中度污染,并有向偏重度污染发展的趋势.而Sc、V、Cr、Co、Ni等重金属在河床沉积物中为轻度污染.湘江下游河床沉积物的主要重金属污染因子为Mn、Cu、Pb和Zn,治理湘江下游河床沉积物重金属污染应主要针对这几种重金属.Abstract: Sediment core samples were collected at Zhuzhou, Xiangtan, and Changsha sections of the lowermost Xiangjiang River, and concentrations of heavy metals and Al2O3 in the sediments were analyzed using ICP-MS and XRF techniques respectively, in this study. Then heavy metal contamination of the sediments was evaluated using the Geo-accumulation index (Igeo) after it's coefficient K value was corrected using a theoretical coupling model that is established on the base of stochastic simulation and triangular fuzzy number. The results show that sediments in river section of the Zhuzhou city were extremely contaminated by Pb and Zn, and heavily contaminated by Cu. Sediments distributed in river sections of the Xiangtan and Changsha cities were moderately contaminated by Cu, Pb and Zn. Sediments of all the river sections were moderately contaminated by Mn, which displays similar distribution pattern in all the sediments of the river, and slightly contaminated by Sc, V, Cr, Co, and Ni. It is concluded that major contamination factors for the lowermost Xiangjiang River include Mn, Cu, Pb and Zn. Thus, we should pay more attention to these heavy metals in the management of heavy-metal contamination in the sediments of the lowermost river.
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Key words:
- Xiangjiang downstream /
- sediment /
- heavy metals /
- index of geoaeeumulation /
- stochastic simulation
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[1] 童霆.河口三角洲元素含量与矿产资源——以湘资沅澧为例[J]. 第四纪研究,2005,25(3):298-305. TONG T. Element concentrations in river delta sediments and mineral resources potential in the drainage basin: A Case Study in the Xiangjiang, Zishui, Yuanjiang, and Lishui Rivers Basins[J]. Quaternary Sciences, 2005, 25(3): 298-305(in Chinese).
[2] QIAN Y, ZHEN M H, GAO L, et al. Heavy metal contamination and its environment risk assessment in surface sediments from Lake Donating,people's republic of China[J]. Environmental Contamination and Toxicology, 2005, 75(1): 204-210. [3] 郭朝晖,肖细元,陈同斌,等.湘江中下游农田土壤和蔬菜的重金属污染[J]. 地理学报,2008,63(1):3-11. GUO Z H, XIAO X Y, CHEN T B, et al. Heavy metal pollution of soils and vegetables from midstream and downstream of Xiangjiang River[J]. Acta Geographica Sinica, 2008, 63(1): 3-11(in Chinese).
[4] 张立成,董文江,郑建勋,等.湘江河流沉积物重金属的形态类型及其形成因素[J]. 地理学报,1983,38(1):55-64. ZHANG L C, DONG W J, ZHENG J X, et al. The metal form and form factors of heavy metals in the Xiangjiang River sediments[J]. Acta Geographica Sinica, 1983, 38(3): 54-64(in Chinese).
[5] 毛美洲,刘子慧,魏金玺.湘江表层底泥中重金属化学形态的研究[J]. 环境科学,1981,2(5):35-41. MAO M Z,LIU Z H,WEI J X. A study on chemical forms of metals in sediments of the Xiangjiang River[J]. Enviroment Science, 1981, 2(5): 35-41(in Chinese).
[6] PENG B, TANG X Y, YU C X, et al. Geochemistry of trace metals and Pb isotopes of sediments from the lowermost Xiangjiang River, Hunan Province (China): Implications on sources of trace metals[J]. Environmental Earth Sciences, 2011, 64(5), 1455-1473. [7] 彭渤,唐晓燕,余昌训,等.湘江入湖河段沉积物重金属污染及其Pb同位素地球化学示踪[J]. 地质学报,2011,85(2):282-299. PENG B,TANG X Y,YU C X, et al. Heavy metal contamination of inlet sediments of the Xiangjiang River and Pb isotopic geochemical implication[J]. Acta Geologica Sinica, 2011, 85(2): 282-299(in Chinese).
[8] SUN G X, WANG X J,HU Q H. Using stable lead isotopes to trace heavy metal contamination sources in sediments of Xiangjiang and Lishui Rivers in China[J]. Environmental Pollution, 2011, 159(12), 3406-3410. [9] 曾北危,潘佑民,黄璋.湘江沉积物污染初步评价[J]. 环境化学,1982,1(5):352-358. ZENG B W, PAN Y M, HUANG Z. Preliminary eviluation on contamination extent for sediments of the Xiangjiang River[J]. Enviroment Chemistry, 1982, 1(5): 352-358(in Chinese).
[10] 姚志刚,鲍征宇,高璞.洞庭湖沉积物重金属环境地球化学[J]. 地球化学,2006,35(6):629-638. YAO Z G, BAO Z Y,GAO P. Environmental geochemistry of heavy metals in sediments of Dongting Lake[J]. Geochimica, 2006. 35(6): 629-638(in Chinese).
[11] [12] 王晨,曾祥英,于志强,等.湘江衡阳段沉积物中铊等重金属的污染特征及其生态风险评估[J]. 生态毒理学报,2013,8(1):16-22. WANG C, ZENG X Y, YU Z Q, et al. Distribution and risk assessment of thallium and other metals in sediments from iangjiang River Hengyang Section[J]. Asian Journal of Ecotoxicology, 2013, 8(1): 16-22(in Chinese).
[13] 鲍志诚,彭渤,徐婧喆,等.湘江入湖河段沉积物主元素组成对重金属污染的指示[J]. 地球化学,2012,41(6):545-558. BAO Z C, PENG B, XU J Z, et al. Geochemical study on the relation of chemical compositions to heavy metal contamination of sediments from the lowermost Xiangjiang River,Hunan Province,China[J]. Geochimica, 2012, 41(6): 545-558(in Chinese).
[14] 智国铮,陈耀宁,袁兴中,等.基于随机模拟与三角模糊数耦合的重金属污染评价模型[J]. 环境科学学报,2014,34(2):488-495. ZHI G Z, CHEN Y N, YUAN X Z, et al. Heavy metal pollution assessment model of river sediment by coupling stochastic simulation with triangular fuzzy numbers[J]. Acta Scientiae Circumstantiae, 2014, 34(2): 488-495(in Chinese).
[15] 李如忠.基于不确定信息的城市水源水环境健康风险评价[J]. 水利学报,2007,38(8):895-900. LI R Z. Assessment for health risk on water environment and water supply source of urban areas based on uncertain information[J]. Journal of Hydraulic Engineering, 2007, 38(8): 895-900(in Chinese).
[16] Muniz P, Danulat E, Yannicelli B, et al. Assessment of contamination by heavy metals and petroleum hydrocarbons in sediment of Montevideo Harbour (Uruguary)[J]. Environmental International, 2004, 29(8): 1019-1028. [17] 樊梦佳,袁兴中,祝慧娜,等.基于三角模糊数的河流沉积物中重金属污染评价模型[J]. 环境科学学报,2010,30(8):1700-1706. FAN M J, YUAN X Z, ZHU H N, et al. A ssessment model for heavy metal pollution in river sediment based on triangular fuzzy numbers[J]. Acta Scientiae Circumstantiae, 2010, 30(8): 1700- 1706(in Chinese).
[18] 李飞,黄瑾辉,李雪,等.基于随机模糊理论的土壤重金属潜在生态风险评价及溯源分析[J]. 环境科学学报,2015,35(4):1233-1240. LI F, HUANG J H, LI X, et al. Potential ecological risk assessment based on stochastic-fuzzy simulation for soils and pollution source identification[J]. Acta Scientiae Circumstantiae, 2015, 35(4): 1233-1240(in Chinese).
[19] 张立成,章申,董文江,等.湘江干流水体元素背景值的初步研究[J]. 地理研究,1984,3(1):87-95. ZHANG L C, ZHANG S, DONG W J, et al. Studies on the background value of some elements in the Xiangjiang River[J]. Geographical Research, 1984, 3(1): 87-95(in Chinese).
[20] 潘佑民,杨国治.湖南土壤背景值及研究方法[M].北京:中国环境科学出版社,1988:338. PAN Y M, YANG G Z. Research method and background values of Hunan's soil[M]. Beijing:Chinese Envirorunental Science Press,1988: 338(in Chinese). [21] 王东坡,陈宗团,汪碧华.湘江株州至洞庭湖口江段现代沉积速率研究[J]. 长春地质学院学报,1987,17(1):29-34. WANG D P, CHEN Z T, WANG B H. Research on modern sediment attention of Xiangjiang River in the reach between Zhuzhou and the mouth of lake Dong-ting, Hunan Province[J]. Journal of Changchun college of Geology, 1987, 17(1): 29-34(in Chinese).
[22] 刘颖,刘海臣,李献华.用ICP-MS准确测定岩石样品中的40余种微量元素[J]. 地球化学,1996,25(6):552-558. LIU Y, LIU H C, LI X H. Simultaneous and precise determination of 40 trace elements in rock samples using ICP-MS[J]. Geochimica, 1996, 25(6): 552-558(in Chinese).
[23] Muller G. Index of geoaccumulation in sediments of the Rhine River[J]. Geojournal, 1969, 2(3): 108-118. [24] 李健,曾北危,姚岳云,等.洞庭湖水系水体环境背景值调查研究[J]. 环境科学,1986,7(4):62-68 ,104. LI J, ZENG B W,YAO Y Y, et al. Research background value in system of the water in Dongting Lake[J]. Environmental Science, 1986, 7(4): 62-68,104(in Chinese).
[25] 钱杏珍,李岫霞.洞庭湖水系沉积物的地球化学背景值[J]. 科学通报,1988,33(6):458-462. QIAN X Z, LI X X. Geochemical background values of elements in sediments of the Dongting Lake watershed[J]. Chinese Science Bulletin, 1988, 33(6): 458-462(in Chinese).
[26] 刘汉元,李远鄂.湘江流域若干重金属元素在岩石、残坡积物及水中的背景值研究[J]. 环境科学学报,1984,4(1):17-32. LIU H Y, LI Y E. Background values of some metals in rocks,soil and water in Xiangjiang basin[J]. Acta Scientiae Circumstantiae, 1984, 4(1): 17-32(in Chinese).
[27] 国家环保总局. 中国土壤元素背景值[M].北京:中国环境科学出版社,1990. CEPA. Elemental background values of soil in China[M]. Beijing:China Environmental Science Press, 1990(in Chinese). [28] 鲍志诚.湘江株洲-湘潭河段河床沉积物主量元素地球化学特征[D].长沙:湖南师范大学硕士学位论文,2013. BAO Z C. Geo chemical Characteristics of major element sin bed sediments from the Zhuzhou-Xiangtan section Xiangjiang River[D]. Changsha: The Master Degree Dissertation of Hunan Normal University,2013(in Chinese). [29] 赵桂久,张立成,章申. 湘江水系铁锰背景值及其形成因素的研究[J]. 地理科学,1987,7(2):179-185 ,98. ZHAO G J, ZHANG L C, ZHANG S, et al. A study on background values of Fe and Mn and their formation factors in the Xiangjiang Rivers system[J]. Scientia Geographica Sinica, 1987,7(2):179-185,98(in Chinese).
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